TUGAS (3)

THERMODINAMIKA

Oleh
Waleed Nour Eldien (NRP: 2306 201 701)
Abas Sato (NRP: 2307 201 005)
I Wavan Susila (NRP: 2306 301 201)

DOSEN:
Dr.Ir. Kuswandi .DEA

JURUSAN TEKNIK KIMIA

INSTITUT TEKNOLOGI SEPULUH NOPEMBER
SURABAYA
2007
 ‫بسم ا الرحمن الرحيم‬

Diketahui
Campuran liquid yang terdiri dari etanol (1)/benzene (2)/methylcyclopentana (3)
x1 = 0.047 , x2 =0.107 , x3 = 0.846 , P =1.013bar
Ditanya :
T , y1 ,y2 ,y3
Data known

Komponen x1 r q
i j a ij, K a ji, K
1 0.047 2.11 1.97
1 2 -128.9 997.4
2 0.107 3.19 2.4
1 3 -118.3 1384
3 0.846 3.97 3.01
2 3 -6.47 56.47

Persamaan - persamaan yang applied

z
li   ri  qi    ri  1 ; z  10
2
qi xi rx  aij   a ji 
i  ; i  i i ;  ij  exp   ; τ ji  exp  
qjxj j
 rj x j j
 T   T 

Asumsi Awal applies rumus :

B B
Ti sat   C  273.15 , log10 Pi sat  A 
A  log10 P T  C  273.15

A B C Ti sat log 10 Pis Pis

5.3368 1648.2200 230.9180 351.4004 -0.0866 0.8193

3.9852 1184.2400 217.5720 353.1541 -0.0904 0.8121

4.1820 1295.5430 238.3900 344.9671 0.0214 1.0505

T   X iTi sat , T = x1 T1sat + x2 T2sat + x3 T3sat = 346.145

Prediction T =346.145k
i j a ij, K a ji, K  ij  ji i i li
1 2 -128.9 997.4 1.4512 0.0561 0.0320 0.0261 -0.4100

1 3 -118.3 1384 1.4074 0.0183 0.0887 0.0898 1.7600

2 3 -6.47 56.47 1.0189 0.8495 0.8793 0.8841 1.8300

(1)  
j
j ji  1 11   2 21   3 31
= 0.0531
( 2)   j
j ji  1 12   2 22   3 32
= 0.8821
(3)   j
j ji  1 13   2 23   3 33
  j ij  1 11 = 1.0147  2 12  3 13
(1)    
j   k kj  1 11   2 21   3 31  1 12   2 22   3 32  1 13   2 23   3 33
+ + = 1.9680
k 0.6024 0.1459 1.2197
=
 j ij  1 21  2 22  3 23
(2)    
j   k kj  1 11   2 21   3 31  1 12   2 22   3 32  1 13   2 23   3 33
k = 0.033766 + 0.100536 + 0.88296 = 1.0173
 j ij  1 31  2 32  3 33
(3)    
j   k kj  1 11   2 21   3 31  1 12   2 22   3 32  1 13   2 23   3 33
0.085402 + 0.86661 = 0.9631
k = 0.011052 +

ln  1  ln  iC  ln  iR
i z  
ln  iC  ln  qi ln i  li  i
xi 2 i xi
x l j
j j

 
    j ij 
ln  R
 qi 1  ln   j ji   
j   k kj
i  
  j  
k

 i / xi ln  i / xi ln  i /  i xi. l i
0.5554 -0.5881 0.2028 -0.0193

0.8397 -0.1747 -0.0131 0.1883

1.0450 0.0440 -0.0053 1.5482

= 1.7172
xj
j lj

ln  i C
ln  i R
ln  i  i
0.0461 3.8770 3.9231 50.5590

-0.0134 0.2598 0.2464 1.2794

-0.0008 0.0673 0.0665 1.0687

Data-data yang required:

Pc
Komponen Tc, K (bar) Zc Vc (cm3.ml-1) ω Tr

1 513.9 61.48 0.24 167 0.645 0.674

2 562.2 48.98 0.271 259 0.21 0.616

3 532.8 37.85 0.272 319 0.23 0.650

3
 Vc 13  Vc 13  Zci  Zc j Zcij .RTc ij i   j
Vcij   
i j
Zcij  Pcij  ij 
 2  2 Vcij 2
 
Tc ij  Tc i .Tc j  2 1  kij  dimana kij  0
1 T
Tr  R = 83.14
Tc
0,172 RTc ij
B1  0,139  Bij  ( B 0  ij B1 ) 0,422
Tr 4, 2 Pcij B 0  0,083 
Tr 1, 6
 i j Vc ij Tc ij Zc ij Pc ij ω ij Tr Bo B1 B ij

1 1 167.000 513.900 0.240 61.402 0.645 0.674 -0.711 -0.765 -838.339

1 2 209.648 537.508 0.256 54.462 0.428 0.644 -0.770 -0.953 -966.405

1 3 234.865 523.265 0.256 47.419 0.438 0.662 -0.734 -0.837 -1009.596

2 2 259.000 562.200 0.271 48.907 0.210 0.616 -0.834 -1.180 -1033.768

2 3 287.959 547.303 0.272 42.902 0.220 0.632 -0.795 -1.039 -1086.026

3 3 319.000 532.800 0.272 37.770 0.230 0.650 -0.758 -0.913 -1135.847

BM  y12 B11  y22 B22  y32 B33  2 y1 y2 B12  2 y1 y3 B13  2 y2 y3=

B23
-950.193
3
P
ln  i  (2 y j Bij  BM )
j 1 RT
P
ln  i   2 y1 Bi1  y2 Bi 2  y3 Bi 3   BM 
RT
P
ln 1   2 y1 B11  y2 B12  y3 B13   BM 
RT
P
ln  2   2 y1 B21  y2 B22  y3 B23   BM 
RT
P
ln  3   2 y1 B31  y2 B32  y3 B33   BM 
RT

Pjsat = P = P
 [( xii)/Φi](Pisat/Pjsat ) (x1 1 )(P1sat/P1sat) +( (x2 2 )(P2sat/P1sat) +((x3 3 ) (P3sat/P1sat )

P1sat =0.276
Tlama =346.15 , Tbaru =321.78K
xi i Pi s
yi 
P

T, K Pis Φ1 yi
346.145 0.9586
0.276 0.647
0.9511
0.274 0.037
0.354 0.9470 0.316
∑=
1.000