BAB 4 HASIL DAN PEMBAHASAN

4.1 Hasil

1. Tabel Standar Adisi

Larutan A B C D E
Volume sampel 0,5 mL 0,5 mL 0,5 mL 0,5 mL 0,5 mL
Standar 11,03 ppm 0 mL 0,5 mL 1,0 mL 1,5 mL 2,0 mL
KSCN qs qs qs qs qs
Aquades 5 mL 5 mL 5 mL 5 mL 5 mL
Diukur pada panjang gelombang maksimum standar (460 nm)
Konsentrasi larutan A : 0
Konsentrasi larutan B :

V1 x N1 = V2 x N2
0,5 mL x 11,03 ppm = 5 mL x N2
0,5 𝑚𝐿 𝑥 11,03 𝑝𝑝𝑚
N2 = 5 𝑚𝐿

= 1,103 ppm
Konsentrasi larutan C :
V1 x N1 = V2 x N2
1,0 mL x 11,03 ppm = 5 mL x N2
1,0 𝑚𝐿 𝑥 11,03 𝑝𝑝𝑚
N2 = 5 𝑚𝐿

= 2,206 ppm
Konsentrasi larutan D :

V1 x N1 = V2 x N2
1,5 mL x 11,03 ppm = 5 mL x N2
1,5 𝑚𝐿 𝑥 11,03 𝑝𝑝𝑚
N2 = 5 𝑚𝐿

= 3,309 ppm

Konsentrasi larutan E :
V1 x N1 = V2 x N2
2,0 mL x 11,03 ppm = 5 mL x N2
 2,0 𝑚𝐿 𝑥 11,03 𝑝𝑝𝑚
N2 = 5 𝑚𝐿

= 4,412 ppm
2. Tabel Kurva Baku
Konsentrasi PCT (ppm) 𝜆 maks (nm) Absorbansi
0 460 0,431
1,103 460 0,572
2,206 460 0,637
3,309 460 0,712
4,412 460 0,834

Absorbansi
0.9
y = 0.0858x + 0.448
0.8 R² = 0.9824
0.7
0.6
0.5
Absorbansi
0.4
Linear (Absorbansi)
0.3
0.2
0.1
0
0 1 2 3 4 5

Gambar 4.1.2 Kurva Baku 𝛌 460 nm

𝛼 .𝐶𝑠 0,448 𝑥 11,03 4,941
Cx = 𝛽 .𝑉𝑥 = 0,085 𝑥 0,005 = 0,0004285 = 11.530

Perhitungan :
CAVIPLEX TABLET
(Fe-fumarat = 135 mg)
Diketahui :
BM Fe-fumarat = 169,9013 g/mol
BM Fe = 55,874 g/mol
 Berat rata-rata = 1,284 g = 1284 mg
Berat etiket = 135 mg/tablet
Berat yg ditimbang = 10 mg

Ditanyakan :
Berat Fe = .......?
mol Fe = mol Fe-fumarat
𝐵𝑒𝑟𝑎𝑡 𝐹𝑒 𝐵𝑒𝑟𝑎𝑡 𝐹𝑒−𝑓𝑢𝑚𝑎𝑟𝑎𝑡
=
𝐵𝑀 𝐹𝑒 𝐵𝑀 𝐹𝑒−𝑓𝑢𝑚𝑎𝑟𝑎𝑡
𝐵𝑒𝑟𝑎𝑡 𝐹𝑒 10 𝑚𝑔
=
55,874 𝑔/𝑚𝑜𝑙 169,9013 𝑔/𝑚𝑜𝑙
55,874 𝑔/𝑚𝑜𝑙 𝑥 10 𝑚𝑔
Berat Fe = = 3,287 mg
169,9013 𝑔/𝑚𝑜𝑙

𝐶𝑥 𝑥 𝑉 𝑠𝑎𝑚𝑝𝑒𝑙 𝑥 𝑓𝑝
% kadar besi = x 100%
𝑏𝑒𝑟𝑎𝑡 𝑠𝑎𝑚𝑝𝑒𝑙
11.530 𝑚𝑔/𝐿 𝑥 0,005 𝐿 𝑥 1
= x 100%
3,287 𝑚𝑔

= 1.753,87 %