EXAMPLE 8.

32

Diketahui:
E, XiE pada T = 45 o
C = 318.15 K
Komponen n (mol)
Acetonitril (1) 0.4873
F, zi Benzene (2) 0.1564
n-heptane (3) 0.3563
Total 1
R, XiR
Ditanyakan : a. Komposisi fase ekstrak (X )
E

b. Komposisi fase raffinat (XR)

c. Fraksi feed yang terekstrak (α)
Penyelesaian:
1. Menentukan nilai α,ɣinE,ɣinR �=∑_�^3▒((�_�−1)
�_�)/((�_�−1)𝛼+1)
2. Menghitung nilai Ki,FE,XiE,XiR,
Trial α 0.48
Komponen Fi Zi ɣ iE ɣ iR Ki F XiE XiR
1 0.4873 0.4873 2 3 1.5000 0.1965 0.5895 0.3930
2 0.1564 0.1564 2 1 0.5000 -0.1029 0.1029 0.2058
3 0.3563 0.3563 6 1 0.1667 -0.4949 0.0990 0.5938
∑ 1 1 -0.4013 0.7913 1.1926

3. Menghitung ɣin+1E, ɣin+1R (Menghitung koefisien aktivitas menggunakan model UNIQUAC)

Pure Component Parameters
Komponen r q z
1 1.87 1.72 10
2 3.19 2.4
3 5.17 4.4
�_�𝑗=exp(−𝑎_�𝑗/𝑇) �_𝑗�=exp(−𝑎_𝑗�/𝑇)

komponen i = j maka aij = aji = 1

aij, K aji, K Ʈij,K Ʈji,K
i j
1 2 60.28 89.57 0.8274 0.7546
1 3 23.71 545.8 0.9282 0.1799
2 3 -135.9 245.4 1.5329 0.4624

�_�=(𝑟_1 𝑥_1)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3 𝑥_3 ); �_�=(𝑟_2 𝑥_2)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3

𝑥_3 );�_�=(𝑟_3 𝑥_3)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3 𝑥_3 )
�_�=(𝑞_1 𝑥_1)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3 𝑥_3 );�_�=(𝑞_2 𝑥_2)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3
𝑥_3 );�_�=(𝑞_3 𝑥_3)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3 𝑥_3 )
�_�=�/2 (𝑟_1−𝑞_1 )−(𝑟_1−1); �_�=�/2 (𝑟_2−𝑞_2 )−(𝑟_2−1);�_�=�/2 (𝑟_3−𝑞_3 )−
(𝑟_3−1)
�=��

���_�=𝑙𝑛 𝜙_1/𝑥_1 +�/2 𝑞_1 𝑙𝑛 𝜃_1/𝜙_1 +𝑙_1−𝜙_1/𝑥_1 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_1 ln(𝜃_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+𝑞_1−𝑞_1
((𝜃_1 �_11)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_12)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_13)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))

���_�=𝑙𝑛 𝜙_2/𝑥_2 +�/2 𝑞_2 𝑙𝑛 𝜃_2/𝜙_2 +𝑙_2−𝜙_2/𝑥_2 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_2 ln(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 )+𝑞_2−𝑞_2
((𝜃_1 �_21)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_22)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_23)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))

���_�=𝑙𝑛 𝜙_3/𝑥_3 +�/2 𝑞_3 𝑙𝑛 𝜃_3/𝜙_3 +𝑙_3−𝜙_3/𝑥_3 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_3 ln(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 )+𝑞_3−𝑞_3
((𝜃_1 �_31)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_32)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_33)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))
Koefisien aktivitas fase ekstrak ɣiE
Komponen XiE ɸi θi
li ln ɣiR ln ɣiC ln ɣiE ɣiE
1 0.5895 0.5676 0.5977 -0.12 0.5044 0.211513 0.7159 2.0461
2 0.1029 0.1690 0.1456 1.76 1.1835 0.336861 1.5203 4.5737
3 0.0990 0.2635 0.2567 -0.32 2.0954 -0.11999 1.9754 7.2093
0.7913

Koefisien aktivitas fase ekstrak ɣiR

Komponen XiR ɸi θi
li ln ɣiR ln ɣiC ln ɣiR ɣiR
1 0.3930 0.1647 0.1787 -0.12 1.0786 -0.34166 0.7369 2.0895
2 0.2058 0.1471 0.1306 1.76 1.1162 -0.09897 1.0173 2.7656
3 0.5938 0.6881 0.6907 -0.32 0.3595 -0.23446 0.1250 1.1332
1.1926
 EXAMPLE 8.32

Diketahui:
E, XiE pada T = 45 o
C = 318.15 K
Komponen n (mol)
Acetonitril (1) 0.4873
F, zi Benzene (2) 0.1564
n-heptane (3) 0.3563
Total 1
R, XiR
Ditanyakan : a. Komposisi fase ekstrak (X )
E

b. Komposisi fase raffinat (XR)

c. Fraksi feed yang terekstrak (α)
Penyelesaian:
1. Menentukan nilai α,ɣinE,ɣinR
2. Menghitung nilai Ki,FE,XiE,XiR,
Trial α 0.49
Komponen Fi Zi ɣ iE ɣ iR Ki FE XiE XiR
1 0.4873 0.4873 1 3.5 3.5000 0.7665 0.7665 0.2190
2 0.1564 0.1564 1.5 1.0 0.6667 0.1246 0.1246 0.1869
3 0.3563 0.3563 6 1.0 0.1667 0.1004 0.1004 0.6022
∑ 1 1 0.9915 0.9915 1.0081

3. Menghitung ɣin+1E, ɣin+1R (Menghitung koefisien aktivitas menggunakan model UNIQUAC)

Pure Component Parameters
Komponen r q z
1 1.87 1.72 10
2 3.19 2.4
3 5.17 4.4
�_�𝑗=exp(−𝑎_�𝑗/𝑇) �_𝑗�=exp(−𝑎_𝑗�/𝑇)

komponen i = j maka aij = aji = 1

aij, K aji, K Ʈij,K Ʈji,K
i j
1 2 60.28 89.57 0.8274 0.7546
1 3 23.71 545.8 0.9282 0.1799
2 3 -135.9 245.4 1.5329 0.4624

�_�=(𝑟_1 𝑥_1)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3 𝑥_3 ); �_�=(𝑟_2 𝑥_2)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3

𝑥_3 );�_�=(𝑟_3 𝑥_3)/(𝑟_1 𝑥_1+𝑟_2 𝑥_2+𝑟_3 𝑥_3 )
�_�=(𝑞_1 𝑥_1)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3 𝑥_3 );�_�=(𝑞_2 𝑥_2)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3
𝑥_3 );�_�=(𝑞_3 𝑥_3)/(𝑞_1 𝑥_1+𝑞_2 𝑥_2+𝑞_3 𝑥_3 )
�_�=�/2 (𝑟_1−𝑞_1 )−(𝑟_1−1); �_�=�/2 (𝑟_2−𝑞_2 )−(𝑟_2−1);�_�=�/2 (𝑟_3−𝑞_3 )−
(𝑟_3−1)
�=��

���_�=𝑙𝑛 𝜙_1/𝑥_1 +�/2 𝑞_1 𝑙𝑛 𝜃_1/𝜙_1 +𝑙_1−𝜙_1/𝑥_1 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_1 ln(𝜃_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+𝑞_1−𝑞_1 ((𝜃_1
�_11)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_12)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_13)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))

���_�=𝑙𝑛 𝜙_2/𝑥_2 +�/2 𝑞_2 𝑙𝑛 𝜃_2/𝜙_2 +𝑙_2−𝜙_2/𝑥_2 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_2 ln(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 )+𝑞_2−𝑞_2 ((𝜃_1
�_21)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_22)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_23)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))

���_�=𝑙𝑛 𝜙_3/𝑥_3 +�/2 𝑞_3 𝑙𝑛 𝜃_3/𝜙_3 +𝑙_3−𝜙_3/𝑥_3 (𝑥_1 𝑙_1+𝑥_2 𝑙_2+𝑥_3 𝑙_3 )−𝑞_3 ln(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 )+𝑞_3−𝑞_3 ((𝜃_1
�_31)/(𝜗_1 �_11+𝜃_2 �_21+𝜃_3 �_31 )+(𝜃_2 �_32)/(𝜃_1 �_12+𝜃_2 �_22+𝜃_3 �_32 ) + (𝜃_3 �_33)/(𝜃_1 �_13+𝜃_2 �_23+𝜃_3 �_33 ))
Koefisien aktivitas fase ekstrak ɣiE
Komponen XiE ɸi θi
li ln ɣiE ln ɣiC ln ɣiE ɣiE
1 0.7665 0.6100 0.6403 -0.12 0.2252 -0.007534 0.2177 1.2432
2 0.1246 0.1692 0.1453 1.76 0.9479 0.1065264 1.0545 2.8704
3 0.1004 0.2208 0.2145 -0.32 2.0030 -0.383497 1.6195 5.0508
0.9915

Koefisien aktivitas fase ekstrak ɣiR

Komponen XiR ɸi θi
li ln ɣiR ln ɣiC ln ɣiE ɣiR
1 0.2190 0.0994 0.1084 -0.12 1.5416 -0.216157 1.3255 3.7640
2 0.1869 0.1448 0.1291 1.76 1.3959 0.0453611 1.4413 4.2262
3 0.6022 0.7558 0.7625 -0.32 0.2881 -0.037251 0.2508 1.2851
1.0081

Cara Mensolver
1. Set Objective ∑FE to value of: 1
2. By changing variables cell : α,ɣinE,ɣinR
3. Subject to the constraints: ɣinE = ɣin+1E, ɣinR = ɣin+1R