Solutions TO Test-Ii

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SOLUTIONS
TO
TEST- II
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(Solutions)
PHYSICS
SECTION – I
SINGLE CORRECT CHOICE TYPE
m
1. VOLUME OF BALL V =
ρ
ACCELERATION OF BALL INSIDE THE LIQUID
F upthrust− weight
a = net =
m m
v=0
g H
h
a
om
m
 ( 3ρ)( g) − mg
ρ
OR a =
c
= 2G (UPWARDS)
m
∴ VELOCITY OF BALL WHILE REACHING AT SURFACE
g.
ng
v = 2ah = 4gh
∴ THE BALL WILL JUMP TO A HEIGHT
ye
v 2 4gh
H= = = 2h
2g 2g
.m
∴ (C)
2. Maximum heat is released when block reaches till point A. v 02 = 2 µgl , v 0 = 2µgl
w
∴ (b)
w
3. Loss in potential energy = gain in kinetic energy

w
1  ML2  2 12 2Q
QL 3 2 =  ω ; ω =
://
2  2 
 ML
tp
iˆ ˆj kˆ
r r r
τ = p × E = QL ( )
0 0 = kˆ − ˆj 3QL
ht
0 3 3
kˆ − jˆ
∴ unit vector along the direction of ω is
2
⇒
r
ω=
6 2Q ˆ ˆ
ML
k− j ( )
∴ (b)
4. BY CONSERVATION OF ENERGY
k
FOR x < 0, ω = ,
m
m
FOR HALF OSCILLATION, T1 = π
k
FOR X>0 a = −g
East Delhi : PH.: 22792226-29, West Delhi : PH.: 25527515-18, North Delhi : PH.: 25221424- 25, South Delhi : PH.: 26537392-95, Dwarka : PH.: 25086117-18, FAX: 26537396
v max 2E
t2 =
=
g mg 2
TIME PERIOD IS T1 + 2t 2
∴ (C)
5. − Tdt = MRω − M 2 gR
2MR 2 ω
(T dt)R = ⇒ ω=
g
2 2R
∴ (b)
mu
6. N dt = + mu , − µN dt = mv '− mv ,
2
3m
−µ 2 gh = m( v' −v) , v − v ' = 0. 3 2 gh
2
om
∴ (c)
SECTION − II
c
One or more than one type
r
LET AT ANY INSTANT, THE VELOCITY IS v .
g.
7.
r r r
v = v x iˆ + v y jˆ AND F = q v × B
r
( )
ng
r
a = v x x ˆj − v y x iˆ ALSO v x + v y = v 2
2 2
dv y dv y
ye
ay = =vy = vx x
dt dy
.m
∴ v x dv x = −v y dv y …(I)
dv y
= vx x
w
vy …(II)
dy
w
dvx
vx = −v y x …(III)
w
dx
x2 x4
://
FROM (I), (II) & (III) v y = AND v x2 = v 2 −

2 4
tp
v
ALSO, vx =
2
ht
v 3
∴ a= AND B = 0
2
1/2
WHEN VX = 0, X = (2V)
∴ (B, C)
1  mR 2 mR 2  2 3
8. K.E. =  +  ω = mv 2
2  2 4  8
 mR 2 mR 2  3
ANGULAR MOMENTUM =  +  ω = mR 2 ω

 2 4  4
∴ (A, C)
9. (A, B, C, D)
10. φNET = 0
φCROSSING = E 2RL
→ l
E
A A 
φ crossing = E  1 sin θ + A2 cos θ + 3 sin θ 
 2 2 
 πR 2 πR 2 
= E  sin θ + 2Rl cos θ + sin θ 
 2 2 
A1
r A2
E
θ
om
A3
(
φ crossing = E πR 2 sin θ + 2Rl cos θ )
c
g.
A1
θ
(A1/2)sinθ
ng
ye
A3 θ A2 cosθ
θ A2
.m
(A3/2)sinθ
w
∴ (A, B, C)
SECTION− III
w
Reasoning type
w
11. (D)
12. (A)
://
13. (A)
14. (A)
tp
SECTION− IV
Comprehension Type
ht
PASSAGE – I
dN A
= −( 3λ ) N A ⇒ N A = N 0 e −3λ t ;
dt
dN B1 N B1 1
= −2λN B1 + λ N A ⇒ =
dt NA 2
ALSO,
dN B2 N B2
= −λ N B2 + 2λ N A ⇒ =2
dt NA
15. (B)
16. (C)
17. (D)
PASSAGE-II
18. As the process in cylinder A is adiabatic
PVγ = constant
Initial pressure in A, P0 = 105 N/m2
Initial volume in A, V0 = 10-2 m2
Final volume in A = V0 /4 = 25 × 10–4
Let final pressure is A = P1
1.5
V 
= P1  0  ; P1 = 8P0
1.5
P0V0
 4 
For equilibrium of pistons (let pressure in cylinder B finally = P2 )
P1S
P2(2S)
P1 = 2P2 ∴ P2 = 4P0
m
For gas in cylinder A, P0V0 = RT 0 … (i)
M
5 m'
For gas in cylinder B, P2 × V0 = RT 0 … (ii)
2 M
m ' = 10m = 1 kg
om
∴ (d)
V0
8P0 × − P2V 0
P V − P1V1 4
19. ∆u = 2 2 =
c
r −1 1. 5 − 1
g.
∆ u = 2P0V0 = 2000 J
∴ (a)
ng
20. F = 8P0 S = 8000 N
∴ (C)
ye
PASSAGE-III
.m
APPLYING KIRCHOFF’S LAW IN A LOOP pp' Qxyp

3
+I R + I 1 r = 12
w
…(1)
4
w
APPLYING KIRCHOFF’S LAW IN A LOOP QxypQ' Q

R
w
− I1 r + (I − I1 ) = 0 …(2)
4
://
3
SOLVING (1) AND (2) WE GET I 1 R + 4I 1 r = 12
4
tp
SINCE r >> R ∴ 4 I1r = 12 ; I 1 r = 3V

ht
I P’
I Q’
I–I 1
Q I I1
1
x V y
SIMILARLY IN THE SECOND CASE WHEN VOLTMETER IS CONNECTED AS IN FIGURE (2)
READING OF VOLTMETER IS 9V.
21. (c)
22. (b)
23. (b)
(Solutions)
CHEMISTRY
SECTION – I
24. (B) INITIALLY THE PH WILL INCREASE SLOWLY DUE TO NEUTRALISATION OF WEAK ACID
BY NAOH. AFTER THE END POINT IS REACHED, PH WILL INCREASE RAPIDLY DUE TO
ADDITION OF NAOH.
25. (b)
26. (c)
27. (c) H3A H + + H 2 A − ; Ka 1
om
H2A− H + + HA 2− ; Ka 2
HA 2− H + + A3− ; Ka 3
c
At second equivalence point, the only species present in appreciable concentration is HA 2− .
pH =
pKa 2 + pK a 3 8 + 12
= = 10
g.
ng
2 2
[ ]
H + = 10 −10
[H ]
ye
[H 3A] = + 3
= 10 − 7
and
[A ]
3− Ka 1 × Ka 2 × Ka 3
.m
3P
w
28. (b) U1 =
d1
w
∆ U RMS =
3
(P − P1 )
w
2
d
://
= 3 (300 − 200)
0.75
tp
= 4 × 100 = 200 m/s

ht
29. (c) (A) is Lunar caustic i.e. AgNO3

∆
2AgNO3 (A) → 2NO2 (B) + O2 (C) + 2Ag(D)
AgNO3 (A) + KCN → AgCN + KNO3
(white ppt.)
AgCN + KCN → K[Ag(CN)2 ]

(Soluble complex
Potassium argentocyanide)
SECTION − II
More than one type
30. (a, c, d)
O O O O
S S OH, S S OH,
HO O O HO O
O O O O
O
O
S O O
HO O OH, Cr
O O O
31. (a, c, d)
C + O2 → CO + CO2
t=0 0.1 – –
t=t 0 x (0.1 – x)
5CO + I2 O5 → 5CO2 + I2
t=0 x – –
t=t 0 x x/5
om
1 1
Moles of I2 liberated = moles of hypo consumed = × 120 × 10–3 × 0.1 = 60 × 10–4
2 2
So, x = 5 × 60 × 10–4 = 0.03
c
Percentage of C converted to CO is 30% .
Moles of CO2 left = [0.1 – x]1st reaction + [x]IInd reaction

g.
ng
= [0.1 – 0.03] + [0.03] = 0.1
ye
CO2 + H2 O → H2 CO3
0.1 0.1
.m
H2 CO3 + Ca(OH)2 → CaCO3 + 2H2 O

0.1 0.1
w
32. (a, b, c)
w
Since, product is an alcohol, so compound (A) is a 10 aliphatic amine.

w
33. (c, d)
://
Le Chatelier’s principle is not quantitative. If both the stresses are caused in the same direction, the shift is
determinable. If both the stresses are caused in the opposite direction, the shift is undeterminable.
tp
SECTION− III
ht
Reasoning type
34. (c)
35. (a) The conductivity due to free electrons is more than due to charged ions.
36. (b)
37. (a) 0 n 1 
→ 1 p1 + −1 e 0 (β-particle). β-particle emission occurs when n/p ratio is higher than 1.6.
SECTION− IV
Comprehension Type
PASSAGE – I
THE REQUIRED REACTIONS OCCURING AT THE ELECTRODES ARE
+ –
CATHODE: 2H + 2E → H2
2+ –
CU + 2E → CU
– –
ANODE: 2OH → ½ O2 + H2O + 2E
38. (B) THE MOLAR VOLUME OF A GAS AT 1 ATM AND 273 K IS 22.4 L/MOLE. SINCE, THE
3
VOLUME OF H2 COLLECTED AT 0.1 ATM AND 273 K IS 2.024 CM , SO THE VOLUME OF H2
3
COLLECTED AT 1 ATM AND 273 K (STP CONDITIONS) WOULD HAVE BEEN 0.2024 CM .
0. 2024 –6
∴ n H2 = = 9.04 × 10
22400
Q – 4.305 –5
39. (D) TOTAL MOLES OF E RELEASED AT ANODE = = = 4.46 × 10
F 96500
4.305 1
MOLES OF O2 LIBERATED AT ANODE = ×
96500 4
4.305 22400
× × 10 = 2.5 CM .
3
VOLUME OF O2 LIBERATED AT 0.1 ATM AND 273 K =
96500 4
– + –6 –5
40. (C) MOLES OF E USED FOR THE REDUCTION OF H = 2 × 9.0 × 10 = 1.80 × 10 .
– 2+ –5 –5 –5
MOLES OF E USED FOR THE REDUCTION OF CU = 4.46 × 10 – 1.80 × 10 = 2.66 × 10 .
2. 66 × 10 −5 –5
MOLES OF CU DEPOSITED AT CATHODE = = 1.33 × 10
2
–5 23
NUMBER OF ATOMS OF CU DEPOSITED AT CATHODE = 1.33 × 10 × 6.023 × 10
18
= 8.0 × 10
om
1 
NUMBER OF PT ATOMS ON THE EXPOSED FACE OF A UNIT CELL = 1 +  × 4  = 2
4 
2
c
1  1 −16
AREA OF THE FACE OF A UNIT CELL = A =  × 10 −8  = × 10
2 2
CM
g.
2  4
NUMBER OF PT ATOMS ON THE EXPOSED SURFACE AREA OF THE EL ECTRODE OF 1
ng
2 2 16
CM = = 8 × 10 ATOMS.
1
× 10 −16
ye
4
CU LAYER WILL BE DEPOSITED OVER THE PT LAYER, SO THE NUMBER OF CU ATOMS
.m
16
DEPOSITED ON THE EXPOSED FACE OF THE ELECTRODE IN A MONOLAYER = 8 × 10
ATOMS.
w
8 × 1018
NUM BER OF MONOLAYERS OF CU DEPOSITED =
w
8 × 1016
w
= 100.
://
PASSAGE-II
OH OC 2 H5 OC 2H5 OC 2H5 OC 2H5
41. (c)
tp
NaOH H2 /Ni NaNO2 /HCl C6H 5OH

C2 H5Br 0–5°C
ht
NO2 NO2 NH2 N2 Cl N=N OH

(X) (Y) (Z)
OC2 H5 NH2
42. (d) and
NH2 OH
(W) (R)
OC2H5 OH
43. (a) and
NHCOCH3 NHCOCH3
(P) (Q)
PASSAGE-III
44. (b) Since, it liberates a gas on reaction with dilute H2 SO4 , it cannot be a sulphate salt, it would be a carbonate
salt. Malachite ore of copper, CuCO3 . Cu(OH)2 is green in colour.
45. (c)
[Cu (NH3 )4 ]2+ + 2KCN → Cu (CN )2 ↓ + 2K + + 4NH 3
Blue colour Yellow ppt
2Cu (CN )2 ↓   
→ 2CuCN ↓ + (CN )2 ↑
decomposes
White ppt
CuCN ↓ +3KCN →[Cu (CN )4 ]3− + 3K+
Colourless
+1
Cu has a d configuration, so it is tetrahedral in shape with sp3 hybridization.
10
46. (d)
Gravimetric estimation of Cu 2+ would be possible only when the given procedure gives an insoluble compound
on treatment with a given reagent.
→ Cu (SCN ) 2 ↓ +2K +
Cu 2+ + 2KSCN 
Black ppt
om
2Cu (SCN )2 ↓   
→ 2CuSCN ↓ + (SCN )2 ↑
decomposes
White ppt
c
With other reagents, either there is no reaction or even if it reacts, then the product is a soluble compound.
g.
ng
ye
.m
w
w
w
://
tp
ht
10
(Solutions)
MATHEMATICS
SECTION – I
47. (C)
48. (B)
49. (A)
50. (A) LET THREE NUMBERS ARE 2 α , 2β AND 2 γ
 1 + 2 + 3 + ....... + n − (α + β + γ )  37
 =
 n −3  5
n(n + 1) 37
α +β+ γ= − (n − 3)
om
2 5
(N MUST BE IN THE FORM OF (5N + 3) ) AND α + β + γ MUST BE NATURAL NUMBER LESS
THAN 3n − 3 THUS POSSIBLE VALUES OF N ARE 8 AND 13.
c
g.
∞
k I(k ) = ∫x
k ln x
51. (D) dx LET x = kt
ng
0
2
+ kx + k 2
∞
ye
k I(k ) = ∫t
ln kt
dt
0
2
+ t +1
.m
∞
k I(k ) − I (1) = ∫ (ln k )
dt
w
1 + t + t2
0
w
∞
= (ln k ) ∫
dt
w
2
 1   3 
2
t +  + 
0
://
 2   2 
tp
π 2π
= (ln k )
2
×
ht
3 3 6
k = e3 2
52. (A) S n = n. 2 n−1

NOW FOR ANY VALUE OF N, S n WILL END IN TWO ZERO’S IF THE PRODUCT.
n . 2 n−1 = n(2.2.2.....(n − 1) times)
CONTAINS EXACTLY TWO 5 AS FACTORS.
THIS WILL HAPPEN FOR N = 25, 50, 75, 100
So required probability = 4 100 = 1 25
SECTION − II
One or more than one type
53. (B), (C)
Z = 0 IS ONE OF THE PLANE PERPENDICULAR TO x + y = 0, x − y = 0, x = 1
NOW THE TRIANGLE FORMED IS TAKE ONE LET ON Z-AXIS I.E., (0, 0, k ) , THEN
12 + 12 + k 2 = 2 2 ⇒ k = ± 2
11
NOW THE DIRECTION RATIO OF PLANE HAVING POI NT (0, 0, 2 ), (1, 1, 0) AND (1, − 1, 0) IS
( 2 , 0, 1) AND THE DIRECTION RATIO OF PLANE HAVING POINT (0, 0, − 2 ), (1, 1, 0) AND (1, − 1, 0 )
IS (− 2 , 0, 1) .
(0, 0, 0) (1, 1, 0)
B C
A
(1, –1, 0)
54. (A), (B), (C)
( x − y ) f ( x + y ) − ( x + y) f ( x − y ) = 2 y ( x − y( x + y ))
LET x − y = u ; x + y = v
uf (v ) − vf (u ) = 2uv(v − u )
om
f (v ) f (u)
− = v −u
v u
 f (v )   f (u )
c

 − v =  − u  =CONSTANT
g.
 v   u 
f (x )
ng
LET − x=λ
x
(
⇒ f (x ) = λ x + x 2 )
ye
f (1) = 2
λ +1 = 2
.m
⇒ λ =1
f (x ) = x 2 + x
w
55. (B) LET X ∈ [0, 2]. SINCE f ( x ) SATISFIES ALL THE CONDITIONS OF L.M.V. THEOREM ON [0, 2].
w
∴ IT ALSO SATISFIES ON [0, X] ≤ [0, 2]

w
f ( x ) − f (0)
∴ = f ′( x1 )
://
x−0
WHERE 0 < x1 < x < 2 I.E., 0 < x1 < 2
tp
⇒ f (x ) = x f ′( x1 ) [Q f (0 ) = 0]
ht
f ( x ) = xf ′( x1 )
= | x | f ′( x1 ) ≤ 2 . = 1
1
⇒
2
 1
Q | x | ≤ 2 and f ′( x1 ) ≤ 2  ⇒ | f ( x) | ≤ 1
 
56. (a), (c)
12
SECTION− III
Reasoning type
57. (A) STATEMENT-1: a 2 (b − c ) + b2 (c − a) + c 2 ( a − b) ) < abc
( ) ( )
a 2 (b − c) + a c 2 − b 2 + b 2c − c 2b < abc , THUS
(b − c )(a − b) (a − c ) < abc
STATEMENT-2: a − b < c
58. (A) LET h (x ) = ( f (a ) − f ( x )) ( g (b) − g ( x )). e x

h (a ) = h(b ) = 0 , THEN THERE EXIST c ∈ (a, b) IN SUCH A WAY h ′(c ) = 0
h′ (x ) = − f ′( x )[ g(b) − g ( x) e x ]
− g′( x )( f (a) − f ( x )) e x
om
+ ( f (a ) − f (x )) ( g (b ) − g ( x )) e x = 0
c
f ′ (x ) g ′( x)
OR +
f (a ) − f ( x ) g(b) − g ( x)
=1
g.
ng
59. (D)
ye
60. (A) STATEMENT-2 GIVES THE DEFINITION OF DIFFERENTIABILITY AND HENCE CORRECT.
.m
FOR STATEMENT-1.
TAKE A = f (c ) AND B = f ′(c )
w
DEFINE g (x ) = f ( x ) − f (c ) − f ′(c)(x − c )
w
HENCE g (x ) SATISFIES (I)

w
g (c) = f (c ) − f (c) − f ′(c )(c − c ) = 0

://
HENCE (II) IS SATISFIED

tp
g (x ) f ( x) − f (c) − f ′(c )( x − c)
lim = lim
ht
x →c x − c x →c x−c
f (x ) − f (c )
= lim − f ′(c ) = f ′(c ) − f ′(c ) = 0
x →c x −c
HENCE (III) IS SATISFIED
SECTION− IV
Comprehension Type
PASSAGE-I
61. (C) THE LAST TWO THROWS SHOULD SHOW HEADS AND THE PREVIOUS THROWS SHOULD
ALWAYS SHOW A PAIR OF HEAD AND A TAIL I.E. (HT) (HT) (TH) (HT) (TH) (TH) …….(H H)
4
PROBABILITY OF EITHER HT OR TH IS .
9
SO FINAL PROBABILITY IS
4
4  4 4 
2
4
1 + +   + ......  = 9 =
9  9 9  4 5
 1−
9
62. (B) THE PROBLEM IS OF BAYE’S THEOREM.
13
2 3
4 4 4
WHEN GAME ENDS WITH TWO HEADS THE PROBABILITY IS +   +   + .......
9 9 9
49 5
THEN FOR MINIMUM NUMBER OF THROWS, PROBABILITY IS =
4 1  9
 
9  1 − (4 9) 
63. (D) GAME END WITH EITHER 2 HEADS OR 2 TAILS THEN IT IS 1.
PASSAGE-II
B
A
C
O
E D
r r r r r r
SOL.: Q OA = a, OB = a + b , OC = b , OD = λa, OE = λb
om
r r
∴ AB = b AND BC = − a
r r
| AB |=| BC | ⇒ | a |=| b |
c
g.
NOW, AB = OC AND OA = CB
ng
AND AB = OC = OA = CB
⇒ OABC IS A RHOMBUS
ye
AND OA, OD AND EO, OC ARE COLLINEAR
[OD = λOA AND OE = λOC ]

.m
3π 2π
∴ ∠AOC = ∠ABC = AND ∠OAB = ∠ OCB =
w
5 5
r
w
r 3π
I.E., ANGLE BETWEEN a AND b IS
5
w
r r r
NOW DC = AB ⇒ λa − b = b
://
r r
⇒ λ2 (a )2 + b () rr r
() 2π
tp
2 2
− 2a.bλ = b ⇒ λ = −2 cos
5
(λ − 1)ar
ht
AD 2π
64. (B) = r = λ − 1 = 1 + 2 cos
BC −a 5
65. (A)
66. (D)
PASSAGE-III
67. (A)
68. (A)
69. (C)

Solutions TO Test-Ii

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3. Loss in potential energy = gain in kinetic energy

FROM (I), (II) & (III) v y = AND v x2 = v 2 −

APPLYING KIRCHOFF’S LAW IN A LOOP pp' Qxyp

APPLYING KIRCHOFF’S LAW IN A LOOP QxypQ' Q

SINCE r >> R ∴ 4 I1r = 12 ; I 1 r = 3V

27. (c) H3A H + + H 2 A − ; Ka 1

= 4 × 100 = 200 m/s

29. (c) (A) is Lunar caustic i.e. AgNO3

AgCN + KCN → K[Ag(CN)2 ]

Moles of CO2 left = [0.1 – x]1st reaction + [x]IInd reaction

H2 CO3 + Ca(OH)2 → CaCO3 + 2H2 O

Since, product is an alcohol, so compound (A) is a 10 aliphatic amine.

NaOH H2 /Ni NaNO2 /HCl C6H 5OH

NO2 NO2 NH2 N2 Cl N=N OH

42. (d) and

43. (a) and

52. (A) S n = n. 2 n−1

∴ IT ALSO SATISFIES ON [0, X] ≤ [0, 2]

57. (A) STATEMENT-1: a 2 (b − c ) + b2 (c − a) + c 2 ( a − b) ) < abc

(b − c )(a − b) (a − c ) < abc

58. (A) LET h (x ) = ( f (a ) − f ( x )) ( g (b) − g ( x )). e x

HENCE g (x ) SATISFIES (I)

g (c) = f (c ) − f (c) − f ′(c )(c − c ) = 0

HENCE (II) IS SATISFIED

AND OA, OD AND EO, OC ARE COLLINEAR

[OD = λOA AND OE = λOC ]

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