LAMPIRAN

1. Menentukan kerapatan zat cair

m
ρ=
v
Keterangan:
Ρ = kerapatan zat cair (g/mL)
m = massa zat cair (g)
v = volume zat cair (mL)
 Akuades
Suhu 30oC
m = massa campuran – massa piknometer kosong
m1 = 35,277 g – 24,420 g = 10,857 g
m2 = 35,277 g – 24,420 g = 10,857 g
10,857 g
ρ1 = = 1,0857 g/mL
10 mL
10,857 g
ρ2 = = 1,0857 g/mL
10 mL
1,0857 g/mL +1,0857 g/mL 2,1714 g/mL
ρ̅ = = = 1,0857 g/mL
2 2

Suhu 33oC
m1 = 35,200 g – 24,420 g = 10,78 g
m2 = 35,195 g – 24,420 g = 10,775 g
10,78 g
ρ1 = = 1,078 g/mL
10 mL
10,775 g
ρ2 = = 1,0775 g/mL
10 mL
1,078 g/mL+1,0775 g/mL 2,1555 g/mL
ρ̅ = = = 1,07775 g/mL
2 2

Suhu 35oC
m1 = 35,165 g – 24,420 g = 10,745 g
m2 = 35,167 g – 24,420 g = 10,747 g
10,745 g
ρ1 = = 1,0745 g/mL
10 mL
10,747 g
ρ2 = = 1,0747 g/mL
10 mL
 1,0745 g/mL+1,0747 g/mL 2,1492 g/mL
ρ̅ = = = 1,0746 g/mL
2 2

 Aseton
Suhu 30oC
m1 = 35,222 g – 24,420 g = 10,802 g
m2 = 35,220 g – 24,420 g = 10,8 g
10,857 g
ρ1 = = 1,0802 g/mL
10 mL
10,857 g
ρ2 = = 1,08 g/mL
10 mL
1,0802g/mL +1,08 g/mL 2,1602 g/mL
ρ̅ = = = 1,0801 g/mL
2 2

Suhu 33oC
m1 = 35,176 g – 24,420 g = 10,756 g
m2 = 35,176 g – 24,420 g = 10,756 g
10,756 g
ρ1 = = 1,0756 g/mL
10 mL
10,756 g
ρ2 = = 1,0756 g/mL
10 mL
1,0802g/mL +1,08 g/mL 2,1602 g/mL
ρ̅ = = = 1,0801 g/mL
2 2

Suhu 35oC
m1 = 35,136 g – 24,420 g = 10,716 g
m2 = 35,134 g – 24,420 g = 10,714 g
10,716 g
ρ1 = = 1,0716 g/mL
10 mL
10,714 g
ρ2 = = 1,0714 g/mL
10 mL
1,0716 g/mL +1,0714 g/mL 2,143 g/mL
ρ̅ = = = 1,0715 g/mL
2 2

 Alkohol
Suhu 30oC
m1 = 37,295 g – 24,420 g = 12,875 g
m2 = 37,296 g – 24,420 g = 12,876 g
12,875 g
ρ1 = = 1,2875 g/mL
10 mL
12,876 g
ρ2 = = 1, 2876 g/mL
10 mL
1,2875 g/mL +1,2876 g/mL 2,5751 g/mL
ρ̅ = = = 1,28755 g/mL
2 2
 Suhu 33oC
m1 = 37,280 g – 24,420 g = 12,86 g
m2 = 37,289 g – 24,420 g = 12,869 g
12,86 g
ρ1 = = 1,286 g/mL
10 mL
12,869 g
ρ2 = = 1, 2869 g/mL
10 mL
1,286 g/mL +1,2869 g/mL 2,5729 g/mL
ρ̅ = = = 1,28645 g/mL
2 2

Suhu 35oC
m1 = 37,257 g – 24,420 g = 12,857 g
m2 = 37,253 g – 24,420 g = 12,853 g
12,857 g
ρ1 = = 1,2857 g/mL
10 mL
12,853 g
ρ2 = = 1, 2853 g/mL
10 mL
1,2857 g/mL +1,2853 g/mL 2,571 g/mL
ρ̅ = = = 1,2855 g/mL
2 2

 Zat X
Suhu 30oC
m1 = 37,317 g – 24,420 g = 12,897 g
m2 = 37,311 g – 24,420 g = 12,891 g
12,897 g
ρ1 = = 1,2897 g/mL
10 mL
12,891 g
ρ2 = = 1, 2891 g/mL
10 mL
1,2897g/mL +1,2891 g/mL 2,5788 g/mL
ρ̅ = = = 1,2894 g/mL
2 2

Suhu 33oC
m1 = 37,289 g – 24,420 g = 12,869 g
m2 = 37,289 g – 24,420 g = 12,869 g
12,869 g
ρ1 = = 1,2869 g/mL
10 mL
12,869 g
ρ2 = = 1,2869 g/mL
10 mL
1,2869 g/mL+1,2869 g/mL 2,5738 g/mL
ρ̅ = = = 1,2869 g/mL
2 2
 Suhu 35oC
m1 = 37,276 g – 24,420 g = 12,856 g
m2 = 37,276 g – 24,420 g = 12,856 g
12,856 g
ρ1 = = 1,2856 g/mL
10 mL
12,856 g
ρ2 = = 1,2856 g/mL
10 mL
1,2856 g/mL+1,2856 g/mL 2,5712 g/mL
ρ̅ = = = 1,2856 g/mL
2 2

2. Menentukan kekentalan zat cair

t x ρx ηa
η=
ρa t a
Keterangan:
η = kekentalan zat cair (poise)
t x = waktu yang dibutuhkan zat cair untuk mengalir (s)
ρx = kerapatan zat cair (g/ml)
ηa = kekentalan akuades (poise)
ρa = kerapatan akuades (g/ml)
t a = waktu yang dibutuhkan akuades untuk mengalir (s)
 Akuades
tair pada Suhu 31 °C = 1,6 s
Suhu 29 °C = 2,0 s
Suhu 27 °C = 2,55 s
ηair pada Suhu 31 °C = 0,7840 poise
Suhu 29 °C = 0,8100 poise
Suhu 27 °C = 0,8545 poise
 Alkohol
Suhu 30 °C
g
0,7 s × 1,2875 × 0,7980 poise
η= ml = 2,475 poise
g
1,0857 × 0,65 s
ml
Suhu 33 °C
 g
1,3 s × 1,2864 × 0,7523 poise
η= ml = 2,594 poise
g
1,0777 × 0,45 s
ml
Suhu 35 °C
g
0,6 s × 1,2855 × 0,7240 poise
η= ml = 2,079 poise
g
1,0746 × 0,25 s
ml
 Aseton
Suhu 30 °C
g
2,45 s × 1,0801 × 0,7840 poise
η= ml = 2,991 poise
g
1,0857 × 0,6 s
ml
Suhu 33 °C
g
1,2 s × 1,0756 × 0,7523 poise
η= ml = 2,002 poise
g
1,0777 × 0,45 s
ml
Suhu 35 °C
g
0,6 s × 1,0715 × 0,7240 poise
η= ml = 1,735 poise
g
1,0715 × 0,25 s
ml
 Zat X
Suhu 30 °C
g
1,65 s × 1,2894 × 0,7980 poise
η= ml = 2,411 poise
g
1,083 × 1,6 s
ml
Suhu 33 °C
g
1,05 s × 1,2869 × 0,7523 poise
η= ml = 2,096 poise
g
1,0777 × 0,45 s
ml
Suhu 35 °C
g
0,55 s × 1,2856 × 0,7240 poise
η= ml = 1,905 poise
g
1,0746 × 0,25 s
ml
3. Grafik
ln η terhadap 1/T
 Akuades

X Y
T (K) 1/T η (poise) ln η
308 0.00325 0.724 5
306 0.00327 0.7523 6
303 0.0033 0.798 6.28

Hubungan ln η dengan 1/T

(Akuades)
7
6.28
6
y = 0.4915x + 4.7603
6 R² = 0.9753
ln η

6
5 ln η
5 Linear (ln η)

5
0.00325 0.00327 0.0033
1/T

y = mx + c
y = 0,4915x + 4,7603
m = 0,4915
E
m=
R

E =m×R
= 0,4915 × 0,9876 J/mol
= 0,4854 J/mol
= 4,854 x 10-4 kJ/mol
 Alkohol :

X Y
T (K) 1/T η (poise) ln η
308 0.00325 2 54
306 0.00327 2 100
303 0.0033 3 979

Hubungan ln η dengan 1/T

(Alkohol)
1,200
1,000 979
800 y = 462.58x - 547.07
R² = 0.7873
600
ln η

ln η
400
Linear (ln η)
200
54 100
0
0.00325 0.00327 0.0033
-200
1/T

y = mx + c
y = 462,58x – 547,07
m = 462,58
E
m=R

E =m×R
= 462,58 × 0,8873 J/mol
= 410,45 J/mol
= 4104,5 x 10-4 kJ/mol
 Aseton :

X Y
T (K) 1/T η (poise) ln η
308 0.00325 2 54
306 0.00327 2 100
303 0.0033 3 979

Hubungan ln η dengan 1/T

(Aseton)
1,200
1,000 y = 462.58x - 547.07
979 R² = 0.7873
800
600
ln η

ln η
400
Linear (ln η)
200
54 100
0
0.00325 0.00327 0.0033
-200
1/T

y = mx + c
y = 462,58x – 547,07
m = 462,58
E
m=R

E =m×R
= 462,58 × 0,8873 J/mol
= 410,45 J/mol
= 4104,5 x 10-4 kJ/mol
 Zat X :

X Y
T (K) 1/T η (poise) ln η
308 0.00325 2 80
306 0.00327 2 125
302 0.0033 2 258

Hubungan ln η dengan 1/T

(Zat X)
300
250 258

200 y = 88.64x - 23.038

R² = 0.9233
ln η

150
125 ln η
100
80 Linear (ln η)
50
0
0.00325 0.00327 0.0033
1/T

y = mx + c
y = 88,64x – 23,038
m = 88,64
E
m=R

E =m×R
= 88,64 × 0,9609 J/mol
= 85,17 J/mol
= 851,7 x 10-4 kJ/mol