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Assignment 2018 1
Assignment 2018 1
1. The physical laws that govern the transport of mass, energy and momentum are based on
the notion that the flow of these entities is induced by a driving potential. In transport of
mass, the driving potential is expressed in terms of the molar concentration gradient 𝑑𝐶 ⁄𝑑𝑥
and the proportionality constant, D is known as the mass diffusivity of the species. The
whole expression of mass transport is well expressed by the Fick’s law. Explain, under what
conditions is the concentration gradient in Fick’s law a constant, and when does it become
a variable?
2. CO2 gas is diffusing at steady state through a tube 0.25 m long having a diameter of
0.010 m and containing N2 at 298 K. The total pressure is constant at 101. 32 kPa. The
partial pressure of CO2 is 456 mmHg at one end and 76 mmHg at the other end. The
diffusivity, DAB is 1.67 × 10−5 m2/s at 298 K. Calculate the flux of CO2 for equimolar counter-
diffusion.