Characteristics and Origin of Abnormally High Porosity Zones in Buried Paleogene Clastic Reservoirs in The Shengtuo Area, Dongying Sag, East China

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346 Pet.Sci.

(2014)11:346-362
DOI 10.1007/s12182-014-0349-y

Characteristics and origin of abnormally


high porosity zones in buried Paleogene
clastic reservoirs in the Shengtuo area,
Dongying Sag, East China
Cao Yingchang , Yuan Guanghui, Li Xiaoyan, Wang Yanzhong, Xi Kelai,
Wang Xiaoming, Jia Zhenzhen and Yang Tian
School of Geosciences, China University of Petroleum, Qingdao, Shandong 266580, China

© China University of Petroleum (Beijing) and Springer-Verlag Berlin Heidelberg 2014

Abstract: There are three abnormally high porosity zones developed in buried Paleogene nearshore
subaqueous fan and sublacustrine fan clastic reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900-
4,400 m, respectively, within the Shengtuo area of the Dongying Sag. Here the porosity of reservoirs
buried deeper than 4,000 m can still be greater than 20%. Investigation of these three abnormally high
porosity (AHP) zones in the 3rd to 4thPHPEHURIWKH3DOHRJHQH6KDKHMLH)RUPDWLRQLQWKH6KHQJWXRDUHD
ZDVFDUULHGRXWZLWKXWLOL]DWLRQRIFRUHREVHUYDWLRQWKLQVHFWLRQLGHQWL¿FDWLRQ6(0REVHUYDWLRQLPDJH
analysis, core physical property testing and other technical methods. The results show that, the AHP
]RQHVLQPDQGPDUHYLVLEOHSRUHVSULPDU\$+3]RQHVGRPLQDWHGE\VLJQL¿FDQW
primary intergranular pores (more than 50% of the total porosity), while secondary pores and micropores
in authigenic clays may develop in some reservoirs. AHP reservoirs in the AHP zone of 3,900-4,400 m
are dominated by micropores in matrix, visible pores are mainly grain dissolution pores but with low
absolute content (< 1%), so this zone belongs to the micropores primary AHP zone. The genesis of the
three AHP zones was studied to distinguish between porosity enhancement and porosity preservation.
Our research shows that, in deeply buried clastic reservoirs in the Shengtuo area, mineral dissolution
occurred in a relatively closed diagenetic system with high temperature and high salinity. Reservoir rocks
underwent extensive feldspar dissolution, while detrital carbonate grains and carbonate cements show
QRHYLGHQFHRIH[WHQVLYHGLVVROXWLRQ$OWKRXJKVLJQL¿FDQWIHOGVSDUGLVVROXWLRQSRUHVGHYHORSHGIHOGVSDU
dissolution enhanced porosity only a little due to the precipitation of almost isovolumetric dissolution
products in the nearby primary intergranular pores in forms of authigenic clays and quartz cements. Net
enhanced porosity originating from feldspar dissolution is generally less than 0.25%. Thus, the subsurface
dissolution has little impact on the mid-deep buried high porosity reservoirs. Reservoirs in braided
channels of middle fans in sublacustrine fans and reservoirs in the middle-front of fan bodies of nearshore
VXEDTXHRXVIDQVSURYLGHWKHEDVLVIRUWKHGHYHORSPHQWRI$+3]RQHV7KHVKDOORZGHYHORSPHQWRIÀXLG
overpressure and early hydrocarbon emplacement have effectively retarded compaction and carbonate
FHPHQWDWLRQVRWKDWWKHKLJKSRURVLW\LQWKHVXSHU¿FLDOOD\HUVLVSUHVHUYHGLQWKHPLGGHHSOD\HUV7KHVH
are the main controlling factors in the development of AHP zones.

Key words: Dongying Sag, Shengtuo area, abnormally high porosity zone, pores, genesis

1 Introduction unexpectedly high porosity and permeability at substantial


burial depth. Studies on the origin and distribution of these
Studies by Bloch et al (2002) of global basins show that high-quality abnormally high porosity (AHP) reservoirs are
in specific geological conditions, deeply buried reservoirs of great importance for oil-gas exploration and production.
can still be effective for accumulation and production %ORFKHWDO  GH¿QHG$+3DVUHVHUYRLUSRURVLW\ZKLFK
of petroleum and in particular that some areas exhibit is statistically higher than the porosity values occurring in
typical sandstone reservoirs of a given lithology (composition
*Corresponding author. email: caoych@upc.edu.cn
and texture), age and burial/temperature history. In sandstones
Received May 11, 2013
containing abnormally high porosities, such porosities
Pet.Sci.(2014)11:346-362 347

exceed the maximum porosity of the typical sandstone the secondary AHP zone (the relative percentage content of
VXESRSXODWLRQ:LWKLQVSLUDWLRQIURPWKLVGH¿QLWLRQ0HQJHW secondary pores in reservoirs is more than 50%) (Cao et al,
DO  GH¿QHGWKH$+3]RQHDVWKHUHVHUYRLUGHYHORSPHQW 2013). Also, exploration ideas and methods should differ
zone with porosities higher than the maximum porosity between these types of AHP zones.
of clastic rocks that develop in normal sedimentary and The mid-deep clastic reservoirs (>2,500 m) in the
diagenetic environments. The concept of an AHP zone Shengtuo area of the northern steep slope zone in the
emphasizes only the abnormally high level of reservoir Dongying Sag developed three AHP zones at 2,800-3,200
porosity regardless of the pore types. In addition, Chinese m, 3,250-3,700 m and 3,700-4,400 m, respectively. Great
scholars also referred to the AHP zone as the secondary pore success has been achieved in oil-gas exploration in Es4-Es3z
development zone, secondary pore zone, (abnormal) pore VXEWOH UHVHUYRLUV LQ UHFHQW \HDUV )RU H[DPSOH:HOO7
development zone, secondary pore development section, Well T76, Well T710, Well T719 and Well T764 all obtained
etc., of which, the secondary pore development zone has high yields in the Es4-Es3x formations. However, there is still
been used widely (Yuan and Wang, 2001; Zhu et al, 2006; much debate on pore types and genesis of the AHP reservoirs.
Liu et al, 2009; Wang, 2010). Some scholars considered the Previous studies suggested that, the deep buried Paleogene
relative content of secondary pores in the reservoirs (Wang clastic reservoirs in the Shengtuo area consist mainly of
and Shao, 1999; Wang, 2010), for example, Wang (2010) secondary pores, and subsurface dissolution is the main
VXPPDUL]HGVWXGLHVRIWKH&KLQHVHVFKRODUVDQGGH¿QHGWKH controlling factor of these AHP zones (Zhong et al, 2003; Zhu
secondary pore development zone as a zone where reservoirs et al, 2006; Yuan et al, 2007; Gao et al, 2008). Among them,
with high porosity (higher than the ĭcutoff) developed, based on Zhong et al (2003) and Zhu et al (2006) proposed that the
the introduction of effective reservoir porosity cutoff (ĭcutoff), reservoirs consist mainly of intergranular dissolution pores,
and where the percentage of secondary pores in reservoirs is and significant dissolution of carbonate cements is critical
more than 50%. However, without considering the content to the AHP zones. However, Yuan et al (2007) and Gao et al
of secondary pores in reservoirs, some scholars subjectively (2008) argued that the dissolution of carbonate cements is
GH¿QHGWKHFRQFHQWUDWHGGHYHORSPHQW]RQHRI$+3UHVHUYRLUV not obvious, and significant feldspar pores contribute more
with secondary pores as the secondary pore development WRWKHVH$+3]RQHV*HRORJLFDOIDFWRUVEHQH¿FLDOWRSULPDU\
zone (Zhong et al, 2003; Xiao et al, 2003; Liu and Zhu, 2006; SRUHSUHVHUYDWLRQVXFKDVÀXLGRYHUSUHVVXUHDQGK\GURFDUERQ
Zhu et al, 2007; Zhang et al, 2011). emplacement occur commonly in the Shengtuo area (Zhang
Publications suggest that both geological processes et al, 2009; Wang, 2010; Sun, 2010). However, the AHP
beneficial to porosity preservation (e.g. (1) the shallow zones were identified as secondary AHP zones (secondary
GHYHORSPHQWRIÀXLGRYHUSUHVVXUHDQGFKORULWHFRDWVDQG   pore development zones) by previous studies (Zhong et al,
early hydrocarbon emplacement) and processes beneficial 2003; Zhu et al, 2006; Yuan et al, 2007; Gao et al, 2008),
to porosity enhancement (mineral dissolution) can be the which is questionable. Using core observation, thin section
important controlling factors to the development of mid- identification, SEM analysis, image analysis, rock physical
deep AHP reservoirs (Ehrenberg, 1993; Warren and Pulham, property tests, fluid inclusion analysis, statistical analysis
2001; Luo et al, 2002; Bloch et al, 2002; Marchand et al, and other techniques, on the basis of the distribution of AHP
2002; Zhong et al, 2003; Zhu et al, 2004; 2006; Zhang et al, zones in the Shengtuo area, we studied the pore types and the
2007; Yu et al, 2008; Peng et al, 2009; Zhong et al, 2008; genesis of these AHP zones.
Taylor et al, 2010; Meng et al, 2010; Wang, 2010; Jin et
al, 2011; Chen et al, 2011; Zhu et al, 2012). Even recently, 2 Geological background
most Chinese scholars still thought that burial dissolution of
minerals (particularly mesogenenic dissolution) is the main The Dongying Sag is a sub-tectonic unit lying in the
controlling factor of the mid-deep AHP zones (Zhang et al, southeastern part of the Jiyang Depression of the Bohai Bay
2003; Zhu et al, 2004; Yuan et al, 2007; Zhu et al, 2006; Yu %DVLQ (DVW &KLQD )LJ  D  ,W LV D 0HVR]RLF&HQR]RLF
et al, 2008; Zhong et al, 2008; Zhu et al, 2012). In recent half graben rift-downwarped lacustrine basin, developed on
years, many foreign scholars and some Chinese scholars Paleozoic bedrock paleotopography (Yuan et al, 2007). The
began to accentuate the importance of geological processes Dongying Sag, which is located west of the Qingtuozi Salient,
beneficial to porosity preservation (e.g. fluid overpressure, north of the Luxi Uplift and Guangrao Salient, east of the
hydrocarbon emplacement and chlorite coats), and rethought Linfanjia and Gaoqing Salient, south of the Chenjiazhuang-
the importance of secondary pores (Bloch et al, 2002; Taylor Binxian Salient. It covers an area of 5,850 km2 with an east-
et al, 2010; Berger et al, 2009; Marchand et al, 2002; Higgs ZHVWD[LVRINPDQGDQRUWKVRXWKD[LVRINP,QSUR¿OH
et al, 2007; Jin et al, 2011; Ehrenberg et al, 2012; Yuan et the Dongying Sag is a half graben with a faulted northern
DOE :KHQJHRORJLFDOSURFHVVHVEHQH¿FLDOWRSRURVLW\ margin and a gentle southern margin. In plan, the Dongying
preservation serve as main controlling factors, AHP reservoirs sag is further subdivided into secondary structural units, such
consist mainly of primary pores; while when the secondary as the northern steep slope zone, middle uplift belt, trough
dissolution is the main controlling factor, the AHP reservoirs zones of the Lijin, Minfeng, Niuzhuang and Boxing subsags,
consist mainly of secondary pores (Bloch et al, 2002; Meng et DQGWKHVRXWKHUQJHQWOHVORSH]RQH =KDQJHWDO  )LJ
al, 2006; 2010). Thus, we suggested dividing the AHP zones 1(b)).
into two types: the primary AHP zone (the relative percentage The Shengtuo area is located in the middle part of the
content of primary pores in reservoirs is more than 50%) and northern steep slope zone of the Dongying sag, with the
348 Pet.Sci.(2014)11:346-362

(a) 42° N (b)


Sag N 0 100km

ft
0 10 20km

pli
Uplift lt
Be

gU
ld Ⱦ

on
Fo

od
40°
Beijing Yanshan

Lia
Chenjiazhuang Salient
ift

t
Ƚ Dalian

f
pli
pl ĉ Ċ

Qingtuozi Salient
han U
Bohai Bay

nu
38°

xia fault

lift
an
Chenn slope
ng ċ Coast line

Up
Taihangs

Ca

China
Northern zone

ng
ift
Jinan

odo
steep
pl

36°
Beijing
xi U

racture
Jia
b-f
ng su Minfeng
Lu

eng-Yo
Ď Tanlu strike-slip
Binxian
Tuo-Sh
fault zone
subsag
114° 116° 118° 120° 122° 124° Salient
ag
Binnan-lijin fault zone subs
nt Lijin
lie ag
Sa ubs
jia g s ne
an an t zo
Linf Middle uplift iuzhu g faul
N iaga
n
j e
ang on
ng-w tz
ne

Lizezheng subsag ua l
h u
zo

Shic
un fa anz fa
ngu
ult

ult zo e
ne Che nh
fa

ia
ing

ne m
Qingcheng e zo Ba
oq

Boxing subsag slop


Ga

Salient rn t
Sou
the alien
angrao S
Gu
Boxing fault zone

Paleogene Paleogene
area overlap zone

Luxi Uplift
Study Major Paleogene
area fault denuded zone

Fig. 1 (a) Tectonic setting of the Dongying Sag in the Jiyang Depression ( ) of the Bohai Bay Basin, East China.
Other depressions in the Bohai Bay Basin are Jizhong Depression ( ), Huanghua Depression (II), Bozhong Depression
(IV), Liaohe Depression (V) and Dongpu Depression (VI) (After Liu et al, 2012). (b) Structural map of the Dongying
Sag. The area in the green line is the study area (After Zhang et al, 2006).

Chenjiazhuang Salient to the north, the central faulted in the Shengtuo area, the quartz content is 5%-63% with
anticlinal zone to the south, the Lijin subsag to the southwest an average of 32%, the feldspar content is 4%-74% with an
and the Minfeng subsag to the southeast, with an exploration average of 37% and the detritus content is 3%-88% with an
area of 230 km 2 *DR HW DO   )LJ  E 7KH EDVLQ average of 30%. The reservoir rocks consist mainly of lithic
controlling boundary Chennan fault and the secondary Tuo- DUNRVH DQG IHOGVSDWKLF OLWKLF VDQGVWRQHV )LJ   2Q WKH
Sheng-Yong sub fracture system, jointly controlled the whole, detrital grains are moderately to poorly sorted, with
terrace tectonic style in the Shengtuo area, and had important sub-angular or sub-rounded shapes. Grain contacts are mainly
LQIOXHQFHRQVHGLPHQWVDQGUHVHUYRLUV )LJ 'XULQJWKH point contact and point-line contact.
early period of Es4x, the Tuo-Sheng-Yong sub fracture system
had not yet begun to develop, and nearshore subaqueous 3.2 Diagenesis features
IDQVGHSRVLWHG)URPWKHODWHSHULRGRI(V4x to the period of According to the new diagenetic stage division standard
Es3z, the Tuo-Sheng-Yong sub fracture system developed and of clastic reservoirs in China’s oil and gas industry (Standard
formed the terrace. The nearshore subaqueous fans deposited No. SY/T5477-2003), the Paleogene Es4-Es3z reservoirs at
on the terrace that was constrained by the Chennan fault and depths of 1,500-4,500 m in the Shengtuo area are mainly in
Tuo-Sheng-Yong sub fracture system, and sublacustrine fans the eogenetic and mesogenetic stages. Among them, 1,500-
deposited in the subsag that was close to the Tuo-Sheng- 2,200 m belongs to the eogenetic stage A period, 2,200-3,000
<RQJ VXE IUDFWXUH V\VWHP $Q   )LJ   &RQWUROOHG m belongs to the B period of the eogenetic stage, 3,000-3,500
by the tectonic setting, the formation fluid pressure in the m belongs to the A1 sub-period of the mesogenetic stage,
Shengtuo area has apparent zoning. Normal and weak fluid and 3,500-4,500 m belongs to the mesogenetic stage A2 sub-
overpressure developed mainly in the nearshore subaqueous period (Table 1). The major diagenetic events in the reservoir
fans, and medium-strong overpressure with the pressure rocks include compaction, carbonate cements (mainly calcite,
FRHI¿FLHQWRIGHYHORSHGLQWKHVXEODFXVWULQHIDQV *DR dolomite, ferroan calcite and ankerite), quartz cements,
et al, 2008; An, 2010). feldspar dissolution, quartz dissolution, authigenetic clays
NDROLQLWHDQGLOOLWH DQGLOOLWL]DWLRQRINDROLQLWH )LJ)LJ
3 Petrography and diagenesis 5). Using textural evidence of precipitation and dissolution
of minerals and the homogenization temperatures (Th) of
3.1 Petrography
fluid inclusions, the epigenetic sequence was determined
The data show that in the mid-deep Paleogene reservoirs as follows: 1) compaction, early carbonate cementation
Pet.Sci.(2014)11:346-362 349

(b) Well-T 714 (c) Well-T 145


(a)

Depth, m
N

Depth, m
0 2 4km SP RT SP RT
Lithologic ȍ.m Lithologic ȍ.m
mv mv
column column
Chenjiazhuang Salient 10 100 -10 90 0 80 0 20

T105
Chennan Fault T175 T75
T137 T116

3150

2000
T104
T174
T127 T145 T123
T131 Tg2 T122 T125 T129
T160 T121
T82 T126 120 T128
T24 T156

3200

2050
T170 T158
T112
T81
T167 T17
134 T714
T164

3250

2100
T713 T76 T732
T764
T166 T766 T761
T717 T71 T7
T746 T765
T742 T153
T715

3300

2150
T718

Tuo-Sheng-Yong sub fracture system

60
Well site Normal Contour line Root of fan body Middle-front of fan body Fan edge subfacies Sublacustrine Deep lake Middle Gritstone Fine Fine sandstone Sand- Mudstone
/well number fault of sand content in subaqueous fan in subaqueous fan in subaqueous fan fan facies conglomerate conglomerate conglomerate

Fig. 2 (a) Distribution map of nearshore subaqueous fans and sublacustrine fans in Es4sLQWKH6KHQJWXRDUHD PRGL¿HGIURP$Q
2010). (b) Depositional sequence of sublacustrine fans and deep lake facies. (c) Depositional sequence of nearshore subaqueous fans

Quartz, % 9%. The quartz cements, generally less than 1% in reservoirs,


100
0
Quartz arenite DUHPDLQO\TXDUW]RYHUJURZWKV )LJ F  I  K DQGDIHZ
quartz crystals. The distribution of authigenic clay minerals in
Subfeldsarenite Sublitharenite
reservoirs has a regularity: above 3,150 m is mainly kaolinite,
20
80 DQGVKDUSO\EHORZPNDROLQLWHWUDQVIRUPVWRLOOLWH )LJ
 )URPWKHVKDOORZWRWKHGHHSOD\HUVWKHUHODWLYHFRQWHQW
40
of illite/smectite mixed layer minerals increases, but the ratio
60
of smectite in illite/smectite mix minerals decreases gradually
)LJ   6FDO\ RU SHWDO VKDSHG FKORULWH EXW QR HDUO\ JUDLQ
40
60 coating chlorite, develops in some reservoir rocks (Zhu et al,
2008; Chen et al, 2009).

20
80 4 Distribution of porosity intervals and
zones
Lithic Feldspathic
Feldsarenite feldsarenite litharenite Litharenite 100
0
100 80 60 40 20 0 3RURVLW\LQWHUYDODQG]RQHFODVVL¿FDWLRQVFKHPH
Feldspar, % Rock fragment, %
Core porosities of Paleogene Es4-Es 3z reservoirs were
Fig. 3 Ternary plot showing composition of Paleogene Es4-Es reservoirs 3
z
XVHGWRSORWWKHSRURVLW\GHSWKSUR¿OH,QWKHSRURVLW\GHSWK
in the Shengtuo area, the Dongying Sag (using sandstone classification profile, normal porosity development depth intervals, AHP
VFKHPHRI)RONHWDO development depth intervals, and AHP zones, high porosity
zones, low porosity zones in different depth intervals were
)LJ F  G  IHOGVSDUGLVVROXWLRQTXDUW]FHPHQWDWLRQ identified with the constraints of three curves, namely, the
DXWKLJHQLF NDROLQLWH SUHFLSLWDWLRQ )LJ  F    TXDUW] normal evolution curve of average porosity, the normal
GLVVROXWLRQODWHFDUERQDWHFHPHQWDWLRQ )LJ J  IHOGVSDU evolution curve of maximum porosity and the porosity
GLVVROXWLRQ TXDUW] FHPHQWDWLRQ )LJ  J  LOOLWL]DWLRQ RI HQYHORSHFXUYH,QWKHSRURVLW\GHSWKSUR¿OHWKH]RQHVZKHUH
NDROLQLWHDQGDXWKLJHQLFLOOLWHSUHFLSLWDWLRQ )LJ H  I  reservoirs with porosities that deviated from the normal
The compaction was mainly mechanical compaction, evolution curve of maximum porosity to higher values is
and pressure dissolution was weak. The dissolution mainly recognized as AHP zones; the zones where reservoirs with
LQFOXGHV IHOGVSDU GLVVROXWLRQ )LJ  F  H  J  )LJ  F  porosities that deviated from the normal evolution curve of
(e)), a little dissolution of aluminosilicate detrital grains maximum porosity to lower values but deviated from normal
DQGTXDUW]JUDLQV'HWULWDOFDUERQDWHJUDLQV )LJ E  H  evolution curve of average porosity to higher values is
I DQGFDUERQDWHFHPHQWV )LJ F  K VKRZQRHYLGHQFH recognized as high porosity zones; the zones where reservoirs
of significant dissolution. Carbonate cements represent the with porosities that deviated from normal evolution curve of
PRVWDEXQGDQWSRUH¿OOLQJFHPHQWV )LJ ZLWKDPD[LPXP average porosity to lower values is recognized as low porosity
FRQWHQWXSWR )LJ DQGDQDYHUDJHFRQWHQWRI zones. In the porosity-depth profile, the depth interval
350 Pet.Sci.(2014)11:346-362

Table 1 Diagenetic stages and main characteristics of the Es4-Es3z reservoirs in the Shengtuo area, the Dongying Sag

Temperature, °C
Diagenetic Authigenic cements in sandstones Dissolution

Compaction
Organic matter
stage %S
Depth, m
Contact Pore

Carbonate
cements
Feldspar

Feldspar
cements
Quartz

cements
in

Quartz

Debris
Relative Maturity I/S K I I/S Ch type type
Stage Period R o, % yield

Organic
acids
Oil Immature Primary
A CO2 65 Point dominant

2200 100
Eodiagenesis

0.35
65

Middle Line Primary


B mature ĉ point secondary

40
3000 120 0.5
30 Line
Low point, Primary
A1 mature ĉ Point secondary
20 line
3500 35 0.7
Mesodiagenesis

Point
Ċ Primary
Mature line,
A2 20 secondary
Line

4500 160 1.3


High Point
B Ċ Secondary
mature line,
20 dominant
5000 180 1.5
Line

with AHP zones is recognized as the AHP development Comparison between calculated mudstone fluid pressure
depth interval and the depth interval without AHP zones and measured adjacent sandstone fluid pressure shows
is recognized as the normal porosity development depth that the difference is always less than 5%. As well, the oil-
interval. bearing properties of more than 8,000 reservoir samples
with core porosity data were analyzed with core-logging
4.2 Normal evolution curve of maximum (average) PDWHULDOV6HFRQGE\UHMHFWLQJWKHSRURVLWLHVUHODWLQJWRÀXLG
porosity overpressure and/or high-level oil saturation (oil immersion,
The normal evolution curve of maximum porosity oil saturated and oil rich) from the porosity database, one
in clastic reservoirs refers to the evolution curve of the SRURVLW\GHSWKSUR¿OHZDVSORWWHGXVLQJUHVHUYRLUSRURVLWLHV
maximum porosity evolving with the burial depth in with normal pressure and low level oil content (oil-free, oil
reservoirs that did not experience abnormal geological trace, fluorescence and oil patches). The normal evolution
processes in favor of porosity enhancement and porosity curve of maximum porosity in Es 4-Es 3z reservoirs in the
preservation during deep burial. It can be determined by northern steep slope zone in the Dongying Sag was then
connecting the maximum porosity at different depths with determined through the smooth connection of maximum
a smooth curve in the porosity-depth profile. Among these SRURVLWLHVDWGLIIHUHQWGHSWKVLQVXFKDSRURVLW\GHSWKSUR¿OH
abnormal geological processes, the process in favor of )LJ $VHDUO\JUDLQFRDWLQJFKORULWHZDVQRWGHYHORSHG
porosity enhancement is the dissolution of unstable minerals and reservoirs with significant dissolution also have
(e.g. feldspars and carbonate minerals), while the processes relatively good oiliness, the rejection of porosities relating
in favor of porosity preservation consist mainly of fluid to fluid overpressure and/or high-level oil saturation from
overpressure, early hydrocarbon emplacement, and grain porosity database promises the elimination of the influence
coats. Thus, the normal evolution curve of maximum porosity of abnormal geological processes (fluid overpressure,
almost follows the compaction curve. hydrocarbon emplacement, grain coats and rims, and
In order to determine the distribution of AHP zones in dissolution) on porosities in the Shengtuo area.
WKH 6KHQJWXR DUHD ZH GLG WKH IROORZLQJ ZRUN )LUVW ZLWK The normal evolution curve of average porosity in clastic
WKHFRQVWUDLQWVRIWKHPHDVXUHGIRUPDWLRQÀXLGSUHVVXUHWKH reservoirs refers to the evolution curve of the average porosity
formation fluid pressure of over 300 wells in the northern evolving with the burial depth in reservoirs that did not
steep slope zone in the Dongying Sag was calculated by experience abnormal geological processes in favor of porosity
the equivalent-depth method with acoustic logging data. enhancement and porosity preservation during deep burial. On
Pet.Sci.(2014)11:346-362 351

Qa
FD

Qa
Qa

FD

Qa
FD FD
200ȝP 200ȝP
(a) Well T165, 3236.08 m (-) (b) Well T145, 2018.3 m (-)

FD K
K

FD
FD
FD
FD
FD
Qa
K
K
FD

100ȝP 25ȝP
(c) Well T714, 2841.3 m (-) (d) Well T714, 2841.3 m (-)

Qa

Qa
FD
I
I Qa

FD

100ȝP 100ȝP
(e) Well T720, 3671.1 m (-) (f) Well T720, 3671.1 m (-)

An

FD
An

Qa

(g) 50ȝP 100ȝP


Well T168, 3110.1 m (-) (h) Well T713, 3032.45 m (+)

Fig. 4 Photomicrographs showing diagenetic features related to feldspar dissolution in Paleogene


Es4-Es3z reservoirs in the Shengtuo area, the Dongying Sag. (a) Primary pores dominate, surface porosity
of feldspar dissolution is 0.1%; (b) Primary pores dominate, surface porosity of feldspar dissolution is
0.5%; (c) Massive quartz overgrowths and kaolinite, surface porosity of feldspar dissolution is 2.462%;
(d) Authigenic kaolinite and its micropores; (e) feldspar secondary pores and authigenic illite; (f) Quartz
RYHUJURZWKVDQGDXWKLJHQLFLOOLWH J )HOGVSDUSRUHVSDUWLDOO\¿OOHGZLWKDQNHULWH K 4XDUW]RYHUJURZWKV
SDUWLDOO\UHSODFHGE\DQNHULWHWKLQVHFWLRQ DJ UHGHSR[\UHVLQ±LPSUHJQDWHGWKLQVHFWLRQ)')HOGVSDU
dissolution pores; Qa: Quartz overgrowths; K: Kaolinite; I: Illite; An: Ankerite

the basis of the normal evolution curve of maximum porosity 4.3 Porosity intervals and zones
in clastic reservoirs, the normal average porosity of different With the constraints of the three curves, 3,880 core
depth intervals can be calculated using reservoir porosities porosities in the Shengtuo area show one normal porosity
with normal pressure and low oil-bearing saturation. Then development depth interval at depth of 1,300-2,800 m and
in the porosity-depth profile, the normal evolution curve of three AHP development depth intervals developed vertically
average porosity in clastic reservoirs can be determined by in Es4-Es3z reservoirs in the Shengtuo area. The three AHP
connecting the average porosities at different depths with a development depth intervals are at 2,800-3,200 m, 3,250-
VPRRWKFXUYH )LJ  3,700 m, 3,900-4,400 m respectively, and three AHP zones
352 Pet.Sci.(2014)11:346-362

Cc

Cc

Cc Cd

200ȝP (b) 100ȝP


(a) Well T167, 2969.63 m (+) Well T165, 3236.08 m (+)

Cc
Cc

FD

F F
As

(c) Well T73, 3371.25 m (-) 50ȝP (d) Well T73, 3371.25 m (+)
50ȝP

Cc Cc

Cd Cd

FD FD

(e) Well T720, 3535.0 m (-) 200ȝP (f) Well T720, 3535.0 m (+) 200ȝP

D D

Qa-Ċ
An An

Qa-ĉ
FD

(g) Well T720, 3535.0 m (+) 25ȝP (h) Well T724, 4169.8 m, SEM
5/11/2006 HFW WD Mag 20.0μm

Fig. 5 Photomicrographs showing diagenetic features related to carbonate cements in Paleogene Es4-Es3z
reservoirs in the Shengtuo area, the Dongying Sag. (a) Carbonate cement filled most pores, (b) Carbonate
detrital grain and the carbonate overgrowths, (c), (d) Intact early carbonate cement cladding and extensive
GLVVROYHGIHOGVSDUIHOGVSDUGLVVROXWLRQSRUHVSDUWLDOO\¿OOHGZLWKDVSKDOW H  I ,QWDFWFDUERQDWHGHWULWDOJUDLQV
and early carbonate cement cladding, extensively dissolved feldspars, (g) Two stages of quartz overgrowths,
intact ankerite wrapped in Qa-II, (h) Euhedral ankerite cements. (a, b, g): thin sections; (c-f) red epoxy resin–
LPSUHJQDWHGWKLQVHFWLRQ&F&DUERQDWHFHPHQWV&G'HWULWDOFDUERQDWHJUDLQ)')HOGVSDUGLVVROXWLRQSRUHV
As: Asphalt; An: Ankerite; Qa: Quartz overgrowths

H[LVWLQWKHWKUHH$+3GHYHORSPHQWGHSWKLQWHUYDOV )LJ  GLVWULEXWHGLQ )LJ ,QWKHSRURVLW\GDWDVHWWKH


Low porosity zones and high porosity zones develop in the low porosities account for 35%, the high porosities 33%, and
normal porosity development depth interval, while the three the abnormally high porosities 32%. In the AHP development
AHP development depth intervals contain the corresponding interval II (3,250-3,700 m), the histogram of porosities
low porosity zones, high porosity zones and AHP zones. shows negative skewness, and the porosities are mainly
In the AHP development interval I (2,800-3,200 m), GLVWULEXWHGLQ )LJ ,QWKHSRURVLW\GDWDVHWWKH
porosities have a bimodal distribution pattern, and are mainly low porosities account for 46%, the high porosities 37%, and
Pet.Sci.(2014)11:346-362 353

Core porosity, % Kaolinite, wt% Illite, wt% Illite/Smectite, wt% %Smectite in I/S Chlorite, wt% Carbonate cements, wt%
0 10 20 30 40 50 0 20 40 60 80 0 20 40 60 80 0 20 40 60 80 0 20 40 60 80 0 20 40 60 80 0 10 20 30 40 50
1.0 1.0
Es3z
Es3x
Es4s
Es4x
1.5 1.5

Normal
porosity
development
2.0 interval 2.0

Normal evolution
curve of
average porosity
2.5 2.5
Depth, km

Porosity Depth, km
envelope
curve

Abnormally
high porosity
3.0 Anomalously development 3.0
high porosity intervalĉ
zoneĉ

Abnormally
high porosity
3.5 Anomalously development 3.5
high porosity intervalĊ
zoneĊ

4.0 4.0 Es3z Es3z Es3z Es3z Es3z Es3z


Abnormally
Anomalously high porosity Es3x Es3x Es3x Es3x Es3x Es3x
high porosity development Es4s
zone ċ interval ċ Es4s Es4s Es4s Es4s Es4s
Normal evolution curve Es4x Es4x Es4x Es4x Es4x Es4x
of maximum porosity
4.5 4.5

Fig. 6 Vertical distribution of core porosities, clays and carbonate cements in Paleogene Es4-Es3z
reservoirs in the Shengtuo area, the Dongying Sag

the abnormally high porosities 23%. In the AHP development PDLQO\GLVWULEXWHGLQ )LJ 7KHORZSRURVLWLHV
interval III (3,900-4,400 m), the histogram of porosities account for 1%, the high porosities 9%, and the abnormally
distribution shows positive skewness, and the porosities are high porosities 90%.

30 30 30
2800-3200 m 3250-3700 m 3900-4400 m
25 Sample No.: 1203 25 Sample No.: 1105 25 Sample No.: 88
Frequency, %

Frequency, %

Frequency, %

20 20 20

15 15 15

10 10 10

5 5 5

0 0 0
0 4 8 12 16 20 24 28 0 4 8 12 16 20 24 28 0 4 8 12 16 20 24 28
Porosity, % Porosity, % Porosity, %

Fig. 7 Histograms of porosities in different AHP development depth intervals in the Shengtuo area, the Dongying Sag

5 Reservoir pores )RU$+3 ]RQH ,,,  P  WKH SHUFHQWDJH RI


secondary surface porosity in the total surface porosity
In order to determine the type of an AHP zone, the relative is about 100%, but its absolute value is always less than
content and absolute content of primary pores and secondary  &RUH SRURVLWLHV FDQ UHDFK XS WR  )LJ  
SRUHVLQUHVHUYRLUVVKRXOGEHFRQVLGHUHGWRJHWKHU)URP)LJ and polished thin section and SEM samples show that
it can be seen that, with an increase of core porosity, both the PLFURSRUHVLQWKHPDWUL[ )LJ J  K )LJ F GHYHORS
primary thin section porosity and the secondary thin section
and contribute much more to the core porosity than secondary
porosity tend to increase, but the percentage of primary thin
SRUHV$VDUHVXOWWKLV]RQHVKRXOGDOVREHLGHQWL¿HGDVWKH
section porosity increases and the percentage of secondary
primary AHP zone, but with predominantly micropores in the
WKLQ VHFWLRQ SRURVLW\ GHFUHDVHV JHQHUDOO\ )RU$+3 ]RQH ,
matrix.
(2,800-3200 m) and II (3,250-3,700 m), reservoirs with AHP
FRQVLVWPDLQO\RIYLVLEOHSRUHV )LJ D  E )LJ D  E  The pores in high porosity sandstones in different AHP
and the content of micropores is much less than that of visible development depth intervals are complex, and the reservoir
pores. In reservoirs with AHP, primary pores dominate the VSDFHFRQVLVWVRIQRWRQO\SULPDU\SRUHV )LJ)LJ E 
visible pores and account for 50%-90% of the total visible (e)), but sometimes secondary pores. However, for the low
SRUHV )LJ VR$+3]RQHV,DQG,,VKRXOGEHSULPDU\$+3 porosity reservoirs, due to strong compaction or extensive
zones. The secondary surface porosity in reservoirs with AHP carbonate cementation, the reservoir space consists just a
ranges from 0.5% to 3.0%. Micropores in authigenic clays small proportion of secondary pores or matrix micropores
DOVRGHYHORSZKHQVLJQL¿FDQWGLVVROXWLRQSRUHVGHYHORS )LJ)LJ F  I  L DQGYLVLEOHSRUHVGRQRWGHYHORS
354 Pet.Sci.(2014)11:346-362

Percentage of primary Percentage of secondary


Primary Secondary
surface porosity in total surface porosity in total Porosity
surface porosity, % surface porosity, % Core porosity, %
surface porosity, % surface porosity, % intervals
0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 20 40 60 80 0 20 40 60 80 100 0 10 20 30 40 50
1.5 1.5

2.0 2.0
Normal
porosity
development
interval
Normal evolution
curve of
2.5 2.5 average porosity
Porosity
envelope
curve
Depth, km

Depth, km
Abnormally
Primary high porosity
3.0 3.0 abnormally
development
high porosity intervalĉ
zoneĉ

Abnormally
Primary high porosity
3.5 3.5 abnormally development
high porosity intervalĊ
zoneĊ

4.0 4.0 Primary


abnormally Abnormally
high porosity high porosity
zone ċ development
2% 2% interval ċ
Normal evolution curve
1% 1%
4.5 of maximum porosity
4.5
Anomalously high porosity reservoir High porosity reservoir Low porosity reservoir

Fig. 8 Core plug porosity, secondary surface porosity, percentage of secondary surface porosity in total surface porosity and
percentage of primary surface porosity in total surface porosity in Paleogene Es4-Es3z reservoirs in the Shengtuo area, Dongying
6DJ)RUHDFKFRUHSRURVLW\VDPSOHWKHUHDUHPDWFKHGWKLQVHFWLRQDQGUHGHSR[\UHVLQ±LPSUHJQDWHGWKLQVHFWLRQ

Anomalously high porosity sandstones High porosity sandstones Low porosity sandstones
porosity development interval Ⅰ
(2800m-3200m) Abnormally high

(a) 200ȝP (b) 100ȝP (c) 200ȝP


Tuo76, 2942.02 m, ĭ=22.3%; Tuo168, 3098.24 m, ĭ=15.6%; Tuo167, 2969.63 m, ĭ=2.6%;
primary pores (-) primary pores (-) little secondary pores (-)
(3250m-3700m) Abnormally high
porosity development interval Ⅱ

B-1
(d) 200ȝP B-2
(e) 100ȝP B-3
(f) 100ȝP
Tuo720, 3671.1 m, ĭ=14.2%; Tuo73, 3371.25 m, ĭ=10.2%; Tuo73, 3368.4 m, ĭ=3.5%;
primary pores (-) mainly primary pores (-) debris secondary pores (-)
porosity development interval Ⅲ
(3900-4400m) Abnormally high

(g) 200ȝP (h) 200ȝP


5/9/2006 HFW WD Mag 50.0μm (i)
B-3
3 20 47 PM SD 13 μm SD μm

Tuo764, 3949.45 m, ĭ=10.9%; Tuo764, 3951.05 m, ĭ=14.6%; Tuo764, 3950.25 m, ĭ=1.8%;


micropores in matrix dominate (-) micropores in matrix, SEM little debris secondary pores (-)

Fig. 9 Photomicrographs showing pores of Paleogene Es4-Es3z reservoirs with different porosity levels in different AHP development
intervals. (a-g, i): red epoxy resin–impregnated thin section
Pet.Sci.(2014)11:346-362 355

50 50 50
D PP :HOO7P (b) PP Well T720,P, (c) PP Well T764,P,
ĭ=22.3%, k P' ĭ=19.0%,k P' ĭ=14.4%,k P'
40 Well T126,P, 40 Well T76,P, 40 Well T764,P,
Percentage, %

Percentage, %

Percentage, %
ĭ=16.6%,k P' ĭ=12.9%,k P' ĭ=6.1%,k P'
Well T167,P, Well T73,P, Well 764,P,
30 ĭ=4.6%,k P' 30 ĭ=3.5%,k P' 30 ĭ=1.8%,k P'

20 20 20

10 10 10

0 0 0

1030
16.0
25.0
40.0
63.0
0.16
0.25
0.40
1.63
1.00
2.60
4.50
6.00
0.000
0.006
0.010
0.016
0.025
0.040
0.63
0.10
4.50
6.00
1030
16.0
25.0
40.0
63.0
.0
0.10
0.16
0.25
0.40
1.63
1.00
2.60
40.0
63.0
.0

0.000
0.006
0.010
0.016
0.025
0.040
0.63
1.63
1.00
2.60
4.50
6.00
1030
16.0
25.0
0.000
0.006
0.010
0.016
0.025
0.040
0.63
0.10
0.16
0.25
0.40

.0
0
0
0

0.
0.
0.

3RUHUDGLXVȝP Pore radius, ȝP Pore radius, ȝP


Micro pores Macro pores Micro pores Macro pores Micro pores Macro pores

AQRPDORXVO\KLJKSRURVLW\VDQGVWRQHV +LJKSRURVLW\VDQGVWRQHV /RZSRURVLW\VDQGVWRQHV

Fig. 10 Pore-throat radius distribution of Paleogene Es4-Es3z reservoirs with different porosity levels in
different AHP development intervals

6 Genesis of AHP zones 1) Fluid inclusions


Quartz overgrowths are common in reservoirs and their
WKLFNQHVVJHQHUDOO\UDQJHVIURPȝPWRȝP$VSUHVVXUH
6.1 Diagenetic environment and mineral dissolution dissolution was weak, the quartz cements probably mainly
originate from feldspar dissolution (Yuan et al, 2013a). Th of
6.1.1 Diagenetic environment ÀXLGLQFOXVLRQVLQTXDUW]RYHUJURZWKVFRQFHQWUDWHVLQƒ&
)HOGVSDU GLVVROXWLRQ FDUERQDWH dissolution, authigenic -130 °C and 160 °C -180 °C (Table 2), respectively, indicating
kaolinite and quartz cements indicate that reservoirs that reservoirs experienced two stages of feldspar dissolution
experienced an acidic diagenetic environment; and quartz and product precipitation in the diagenetic process. This
dissolution, feldspar overgrowths, carbonate cements are FDQDOVREHYHUL¿HGE\WKHWZRVWDJHVRITXDUW]RYHUJURZWKV
symbols that reservoirs experienced an alkaline diagenetic LQWKLQVHFWLRQV )LJ J 7KHVDOLQLW\RIIOXLGLQFOXVLRQV
environment (Zhou et al, 2011). With extensive feldspar usually exceeds 10%. The high Th and salinity indicate a weak
dissolution and weak quartz dissolution in Paleogene LQÀXHQFHRIPHWHRULFZDWHURQIHOGVSDUOHDFKLQJ 7DEOH VR
we conclude that feldspar dissolution and authigenic quartz
reservoirs, we focus on the acidic diagenetic environment that
cementation in Es4-Es3z reservoirs occurred in a deep burial
is critical to secondary pores. diagenetic environment.

Table 2)OXLGLQFOXVLRQVGDWDRITXDUW]RYHUJURZWKVLQ3DOHRJHQH(V4UHVHUYRLUVLQWKH6KHQJWXRDUHD 'DWDIURPWKH*HRORJLFDO6FLHQWL¿F


5HVHDUFK,QVWLWXWHRI6,123(&6KHQJOL2LO¿HOG&RPSDQ\

Size, Vapor phase, Salinity,


Well No. Depth, m Strata Host minerals Type Th, °C Tice, °C
ȝP vol.% %NaCl

Tuo719 3562.1 Es4s Quartz overgrowth Salt-water 7 6 103.7 -10.4 14.4

Tuo719 3562.1 Es4s Quartz overgrowth Salt-water 4 5 124.4 -8.0 11.7


s
Tuo719 3562.1 Es4 Quartz overgrowth Salt-water 7 10 128.1 -6.9 10.4
s
Tuo719 3562.1 Es4 Quartz overgrowth Salt-water 5 7 179.6 -13.5 17.3
s
Tuo762 3451 Es4 Quartz overgrowth Salt-water 6 9 168.7 -6.2 9.5

2) Fluid pressure at 40 Ma and in Es3z reservoirs at 14 Ma (Tang, 2007; Sun,


With disequilibrium compaction, hydrocarbon generation 2010) when the reservoir burial depth exceeded 2,200 m. In
and clay dehydration, fluid overpressure developed in the source rocks, kerogen began to generate large amounts of
Es4-Es3z reservoirs in the Shengtuo area, especially in the organic acids and CO2 when the depth exceeded 2,000 m. So
sublacustrine fans (Zhang et al, 2009). According to the ZKHQVLJQL¿FDQWRUJDQLFDFLGVDQG&22 were expelled into the
PHDVXUHGÀXLGSUHVVXUHGDWDZHDNÀXLGRYHUSUHVVXUHEHJDQ reservoirs, overpressure was generated. This suggested that
to develop at 2,000 m in the northern steep slope zone, and feldspar dissolution occurred in a relatively closed diagenetic
medium-strong fluid overpressure developed commonly V\VWHPZLWKÀXLGRYHUSUHVVXUH
ZKHQWKHEXULDOGHSWKH[FHHGHGP )LJ $FFRUGLQJ 3) Thermal evolution of organic matter and acidic fluid
WRHYROXWLRQKLVWRU\RIÀXLGSUHVVXUHLQWKH6KHQJWXRDUHD )LJ source
12), fluid overpressure began to develop in Es4 reservoirs )URPƒ&WRƒ&WKHNHURJHQYLWULQLWHUHIOHFWDQFH
356 Pet.Sci.(2014)11:346-362

Fluid pressure, MPa Fluid pressure coefficient R o, % Temperature, °C CO2 in natural gas, %

0 10 20 30 40 50 60 0.6 0.8 1.0 1.2 1.4 1.6 1.8 0 0.5 1.0 1.5 0 50 100 150 0 5 10 15 20
1.0
0.35 0.7 1.3

1.5

2.0

2.5 B sub-stage
Depth, km

of eogenesis

3.0
Early-A sub-stage
of mesogenesis

3.5

Late-A sub-stage
of mesogenesis
Hydrostatic pressure
4.0

4.5

Fig. 11'LVWULEXWLRQRIPHDVXUHGÀXLGSUHVVXUHNHURJHQYLWULQLWHUHÀHFWDQFH Ro), formation temperature and CO2


contents in the northern steep slope zone of the Dongying Sag

(Ro) is 0.35%-0.70% in the diagenetic stage from period B authigenic kaolinite and quartz overgrowths with red epoxy
of the eogenetic stage to sub-period A1 of the mesogenetic UHVLQ±LPSUHJQDWHGWKLQVHFWLRQV)LJVKRZVWKDWZLWKRXW
stage. Thermal evolution of organic matter can generate calibration of kaolinite micropores, the difference between the
large amounts of organic acids and CO2 )LJ  7KHVH contents of feldspar pores and byproducts is generally below 0.
acidic fluids expelled into reservoirs from source rocks He and Nan (2004) found authigenic kaolinite microporosity
by compaction and overpressure related to hydrocarbon to be 25%-50%. With an average value of 37%, we made the
generation and clay dehydration should be the most likely correction of kaolinite content. Then, the difference between
source of acids for stage-I feldspar leaching. The stage-II contents of feldspar pores and byproducts was generally less
feldspar dissolution mainly occurred at 160 °C to 180 °C. WKDQDQGXVXDOO\YHU\FORVHWR )LJ 7UDQVIHU
When the temperature exceeded 160 °C, the degradation of of the dissolution byproducts out of the sandstones may take
organic matter in source rocks generated CO2. Meanwhile, place during dissipation of overpressure, resulting in some
the organic acid generated earlier experienced intense enhanced porosity. However, the data demonstrate that, in a
decarboxylation, and its concentration decreased sharply. UHODWLYHO\FORVHGV\VWHPVLJQL¿FDQWIHOGVSDUSRUHVH[LVWEXW
CO 2 generated in these processes diffused into the pore the feldspar dissolution has little impact on porosity. The main
water and released H+, which controlled the pH and provided function of feldspar dissolution is converting primary pores
acidic fluids for the stage II feldspar leaching (Surdam et into isovolumetric feldspar secondary pores and micropores
al, 1989). CO 2 detected in the fluid inclusions in quartz in authigenic clays.
overgrowths also suggests the formation of these cements in In relatively closed diagenetic systems, the feldspar
the presence of CO2 (Chen et al, 2010). In addition, in the oil- dissolution products cannot be effectively removed from the
gas reservoirs below 4,000 m, the low CO2 content indicates sandstones. Precipitation occurs in forms of authigenic clay
the consumption of CO2E\IHOGVSDUGLVVROXWLRQ )LJ  minerals (kaolinite and illite) and quartz cements in situ, and
6.1.2 Little porosity enhancement from feldspar the maximum enhanced porosity by dissolution of one unit
dissolution volume of K-feldspar, albite and anorthite is 13%, 7% and
Whether feldspar dissolution can effectively increase 4%, respectively (Giles and de Boer, 1990). The maximum
the reservoir porosity depends on whether the dissolution amount of feldspar pores in reservoirs in the Shengtuo area
byproducts can be removed from the dissolution area. The is about 3%, then, the maximum enhanced porosity due to
feldspar dissolution in Es 4-Es 3z reservoirs occurred in a feldspar dissolution (suppose all are K-feldspars) is just 0.4%
relatively closed diagenetic system with high temperature and (3%×13%=0.4%), which is in consistent with the statistical
salinity. We can also determine this from microscopy, which data.
shows that if the feldspar dissolution is weak, the dissolution 6.1.3 Little dissolution of carbonate minerals
byproducts are less; if feldspar dissolution is abundant, the Based on the negative relationship between core porosity
dissolution byproducts are abundant. To objectively evaluate and the amount of carbonate cements, Zhong et al (2003),
the impact of feldspar dissolution on reservoir porosities, Zhu et al (2007) and Zhang et al (2007) argued that the low
using interactive image analysis techniques, quantitative content of carbonate cements in the high porosity reservoirs
statistics were collected for the contents of feldspar pores, LQWKH6KHQJWXRDUHDRULJLQDWHGIURPVLJQL¿FDQWGLVVROXWLRQRI
Pet.Sci.(2014)11:346-362 357

Tectonic stage Rifting stage Tectonic uplift stage Depression period


Age, Ma 50 40 30 20 10 0

Es4s
Es3x

Es3z
Es3s
Stratigraphy Es4x Es2 Es1 Ed Ng Nm Q
0 20 ņ
40 ņ
1 60 ņ
Burial and thermal history

80 ņ
Depth, km

2 100 ņ
120 ņ

3 140 ņ

160 ņ
4
Well Tuo-764
160 ņ
1.8
Pressure increasing stage Pressure stable Pressure decreasing Pressure increasing stage due to
1.6 due to low compaction stage with stage with hydrocarbon generation with
Pressure evolution and oil
charging history in Es3x-Ex3z

with rapid subsidence slow subsidence tectonic uplift relative rapid subsidence
Pressure coefficient

1.4

1.2

1.0 Oil charging periodⅠ


(35-26Ma)
Oil charging periodⅡ (13.8-0Ma)
Normal-weak Hydrocarbon charging
0.8 Medium-high overpressure
overpressure intermission period
accumulation system
accumulation system
1st period hydrocarbon including fluid 1st period hydrocarbon including fluid
Es3x-Ex3z 2nd period hydrocarbon including fluid Es4 2nd period hydrocarbon including fluid
Present formation fluid Present formation fluid

1.8 Normal pressure Pressure increasing stage Stable pressure Pressure decreasing Pressure increasing stage due to
stage with rapid due to low compaction stage with stage with hydrocarbon generation with
1.6 subsidence with rapid subsidence slow subsidence tectonic uplift relative rapid subsidence
and hydrocarbon
Pressure evolution and oil
charging history in Es4

generation
Pressure coefficient

1.4

1.2

Oil charging period


1.0 Ⅰ(39-31.9Ma)
Weak-medium
Hydrocarbon charging Oil charging periodⅡ(13-0Ma)
overpressure
0.8 intermission period Medium-high overpressure
accumulation
accumulation system
system

Fig. 12 Burial and thermal history, fluid pressure evolution history and hydrocarbon charging history of
VXEODFXVWULQHIDQVLQWKH6KHQJWXRDUHD 'DWDRIK\GURFDUERQFKDUJLQJKLVWRU\DQGÀXLGSUHVVXUHHYROXWLRQKLVWRU\
from Cai et al (2009) and Sun (2010))

FDUERQDWHFHPHQWVDQGWKHVLJQL¿FDQWLQWHUJUDQXODUSRUHVDUH These phenomena demonstrate that carbonate cements and


mainly carbonate cement dissolution pores. detrital carbonate grains were not noticeably corroded. As no
With observation of nearly 200 thin sections and red HYLGHQFHVKRZVVLJQL¿FDQWGLVVROXWLRQRIFDUERQDWHFHPHQWV
epoxy resin–impregnated thin sections and 55 SEM samples a large number of intergranular pores are likely to be primary
in the Shengtuo area, we found carbonate cements occur as intergranular pores instead of carbonate cement dissolution
FRQQHFWHG SDWFKHV )LJ  D  VLQJOH FU\VWDO )LJ  J  RU pores. The most likely reason for the negative relationship
JUDLQFRDWLQJFDUERQDWH )LJ F  I DQGFRPPRQO\H[KLELW between porosity and percent carbonate cements should be
HXKHGUDOFU\VWDOIDFHVZKHUHDEXWWLQJRSHQSRUHVSDFH )LJ the carbonate cementation degree, rather than the carbonate
5(h)). The euhedral dolomite coated with stage-II quartz cement dissolution degree.
RYHUJURZWKV )LJ  J  VXJJHVWV WKDW FDUERQDWH PLQHUDOV About the selective dissolution phenomena between
were not leached when stage-II feldspar dissolution and feldspars and carbonate minerals, we explain this as follows:
quartz cement precipitation took place. In addition, detrital 1) At depths of 2,500-3,500 m, the formation temperature
carbonate grains and grain coating carbonate cements show in the Dongying Sag is about 100 °C-130 °C, and the Ro of
QR HYLGHQFH RI GLVVROXWLRQ )LJ  F  I 7KH FDUERQDWH NHURJHQLQVRXUFHURFNVLVZKLFKDUHEHQH¿FLDO
overgrowths are often found accompanying detrital carbonate for the generation and preservation of organic acids. Organic
JUDLQV )LJ  E  +RZHYHU IHOGVSDU JUDLQV ZUDSSHG E\ acids control the alkalinity of pore water, and the pCO2 is
early grain coating carbonate cements or close to detrital UHODWLYHO\KLJK )LJ ,QVXFKDQRUJDQLFDFLGV±FDUERQLF
FDUERQDWHJUDLQVZHUHGLVVROYHGH[WHQVLYHO\ )LJ F  I  acid–pCO2–carbonate minerals–aluminum silicate minerals
358 Pet.Sci.(2014)11:346-362

Feldspar pores, % Kaolinite, % Quartz overgrowth, % A, % B, %


0 1 2 3 0 1 2 3 0 0.2 0.4 0.6 0.8 1 -1 0 1 -0.5 0 0.5 1.0
1.9

2.1

2.3
Depth, km

2.5

2.7

2.9

3.1

3.3
A, %: Difference between feldspar pore content and dissolution byproducts;
B, %: Difference between feldspar pore content and 62.5% of kaolinite content and quartz overgrowth content

Fig. 13 Amount of feldspar pores, dissolution products, and their differences in Es4-Es3z reservoirs

buffer system, the carbonate minerals tend to be precipitated 5) The calculation of Meshri (1986) shows that at 25 °C
rather than to be corroded, but the feldspars tend to be leached DQGEDUWKH*LEEVIUHHHQHUJ\ ǻG) for leaching of anorthite
(Surdam et al, 1989). and K-feldspar by acetic acid to form kaolinite is –36.9 kJ/
2) Thick gypsum and salt layers and carbonate layers PRODQG±N-PRODQGǻG of the reaction between calcite
exist in the Palaeogene Es4 )RUPDWLRQ DQG VXJJHVW D KLJK and acetic acid is +11.20 kJ/mol. Meanwhile, as temperature
salinity and strong alkalinity of the sedimentary water (Wang, DQG SUHVVXUH LQFUHDVHǻG of reaction between organic
 6DOLQLW\GDWDRIÀXLGLQFOXVLRQVLQTXDUW]RYHUJURZWKV acid and feldspars decreases (Huang et al, 2009b), while as
LQGLFDWHWKHOHDFKLQJRIIHOGVSDUVE\DFLGLFÀXLGVZLWKKLJK temperature increases, the solubility of carbonate minerals
salinity (Table 2). The modern pore water in reservoirs has decreases sharply. Therefore, in a relatively closed diagenetic
high salinity, and the concentration of Ca2+ and Mg2+ is high environment with high temperature, the organic acids tend to
)LJ +LJKVDOLQLW\DQGKLJKFRQFHQWUDWLRQRI&D2+ and dissolve feldspars rather than carbonate minerals.
Mg2+ probably inhibit carbonate dissolution, and promote its
precipitation due to the common-ion effect. 6.2 Geological processes in favor of porosity
3) The main source rocks in the Dongying Sag contain preservation
high percentage of carbonate minerals (up to 50%), feldspars
6.2.1 Sedimentary facies
DQGRWKHUXQVWDEOHPLQHUDOV 4LDQHWDO )LQHXQVWDEOH
minerals with high specific surface area in source rocks Statistical data show that sedimentary facies in the
UHDFWHG¿UVWZLWKWKHRUJDQLFDFLGVWKDWZHUHUHOHDVHGGXULQJ Shengtuo area have significant influence on the reservoir
thermal evolution of organic matter due to their proximity porosity. On the whole, porosities of sublacustrine fan
(Giles and Marshall, 1986). In addition, the initial salinity of reservoirs are higher than those of nearshore subaqueous
SRUHZDWHUZDVKLJKVRÀXLGH[SHOOHGIURPVRXUFHURFNVLQWR fans, which might be related to the fluid overpressure in
reservoirs would be rich in various ions. As the fluid with VXEODFXVWULQH IDQV )RU H[DPSOH LQ$+3 GHYHORSPHQW
high salinity and weak acidity entered into the reservoirs, its intervals I and II, reservoirs in sublacustrine fans have an
acidity decreased further, in such condition, the carbonate average porosity of 15.03% and 10.72%, while the average
minerals tended to be precipitated, rather than be dissolved porosity of reservoirs in nearshore subaqueous fans is
(Zeng, 2001). just 10.43% and 6.43% (Table 3). In sublacustrine fans,
4) The study by Song and Huang (1990) shows that porosities of reservoirs in braided channels in the mid-fan
carbonate minerals may precipitate at a pH between 5 and are the best, followed by porosities of main channels inner-
6, although most scholars argued that carbonate minerals fan, and porosities of outer fan and inter-channels in mid-
begin to precipitate when pH exceeds 8.4. In addition, the fan are the worst. In nearshore subaqueous fans, porosities of
calculation results by Huang et al (2009a) show that, for reservoirs in middle-front of fan body are the best, porosities
carbonate dissolution in deep buried reservoirs (>3,000 m), of reservoirs in root of fan body and fan edge are worse (Table
the pH of fluid should be lower than 5. However, CaCl2- 3).
type pore water with high salinity of the relatively stagnant 6.2.2 Fluid overpressure
environment in the Shengtuo area is generally weakly acidic The fluid pressure in the Es4 formation experienced five
ZLWKS+EHWZHHQDQG )LJ ZKLFKLVQRWIDYRUDEOHIRU stages: 1) normal pressure stage with rapid subsidence at 49-
carbonate dissolution in deep burial. 40 Ma, 2) pressure increase stage due to low compaction with
Pet.Sci.(2014)11:346-362 359

pH K+ & Na+, mg/L Ca2+, mg/L Mg2+, mg/L Clí, mg/L SO 42í, mg/L HCO3í , mg/L Total salinity, mg/L Water type
6.0 7.0 1000 100000 100 10000 10 1000 1000 100000 100 1000 100 10000 1000 100000 CaCl2 NaHCO3 MgCl2
1.5

2.0

2.5
Depth, km

3.0

3.5
Es3s
Es3z
Es3x
Es4s
Es4x
4.0

Fig. 14 Characteristics of pore water in Palaeogene Es4-Es3 formation

Table 35HVHUYRLUSRURVLW\RIGLIIHUHQWVHGLPHQWDU\IDFLHV PLFURIDFLHV ÀXLGSUHVVXUHDQGRLOLQHVVLQGLIIHUHQW$+3GHYHORSPHQWLQWHUYDOV

Sedimentray facies )OXLGSUHVVXUH Oiliness of sandstones


Contro
olling
Controlling
fa
actors
factors Nearshore subaqueous fan Normal
Sublacustrine fan
Medium Strong Oil
Root of Middle- Main -weak No oil, Oil
Braided Inter over- over- immersion,
P
Porosity Total
Tot fan front of )DQHGJH Total water )DQHGJH over- oil trace spot
channel channel pressure pressure oil bearing
i
intervals Porosity
Poro
osity body fan body channel pressure

Min, %
M 1.0
1. 1.0 2.6 1.9 1.4 3.5 1.4 1.7 1.8 1.0 1.8 1.4 1.0 1.4 2.9
Abnormally
high porosity Max, % 22.0 19.2 22.0 23.6 29.5 19.7 29.5 21.1 19.9 27.0 19.9 29.5 26.9 23.8 29.5
development Ave, % 10.43 7.46 12.92 6.62 15.03 10.33 17.70 8.34 9.02 11.20 11.62 15.39 10.22 11.35 16.55
interval ĉ
Sample No. 516 50 302 164 873 78 595 27 173 426 294 669 363 425 601

Min, % 0.7 0.7 1.8 2.9 1.1 1.5 1.6 1.2 1.1 0.7 1.1 1.2 0.7 1.3 1.5
Abnormally
high porosity Max, % 20.9 8.8 20.9 20.9 32.9 28.1 32.9 16.8 19.9 11.4 22.1 32.9 22.1 28.1 32.9
development Ave, % 6.43 3.57 8.60 11.06 10.72 9.66 12.55 6.89 7.16 5.27 10.18 11.92 6.44 10.02 13.63
interval Ċ
Sample No. 171 71 70 30 793 166 451 93 83 142 544 278 345 293 326

Min, % ʊ ʊ ʊ ʊ 1.8 ʊ 1.8 ʊ ʊ ʊ 1.8 ʊ 1.8 6.1 8.6


Abnormally
high porosity Max, % ʊ ʊ ʊ ʊ 22.3 ʊ 22.3 ʊ ʊ ʊ 22.3 ʊ 13.9 22.3 21.7
development Ave, % ʊ ʊ ʊ ʊ 15.12 ʊ 15.12 ʊ ʊ ʊ 15.12 ʊ 9.56 14.71 16.22
interval ċ
Sample No. ʊ ʊ ʊ ʊ 88 ʊ 88 ʊ ʊ ʊ 88 ʊ 11 13 64

rapid subsidence and hydrocarbon generation at 40-31.9 Ma, development at 35-24.6 Ma. Moderate-strong overpressure
3) stable pressure stage with slow subsidence at 31.9-24.6 EHJDQWRGHYHORSDIWHUDERXW0D )LJ  &DLHWDO 
Ma, 4) pressure decrease stage with tectonic uplifting at 24.6- :KHQÀXLGRYHUSUHVVXUHEHJDQWRGHYHORSWKHEXULDOGHSWKV
14 Ma and 5) pressure increase stage due to hydrocarbon of sublacustrine fan reservoirs in Es3 and Es 4 are always
JHQHUDWLRQZLWKUHODWLYHO\UDSLGVXEVLGHQFHDW0D )LJ shallower than 2,200 m. The shallow development of fluid
12) (Zhang et al, 2009; Sun, 2010). overpressure retarded compaction during deeper burial and
Before 13 Ma, fluid pressure in sublacustrine fans in pores in reservoirs were preserved to greater depths.
Es 3 was generally normal, but with weak overpressure Data in Table 3 show that as fluid overpressure
360 Pet.Sci.(2014)11:346-362

increases, the average porosity of reservoirs in the three 7 Conclusions


AHP development intervals increases significantly. In AHP
development interval I, reservoirs with normal-weak pressure 1) Three AHP zones developed in Palaeogene Es4-Es3z
KDYHDQDYHUDJHSRURVLW\RIWKRVHZLWKPLGGOHÀXLG reservoirs in the Shengtuo area of the Dongying Sag, at
overpressure have an average porosity of 11.62%, and those depths of 2,800-3,200 m, 3,250-3,700 m and 3,900-4,400 m,
with high fluid overpressure have an average porosity of respectively.
15.39% (Table 3). In AHP development interval II, reservoirs 2) AHP zones at depths of 2,800-3,200 m and 3,250-3,700
ZLWKQRUPDOÀXLGSUHVVXUHDQGZHDNÀXLGRYHUSUHVVXUHKDYH m are visible pore primary AHP zones, with visible primary
an average porosity of 5.27%, those with middle overpressure intergranular pores dominating. AHP zones at the depth of
have an average porosity of 10.18%, and those with strong 3,900-4,400 m are micropores primary AHP zones, with
overpressure have an average porosity of 11.92% (Table 3). In micropores in matrix dominating.
$+3GHYHORSPHQWLQWHUYDO,,,DOOUHVHUYRLUVKDYHPLGGOHÀXLG 3) In the relatively closed diagenetic system with high
overpressure, and the average porosity is up to 15.12% (Table temperature and salinity, burial dissolution contribute
3). So we can say that the shallow development of fluid little to the AHP zone due to low porosity enhancement
overpressure effectively retarded the compaction, leading to by feldspar dissolution and little dissolution of carbonate
point contact and line-point contact of detrital grains in deeply cements. Reservoirs in braided channels of middle fans
EXULHGUHVHUYRLUV )LJ D  J 7KXVVKDOORZGHYHORSPHQW in sublacustrine fans and reservoirs in middle-front of fan
RIÀXLGRYHUSUHVVXUHLVRIVLJQL¿FDQFHWRWKHGHYHORSPHQWRI bodies of nearshore subaqueous fans provided the basis for
AHP zones in deeply buried strata. WKHGHYHORSPHQWRI$+3]RQHV6KDOORZGHYHORSPHQWRIÀXLG
6.2.3 Hydrocarbon emplacement overpressure and early hydrocarbon emplacement preserved
high porosity in deep layers by inhibiting compaction and
Hydrocarbon emplacement in Es4 reservoirs occurred
carbonate cementation effectively during deep burial. Thus,
PDLQO\ DW  0D DQG  0D )LJ   6XQ  
the favorable exploration targets should be reservoirs with
Hydrocarbon emplacement in Es3x-Es3z reservoirs occurred
good primary porosity that experienced fluid overpressure
PDLQO\ DW  0D DQG  0D )LJ   &DL HW
developed from shallow layers, early hydrocarbon
al, 2009), and the second stage is more important. When
emplacement, and good preservation during later burial.
hydrocarbon emplacement took place, the reservoirs were
always shallower than 2,500 m. The early hydrocarbon Acknowledgements
emplacement inhibited carbonate cementation during late
burial and reservoir pores were preserved to deeper depth. This study was financially supported by the National
Data in Table 3 show that as oil saturation increases, the 1DWXUDO6FLHQFH)RXQGDWLRQRI&KLQD 1R81R
average porosity of reservoirs in the three AHP development 41102058), a National Science and Technology Special Grant
intervals increases sharply, and carbonate cement content 1R=; DQG)RXQGDWLRQIRUWKH$XWKRURI
decreases significantly. In AHP development interval I, National Excellent Doctoral Dissertation of China. We also
reservoirs with no oil, fluorescence or oil trace have an thank the following individuals and institutions: Jon Gluyas
average porosity of 10.22% and an average carbonate cement of Durham University, Meng Yuanlin of Northeast Petroleum
content of 11.22%. Reservoirs with oil spots have an average University, Zhu Guohua in the Hangzhou Institute of
porosity of 11.35% and an average carbonate cement content Petroleum Geology, CNPC, and reviewers of this manuscript.
of 12.32%. Oil saturated or oil rich reservoirs have an 7KH6KHQJOL2LO¿HOG&RPSDQ\RI6,123(&SURYLGHGDOOWKH
average porosity of 16.55% and an average carbonate cement related core samples and some geological data.
content of 6.99% (Table 3). In AHP development interval
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