LAMPIRAN

Lampiran 1. Pembuatan Larutan

1. Larutan NaOH 6M 250 mL 3. Larutan Na2CO3 2M 100 mL
𝑛 𝑚𝑎𝑠𝑠𝑎⁄ 𝑛 𝑚𝑎𝑠𝑠𝑎⁄
𝑀𝑟 𝑀𝑟
M=𝑉= M=𝑉=
𝑉 𝑉

Massa = M × V × Mr Massa = M × V × Mr
𝑚𝑜𝑙 𝑔𝑟𝑎𝑚 𝑚𝑜𝑙 𝑔𝑟𝑎𝑚
Massa = 6 × 0.25 L × 40 Massa = 2 × 0.1 L × 106
𝐿 𝑚𝑜𝑙 𝐿 𝑚𝑜𝑙

Massa = 60 gram Massa = 21.194 gram

2. Larutan H2SO4 3M 100 mL (H2SO4 4. Larutan HNO3 2M 100 mL (HNO3

98%) 65%)
10.%.𝜌 10.98.1,84 10.%.𝜌 10.98.1,51
M= = = 18.4 M M= = = 15.6 M
𝑀𝑟 98 𝑀𝑟 63

M1V1 = M2V2 M1V1 = M2V2

18.4 M. V1 = 3 M. 100 ml 15.6 M. V1 = 2 M. 100 ml
3𝑀.100𝑚𝑙 2𝑀.100𝑚𝑙
V1 = = 16.31 ml V1 = = 12.837 ml
18.4𝑀 15.6𝑀

Lampiran 2. Pembuatan Larutan Induk Fe(NO3)3

1. Larutan Fe(NO3)3 1000 ppm 25 mL
𝑚𝑎𝑠𝑠𝑎(𝑚𝑔) Massa yang ditimbang:
ppm = 𝑉(𝐿)
𝑀𝑟.Fe(NO3)3.9H2O
𝑚𝑎𝑠𝑠𝑎 massa = ×gram ppm
1000 ppm = 0.025𝐿 𝐴𝑟.𝐹𝑒
403.9 𝑔𝑟/𝑚𝑜𝑙
massa = 25 mg = 0.025 gram massa = × 0.025 𝑔𝑟𝑎𝑚 =
55.85 𝑔𝑟/𝑚𝑜𝑙

0.18079 gram
2. Larutan Fe(NO3)3 100 ppm 25 mL 4. Larutan Fe(NO3)3 50 ppm 25 mL
ppm.V1 = ppm.V2 ppm.V1 = ppm.V2
1000ppm. V1= 100 ppm.25 mL 75ppm. V1= 50 ppm.25 mL
V1 = 2.5 mL V1 = 16.67 mL

3. Larutan Fe(NO3)3 75 ppm 25 mL 5. Larutan Fe(NO3)3 25 ppm 25 mL

ppm.V1 = ppm.V2 ppm.V1 = ppm.V2
100ppm. V1= 75 ppm.25 mL 50ppm. V1= 25 ppm.25 mL
V1 = 18.75 mL V1 = 12.50 mL
6. Larutan Fe(NO3)3 10 ppm 25 mL
ppm.V1 = ppm.V2
25ppm. V1= 10 ppm.25 mL
V1 = 10 mL

Lampiran 3. Data Hasil Absorbansi

1. Data absorbansi larutan induk Fe(NO3)3
Larutan Fe(NO3)3
Panjang
Gelombang Konsentrasi(ppm) Absorbansi (1) Absorbansi (2) Rata-rata 𝑥̅

480 nm 10 0.049 0.048 0.0485

480 nm 25 0.101 0.101 0.101
480 nm 50 0.181 0.181 0.181
480 nm 75 0.277 0.277 0.277
480 nm 100 0.304 0.303 0.3035

2. Data absorbansi sampel

Panjang Rata-rata 𝑥̅
Sampel Absorbansi (1) Absorbansi (2)
Gelombang
Kel. 1-2 480 nm 0.110 0.109 0.1095
Kel. 3-6 480 nm 0.219 0.217 0.218
Kel. 7-8 480 nm 0.230 0.223 0.2265

3. Grafik Hukum Lambert-Beer Konsentrasi Larutan Fe(NO3)3 terhadap Absorbansi

Grafik Hukum Lambert-Beer Konsentrasi Larutan Fe(NO3)3

terhadap Absorbansi
0.35
y = 0.003x + 0.0279
0.3
R² = 0.9739
Absorbansi (Ǻ)

0.25
0.2
0.15 y
0.1 Linear (y)
0.05
0
0 20 40 60 80 100 120
Konsentrasi (ppm)
Lampiran 4. Kadar Fe dalam Sampel Fe(NO3)3
y = 0.003x + 0.0279
0.2265 = 0.003x + 0.0279
0.003 x = 0.1986
0.1986
x= = 66.2 ppm
0.003

Maka, kadar Fe dalam sampel water glass kel.7-8 sebesar 66.2 ppm.

Lampiran 5. Pemisahan dan Pemurnian NaCl

1. Sampel ditambahkan akuades
𝑚𝑎𝑠𝑠𝑎 𝑎𝑤𝑎𝑙−𝑚𝑎𝑠𝑠𝑎 𝑠𝑒𝑡𝑒𝑙𝑎ℎ 𝑝𝑒𝑚𝑎𝑛𝑎𝑠𝑎𝑛
%Fe2O3 yang hilang = × 100%
𝑚𝑎𝑠𝑠𝑎 𝑎𝑤𝑎𝑙
6,0004𝑔 −3,6883 𝑔
%Fe2O3 yang hilang = × 100% = 38,53%
6,0004 𝑔

2. Sampel ditambahkan larutan HNO3

𝑚𝑎𝑠𝑠𝑎 𝑎𝑤𝑎𝑙−𝑚𝑎𝑠𝑠𝑎 𝑠𝑒𝑡𝑒𝑙𝑎ℎ 𝑝𝑒𝑚𝑎𝑛𝑎𝑠𝑎𝑛
%NaCl yang hilang = × 100%
𝑚𝑎𝑠𝑠𝑎 𝑎𝑤𝑎𝑙
6,0004 𝑔 − 2,2355 𝑔
%NaCl yang hilang = × 100% = 63,74%
6,0004 𝑔

Lampiran 6. Perhitungan Uji Kemurnian NaCl

1. Standarisasi AgNO3 menggunakan larutan NaCl p.a 0,1N
𝑀𝑁𝑎𝐶𝑙 = 𝑁𝑁𝑎𝐶𝑙 (ekivalen NaCl = 1)
𝑀𝑁𝑎𝐶𝑙 = 0,1 𝑀

Data percobaan:
 VNaCl = 10 mL
 [NaCl] = 1 N = 1M
 𝑉𝐴𝑔𝑁𝑂3 = 10,8 mL

𝑀𝐴𝑔𝑁𝑂3 . 𝑉𝐴𝑔𝑁𝑂3 = 𝑀𝑁𝑎𝐶𝑙 . 𝑉𝑁𝑎𝐶𝑙

𝑀𝐴𝑔𝑁𝑂3 . 10,8 𝑚𝐿 = 0,1 𝑀. 10 𝑚𝐿
0,1 𝑀 . 10 𝑚𝐿
𝑀𝐴𝑔𝑁𝑂3 =
10,8 𝑚𝐿
𝑀𝐴𝑔𝑁𝑂3 = 0,0926 𝑁
2. Penetapan kadar Cl dalam air (metode Mohr)
Data percobaan
 𝑉𝑠𝑎𝑚𝑝𝑒𝑙 𝑁𝑎𝐶𝑙 = 10 𝑚𝐿
 [AgNO3] = 0,0926 M
 𝑉𝑡𝑖𝑡𝑟𝑎𝑠𝑖 9,5 𝑚𝐿 = 9,5. 10−3 𝐿

Mol Cl
𝑚𝑜𝑙𝐶𝑙 = [𝐴𝑔𝑁𝑂3 ] × 𝑉𝑡𝑖𝑡𝑟𝑎𝑠𝑖
𝑚𝑜𝑙𝐶𝑙 = 0,0926 𝑀 × 9,5. 10−3 𝐿
𝑚𝑜𝑙𝐶𝑙 = 0,8797. 10−3 mol

Massa Cl
𝑚𝑎𝑠𝑠𝑎𝐶𝑙 = 𝑚𝑜𝑙𝐶𝑙 × 𝐴𝑟𝐶𝑙
𝑚𝑎𝑠𝑠𝑎𝐶𝑙 = 0,8797.10−3 𝑚𝑜𝑙 × 35,5 𝑔⁄𝑚𝑜𝑙
𝑚𝑎𝑠𝑠𝑎𝐶𝑙 = 0,03123 𝑔

Massa Cl Sampel
𝑉𝑙𝑎𝑏𝑢 𝑢𝑘𝑢𝑟
𝑚𝑎𝑠𝑠𝑎 𝐶𝑙 𝑠𝑎𝑚𝑝𝑒𝑙 = 𝑚𝑎𝑠𝑠𝑎𝐶𝑙 ×
𝑉𝑝𝑖𝑝𝑒𝑡
50 𝑚𝐿
𝑚𝑎𝑠𝑠𝑎 𝐶𝑙 𝑠𝑎𝑚𝑝𝑒𝑙 = 0,03123 𝑔 ×
10 𝑚𝐿

𝑚𝑎𝑠𝑠𝑎 𝐶𝑙 𝑠𝑎𝑚𝑝𝑒𝑙 = 0,15615 𝑔

Kadar (%) Cl
𝑚𝑎𝑠𝑠𝑎 𝐶𝑙
𝐾𝑎𝑑𝑎𝑟 (%) 𝐶𝑙 = × 100%
𝑚𝑎𝑠𝑠𝑎 𝐶𝑙 𝑠𝑎𝑚𝑝𝑒𝑙
0,03123 𝑔
𝐾𝑎𝑑𝑎𝑟 (%) 𝐶𝑙 = × 100%
0,15615 𝑔
𝐾𝑎𝑑𝑎𝑟 (%) 𝐶𝑙 = 20%
 LAMPIRAN

1. Persamaan reaksi water glass

 SiO2 (s) + 2NaOH(aq) → Na2SiO3 (aq) + H2O(l)
 Na2SiO3 + H2O(l) → Na2SiO3 (aq) + H2O(l)
 Na2SiO3 (s) + H2SO4 (aq) → H2SiO3 (l) + Na2SO4 (aq)
 H2SiO3 (l) + Na2CO3 (aq) → Na2SiO3 (aq) + H2CO3 (aq)
2. Persamaan reaksi pemisahan dan pemurnian NaCl & Fe2O3
 (NaCl+Fe2O3) (s) + H2O (l) → NaCl (aq) + Fe2O3 (s) + H2O (l)
𝑑𝑖𝑝𝑎𝑛𝑎𝑠𝑘𝑎𝑛
 NaCl (aq) + H2O (l) → NaCl (s) + H2O (g)
 Fe + HNO3 + 3H+ → Fe3+ + NO + 2H2O
 2Fe3+ (aq) + 3Na2CO3 (aq) → Fe2(CO3)3 (s) + 3Na+(aq)
3. Persamaan reaksi standarisani larutan dan penentuan kadar Cl
 NaCl (aq)+ K2CrO4 (aq) + 3AgNO3(aq) → AgCl (s) + Ag2CrO4 (s) +NaNO3 (aq) + 2KNO3 (aq)