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Latihan Termodinamika Lanjut-Real Systems
Latihan Termodinamika Lanjut-Real Systems
Trial: T, C = 26.16181
PSI 1 = 0.98299
PSI 2 = 1.02076
PSI 3 = 1.06532
PSI 4 = 1.12262
Pi0, Pi0, B,
xi vi xI vi di dav gama i mmHg atm Ki cm3/mol yi
17.83 747.16 1.01992 7265.4 9.5597 3.30630 -386.54 0.66126
29.05 1261.76 1.00247 1887.9 2.4840 0.81317 -699.39 0.24395
46.00 2069.08 1.00263 535.3 0.7044 0.22097 -1165.20 0.08839
13.15 611.74 1.02845 159.3 0.2096 0.06402 -1897.67 0.00640
106.03 4689.74 44.231
B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i del Psi Ki
671.118 856.465 255.605 343.820 443.783 566.346 295.7471 0.98299 0.00000 3.30630
902.734 1152.048 126.842 170.618 220.224 281.044 146.7620 1.02076 0.00000 0.81317
1165.198 1486.998 59.318 79.790 102.988 131.431 68.6336 1.06532 0.00000 0.22097
1486.998 1897.673 5.483 7.375 9.520 12.149 6.3442 1.12262 0.00000 0.06402
447.248 601.602 776.514 990.970 517.4869
Sum Sum yiyjBij
S-H parameters:
di, atm^0,5
41.90
43.44
44.98
46.52
B1j B2j
386.54 519.95
519.95 699.39
671.12 902.73
856.47 1152.05
yi del yi
0.66126
0.24395 0.00000
0.08839 0.00000
0.00640 0.00000
1.00000
Sum yi
Catatan: boleh menghitung del yi atau del Ki, sama saja
Bubble Point Pressure: Non-Ideal Gases and Non-Ideal Liquids
Second Virial Coefficient and Scatchard-Hildebrand
Pi0, Pi0, B,
xi vi xI vi di dav gama i mmHg atm Ki yi cm3/mol B1j B2j
17.832 747.16 1.0197 7980.6 10.5008 3.27682 0.655365 -376.119 376.12 505.48
29.046 1261.76 1.0024 2120.5 2.7901 0.82226 0.2466781 -679.324 505.48 679.32
46.000 2069.08 1.0026 615.3 0.8096 0.22805 0.091219 -1129.074 651.66 875.79
13.150 611.74 1.0281 187.4 0.2466 0.06738 0.0067385 -1832.170 830.13 1115.63
106.028 4689.737 44.23112 1.0000 1.0
B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i Ki yi del yi
651.66 830.13 246.49 331.27 427.08 544.04 285.89 0.98151 3.27682 0.65536 0.00000
875.79 1115.63 124.69 167.57 216.04 275.20 144.62 1.02173 0.82226 0.24668 0.00000
1129.07 1438.28 59.44 79.89 102.99 131.20 68.94 1.06917 0.22805 0.09122 0.00000
1438.28 1832.17 5.59 7.52 9.69 12.35 6.49 1.13007 0.06738 0.00674 0.00000
436.22 586.25 755.80 962.78 505.93 1.00000
Sum Sum yiyjBij
Sum yi
Dew Point Temperature: Non-Ideal Gases and Non-Ideal Liquids
Second Virial Coefficient and Scatchard-Hildebrand
Pi0, Pi0,
mmHg atm Ki xi xi vi xI vi di
16966.93 22.3249 8.11547 0.02464 2.1973 92.0663
5373.02 7.0698 2.42430 0.12375 11.9812 520.4632
1869.65 2.4601 0.80424 0.49737 57.1971 2572.7270
680.11 0.8949 0.28229 0.35424 46.5829 2167.0342
117.9585 5352.2907
Non-Ideal Liquids
B1j B2j B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i
296.93 397.70 506.89 634.31 59.39 79.54 101.38 126.86 88.98 0.95321
397.70 532.68 678.92 849.58 119.31 159.80 203.68 254.88 178.76 0.98483
506.89 678.92 865.32 1082.84 202.76 271.57 346.13 433.13 303.79 1.02029
634.31 849.58 1082.84 1355.03 63.43 84.96 108.28 135.50 95.04 1.06327
444.89 595.87 759.47 950.37 666.56
Sum Sum yiyjBij
Pi0, Pi0,
mmHg atm Ki xi xi vi xI vi di dav gama i Ki
18544.8 24.401 7.80489 0.02562 2.2847 95.7298 1.03865 7.80490
5992.92 7.88541 2.37339 0.12640 12.2382 531.6266 1.01276 2.37339
2129.57 2.80206 0.80197 0.49877 57.3588 2579.9987 1.00059 0.80197
790.386 1.03998 0.28637 0.34920 45.9202 2136.2066 1.00630 0.28637
117.8019 5343.5616 45.3606
R, mL atm/mol/K = 82.057
A - B / (T + C) )
B2j B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i
385.94 491.11 612.98 57.62 77.19 98.22 122.60 86.23 0.94930
516.99 657.87 821.12 115.78 155.10 197.36 246.34 173.26 0.98369
657.87 837.13 1044.88 196.44 263.15 334.85 417.95 293.97 1.02205
821.12 1044.88 1304.17 61.30 82.11 104.49 130.42 91.73 1.06838
431.15 577.54 734.92 917.30 645.19
Sum Sum yiyjBij
xi del xi
0.02562 0.00000
0.12640 0.00000
0.49877 0.00000
0.34920 0.00000
1.00000
Partial Vaporization: Non-Ideal Gases and Non-Ideal Liquids
Second Virial Coefficient and Scatchard-Hildebrand
Pi0, Pi0,
mmHg atm xi yi xi vi xI vi di dav gama i B1j B2j
10072.81 13.25370 0.09880 0.46008 8.809 369.099 1.0255 350.82 470.63
2827.312 3.72015 0.28137 0.34789 27.242 1183.384 1.0050 470.63 631.35
868.3419 1.14256 0.48681 0.17690 55.983 2518.109 1.0007 604.83 811.38
279.7622 0.36811 0.13303 0.01512 17.493 813.774 1.0191 766.74 1028.60
109.527 4884.366 44.595208
B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i Ki del Ki xi
604.83 766.74 161.41 216.53 278.27 352.77 204.15 0.9729 4.65670 0.00000 0.09880
811.38 1028.60 163.73 219.64 282.27 357.84 207.09 1.0080 1.23644 0.00000 0.28137
1042.75 1321.90 107.00 143.54 184.47 233.85 135.33 1.0487 0.36340 0.00000 0.48681
1321.90 1675.78 11.59 15.55 19.99 25.34 14.66 1.1001 0.11367 0.00000 0.13303
443.72 595.26 765.00 969.80 561.23 1.00000
Sum xi
Pi0, Pi0,
mmHg atm xi yi xi vi xI vi di dav gama i B1j B2j
10072.81 13.254 0.09880 0.46008 8.8090 369.10 1.0255 350.82 470.63
2827.31 3.720 0.28137 0.34789 27.2418 1183.38 1.0050 470.63 631.35
868.34 1.143 0.48681 0.17690 55.9829 2518.11 1.0007 604.83 811.38
279.76 0.368 0.13303 0.01512 17.4930 813.77 1.0191 766.74 1028.60
109.527 4884.366 44.5952
B3j B4j yjB1j yjB2j yjB3j yjB4j Sum yjBij yi Sum yjBij PSI i Ki del Ki
604.83 766.74 161.41 216.53 278.27 352.77 1008.97 204.15 0.9729 4.65670 0.00000
811.38 1028.60 163.73 219.64 282.27 357.84 1023.48 207.09 1.0080 1.23644 0.00000
1042.75 1321.90 107.00 143.54 184.47 233.85 668.85 135.33 1.0487 0.36340 0.00000
1321.90 1675.78 11.59 15.55 19.99 25.34 72.48 14.66 1.1001 0.11367 0.00000
443.72 595.26 765.00 969.80 561.23
Sum Sum yiyjBij
B1j B2j B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i
359.400 482.405 620.653 788.158 183.756 246.646 317.330 402.972 226.961 0.9757
482.405 647.509 833.072 1057.905 157.744 211.732 272.410 345.930 194.834 1.0113
620.653 833.072 1071.814 1361.080 92.844 124.620 160.333 203.604 114.674 1.0529
788.158 1057.905 1361.080 1728.413 9.561 12.833 16.511 20.967 11.809 1.1056
443.905 595.831 766.585 973.473 548.278
Sum Sum yiyjBij
log (Pi0, mmHg) = A - B / (T + C) R, mL atm/mol/K = 82.057
Pi0, mmHg = 10 ^ (A - B / (T + C) )
Pi0, atm = Pi0, mmHg / 760
Ki = GAMA i * Pi0 / P / PSI i
Pi0, Pi0,
mmHg atm xi yi xi vi xI vi di dav gama i
9300.433 12.237 0.11941 0.51128 10.64683 446.102 1.0241
2562.078 3.371 0.29301 0.32699 28.36936 1232.365 1.0043
771.775 1.015 0.46483 0.14959 53.45520 2404.415 1.0010
243.942 0.321 0.12275 0.01213 16.14139 750.897 1.0212
1.00000 1.00000 108.61278 4833.779 44.5047
Trial: T, C = 44.04038
V/F 0.37283
K1 = 5.11838
K2 = 1.38738
K3 = 0.41650
K4 = 0.13298
Pi0, Pi0,
mmHg atm xi yi xi vi xI vi di dav gama i B1j B2j
11016.3 14.495 0.07888 0.40374 7.0331 294.69 1.02725 341.3 457.6
3157.5 4.155 0.26214 0.36369 25.3804 1102.52 1.00594 457.6 613.6
991.0 1.304 0.51121 0.21292 58.7896 2644.35 1.00034 587.3 787.5
326.1 0.429 0.14777 0.01965 19.4312 903.94 1.01685 743.1 996.3
110.634 4945.50 44.7013919
B3j B4j yjB1j yjB2j yjB3j yjB4j yi Sum yjBij PSI i Ki del Ki
587.3 743.1 137.80 184.76 237.13 300.02 179.21 0.96971 5.11838 0.00000
787.5 996.3 166.43 223.15 286.41 362.35 216.45 1.00413 1.38738 0.00000
1010.8 1278.8 125.06 167.67 215.21 272.27 162.64 1.04395 0.41650 0.00000
1278.8 1617.9 14.60 19.58 25.13 31.79 18.99 1.09385 0.13298 0.00000
443.88 595.16 763.88 966.43 577.30
Sum Sum yiyjBij
B,
cm3/mol
-341.30
-613.57
-1010.75
-1617.87
xi
0.07888
0.26214
0.51121
0.14777
1.00000
Sum xi
Partial Condensation With Non-Condensable Gas: Non-Ideal Liquids and Non-Ideal Gases
Second Virial Coefficient and Scatchard-Hildebrand
Pi0, Pi0,
mmHg atm xi yi xi vi xI vi di dav gama i B1j B2j B3j
1E+10 1E+07 0.00000 0.43330 5.4478E-07 5.4478E-06 6.83051 16.41 -167.21 -307.47
10072.81 13.254 0.02974 0.13122 2.6515 111.10 1.03693 -167.21 350.82 470.63
2827.31 3.720 0.17600 0.21067 17.0400 740.22 1.01086 -307.47 470.63 631.35
868.34 1.143 0.53738 0.19453 61.7982 2779.68 1.00010 -513.17 604.83 811.38
279.76 0.368 0.25689 0.03029 33.7808 1571.48 1.00990 -829.69 766.74 1028.60
115.2706 5202.48 45.133
B4j B5j yjB1j yjB2j yjB3j yjB4j yjB5j yi Sum yjBij Ki del Ki
-513.17 -829.69 7.108 -72.451 -133.228 -222.36 -359.50 -88.64 PSI i 3.18.E+07 0.00000
604.83 766.74 -21.941 46.034 61.755 79.36 100.61 28.03 0.94165 4.41233 0.00000
811.38 1028.60 -64.774 99.145 133.005 170.93 216.69 52.78 1.03824 1.19698 0.00000
1042.75 1321.90 -99.826 117.655 157.836 202.84 257.15 52.68 1.04723 0.36199 0.00000
1321.90 1675.78 -25.131 23.224 31.156 40.04 50.76 8.05 1.05220 0.11791 0.00000
-204.563 213.609 250.524 270.82 265.70 52.90 1.05094
Sum Sum yiyjBij