THE MINISTRY OF AGRICULTURE

OF
THE REPUBLIC OF INDONESIA

DIRECTORATE GENERAL
OF
AGRICULTURAL INFRASTRUCTURE AND FACILITIES
DIRECTORATE OF FERTILIZER AND PESTICIDE
Jl. Harsono RM No. 3, D Building 8-9th Floor, Ragunan Pasar Minggu - Jakarta Selatan
Phone (62.21) 7890043 - 7810044, Fax (62.21) 7890043

No. : 1194/Kompes/2016

In accordance with the Decree of the Minister of Agriculture number

693/Kpts/SR.330/10/2016

We hereby certify that :

Company name : PT BASF Indonesia

Company address : DBS BANK TOWER CIPUTRA WORLD 1 LT 26-
27
JL. PROF. DR. SATRIO KAV 3-5
KARET KUNINGAN - SETIABUDI
JAKARTA SELATAN - DKI JAKARTA 12940

Is recognized as the registration holder of the following product :

Trade name : ABATE 1 GR

Common name and content of a.i. : temephos : 1%
Registration number : RI. 060901197496

The product mentioned above is offically registered.

Expiry: 18 October 2021 Jakarta, 9 November 2016

Director,

Dr. Ir. Muhrizal Sarwani, MSc

This document is official document of Ministry of Agriculture which do not require signature
since being issued electronically from Sistem Informasi Manajemen Pelayanan Perizinan Pertanian (SIM-PPP).
Ministry of Agriculture is responsible for any information in this document.
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Safety data sheet

Page: 1/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G
(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013

1. Substance/preparation and company identification

ABATE 1 G
Use: crop protection product, insecticide

Company:
BASF South East Asia Pte Ltd.
7 Temasek Boulevard,
#35-01 Suntec Tower One, 038987, SINGAPORE
Telephone: +65 6 337-0330
Telefax number: +65 6 334-0330
E-mail address: tommy.chng@basf.com

Emergency information:
International emergency number:
Telephone: +49 180 2273-112

2. Hazard identification

Classification of the substance and mixture:

Specific target organ toxicity — repeated exposure: Cat. 2
Hazardous to the aquatic environment - acute: Cat. 1
Hazardous to the aquatic environment - chronic: Cat. 1

Label elements and precautionary statement:

Pictogram:

Signal Word:
 Page: 2/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Warning

Hazard Statement:
May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.

Precautionary Statements (Prevention):

Do not breathe dust.

Precautionary Statements (Response):

Get medical advice/attention if you feel unwell. Collect spillage.

Precautionary Statements (Disposal):

Dispose of contents/container to hazardous or special waste collection point.

Other hazards which do not result in classification:

See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/information on ingredients
Chemical nature

crop protection product, insecticide, Granule (GR)

Hazardous ingredients

Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester

Content (W/W): 1 %
CAS Number: 3383-96-8
Acute Tox.: Cat. 4 (Inhalation - vapour)
Acute Tox.: Cat. 5 (oral)
Acute Tox.: Cat. 5 (dermal)
STOT RE: Cat. 1
Aquatic Acute: Cat. 1
Aquatic Chronic: Cat. 1

methanol
Content (W/W): < 1 % Flam. Liq.: Cat. 2
CAS Number: 67-56-1 Acute Tox.: Cat. 3 (Inhalation - vapour)
Acute Tox.: Cat. 3 (oral)
Acute Tox.: Cat. 3 (dermal)
STOT SE (Central nervous system, Optic
nerve): Cat. 1

Benzene, trimethyl-
 Page: 3/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

Content (W/W): < 1 %
CAS Number: 25551-13-7
(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Flam. Liq.: Cat. 3
Acute Tox.: Cat. 4 (Inhalation - vapour)
Skin Corr./Irrit.: Cat. 2
Eye Dam./Irrit.: Cat. 2A
STOT SE: Cat. 3 (irr. to respiratory syst.)
Aquatic Acute: Cat. 2
Aquatic Chronic: Cat. 2

calciumdodecylbenzenesulfonate
Content (W/W): < 1 % Skin Corr./Irrit.: Cat. 2
CAS Number: 26264-06-2 Eye Dam./Irrit.: Cat. 1

Quartz (SiO2)
Content (W/W): < 100 %
CAS Number: 14808-60-7

Kieselguhr
Content (W/W): < 5 %
CAS Number: 61790-53-2

4. First-Aid Measures
General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician:
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, foam, dry powder
 Page: 4/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Unsuitable extinguishing media for safety reasons:
carbon dioxide

Specific hazards:
carbon monoxide, carbon dioxide, sulfur oxides, phosphorus oxides
The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying
with water if exposed to fire.

6. Accidental Release Measures

Personal precautions:
Avoid dust formation. Use personal protective clothing. Avoid contact with the skin, eyes and
clothing.

Environmental precautions:
Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

Methods for cleaning up or taking up:

For small amounts: Contain with dust binding material and dispose of.
For large amounts: Sweep/shovel up.
Avoid raising dust. Dispose of absorbed material in accordance with regulations. Collect waste in
suitable containers, which can be labeled and sealed. Clean contaminated floors and objects
thoroughly with water and detergents, observing environmental regulations.

7. Handling and Storage

Handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.

Protection against fire and explosion:

Avoid dust formation. Dust can form an explosive mixture with air. Prevent electrostatic charge -
sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Storage
Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect against moisture. Protect
from direct sunlight.

Storage stability:
 Page: 5/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Storage duration: 24 Months

8. Exposure controls and personal protection

Components with occupational exposure limits

methanol, 67-56-1;
TWA value 200 ppm (ACGIHTLV)
STEL value 250 ppm (ACGIHTLV)
Skin Designation (ACGIHTLV)
The substance can be absorbed through the skin.
TWA value 262 mg/m3 ; 200 ppm (OEL (SG))
STEL value 328 mg/m3 ; 250 ppm (OEL (SG))

temephos, 3383-96-8;
TWA value 10 mg/m3 (OEL (SG))
TWA value 1 mg/m3 (ACGIHTLV), Inhalable fraction and vapor
Skin Designation (ACGIHTLV), Inhalable fraction and vapor
The substance can be absorbed through the skin.

Quartz (SiO2), 14808-60-7;

TWA value 0.1 mg/m3 (OEL (SG)), Respirable dust
TWA value 0.025 mg/m3 (ACGIHTLV), Respirable fraction

Personal protective equipment

Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with
medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures:

The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.
 Page: 6/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
9. Physical and Chemical Properties
Form: granules
Colour: brown
Odour: of mercaptans
Odour threshold: Not determined due to potential health hazard by inhalation.

pH value:
The product has not been tested.

Melting point:
The product has not been tested.
Boiling point:
The product has not been tested.

Flash point:
not applicable
Evaporation rate:
not applicable

Flammability (solid/gas): not flammable

Lower explosion limit:
not determined
Upper explosion limit:
not determined

Thermal decomposition: not determined

Self ignition: Based on its structural properties the
product is not classified as self-
igniting.

Explosion hazard: not explosive

Fire promoting properties: not fire-propagating

Vapour pressure:
The product has not been tested.

Bulk density: 1,200 - 1,520 kg/m3

Relative vapour density (air):
not determined

Solubility in water: not soluble

Information on: Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester
Partitioning coefficient n-octanol/water (log Pow): 4.9
----------------------------------

Viscosity, dynamic:
not applicable

10. Stability and Reactivity

 Page: 7/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Conditions to avoid:
See MSDS section 7 - Handling and storage.

Thermal decomposition: not determined

Substances to avoid:
strong acids, strong bases, strong oxidizing agents

Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually
nontoxic by inhalation.

Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401)
No mortality was observed.

(by inhalation):The product has not been tested. The statement has been derived from the
properties of the individual components.

LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)

No mortality was observed.

Information on: Temephos

Experimental/calculated data:
LC50 rat (by inhalation): > 4.79 mg/l 4 h (OECD Guideline 403)
An aerosol was tested.
----------------------------------

Irritation

Assessment of irritating effects:

Not irritating to the skin. Not irritating to the eyes.

Experimental/calculated data:
Skin corrosion/irritation rabbit: (OECD Guideline 404)

Serious eye damage/irritation rabbit: (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.
 Page: 8/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Experimental/calculated data:
Guinea pig maximization test guinea pig: (OECD Guideline 406)

Germ cell mutagenicity

Assessment of mutagenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity

Assessment of carcinogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. The results of various animal studies gave no indication of a carcinogenic
effect.

Reproductive toxicity

Assessment of reproduction toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Animal studies gave no indication of a developmental toxic effect at doses
that were not toxic to the parental animals.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Temephos

Assessment of repeated dose toxicity:
Causes mortality and signs of neurotoxicity through prolonged or repeated exposure.
----------------------------------

Other relevant toxicity information

Misuse can be harmful to health.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:

Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
 Page: 9/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Toxicity to fish:
LC50 (96 h) 5.4 mg/l, Cyprinodon variegatus (Flow through.)

Aquatic invertebrates:
EC50 (96 h) 0.014 mg/l, other (Flow through.)

Aquatic plants:
not determined

Mobility

Assessment transport between environmental compartments:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Temephos

Assessment transport between environmental compartments:
Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
----------------------------------

Persistence and degradability

Assessment biodegradation and elimination (H2O):

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Temephos

Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
----------------------------------

Bioaccumulation potential

Assessment bioaccumulation potential:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Temephos

Bioaccumulation potential:
Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is
possible.
----------------------------------

Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

13. Disposal Considerations

Must be sent to a suitable incineration plant, observing local regulations.
 Page: 10/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.

14. Transport Information

Domestic transport:
Hazard class: 9
Packing group: III
ID number: UN 3077
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains TEMEPHOS 1%)

Sea transport
IMDG
Hazard class: 9
Packing group: III
ID number: UN 3077
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains TEMEPHOS 1%)

Air transport
IATA/ICAO
Hazard class: 9
Packing group: III
ID number: UN 3077
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains TEMEPHOS 1%)

15. Regulatory Information

Regulations of the European union (Labelling)

EEC Directives:

Hazard symbol(s)
N Dangerous for the environment.

R-phrase(s)
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
 Page: 11/11
BASF Safety data sheet
Date / Revised: 03.12.2012 Version: 2.0
Product: ABATE 1 G

(30150912/SDS_CPA_SG/EN)
Date of print 11.07.2013
S-phrase(s)
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S29/35 Do not empty into drains, this material and its container must be
disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.

Other regulations

For the user of this plant-protective product applies: 'To avoid risks to man and the environment,
comply with the instructions for use.' (Directive 1999/45/EC, Article 10, No. 1.2)

16. Other Information

Recommended use: Product for exclusive agricultural use., Use prescriptions is shown in the label of
the product.

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.