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Paschen's Law PDF
Paschen's Law PDF
Paschen's Law PDF
1 Paschen curve
Early vacuum experimenters found a rather surprising be-
havior. An arc would sometimes take place in a long ir-
regular path rather than at the minimum distance between
the electrodes. For example, in air, at a pressure of 10−3
atmospheres, the distance for minimum breakdown volt-
age is about 7.5 µm. The voltage required to arc this dis-
tance is 327 V which is insufficient to ignite the arcs for
gaps that are either wider or narrower. For a 3.5 µm gap,
the required voltage is 533 V, nearly twice as much. If
500 V were applied, it would not be sufficient to arc at
the 2.85 µm distance, but would arc at a 7.5 µm distance.
It was found that breakdown voltage was described by the
equation:[1]
Bpd
Paschen curves obtained for helium, neon, argon, hydrogen and VB =
ln(Apd) − ln[ln(1 + 1
γse )]
nitrogen, using the expression for the breakdown voltage as a
function of the parameters A,B that interpolate the first Townsend Where V is the breakdown voltage in Volts, p is the pres-
coefficient.[1] sure in Pascals, d is the gap distance in meters, γse is
the secondary electron emission coefficient at the cath-
ode, A is the saturation ionization in the gas at a par-
Paschen’s Law is an equation that gives the breakdown ticular E/p (electric field/pressure), and B is related to
voltage, that is the voltage necessary to start a discharge or the excitation and ionization energies. The constants A
electric arc, between two electrodes in a gas as a function and B are determined experimentally and found to be
of pressure and gap length.[2][3] It is named after Friedrich roughly constant over a restricted range of E/p for any
Paschen who discovered it empirically in 1889.[4] given gas. For example, air with an E/p in the range of
450 to 7500 V·(kPa·cm)−1 , A = 112.50 (kPa·cm)−1 and
Paschen studied the breakdown voltage of various gases B = 2737.50 V·(kPa·cm)−1 .[6] The graph of this equation
between parallel metal plates as the gas pressure and gap is the Paschen curve. By differentiating it with respect to
distance were varied. The voltage necessary to arc across pd and setting the derivative to zero, the minimum volt-
the gap decreased as the pressure was reduced and then age can be found. This yields
increased gradually, exceeding its original value. He also
found that at normal pressure, the voltage needed to cause
an arc reduced as the gap size was reduced but only to pd = e1−b
a point. As the gap was reduced further, the voltage re-
quired to cause an arc began to rise and again exceeded its and predicts the occurrence of a minimum breakdown
original value. For a given gas, the voltage is a function voltage for pd = 7.5×10−6 m·atm. This is 327 V in air
only of the product of the pressure and gap length.[2][3] at standard atmospheric pressure at a distance of 7.5 µm.
The curve he found of voltage versus the pressure-gap The composition of the gas determines both the mini-
length product (right) is called Paschen’s curve. He mum arc voltage and the distance at which it occurs. For
found an equation that fit these curves, which is now argon, the minimum arc voltage is 137 V at a larger 12
called Paschen’s law.[3] µm. For sulfur dioxide, the minimum arc voltage is 457
At higher pressures and gap lengths, the breakdown volt- V at only 4.4 µm.
age is approximately proportional to the product of pres- For air at STP, the voltage needed to arc a 1-meter gap is
sure and gap length, and the term Paschen’s law is some- about 3.4 MV. The intensity of the electric field for this
times used to refer to this simpler relation.[5] However gap is therefore 3.4 MV/m. The electric field needed to
this is only roughly true, over a limited range of the curve. arc across the minimum voltage gap is much greater than
1
2 3 DERIVATION
Nσ x ( )
P = = (6)
A λ x
Γe (x) = Γe (0) exp − (10)
λe
As expressed by the second part of the equation, it is also
possible to express the probability as relation of the path The probability that λ > x (that there was not yet a col-
traveled by the electron x to the mean free path λ (dis- lision at the point x ) is
tance at which another collision occurs).
( )
Γe (x) x
P (λ > x) = = exp − (11)
Γe (0) λe
According to its definition α is the number of ionizations
per length of path and thus the relation of the probability
that there was no collision in the mean free path of the
a
ions, and the mean free path of the electrons:
( ) ( )
P (λ > λI ) 1 λI 1 EI
b
α= = exp - = exp - (12)
λe λe λe λe Ee
It was hereby considered that the energy E that a charged
particle can get between a collision depends on the
electric field strength E and the charge Q :
The adjoining sketch illustrates that σ = π(ra + rb )2 . Putting this into (5) and transforming to U we get the
As the radius of an electron can be neglected compared Paschen law for the breakdown voltage Ubreakdown that was
to the radius of an ion rI it simplifies to σ = πrI2 . Using first investigated by Paschen in [10] and whose formula was
this relation, putting (7) into (6) and transforming to λ first derived by Townsend in,[11] section 227:
one gets
Ubreakdown =
L·p·d·EI
e(ln(L·p·d)−ln(ln(1+γ −1 ))) (15)
kB T 1 πrI2
λ= = (8) with L =
pπrI2 L·p kB T
an external source of free electrons. This means that elec- been knocked out of orbit. All three effects change
trons from the cathode can reach the anode in the distance the number of collisions needed to cause an exponential
d and ionize at least one atom on its way. So according to growth in free electrons. These free electrons are neces-
the definition of α this relation must be fulfilled: sary to cause an arc.
L · p · d · EI d · EI • Atmospheric pressure
Ubreakdown Townsend = = ( ) (17)
e · ln(L · p · d) e · λe ln λde
7 References
4 Conclusions / Validity [1] Lieberman, Michael A.; Lichtenberg, Allan J. (2005).
Principles of plasma discharges and materials processing
Paschen’s law requires that (2nd ed.). Hoboken, N.J.: Wiley-Interscience. 546.
ISBN 978-0471005773. OCLC 59760348.
• there are already free electrons at the cathode ( [2] “Paschen’s Law”. Merriam-Webster Online Dictionary.
Γe (x = 0) ̸= 0 ) which can be accelerated to trig- Merriam-Webster, Inc. 2013. Retrieved April 10, 20113.
ger impact ionization. Such so-called seed electrons Check date values in: |access-date= (help)
can be created by ionization by cosmic x-ray back-
ground. [3] Wadhwa, C.L. (2007). High Voltage Engineering (2nd
ed.). New Age International. pp. 10–12. ISBN
• the creation of further free electrons is only achieved 8122418597.
by impact ionization. Thus Paschen’s law is not valid [4] Friedrich Paschen (1889). "Ueber die zum Funkenüber-
if there are external electron sources. This can for gang in Luft, Wasserstoff und Kohlensäure bei
example be a light source creating secondary elec- verschiedenen Drucken erforderliche Potentialdif-
trons via the photoelectric effect. This has to be con- ferenz (On the potential difference required for
sidered in experiments. spark initiation in air, hydrogen, and carbon diox-
ide at different pressures)". Annalen der Physik.
• each ionized atom leads to only one free electron. 273 (5): 69–75. Bibcode:1889AnP...273...69P.
But multiple ionizations occur always in practice. doi:10.1002/andp.18892730505.
• free electrons at the cathode surface are created by [5] Graf, Rudolf F. (1999). Modern Dictionary of Electronics
the impacting ions. The problem is that the num- (7th ed.). Newnes. p. 542. ISBN 0750698667.
ber of thereby created electrons strongly depends on
[6] Husain, E.; Nema, R. (August 1982). “Analy-
the material of the cathode, its surface (roughness,
sis of Paschen Curves for air, N2 and SF6 Using
impurities) and the environmental conditions (tem- the Townsend Breakdown Equation”. IEEE Transac-
perature, humidity etc.). The experimental, repro- tions on Electrical Insulation. EI-17 (4): 350–353.
ducible determination of the factor γ is therefore doi:10.1109/TEI.1982.298506.
nearly impossible.
[7] Emmanouel Hourdakis; Brian J. Simonds & Neil M. Zim-
• the electrical field is homogeneous. merman (2006). “Submicron gap capacitor for mea-
surement of breakdown voltage in air”. Rev. Sci. In-
strum. 77 (3): 034702. Bibcode:2006RScI...77c4702H.
doi:10.1063/1.2185149.
5 Effects with different gases
[8] Electrical Discharges-How the spark, glow and arc work
Different gases will have different mean free paths for [9] J. Townsend, The Theory of Ionization of Gases by Colli-
molecules and electrons. This is because different sion. Constable, 1910. Online: http://www.worldcat.org/
molecules have different diameters. Noble gases like he- wcpa/oclc/8460026
lium and argon are monatomic and tend to have smaller
diameters. This gives them a greater mean free path [10] Paschen, F. (1889). “Ueber die zum Funkenübergang
length. in Luft, Wasserstoff und Kohlensäure bei verschiedenen
Drucken erforderliche Potentialdifferenz”. Annalen der
Ionization potentials differ between molecules as well as Physik. 273 (5): 69–96. Bibcode:1889AnP...273...69P.
the speed that they recapture electrons after they have doi:10.1002/andp.18892730505.
5
8 External links
• High Voltage Experimenter’s Handbook
• Paschen’s law calculator
• Electrical Discharges
• Pressure Dependence of Plasma Structure in Mi-
crowave Gas Breakdown at 110GHz
6 9 TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES
9.2 Images
• File:Paschen_curves.svg Source: https://upload.wikimedia.org/wikipedia/commons/e/e2/Paschen_curves.svg License: CC BY-SA 4.0
Contributors: Own work Original artist: Krishnavedala
• File:Wirkungsquerschnitt-Skizze.svg Source: https://upload.wikimedia.org/wikipedia/commons/d/dd/Wirkungsquerschnitt-Skizze.
svg License: CC BY-SA 3.0 Contributors: Own work Original artist: Muso