The document describes three trials of a distillation process. Each trial calculates the distribution coefficient (Ki) for each component (A, B, C, D) and uses these values along with the assumed boiling point temperature to calculate a new composition for each component. The process is repeated iteratively with the boiling point adjusting slightly with each trial until it converges.
The document describes three trials of a distillation process. Each trial calculates the distribution coefficient (Ki) for each component (A, B, C, D) and uses these values along with the assumed boiling point temperature to calculate a new composition for each component. The process is repeated iteratively with the boiling point adjusting slightly with each trial until it converges.
The document describes three trials of a distillation process. Each trial calculates the distribution coefficient (Ki) for each component (A, B, C, D) and uses these values along with the assumed boiling point temperature to calculate a new composition for each component. The process is repeated iteratively with the boiling point adjusting slightly with each trial until it converges.
A 0.35 2.2 6.7692307692 2.3692307692 0.7067 A B 0.28 0.8 2.4615384615 0.6892307692 0.2056 B C 0.24 0.325 1 0.24 0.0716 C D 0.13 0.135 0.4153846154 0.054 0.0161 D Σαixi = 3.3524615385 Kc = 1/Σαixi = 1/3.35246154 = 0.298288284 Kc = Using DePriester Chart = Tb = 61.22 °C U
Trial 2 (Assume 61.22 °C)
Comp xi Ki Ki / Kc = αi αixi xi(new) Comp A 0.35 2.1 7.0398927254 2.4639624539 0.7118 A B 0.28 0.75 2.5142474019 0.7039892725 0.2034 B C 0.24 0.2983 1 0.24 0.0693 C D 0.13 0.123 0.4123365739 0.0536037546 0.0155 D Σαixi = 3.4615554811 Kc = 1/Σαixi = 1/3.461555481 = 0.288887469 Kc = Using DePriester Chart = Tb = 61.11 °C U
Trial 3 (Assume 61.11 °C)
Comp xi Ki Ki / Kc = αi αixi xi(new) Comp A 0.35 2.08 7.1997230876 2.5199030807 0.7174 A B 0.28 0.72 2.492211838 0.6978193146 0.1987 B C 0.24 0.2889 1 0.24 0.0683 C D 0.13 0.122 0.4222914503 0.0548978885 0.0156 D Σαixi = 3.5126202838 Kc = 1/Σαixi = 1/3.512620284 = 0.28468776 Kc = Using DePriester Chart = Tb = 61.1 °C Trial 1 (Assume 110 °C) yi Ki Ki / Kc = αi yi/αi xi(new) Comp xi 0.35 4.81 4.8585858586 0.072037422 0.1001 A 0.35 0.28 2.07 2.0909090909 0.1339130435 0.1860 B 0.28 0.24 0.99 1 0.24 0.3334 C 0.24 0.13 0.47 0.4747474747 0.2738297872 0.3804 D 0.13 Σyi/αi = 0.7197802527 Kc = 1/Σαixi = 1/0.71978025 = 1.389312919 Kc = 1/Σαi Using DePriester Chart = Tb = 125.67 °C Using
Trial 2 (Assume 125.67 °C)
yi Ki Ki / Kc = αi yi/αi xi(new) Comp xi 0.35 6 4.3187216584 0.0810425 0.1126 A 0.35 0.28 2.7 1.9434247463 0.1440755556 0.2002 B 0.28 0.24 1.3893 1 0.24 0.3334 C 0.24 0.13 0.68 0.4894551213 0.2656014706 0.3690 D 0.13 Σyi/αi = 0.7307195261 Kc = 1/Σαixi = 1/0.73071953 = 1.368514127 Kc = 1/Σαi Using DePriester Chart = Tb = 125.56 °C Using
Trial 3 (Assume 125.56 °C)
yi Ki Ki / Kc = αi yi/αi xi(new) Comp xi 0.35 6 4.3843624406 0.0798291667 0.1103 A 0.35 0.28 2.69 1.9656558275 0.1424460967 0.1968 B 0.28 0.24 1.3685 1 0.24 0.3315 C 0.24 0.13 0.68 0.4968944099 0.261625 0.3614 D 0.13 Σyi/αi = 0.7239002633 Kc = 1/Σαixi = 1/0.72390026 = 1.381405775 Kc = 1/Σαi Using DePriester Chart = Tb = 125.6 °C Using Trial 1 (Assume 85 °C) Ki Ki / Kc = αi Kcαi - 1 f(Kcαi - 1) + 1 xi/ f(Kcαi-1)+1 3.18 5.7818181818 2.18 1.9810 0.1767 1.27 2.3090909091 0.27 1.1215 0.2497 0.55 1 -0.45 0.7975 0.3009 0.283 0.5145454545 -0.717 0.6774 0.1919 Σαixi = 0.9192 Kc = 1/Σαixi = 1/0.919208922 = 1.087891965 1.0327385089 Using DePriester Chart = Tb = 111.1 °C