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  • PERHITUNGAN

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    Laila Roikhatul
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    1. The document provides calculations for the equilibrium constant (Kc) of esterification reactions performed in 4 different experiments. 2. It gives the initial and remaining amounts of reactants and products for each experiment, and uses these values to calculate the concentration of each species at equilibrium. 3. The equilibrium constant is then calculated for each experiment by taking the ratio of the concentration of products over the concentration of reactants, raised to their stoichiometric coefficients.

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    1. The document provides calculations for the equilibrium constant (Kc) of esterification reactions performed in 4 different experiments. 2. It gives the initial and remaining amounts of reactants and products for each experiment, and uses these values to calculate the concentration of each species at equilibrium. 3. The equilibrium constant is then calculated for each experiment by taking the ratio of the concentration of products over the concentration of reactants, raised to their stoichiometric coefficients.

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    © All Rights Reserved
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    12 views6 pages

    PERHITUNGAN

    Uploaded by

    Laila Roikhatul
    1. The document provides calculations for the equilibrium constant (Kc) of esterification reactions performed in 4 different experiments. 2. It gives the initial and remaining amounts of reactants and products for each experiment, and uses these values to calculate the concentration of each species at equilibrium. 3. The equilibrium constant is then calculated for each experiment by taking the ratio of the concentration of products over the concentration of reactants, raised to their stoichiometric coefficients.

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    © All Rights Reserved
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    of 6

    PERHITUNGAN

    Diket :

    M NaOH = 2 mol/L

    V rata-rata NaOH = 5,37 mL = 5,37×10-3 L

    N Blanko = V × M

    = 5,37×10-3 L × 2 mol/L

    = 0,01074 mol

    1) Erlenmeyer 1
    Diketahui : ρ CH3COOH = 1,05 gr/cm3
    V CH3COOH = 4 mL
    gr
    ρ×V 1,05cm3 × 4 mL
    n CH3COOH = = = 0,070 mol
    𝑀𝑟 60 𝑔𝑟/𝑚𝑜𝑙
    ρ C2H5OH = 0,789 gr/cm3
    V C2H5OH = 1 mL
    gr
    ρ×V 0,789 cm3 × 1 mL
    n C2H5OH = = = 0,01715 mol
    𝑀𝑟 46 𝑔𝑟/𝑚𝑜𝑙

     n ekivalen H+ = n ekivalen OH-


    = M NaOH × V NaOH

    = 2 mol/L × 41 mL

    = 0,07126 mol

     [H+] sisa = n ekivalen [H+] – n larutan blanko


    = 0,082 mol - 0,01074 mol
    = 0,07126 mol
     Mol yang bereaksi = mol mula-mula-mol sisa
    =0,07-0,07126\
    =-0,00126 mol

    CH3COOH (aq) + C2H5OH (aq) ⇄ CH3COOC2H5 (aq) + H2O (l)

    M 0,0700 0,01715 - -

    R -0,00126 -0,00126 -0,00126 -0,00126

    S 0,07126 0,0038 -0,00126 -0,00126

    𝑛 0,07126 mol
    [CH3COOC2H5] = = = 7,126 M
    𝑉 0,01 𝐿

    𝑛 0,01841 mol
    [CH3COOH] = = = 1,841 M
    𝑉 0,01 𝐿

    𝑛 −0,00126 mol
    [C2H5OH] = = = -0,126 M
    𝑉 0,01 𝐿

    [CH3 COOC2 H5 ]
    Kc1 =
    [CH3 COOH] [C2 H5 OH]

    0,126 M
    =
    7,126M ×1,841 M

    −0,126
    = = 0,0095
    13,19

    2) Erlenmeyer 2
    Diketahui : ρ CH3COOH = 1,05 gr/cm3
    V CH3COOH = 3 mL
    gr
    ρ×V 1,05cm3 × 3 mL
    n CH3COOH = = = 0,0525 mol
    𝑀𝑟 60 𝑔𝑟/𝑚𝑜𝑙
    ρ C2H5OH = 0,789 gr/cm3
    V C2H5OH = 2 mL
    gr
    ρ×V 0,789 × 2 mL
    cm3
    n C2H5OH = = = 0,0343 mol
    𝑀𝑟 46 𝑔𝑟/𝑚𝑜𝑙

     n ekivalen H+ = n ekivalen OH-


    = M NaOH × V NaOH

    = 2 mol/L × 22,8 mL

    = 0,0456 mol

     n sisa = n ekivalen – n larutan blanko


    = 0,0456 mol - 0,01074 mol
    = 0,03486 mol

    CH3COOH (aq) + C2H5OH (aq) ⇄ CH3COOC2H5 (aq) + H2O (l)

    M 0,0525 0,0343 - -

    R 0,01764 0,01764 0,01764 0,01764

    S 0,03486 0,0166 0,01764 0,01764

    𝑛 0,03486 mol
    [CH3COOC2H5] = = = 3,486 M
    𝑉 0,01 𝐿

    𝑛 0,0166mol
    [CH3COOH] = = = 1,66 M
    𝑉 0,01 𝐿

    𝑛 0,0764 mol
    [C2H5OH] = = = 1,764 M
    𝑉 0,01 𝐿

    [CH3 COOC2 H5 ]
    Kc2 =
    [CH3 COOH] [C2 H5 OH]

    1,764 M
    =
    3,486 M ×1,66 M

    1,764
    = = 0,308 M
    5,724
    3) Erlenmeyer 3
    Diketahui : ρ CH3COOH = 1,05 gr/cm3
    V CH3COOH = 2 mL
    gr
    ρ×V 1,05cm3 × 2 mL
    n CH3COOH = = = 0,0350 mol
    𝑀𝑟 60 𝑔𝑟/𝑚𝑜𝑙
    ρ C2H5OH = 0,79 gr/cm3
    V C2H5OH = 3 mL
    gr
    ρ×V 0,789 cm3 × 3 mL
    n C2H5OH = = = 0,05145 mol
    𝑀𝑟 46 𝑔𝑟/𝑚𝑜𝑙

     n ekivalen H+ = n ekivalen OH-


    = M NaOH × V NaOH

    = 2 mol/L × 9,9 mL

    = 19,8 ×10-3 mol

    =0,0198 mol

     [H+] sisa = n ekivalen [H+] – n larutan blanko


    = 0,0198 mol - 0,01074 mol
    = 0,00906 mol
     Mol yang bereaksi = mol mula-mula-mol sisa
    =0,035-0,00906 mol
    =-0,02594 mol

    CH3COOH (aq) + C2H5OH (aq) ⇄ CH3COOC2H5 (aq) + H2O (l)

    M 0,0350 0,05145 - -

    R 0,02594 0,02594 0,02594 0,02594

    S 0,00906 0,02551 0,02594 0,02594


    𝑛 0,00906 mol
    [CH3COOC2H5] = = = 0,906 M
    𝑉 0,01 𝐿

    𝑛 0,02551 mol
    [CH3COOH] = = = 2.551 M
    𝑉 0,01 𝐿

    𝑛 0,02594 mol
    [C2H5OH] = = = 2,594M
    𝑉 0,01 𝐿

    [CH3 COOC2 H5 ]
    Kc3 =
    [CH3 COOH] [C2 H5 OH]

    2,594M
    =
    0,906 M ×2.551 M

    2,594
    = = 1,122 M
    2,311

    4) Erlenmeyer 4
    Diketahui : ρ CH3COOH = 1,05 gr/cm3
    V CH3COOH = 1 mL
    gr
    ρ×V 1,05cm3 × 1 mL
    n CH3COOH = = = 0,0175 mol
    𝑀𝑟 60 𝑔𝑟/𝑚𝑜𝑙
    ρ C2H5OH = 0,79 gr/cm3
    V C2H5OH = 4 mL
    gr
    ρ×V 0,79 cm3 × 4 mL
    n C2H5OH = = = 0,0686 mol
    𝑀𝑟 46 𝑔𝑟/𝑚𝑜𝑙

     n ekivalen H+ = n ekivalen OH-


    = M NaOH × V NaOH

    = 2 mol/L × 7,3 mL

    = 0,0146 mol

     H+ sisa = n ekivalen – n larutan blanko


    = 0,0146 mol - 0,00386 mol
    = 0,01364 mol
     Mol yang bereaksi = mol mula-mula-mol sisa
    =0,0175-0,00386 mol
    =0,01364 mol

    CH3COOH (aq) + C2H5OH (aq) ⇄ CH3COOC2H5 (aq) + H2O (l)

    M 0,0175 0,0686 - -

    R 0,01364 0, 01364 0,01364 0, 01364

    S 0,005 0,05496 0,01364 0, 01364

    𝑛 0,00386 mol
    [CH3COOC2H5] = = = 0,386 M
    𝑉 0,01 𝐿

    𝑛 0,005496 mol
    [CH3COOH] = = = 5,496 M
    𝑉 0,01 𝐿

    𝑛 0,0562 mol
    [C2H5OH] = = = 1,364 M
    𝑉 0,01 𝐿

    [CH3 COOC2 H5 ]
    Kc4 =
    [CH3 COOH] [C2 H5 OH]

    1,364 M
    =
    5,496 M×0,386 M

    1,364
    = = 0,643
    2,121

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