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Total dissolved solids

in nutrient runoff, general stormwater runoff and runoff


from snowy climates where road de-icing salts are ap-
plied. The chemicals may be cations, anions, molecules
or agglomerations on the order of one thousand or fewer
molecules, so long as a soluble micro-granule is formed.
More exotic and harmful elements of TDS are pesticides
arising from surface runoff. Certain naturally occurring
total dissolved solids arise from the weathering and dis-
solution of rocks and soils. The United States has estab-
lished a secondary water quality standard of 500 mg/l to
provide for palatability of drinking water.
Total dissolved solids are differentiated from total sus-
pended solids (TSS), in that the latter cannot pass through
a sieve of two micrometers and yet are indefinitely sus-
pended in solution. The term “settleable solids” refers
to material of any size that will not remain suspended
or dissolved in a holding tank not subject to motion, and
excludes both TDS and TSS.[1] Settleable solids may in-
clude larger particulate matter or insoluble molecules.

1 Measurement
The two principal methods of measuring total dissolved
Bottled mineral water usually contains lower TDS levels than tap
solids are gravimetry and conductivity. Gravimetric
water
methods are the most accurate and involve evaporating
the liquid solvent and measuring the mass of residues left.
Total dissolved solids (TDS) is a measure of the com- This method is generally the best, although it is time-
bined content of all inorganic and organic substances con- consuming. If inorganic salts comprise the great majority
tained in a liquid in molecular, ionized or micro-granular of TDS, gravimetric methods are appropriate.
(colloidal sol) suspended form. Generally the operational Electrical conductivity of water is directly related to the
definition is that the solids must be small enough to sur- concentration of dissolved ionized solids in the water.
vive filtration through a filter with two-micrometer (nomi- Ions from the dissolved solids in water create the ability
nal size, or smaller) pores. Total dissolved solids are nor- for that water to conduct an electric current, which can
mally discussed only for freshwater systems, as salinity be measured using a conventional conductivity meter or
includes some of the ions constituting the definition of TDS meter. When correlated with laboratory TDS mea-
TDS. The principal application of TDS is in the study of surements, conductivity provides an approximate value
water quality for streams, rivers and lakes, although TDS for the TDS concentration, usually to within ten-percent
is not generally considered a primary pollutant (e.g. it is accuracy.
not deemed to be associated with health effects) it is used
as an indication of aesthetic characteristics of drinking The relationship of TDS and specific conductance of
water and as an aggregate indicator of the presence of a groundwater can be approximated by the following equa-
broad array of chemical contaminants. tion:
Primary sources for TDS in receiving waters are
agricultural and residential runoff, leaching of soil con- TDS = keEC
tamination and point source water pollution discharge
from industrial or sewage treatment plants. The most where TDS is expressed in mg/L and EC is the electri-
common chemical constituents are calcium, phosphates, cal conductivity in microsiemens per centimeter at 25 °C.
nitrates, sodium, potassium and chloride, which are found The correlation factor ke varies between 0.55 and 0.8. [2]

1
2 3 PRACTICAL IMPLICATIONS

2 Hydrological simulation
See also: Hydrological transport model
Hydrologic transport models are used to mathemati-

Aquarium at Bristol Zoo, England. Maintenance of filters be-


comes costly with high TDS.

and adding to system maintenance costs. These effects


can be seen in aquariums, spas, swimming pools, and
reverse osmosis water treatment systems. Typically, in
these applications, total dissolved solids are tested fre-
quently, and filtration membranes are checked in order
to prevent adverse effects.
Pyramid Lake, Nevada receives dissolved solids from the
Truckee River.
In the case of hydroponics and aquaculture, TDS is of-
ten monitored in order to create a water quality environ-
cally analyze movement of TDS within river systems. ment favorable for organism productivity. For freshwa-
The most common models address surface runoff, al- ter oysters, trouts, and other high value seafood, highest
lowing variation in land use type, topography, soil type, productivity and economic returns are achieved by mim-
vegetative cover, precipitation, and land management icking the TDS and pH levels of each species' native en-
practice (e.g. the application rate of a fertilizer). Runoff vironment. For hydroponic uses, total dissolved solids is
models have evolved to a good degree of accuracy and considered one of the best indices of nutrient availability
permit the evaluation of alternative land management for the aquatic plants being grown.
practices upon impacts to stream water quality. Because the threshold of acceptable aesthetic criteria for
Basin models are used to more comprehensively evalu- human drinking water is 500 mg/l, there is no general
ate total dissolved solids within a catchment basin and concern for odor, taste, and color at a level much lower
dynamically along various stream reaches. The DSSAM than is required for harm. A number of studies have been
model was developed by the U.S. Environmental Protec- conducted and indicate various species’ reactions range
tion Agency (EPA).[3] This hydrology transport model is from intolerance to outright toxicity due to elevated TDS.
actually based upon the pollutant-loading metric called The numerical results must be interpreted cautiously, as
"Total Maximum Daily Load" (TMDL), which addresses true toxicity outcomes will relate to specific chemical
TDS and other specific chemical pollutants. The suc- constituents. Nevertheless, some numerical information
cess of this model contributed to the Agency’s broadened is a useful guide to the nature of risks in exposing aquatic
commitment to the use of the underlying TMDL proto- organisms or terrestrial animals to high TDS levels. Most
col in its national policy for management of many river aquatic ecosystems involving mixed fish fauna can toler-
systems in the United States.[4] ate TDS levels of 1000 mg/l.[6]
The Fathead minnow (Pimephales promelas), for exam-
ple, realizes an LD50 concentration of 5600 ppm based
3 Practical implications upon a 96-hour exposure. LD50 is the concentration re-
quired to produce a lethal effect on 50 percent of the ex-
High levels of total dissolved solids do not coorelate to posed population. Daphnia magna, a good example of a
hard water, as water softeners do not reduce TDS. Wa- primary member of the food chain, is a small planktonic
ter softners remove magnesium and calcium ions, which crustacean, about 0.5 mm in length, having an LD50 of
cause hard water, but these ions are replaced with an about 10,000 ppm TDS for a 96 hour exposure.[7]
equal number of sodium or potassium ions. This leaves Spawning fishes and juveniles appear to be more sen-
overall TDS unchanged.[5] Hard water can cause scale sitive to high TDS levels. For example, it was found
buildup in pipes, valves, and filters, reducing performance that concentrations of 350 mg/l TDS reduced spawning
3

5 See also
• Acid rain

• Surface runoff
• TDS meter

6 References
[1] DeZuane, John (1997). Handbook of Drinking Water
Quality (2nd ed.). John Wiley and Sons. ISBN 0-471-
28789-X.

[2] http://www.epa.gov/esd/cmb/pdf/JAG-TDSpublished.
pdf

[3] C.M. Hogan, Marc Papineau et al. Development of a


dynamic water quality simulation model for the Truc-
kee River, Earth Metrics Inc., Environmental Protection
Daphnia magna with eggs Agency Technology Series, Washington D.C. (1987)

[4] U.S. Environmental Protection Agency (EPA). Washing-


ton, D.C. “Guidance for Water Quality-Based Decisions:
of Striped bass (Morone saxatilis) in the San Francisco The TMDL Process.” Doc. No. EPA 440/4-91-001.
Bay-Delta region, and that concentrations below 200 mg/l April 1991.
promoted even healthier spawning conditions.[8] In the
Truckee River, EPA found that juvenile Lahontan cut- [5] W. Adam Sigler, Jim Bauder. “TDS Fact Sheet”. http:
throat trout were subject to higher mortality when ex- //waterquality.montana.edu/''. Montana State University.
posed to thermal pollution stress combined with high total Retrieved 23 January 2015.
dissolved solids concentrations.[3] [6] Boyd, Claude E. (1999). Water Quality: An Introduction.
For terrestrial animals, poultry typically possess a safe up- The Netherlands: Kluwer Academic Publishers Group.
per limit of TDS exposure of approximately 2900 mg/l, ISBN 0-7923-7853-9.
whereas dairy cattle are measured to have a safe upper [7] Position Paper on Total Dissolved Solids, State of Iowa,
limit of about 7100 mg/l. Research has shown that ex- IAC 567 61.3 (2)g et sequitur updated March 27, 2003
posure to TDS is compounded in toxicity when other
stressors are present, such as abnormal pH, high turbidity, [8] Kaiser Engineers, California, Final Report to the State of
or reduced dissolved oxygen with the latter stressor acting California, San Francisco Bay-Delta Water Quality Con-
trol Program, State of California, Sacramento, CA (1969)
only in the case of animalia.[9]
[9] Hogan, C. Michael; Patmore, Leda C.; Seidman (Au-
gust 1973). “Statistical Prediction of Dynamic Thermal
Equilibrium Temperatures using Standard Meteorological
4 Water classification Data Bases”. EPA-660/2-73-003. U.S. Environmental
Protection Agency. Retrieved 2007-03-06. |first3= miss-
ing |last3= in Authors list (help)
Water can be classified by the amount of TDS per liter:[10]
[10] Ela, Wendell P., Introduction to Environmental Engineer-
ing and Science, Prentice Hall, 3rd ed. 2007. ISBN 0-13-
• Fresh water < 1000 mg/L TDS 148193-2

• Brackish water 1000 to 10,000 mg/L TDS


7 External links
• Saline water 10,000 to 30,000 mg/L TDS
• Controlling TDS in boiler water
• Brine > 30,000 mg/L TDS

While a TDS of 5,000 mg/L is the minimum threshold


for a water to be considered brine, the typical range is
30,000 to 100,000 mg/L.
4 8 TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES

8 Text and image sources, contributors, and licenses


8.1 Text
• Total dissolved solids Source: https://en.wikipedia.org/wiki/Total_dissolved_solids?oldid=671547858 Contributors: Ubiquity, Michael
Hardy, Arpingstone, Pengo, Nagelfar, Alvestrand, Bobblewik, Kusunose, Mike Rosoft, Spiffy sperry, Vsmith, Brian0918, Circeus, Walk-
erma, Woohookitty, Emerson7, Halidecyphon, Bruce1ee, Wavelength, Zzuuzz, SmackBot, Edgar181, MikeParker, Oatmeal batman, Saip-
puakauppias, Anlace, Six.oh.six, Mbeychok, IronGargoyle, Covalent, Cydebot, Gproud, Christian75, Mbell, Email4mobile, DerHexer,
Xris0, MrBell, Borek, Vanished user 47736712, DoorsAjar, Olly150, UnitedStatesian, Petergans, SieBot, Lucasbfrbot, Happysailor, Jri-
zor8504, Bajsejohannes, Boing! said Zebedee, Moreau1, SchreiberBike, Thewellman, Addbot, Cantaloupe2, Hda3ku, Choij, Materi-
alscientist, Citation bot, Frankenpuppy, JUGGALO ICEBERG, Vingerhoet, Locobot, Citation bot 1, Pinethicket, RedBot, Cjperrittepa,
Theo10011, Iowasciencegal, K6ka, ClueBot NG, MelbourneStar, Piast93, Skoot13, Ghunter3016, Duderush, Mmarre, Saeid5, Mdy66,
Ybl-613h, Wywin, SkateTier, EChastain, PatrickJohnCollins and Anonymous: 71

8.2 Images
• File:Bristol.zoo.aquarium.arp.jpg Source: https://upload.wikimedia.org/wikipedia/commons/1/1d/Bristol.zoo.aquarium.arp.jpg Li-
cense: Public domain Contributors: Photographed by Adrian Pingstone Original artist: Adrian Pingstone
• File:Daphnia_magna01.jpg Source: https://upload.wikimedia.org/wikipedia/commons/2/21/Daphnia_magna01.jpg License: Public do-
main Contributors: ? Original artist: ?
• File:Pyramid_Lake_sat.jpg Source: https://upload.wikimedia.org/wikipedia/commons/5/52/Pyramid_Lake_sat.jpg License: Public do-
main Contributors: ? Original artist: ?
• File:Question_book-new.svg Source: https://upload.wikimedia.org/wikipedia/en/9/99/Question_book-new.svg License: Cc-by-sa-3.0
Contributors:
Created from scratch in Adobe Illustrator. Based on Image:Question book.png created by User:Equazcion Original artist:
Tkgd2007
• File:Stilles_Mineralwasser.jpg Source: https://upload.wikimedia.org/wikipedia/commons/0/02/Stilles_Mineralwasser.jpg License: CC-
BY-SA-3.0 Contributors: Original upload: de.wikipedia.org Original artist: Walter J. Pilsak, Waldsassen, Germany

8.3 Content license


• Creative Commons Attribution-Share Alike 3.0

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