Kertas Ujian

BAB V
TUGAS KHUSUS
5.1 Data/diagram Pengamatan Proses

(5)
(3)
(4)
(7) (6)
(1) (2)
(9)
(10)
(11)
(8)
Keterangan :
Stream (1) Input heat exchanger Stream (7) Refluks De-Propanizer
ṁ = 67780 lb/hr ṁ = 43520
T = 105 °F
P = 211 psi Stream (8) Input reboiler
T = 177.6 °F
Stream (2) Input Kolom De-Propanizer
ṁ = 67780 lb/hr Stream (9) Output reboiler (Vapor)
T = 143.5 °F T = 197.5 °F
P = 202 psi
Stream (10) Output reboiler (Liquid)
Stream (3) Output Kolom De-Propanizer (Top Produk) T = 197.5 °F
T = 113.3 °F
P = 193.3 psig Stream (11) Output Kolom De-Propanizer (Bottom Produk)
ṁ = 43290
Stream (4) Output kondenser T = 205 °F
T = 110.7 °F
Stream (5) Fuel output from akumulator

T = 105 °F
Stream (6) Output akumulator

ṁ = 67800
T = 108 °F
P = 195 psi
C₂H₆ = 0 6.78E+04
C₃H₈ = 54.6014 68860 45400 =
i-C₄H₁₀ = 11.2489 67820 45630
n-C₄H₁₀ = 14.7118 68490 46090
i-C₅H₁₂ = 6.1185 67310 44120
n-C₅H₁₂ = 3.093 44990
C₆H₁₄ = 10.2265
Reboiler
% mol
Komponen
7-Aug 8-Aug 9-Aug 10-Aug 11-Aug Mean
C₂H₆ Err:509 0.05 0.26 0.48 0.10 Err:509
C₃H₈ 54.60 56.94 55.87 57.57 57.33 56.46
i-C₄H₁₀ 11.25 10.95 11.04 10.80 10.83 10.97
n-C₄H₁₀ 14.71 14.12 14.29 13.82 13.90 14.17
i-C₅H₁₂ 6.12 5.74 5.87 5.56 5.62 5.78
n-C₅H₁₂ 3.09 2.86 2.96 2.79 2.83 2.91
C₆H₁₄ 10.23 9.35 9.71 9.00 9.39 9.53
Total Err:509 100 100 100 100 Err:509
1. Menghitung Neraca M
Kolom De-Propanizer se
Komposisi Stream (6)

C₂H₆
C₃H₈
(3) (4) i-C₄H₁₀
n-C₄H₁₀ =
Total
(6) (5)
(7)
(1) (2)
(9) Komposisi NGL masuk

C₂H₆
C₃H₈
(10) i-C₄H₁₀
n-C₄H₁₀ =
(8) i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
(11) Total
Gambar 1. Unit 03-C-4101 (kolom de-propanizer)
Tabel 1. Data laju aliran massa NGL masuk - Stream (2)

Tanggal Flowrate (lb/hr)
07/08/2017 67824
08/08/2017 69223
09/08/2017 68075
10/08/2017 69083
11/08/2017 67712 Gambar L1.
∑ Flow gas NGL
Vngl = 68383
ni
Sumber : logsheet laju aliran massa NGL masuk
Tabel 2. Komposisi NGL masuk - Stream (2) • Neraca Massa

7-Aug 8-Aug 9-Aug 10-Aug 11-Aug Mean ṁ input
C₂H₆ 0 0.05 0.26 0.48 0.10 0.18
C₃H₈ 54.60 56.94 55.87 57.57 57.33 56.46 a) Input kolom De-Propa
i-C₄H₁₀ 11.25 10.95 11.04 10.80 10.83 10.97 ṁ=
n-C₄H₁₀ 14.71 14.12 14.29 13.82 13.90 14.17
i-C₅H₁₂ 6.12 5.74 5.87 5.56 5.62 5.78
n-C₅H₁₂ 3.09 2.86 2.96 2.79 2.83 2.91
C₆H₁₄ 10.23 9.35 9.71 9.00 9.39 9.53 Mencari fraksi mol
Total 100 100 100 100 100 100 C₂H₆ =
Sumber : laboratorium analisis GC PT. Perta-Samtan Gas
Tabel 3. Data laju aliran massa output de-propanizer akumulator - Stream (5)
07/08/2017 67790
08/08/2017 67387 Untuk fraksi mol kompo
09/08/2017 66531 dilihat pada tabel dibawa
10/08/2017 64693
11/08/2017 63548 Mencari BM campuran
∑ Flow gas C₂H₆ =
V= 65990
ni
Sumber : logsheet laju aliran massa output de-propanizer akumulator
Untuk BM campuran ko
dapat dilihat pada tabel d
Komponen
C₂H₆
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total
Mencari mol total stream

mol total
Tabel 4. Komposisi output de-propanizer akumulator - Stream (5)
% mol
Komponen
C₂H₆ 0.04 0.51 0.85 0.06 0.66 0.42
Mencari mol komponen
C₂H₆ =
Untuk mol komponen la

pada tabel dibawah
Mencari massa kompone

C₂H₆ =
Untuk massa komponen

dilihat pada tabel dibawa
C₃H₈ 93.87 93.67 94.53 92.02 94.22 93.66
i-C₄H₁₀ 4.59 4.39 3.91 5.14 4.22 4.45
Komponen
n-C₄H₁₀ 1.59 1.39 0.73 2.81 0.90 1.48
Total 100 100 100 100 100 100 C₂H₆
Sumber : analisis GC online PT. Perta-Samtan Gas C₃H₈
i-C₄H₁₀
Tabel 5. Data laju aliran massa refluks de-propanizer - Stream (6) n-C₄H₁₀
Tanggal Flowrate (lb/hr) i-C₅H₁₂
07/08/2017 43509 n-C₅H₁₂
08/08/2017 41858 C₆H₁₄
09/08/2017 44572 Total
10/08/2017 36430
11/08/2017 43621 b) Output Kolom De-Pro
∑ Flow gas reflu ṁ=
V= 41998
ni
Sumber : logsheet laju aliran massa refluks de-propanizer Mencari fraksi mol
Tabel 6. Data laju aliran massa top product - Stream (7) C₂H₆ =
07/08/2017 24281
Untuk fraksi mol kompo

Mencari BM campuran
C₂H₆ =
Untuk BM campuran ko
dapat dilihat pada tabel d
Komponen
C₂H₆
C₃H₈
08/08/2017 25529 i-C₄H₁₀
09/08/2017 21959 n-C₄H₁₀
10/08/2017 28263 Total
11/08/2017 19927
∑ Flow gas Mencari mol total stream
V= 23992
ni mol total
Sumber : logsheet laju aliran massa to static mixer
Tabel 7. Kondisi operasi pada unit de-propanizer colomn

7-Aug 8-Aug 9-Aug 10-Aug 11-Aug
• Kolom depropanizer
Tekanan input (psi) 202 200 200 200 200 200.4 Mencari mol komponen
Temperatur input (°F) 143.5 128.7 143.4 142.5 128.7 137.36 C₂H₆ =
• Output de-propanizer
Tek. produk atas (psig) 193.3 189.6 200.9 205.4 191.9 196.22

pada tabel dibawah
Mencari massa kompone

C₂H₆ =

Komponen
C₂H₆
C₃H₈
Temp. produk atas (°F) 113.3 112.2 115.1 121.7 111.1 114.68 i-C₄H₁₀
Temp. produk bawah (°F) 205 205 205 205 205 205 n-C₄H₁₀
• Reboiler Total
Temp. input (°F) 177.6 179.3 181.7 184.5 176.5 179.92
Temp. output (°F) 197.5 199.8 202.2 204.9 197.5 200.38
• Kondenser
Tek. input (psig) 193.3 189.6 200.9 205.4 191.9 196.22 c) Output Kolom De-Pro
Temp. input (°F) 113.3 112.2 115.1 121.7 111.1 114.68
Temp. output (°F) 110.7 108.6 112.3 117.3 108 111.38 ṁ bottom product =
• Akumulator ṁ bottom product =
Tek. masuk (psi) 197 200 190 200 199 197.2 ṁ bottom product =
Temp. masuk (°F) 110.7 108.6 112.3 117.3 108 111.38
Tek. keluar (psi) 195 195 190 199 195 194.8 Mencari massa kompone
Temp. vapour (°F) 105 102 99 108 93 101.4 C₃H₈ =
Temp. liquid (°F) 108 106 96 96 118 104.8
Sumber : Logsheet harian Perta-Samtan Gas

Komponen
C₂H₆
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total

C₃H₈ =

pada tabel dibawah
Mencari % mol
C₃H₈ =
Untuk % mol komponen

Komponen
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total
Neraca Massa Kolom De

Komponen
C₂H₆
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total
LAMPIRAN B
PERHITUNGAN
1. Menghitung Neraca Massa, Neraca Energi dan Konsumsi Energi Spesifik pada
Kolom De-Propanizer secara Aktual

C₂H₆ = 0.42 % P = 196.2 psig
C₃H₈ = 93.66 % T = 114.68 °F T = 111.38 °F
i-C₄H₁₀ = 4.45 % (2) (3)
n-C₄H₁₀ = 1.48 %
Total = 100 %
ṁ = 41998 lb/hr P = 194.8 psig

P = 200.4 psi (5) T 104.80 °F
T = 137.36 °F ṁ = 65990 lb/hr
ṁ = 68383 lb/hr (4)
(1) (6)
T = 200.38 °F ṁ = 23992 lb/hr
Komposisi NGL masuk : (8)
C₂H₆ = 0.18 %
C₃H₈ = 56.46 %
i-C₄H₁₀ = 10.97 % (9)
n-C₄H₁₀ = 14.17 %
i-C₅H₁₂ = 5.78 % (7) T = 179.92 °F
n-C₅H₁₂ = 2.91 %
C₆H₁₄ = 9.53 % T = 205.00 °F
Total = 100 % (10) ṁ= …?

C₃H₈ = …?
i-C₄H₁₀ = … ?
n-C₄H₁₀ = … ?
i-C₅H₁₂ = … ?
n-C₅H₁₂ = … ?
C₆H₁₄ = … ?
Gambar L1. Unit 03-C-4101 (kolom de-propanizer)

• Neraca Massa
ṁ input = ṁ top product + ṁ bottom product
a) Input kolom De-Propanizer

ṁ = 68383 lb/hr
T = 137.36 °F
P = 200.4 psi
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.18
100
= 0.002
Untuk fraksi mol komponen lainnya dicari menggunakan cara yang sama dan dapat
dilihat pada tabel dibawah
Mencari BM campuran
C₂H₆ = fraksi mol x BM
= 0.002 x 30 lb/lbmol
= 0.05 lb/lbmol
Untuk BM campuran komponen lainnya dicari menggunakan cara yang sama dan
dapat dilihat pada tabel dibawah
BM BM campuran
Komponen mol (%) fraksi mol
(lb/lbmol) (lb/lbmol)
C₂H₆ 0.18 0.002 30 0.05
C₃H₈ 56.46 0.565 44 24.84
i-C₄H₁₀ 10.97 0.110 58 6.36
n-C₄H₁₀ 14.17 0.142 58 8.22
i-C₅H₁₂ 5.78 0.058 72 4.16
n-C₅H₁₂ 2.91 0.029 72 2.09
C₆H₁₄ 9.53 0.095 86 8.20
Total 100 1 - 53.93
Mencari mol total stream 1

mol total= ṁ
BM campuran
= 68383 lb/hr
53.93 lb/lbmol
= 1267.95 lbmol

C₂H₆ = fraksi mol x mol total
= 0.002 x 1267.95 lbmol
= 2.24 lbmol
Untuk mol komponen lainnya dicari menggunakan cara yang sama dan dapat dilihat
pada tabel dibawah
Mencari massa komponen

C₂H₆ = mol komponen x BM
= 2.24 lbmol x 30 lb/lbmol
= 67 lb
Untuk massa komponen lainnya dicari menggunakan cara yang sama dan dapat
mol BM massa
Komponen fraksi mol
(lbmol) (lb/lbmol) (lb)
C₂H₆ 0.002 2.24 30 67
C₃H₈ 0.565 715.90 44 31500
i-C₄H₁₀ 0.110 139.14 58 8070
n-C₄H₁₀ 0.142 179.65 58 10419
i-C₅H₁₂ 0.058 73.29 72 5277
n-C₅H₁₂ 0.029 36.85 72 2653
C₆H₁₄ 0.095 120.90 86 10397
Total 1 1267.96 - 68383
b) Output Kolom De-Propanizer (top produk)

ṁ = 23992 lb/hr
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.42
100
= 0.004
Mencari BM campuran
= 0.004 x 30 lb/lbmol
= 0.13 lb/lbmol
BM BM campuran
C₂H₆ 0.42 0.0042 30 0.13
C₃H₈ 93.66 0.9366 44 41.21
i-C₄H₁₀ 4.45 0.0445 58 2.58
n-C₄H₁₀ 1.48 0.0148 58 0.86
Total 100 1 - 44.78

mol total= ṁ
BM campuran
= 23992 lb/hr
44.78 lb/lbmol
= 535.82 lbmol

= 0.004 x 535.82 lbmol
= 2.25 lbmol
pada tabel dibawah

= 68 lb
mol BM massa
Komponen fraksi mol
C₂H₆ 0.0042 2.25 30 68
C₃H₈ 0.9366 501.85 44 22081
i-C₄H₁₀ 0.0445 23.84 58 1383
n-C₄H₁₀ 0.0148 7.93 58 460
Total 1 535.87 - 23992
c) Output Kolom De-Propanizer (bottom produk)

ṁ bottom product = ṁ input - ṁ top product
ṁ bottom product = 68383 lb/hr - 23992 lb/hr
ṁ bottom product = 44392 lb/hr

C₃H₈ = massa stream 1 - massa stream 6
= 31500 lb - 22081 lb
= 9418 lb
Massa (lb)
Komponen
Input Top Product Bottom Product
C₂H₆ 67 68 -
C₃H₈ 31500 22081 9418
i-C₄H₁₀ 8070 1383 6687
n-C₄H₁₀ 10419 460 9960
i-C₅H₁₂ 5277 - 5277
n-C₅H₁₂ 2653 - 2653
C₆H₁₄ 10397 - 10397
Total 68316 23924 44392

C₃H₈ = massa komponen
BM
= 9418 lb
44 lb/lbmol
= 214.05 lbmol
pada tabel dibawah
Mencari % mol
C₃H₈ = mol komponen
x 100 %
mol total
= 214 lb
732 lb/lbmol
= 0.29 lbmol
Untuk % mol komponen lainnya dicari menggunakan cara yang sama dan dapat
massa BM mol mol
Komponen
(lb) (lb/lbmol) (lbmol) (%)
C₃H₈ 9418 44 214.05 29
i-C₄H₁₀ 6687 58 115.30 16
n-C₄H₁₀ 9960 58 171.72 23
i-C₅H₁₂ 5277 72 73.29 10
n-C₅H₁₂ 2653 72 36.85 5
C₆H₁₄ 10397 86 120.90 17
Total 44392 - 732.10 100
Neraca Massa Kolom De-Propanizer

Input Output (lb)
Komponen
(lb) top product bottom product
C₂H₆ 67 68 -
C₃H₈ 31500 22081 9418
i-C₄H₁₀ 8070 1383 6687
n-C₄H₁₀ 10419 460 9960
i-C₅H₁₂ 5277 - 5277
n-C₅H₁₂ 2653 - 2653
C₆H₁₄ 10397 - 10397
23992 44392
Total 68383
68384
C₂H₆
C₃H₈
(3) (4) (5) i-C₄H₁₀
n-C₄H₁₀ =
C₆H₁₄
Total
(7) (6)
(8)
(1) (2) (1)
(9) Komposisi NGL masuk

C₂H₆
C₃H₈
(10) i-C₄H₁₀
n-C₄H₁₀ =
(11) i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
(12) Total
Tabel 1. Data laju aliran massa NGL masuk - Stream (2)

07/08/2017 67824
08/08/2017 69223
09/08/2017 68075
10/08/2017 69083
11/08/2017 67712
∑ Flow gas NGL Gambar 2. U
Vngl = 68383
ni
Sumber : logsheet laju aliran massa NGL masuk
Tabel 2. Komposisi NGL masuk - Stream (2)
% mol
Komponen
7-Aug 8-Aug 9-Aug 10-Aug 11-Aug Mean ṁ input
C₂H₆ 0 0.05 0.26 0.48 0.10 0.18 ṁ input
C₃H₈ 54.60 56.94 55.87 57.57 57.33 56.46
i-C₄H₁₀ 11.25 10.95 11.04 10.80 10.83 10.97 • Input kolom De-Propan
n-C₄H₁₀ 14.71 14.12 14.29 13.82 13.90 14.17 ṁ=
i-C₅H₁₂ 6.12 5.74 5.87 5.56 5.62 5.78
n-C₅H₁₂ 3.09 2.86 2.96 2.79 2.83 2.91
C₆H₁₄ 10.23 9.35 9.71 9.00 9.39 9.53
Total 100 100 100 100 100 100 Mencari BM campuran
Sumber : laboratorium analisis GC PT. Perta-Samtan Gas
Komponen
Tabel 3. Data laju aliran massa output de-propanizer akumulator - Stream (6) C₂H₆
Tanggal Flowrate (lb/hr) C₃H₈
07/08/2017 67790 i-C₄H₁₀
08/08/2017 67387 n-C₄H₁₀
09/08/2017 66531 i-C₅H₁₂
10/08/2017 64693 n-C₅H₁₂
11/08/2017 63548 C₆H₁₄
∑ Flow gas Total
V= 65990
ni
Sumber : logsheet laju aliran massa output de-propanizer akumulator Mencari mol total
mol total
Tabel 4. Komposisi output de-propanizer akumulator - Stream (6)
% mol
Komponen
C₂H₆ 0.04 0.6 0.94 0.15 0.75 0.50
C₃H₈ 93.8 93.6 94.46 91.95 94.15 93.59
i-C₄H₁₀ 4.56 4.36 3.88 5.11 4.19 4.42 Mencari massa kompone
n-C₄H₁₀ 1.55 1.35 0.69 2.77 0.86 1.44
Komponen
C₆H₁₄ 0.05 0.09 0.03 0.02 0.05 0.05
Total 100 100 100 100 100 100 C₂H₆
Sumber : analisis GC online PT. Perta-Samtan Gas C₃H₈
i-C₄H₁₀
Tabel 5. Data laju aliran massa refluks de-propanizer - Stream (7) n-C₄H₁₀
Tanggal Flowrate (lb/hr) i-C₅H₁₂
07/08/2017 43509 n-C₅H₁₂
08/08/2017 41858 C₆H₁₄
09/08/2017 44572 Total
10/08/2017 36430
11/08/2017 43621
∑ Flow gas reflu
V= 41998
ni
Sumber : logsheet laju aliran massa refluks de-propanizer • Output kolom De-Prop
1. Top Product
Tabel 6. Data laju aliran massa top product - Stream (8) ṁ=
07/08/2017 24281 Mencari BM campuran
08/08/2017 25529
Komponen
09/08/2017 21959
10/08/2017 28263 C₂H₆
11/08/2017 19927 C₃H₈
∑ Flow gas i-C₄H₁₀
V= 23992
ni n-C₄H₁₀
Sumber : logsheet laju aliran massa to static mixer C₆H₁₄
Total
Tabel 7. Data laju aliran massa bottom product - Stream (12)
Tanggal Flowrate (lb/hr) Mencari mol total
07/08/2017 43285 mol total
08/08/2017 43817
09/08/2017 44236
10/08/2017 42390
11/08/2017 43285
∑ Flow gas
V= 43403
ni Mencari massa kompone
Sumber : logsheet laju aliran massa output kolom de-propanizer
Komponen
Tabel 8. Komposisi bottom product - Stream (12) C₂H₆
% mol C₃H₈
Komponen
7-Aug 8-Aug 9-Aug 10-Aug 11-Aug Mean i-C₄H₁₀
C₃H₈ 19.11 18.67 20.32 19.75 17.51 19.07 n-C₄H₁₀
i-C₄H₁₀ 20.8 20.48 20.51 20.1 20.9 20.56 C₆H₁₄
n-C₄H₁₀ 29.59 29.07 28.9 28.42 29.31 29.06 Total
i-C₅H₁₂ 11.11 11.26 10.75 11.48 11.23 11.17
n-C₅H₁₂ 7.15 7.27 6.93 7.29 7.34 7.20
C₆H₁₄ 12.23 13.25 12.59 12.96 13.71 12.95
Total 100 100 100 100 100 100
Sumber : analisis GC online PT. Perta-Samtan Gas
Tabel 9. Kondisi operasi pada unit de-propanizer 2. Bottom Product
Tanggal (2017) ṁ=
Parameter Mean
7-Aug 8-Aug 9-Aug 10-Aug 11-Aug
• Kolom depropanizer
Tekanan input (psi) 202 200 200 200 200 200.4 Mencari BM campuran
Temperatur input (°F) 143.5 128.7 143.4 142.5 128.7 137.36
Komponen
• Output de-propanizer
Tek. produk atas (psig) 193.3 189.6 200.9 205.4 191.9 196.22 C₃H₈
Temp. produk atas (°F) 113.3 112.2 115.1 121.7 111.1 114.68 i-C₄H₁₀
Temp. produk bawah (°F) 205 205 205 205 205 205 n-C₄H₁₀
• Reboiler i-C₅H₁₂
Temp. input (°F) 177.6 179.3 181.7 184.5 176.5 179.92 n-C₅H₁₂
Temp. output (°F) 197.5 199.8 202.2 204.9 197.5 200.38 C₆H₁₄
• Kondenser Total
Tek. input (psig) 193.3 189.6 200.9 205.4 191.9 196.22
Temp. input (°F) 113.3 112.2 115.1 121.7 111.1 114.68 Mencari mol total
Temp. output (°F) 110.7 108.6 112.3 117.3 108 111.38 mol total
• Akumulator
Tek. masuk (psi) 197 200 190 200 199 197.2
Temp. masuk (°F) 110.7 108.6 112.3 117.3 108 111.38
Tek. keluar (psi) 195 195 190 199 195 194.8
Temp. vapour (°F) 105 102 99 108 93 101.4
Temp. liquid (°F) 108 106 96 96 118 104.8 Mencari massa kompone
Sumber : Logsheet harian Perta-Samtan Gas
Komponen
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total
3. Fuel gas
ṁ fuel gas
ṁ fuel gas
ṁ fuel gas
Mencari BM campuran
Komponen
C₂H₆
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Total
3. Fuel gas
ṁ fuel gas
ṁ fuel gas
ṁ fuel gas
Neraca Massa
Komponen
C₂H₆
C₃H₈
i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
fuel gas
Total
C₂H₆ = 0.50 P = 196.2 psig
C₃H₈ = 93.59 T = 114.68 °F T = 111.38 °F T = 101.40 °F
i-C₄H₁₀ = 4.42 (3) (4) (5)
n-C₄H₁₀ = 1.44
C₆H₁₄ = 0.05
Total = 100
ṁ = 41998 lb/hr P = 194.8 psig

P = 200.4 psi (7) T 104.80 °F
T = 137.36 °F ṁ = 65990 lb/hr
ṁ = 68383 lb/hr (6)
(2) (8)
T = 200.38 °F ṁ= 23992 lb/hr
C₂H₆ = 0.18
C₃H₈ = 56.46
i-C₄H₁₀ = 10.97 (10)
n-C₄H₁₀ = 14.17
i-C₅H₁₂ = 5.78 (11) T = 179.92 °F
n-C₅H₁₂ = 2.91
C₆H₁₄ = 9.53 T = 205.00 °F
Total = 100 (12) ṁ = 43403 lb/hr

C₃H₈ = 19.07
i-C₄H₁₀ = 20.56
n-C₄H₁₀ = 29.06
i-C₅H₁₂ = 11.17
n-C₅H₁₂ = 7.20
C₆H₁₄ = 12.95
Total = 100

PERHITUNGAN
ṁ input = ṁ fuel gas + ṁ top product + ṁ bottom product

ṁ input = (ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom product
• Input kolom De-Propanizer

ṁ = 68383 lb/hr
T = 137.36 °F
P = 200.4 psi
Mencari BM campuran
BM BM campuran
C₂H₆ 0.18 0.002 30 0.05
C₃H₈ 56.46 0.565 44 24.84
i-C₄H₁₀ 10.97 0.110 58 6.36
n-C₄H₁₀ 14.17 0.142 58 8.22
i-C₅H₁₂ 5.78 0.058 72 4.16
n-C₅H₁₂ 2.91 0.029 72 2.09
C₆H₁₄ 9.53 0.095 86 8.20
Total 100 1 - 53.93
Mencari mol total

mol total= ṁ
BM campuran
= 68383 lb/hr
53.93 lb/lbmol
= 1267.95 lbmol

mol BM massa
Komponen fraksi mol fraksi berat
C₂H₆ 0.002 2.24 30 67 0.001
C₃H₈ 0.565 715.90 44 31500 0.461
i-C₄H₁₀ 0.110 139.14 58 8070 0.118
n-C₄H₁₀ 0.142 179.65 58 10419 0.152
i-C₅H₁₂ 0.058 73.29 72 5277 0.077
n-C₅H₁₂ 0.029 36.85 72 2653 0.039
C₆H₁₄ 0.095 120.90 86 10397 0.152
Total 1 1267.96 - 68383 1
• Output kolom De-Propanizer (top produk)
1. Top Product
ṁ = 23992 lb/hr
Mencari BM campuran
BM BM campuran
C₂H₆ 0.50 0.0050 30 0.15
C₃H₈ 93.59 0.9359 44 41.18
i-C₄H₁₀ 4.42 0.0442 58 2.56
n-C₄H₁₀ 1.44 0.0144 58 0.84
C₆H₁₄ 0.05 0.0005 86 0.04
Total 100 1 - 44.77
Mencari mol total

mol total= ṁ
BM campuran
= 23992 lb/hr
44.77 lb/lbmol
= 535.87 lbmol

mol BM massa
C₂H₆ 0.0050 2.66 30 80 0.003
C₃H₈ 0.9359 501.53 44 22067 0.920
i-C₄H₁₀ 0.0442 23.69 58 1374 0.057
n-C₄H₁₀ 0.0144 7.74 58 449 0.019
C₆H₁₄ 0.0005 0.26 86 22 0.001
Total 1 535.87 - 23992 1
2. Bottom Product
ṁ = 43403 lb/hr
T = 205.00 °F
Mencari BM campuran
BM BM campuran
C₃H₈ 19.07 0.191 44 8.39
i-C₄H₁₀ 20.56 0.206 58 11.92
n-C₄H₁₀ 29.06 0.291 58 16.85
i-C₅H₁₂ 11.17 0.112 72 8.04
n-C₅H₁₂ 7.20 0.072 72 5.18
C₆H₁₄ 12.95 0.129 86 11.14
Total 100 1 - 61.52
Mencari mol total

mol total= ṁ
BM campuran
= 43403 lb/hr
61.52 lb/lbmol
= 705.45 lbmol

mol BM massa
C₃H₈ 0.191 134.54 44 5920 0.136
i-C₄H₁₀ 0.206 145.03 58 8412 0.194
n-C₄H₁₀ 0.291 204.99 58 11889 0.274
i-C₅H₁₂ 0.112 78.77 72 5671 0.131
n-C₅H₁₂ 0.072 50.76 72 3655 0.084
C₆H₁₄ 0.129 91.34 86 7855 0.181
Total 1 705.43 - 43403 1
3. Fuel gas
ṁ fuel gas = ṁ input - (ṁ top product + ṁ bottom product)
ṁ fuel gas = 68383 lb/hr - ( 23992 + 43403 ) lb/hr
ṁ fuel gas = 989 lb/hr
Mencari BM campuran
massa (lb)
Komponen
input top product bottom product fuel gas
C₂H₆ 67 80 -
C₃H₈ 31500 22067 5920
i-C₄H₁₀ 8070 1374 8412
n-C₄H₁₀ 10419 449 11889
i-C₅H₁₂ 5277 - 5671
n-C₅H₁₂ 2653 - 3655
C₆H₁₄ 10397 22 7855
Total 68383 23992 43403
3. Fuel gas
ṁ fuel gas = ṁ input - (ṁ top product + ṁ bottom product)
ṁ fuel gas = 68383 lb/hr - ( 23992 + 43403 ) lb/hr
ṁ fuel gas = 989 lb/hr
Neraca Massa
Input Output (lb)
Komponen
C₂H₆ 67 80 -
C₃H₈ 31500 22067 5920
i-C₄H₁₀ 8070 1374 8412
n-C₄H₁₀ 10419 449 11889
i-C₅H₁₂ 5277 - 5671
n-C₅H₁₂ 2653 - 3655
C₆H₁₄ 10397 22 7855
fuel gas - 989 -
24981 43403
Total 68383
68383
LAMPIRAN B
PERHITUNGAN
Kolom De-Propanizer secara Desain

C₂H₆ = #REF! % P = #REF!
C₃H₈ = #REF! % T = #REF! T = #REF!
i-C₄H₁₀ = #REF! % (2) (3)
n-C₄H₁₀ = #REF! %
Total = #REF! %
ṁ= #REF! P = #REF!
P = #REF! (5) T #REF!
T = #REF! ṁ = #REF!
ṁ = #REF! (4)
(1) (6)
T = #REF! ṁ= #REF!
C₂H₆ = #REF! %
C₃H₈ = #REF! %
i-C₄H₁₀ = #REF! % (9)
n-C₄H₁₀ = #REF! %
i-C₅H₁₂ = #REF! % (7) T = #REF!
n-C₅H₁₂ = #REF! %
C₆H₁₄ = #REF! % T = #REF!
Total = #REF! % (10) ṁ= …?

C₃H₈ = …?
i-C₄H₁₀ = … ?
n-C₄H₁₀ = … ?
i-C₅H₁₂ = … ?
n-C₅H₁₂ = … ?
C₆H₁₄ = … ?

Kolom De-Propanizer secara Desain
• Neraca Massa
a) Input kolom De-Propanizer • Input kolom De-Prop

ṁ = 85545 lb/hr ṁ=
T = 127.40 °F
P = 237.6 psig
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.15
100
= 0.002
Mencari BM campuran
= 0.002 x 30 lb/lbmol
= 0.05 lb/lbmol
BM BM campuran
Komponen mol (%) fraksi mol Komponen
C₂H₆ 0.15 0.002 30 0.05 C₂H₆
C₃H₈ 58.40 0.584 44 25.70 C₃H₈
i-C₄H₁₀ 11.63 0.116 58 6.74 i-C₄H₁₀
n-C₄H₁₀ 14.02 0.140 58 8.13 n-C₄H₁₀
i-C₅H₁₂ 5.32 0.053 72 3.83 i-C₅H₁₂
n-C₅H₁₂ 2.91 0.029 72 2.10 n-C₅H₁₂
C₆H₁₄ 3.40 0.034 86 2.92 C₆H₁₄
C₇H₁₆ 2.70 0.027 100 2.70 C7H₁6
C₈H₁₈ 1.23 0.012 114 1.40 C8H₁8
C₉H₂₀ 0.21 0.002 128 0.27 C9H20
C₁₀H₂₂ 0.04 0.000 142 0.05 C10H22
Total 100 1 - 53.88 Total
Mencari mol total stream 1 Mencari mol total

mol total= ṁ mol total
BM campuran
= 85545 lb/hr
53.88 lb/lbmol
= 1587.60 lbmol

= 0.002 x 1587.60 lbmol
= 2.38 lbmol
pada tabel dibawah

= 71 lb
mol BM massa
Komponen fraksi mol Komponen
C₂H₆ 0.002 2.38 30 71 C₂H₆
C₃H₈ 0.584 927.14 44 40794 C₃H₈
i-C₄H₁₀ 0.116 184.59 58 10706 i-C₄H₁₀
n-C₄H₁₀ 0.140 222.57 58 12909 n-C₄H₁₀
i-C₅H₁₂ 0.053 84.46 72 6081 i-C₅H₁₂
n-C₅H₁₂ 0.029 46.22 72 3327 n-C₅H₁₂
C₆H₁₄ 0.034 53.91 86 4637 C₆H₁₄
C₇H₁₆ 0.027 42.91 100 4291 C7H₁6
C₈H₁₈ 0.012 19.53 114 2226 C8H₁8
C₉H₂₀ 0.002 3.30 128 423 C9H20
C₁₀H₂₂ 0.000 0.56 142 79 C10H22
Total 1 1587.57 - 85545 Total
b) Output Kolom De-Propanizer (top produk) • Output kolom De-Pro
ṁ = 34157 lb/hr ṁ=
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.31
100
= 0.003
Mencari BM campuran
= 0.003 x 30 lb/lbmol
= 0.09 lb/lbmol
BM BM campuran
C₂H₆ 0.31 0.003 30 0.09 C₂H₆
C₃H₈ 98.00 0.980 44 43.12 C₃H₈
i-C₄H₁₀ 1.57 0.016 58 0.91 i-C₄H₁₀
n-C₄H₁₀ 0.12 0.001 58 0.07 n-C₄H₁₀
Mencari mol total Mencari mol total

BM campuran
= 34157 lb/hr
44.19 lb/lbmol
= 772.89 lbmol
= 0.003 x 772.89 lbmol
= 2.39 lbmol
pada tabel dibawah

= 72 lb
mol BM massa
C₂H₆ 0.003 2.39 30 72 C₂H₆
C₃H₈ 0.980 757.42 44 33326 C₃H₈
i-C₄H₁₀ 0.016 12.13 58 704 i-C₄H₁₀
n-C₄H₁₀ 0.001 0.95 58 55 n-C₄H₁₀
Total 1 772.89 - 34157 Total
c) Output Kolom De-Propanizer (bottom produk) 2. Bottom Product

ṁ = 51389 lb/hr ṁ=
T = 205.00 °F
Mencari fraksi mol

C₃H₈ = % mol
100
= 20.84
100
= 0.208
Mencari BM campuran
C₃H₈ = fraksi mol x BM
= 0.208 x 44 lb/lbmol
= 9.17 lb/lbmol
BM BM campuran
C₃H₈ 20.84 0.208 44 9.17 C₃H₈
i-C₄H₁₀ 21.17 0.212 58 12.28 i-C₄H₁₀
n-C₄H₁₀ 27.20 0.272 58 15.78 n-C₄H₁₀
i-C₅H₁₂ 10.37 0.104 72 7.46 i-C₅H₁₂
n-C₅H₁₂ 5.67 0.057 72 4.08 n-C₅H₁₂
C₆H₁₄ 6.62 0.066 86 5.69 C₆H₁₄
C₇H₁₆ 5.27 0.053 100 5.27 C7H₁6
C₈H₁₈ 2.40 0.024 114 2.73 C8H₁8
C₉H₂₀ 0.41 0.004 128 0.52 C9H20
C₁₀H₂₂ 0.07 0.001 142 0.10 C10H22

BM campuran
= 51389 lb/hr
63.08 lb/lbmol
= 814.70 lbmol

= 0.208 x 814.70 lbmol
= 169.75 lbmol
pada tabel dibawah

= 7469 lb
mol BM massa
C₃H₈ 0.208 169.75 44 7469 C₃H₈
i-C₄H₁₀ 0.212 172.46 58 10002 i-C₄H₁₀
n-C₄H₁₀ 0.272 221.61 58 12853 n-C₄H₁₀
i-C₅H₁₂ 0.104 84.45 72 6081 i-C₅H₁₂
n-C₅H₁₂ 0.057 46.22 72 3328 n-C₅H₁₂
C₆H₁₄ 0.066 53.92 86 4637 C₆H₁₄
C₇H₁₆ 0.053 42.92 100 4292 C7H₁6
C₈H₁₈ 0.024 19.53 114 2226 C8H₁8
C₉H₂₀ 0.004 3.30 128 422 C9H20
C₁₀H₂₂ 0.001 0.55 142 79 C10H22
Total 1 814.70 - 51389 Total

Input Output (lb)
Komponen Komponen
C₂H₆ 71 72 - C₂H₆
C₃H₈ 40794 33326 7469 C₃H₈
i-C₄H₁₀ 10706 704 10002 i-C₄H₁₀
n-C₄H₁₀ 12909 55 12853 n-C₄H₁₀
i-C₅H₁₂ 6081 - 6081 i-C₅H₁₂
n-C₅H₁₂ 3327 - 3328 n-C₅H₁₂
C₆H₁₄ 4637 - 4637 C₆H₁₄
C₇H₁₆ 4291 - 4292 C7H₁6
C₈H₁₈ 2226 - 2226 C8H₁8
C₉H₂₀ 423 - 422 C9H20
C₁₀H₂₂ 79 - 79 C10H22
34157 51389
Total 85545 Total
85546
msi Energi Spesifik pada

ṁ = 85545 lb/hr
T = 0.00 °F
P = 0.0 psi
cara yang sama dan dapat
BM BM campuran
C₂H₆ 0.15 0.002 30 0.05
C₃H₈ 58.40 0.584 44 25.70
i-C₄H₁₀ 11.63 0.116 58 6.74
n-C₄H₁₀ 14.02 0.140 58 8.13
i-C₅H₁₂ 5.32 0.053 72 3.83
n-C₅H₁₂ 2.91 0.029 72 2.10
C₆H₁₄ 7.58 0.076 86 6.52
C7H₁6 - - 100 -
C8H₁8 - - 114 -
C9H20 - - 128 -
C10H22 - - 142 -
Total 100 1 - 53.06
Mencari mol total

mol total= ṁ
BM campuran
= 85545 lb/hr
53.06 lb/lbmol
= 1612.22 lbmol
ang sama dan dapat dilihat
mol BM massa
Komponen fraksi mol
C₂H₆ 0.002 2.42 30 73
C₃H₈ 0.584 941.52 44 41427
i-C₄H₁₀ 0.116 187.45 58 10872
n-C₄H₁₀ 0.140 226.02 58 13109
i-C₅H₁₂ 0.053 85.77 72 6175
n-C₅H₁₂ 0.029 46.93 72 3379
C₆H₁₄ 0.076 122.21 86 10510
C7H₁6 - - 100 -
C8H₁8 - - 114 -
C9H20 - - 128 -
C10H22 - - 142 -
Total 1 1612.32 - 85545
ṁ = 34157 lb/hr
BM BM campuran
C₂H₆ 0.31 0.003 30 0.09
C₃H₈ 98.00 0.980 44 43.12
i-C₄H₁₀ 1.57 0.016 58 0.91
n-C₄H₁₀ 0.12 0.001 58 0.07
Total 100 1 - 44.19
Mencari mol total

mol total= ṁ
BM campuran
= 34157 lb/hr
44.19 lb/lbmol
= 772.89 lbmol
mol BM massa
Komponen fraksi mol
C₂H₆ 0.003 2.39 30 72
C₃H₈ 0.980 757.42 44 33326
i-C₄H₁₀ 0.016 12.13 58 704
n-C₄H₁₀ 0.001 0.95 58 55
Total 1 772.89 - 34157
2. Bottom Product
ṁ = 51389 lb/hr
T = 0.00 °F

BM BM campuran
C₃H₈ 20.84 0.208 44 9.17
i-C₄H₁₀ 21.17 0.212 58 12.28
n-C₄H₁₀ 27.20 0.272 58 15.78
i-C₅H₁₂ 10.37 0.104 72 7.46
n-C₅H₁₂ 5.67 0.057 72 4.08
C₆H₁₄ 14.77 0.148 86 12.70
C7H₁6 - - 100 -
C8H₁8 - - 114 -
C9H20 - - 128 -
C10H22 - - 142 -
Total 100 1 - 61.47
Mencari mol total

mol total= ṁ
BM campuran
= 51389 lb/hr
61.47 lb/lbmol
= 835.97 lbmol

mol BM massa
Komponen fraksi mol
C₃H₈ 0.208 174.18 44 7664
i-C₄H₁₀ 0.212 176.96 58 10264
n-C₄H₁₀ 0.272 227.39 58 13189
i-C₅H₁₂ 0.104 86.66 72 6239
n-C₅H₁₂ 0.057 47.42 72 3415
C₆H₁₄ 0.148 123.47 86 10619
C7H₁6 - - 100 -
C8H₁8 - - 114 -
C9H20 - - 128 -
C10H22 - - 142 -
Total 1 836.09 - 51389
Input Output (lb)

Komponen
C₂H₆ 73 72 -
C₃H₈ 41427 33326 7664
i-C₄H₁₀ 10872 704 10264
n-C₄H₁₀ 13109 55 13189
i-C₅H₁₂ 6175 - 6239
n-C₅H₁₂ 3379 - 3415
C₆H₁₄ 10510 - 10619
C7H₁6 - - -
C8H₁8 - - -
C9H20 - - -
C10H22 - - -
34157 51389
Total 85545
85546
• Neraca Energi Cp sensibel heat
T
a) Input Kolom De-Propanizer (Qs₁) T²
T input = 127.4 °F = 326.15 K T³
T ref = 60 °F = 288.71 K T⁴
P = 237.6 psi = 16.163 atm P
Komponen
Untuk menghitung harga kapasitas panas pada tekanan konstan digunakan
persamaan berikut : C₂H₆
C₃H₈
Cp = a + b x T + c x T² + d x T³, T in K (Sherwood) i-C₄H₁₀
n-C₄H₁₀
Dimana nilai a, b, c, dan d masing-masing komponen adalah sebagai berikut :i-C₅H₁₂
b c d n-C₅H₁₂
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹) C₆H₁₄
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 Cp sensibel heat
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 T
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 T²
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 T³
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 T⁴
Sumber : Thomas K Sherwood, The Properties of Gases and Liquid, 3rd edition, 1977
P
Mencari Cp
C₂H₆ = a + b x T + c x T² + d x T³ C₂H₆
= 1.292 + ( 0.043 x 326 K ) + -0.000017 x 106374 K C₃H₈
+ ( 2.80E-09 x 34693822 K ) i-C₄H₁₀
= 13.50 cal/gmol K n-C₄H₁₀
= 13.50 Btu/lbmol °F i-C₅H₁₂
n-C₅H₁₂
C₆H₁₄
Untuk nilai Cp komponen lainnya dicari menggunakan cara yang sama dan dapa
Cp sensibel heat
P T Cp T
Komponen
(atm) (K) (Btu/lbmol °F) T³
C₂H₆ 16.163 326.15 13.50 T⁴
C₃H₈ 16.163 326.15 19.08 P
i-C₄H₁₀ 16.163 326.15 25.19
Komponen
n-C₄H₁₀ 16.163 326.15 25.24
i-C₅H₁₂ 16.163 326.15 30.73 C₂H₆
n-C₅H₁₂ 16.163 326.15 30.98 C₃H₈
C₆H₁₄ 16.163 326.15 36.90 i-C₄H₁₀
n-C₄H₁₀
i-C₅H₁₂
Untuk menghitung harga kapasitas panas bertekanan tinggi menggunakan grafik
perpotongan antara Tr dan Pr sehingga didapatkan Cp-Cp*, dimana : n-C₅H₁₂
C₆H₁₄
Tr = T (K) dan Pr = P (atm)
Tc (K) Pc (atm)
Untuk nilai Tc dan Pc masing-masing komponen dapat dilihat pada tabel dibawah
Pc Tc
Komponen
(atm) (K)
C₂H₆ 48.2 305.4
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1
n-C₄H₁₀ 37.5 425.2
i-C₅H₁₂ 33.4 460.4
n-C₅H₁₂ 33.3 469.6
C₆H₁₄ 29.3 507.4
Sumber : J. M. Smith, Chemical Engineering Thermodynamics, 6th edition
Mencari Tr dan Pr
Tr C₂H₆ = 326.15 K Pr C₂H₆ = 16.163 atm
305.4 K 48.2 atm
= 1.068 = 0.335
Untuk nilai Tr dan Pr komponen lainnya dicari menggunakan cara yang sama dan
Mencari Cp-Cp*
Berdasarkan Grafik 108 Hougen, hal. 500 perpotongan antara Tr danPr
didapatkan nilai Cp - Cp* C₂H₆ = 1.9
Untuk nilai Cp-Cp* komponen lainnya dicari menggunakan cara yang sama dan
Mencari Cp*
C₂H₆ = (Cp - Cp*) + Cp
= 1.9 + 13.50 Btu/lbmol °F
= 15.40 Btu/lbmol °F
Untuk nilai Cp* komponen lainnya dicari menggunakan cara yang sama dan dapat
Pc Tc
Komponen Pr Tr Cp-Cp* Cp*
(atm) (K)
C₂H₆ 48.2 305.4 0.335 1.07 2.3 15.80
C₃H₈ 41.9 369.8 0.386 0.88 15 34.08
i-C₄H₁₀ 36 408.1 0.449 0.80 45 70.19
n-C₄H₁₀ 37.5 425.2 0.431 0.77 50 75.24
i-C₅H₁₂ 33.4 460.4 0.484 0.71 55 85.73
n-C₅H₁₂ 33.3 469.6 0.485 0.69 56 86.98
C₆H₁₄ 29.3 507.4 0.552 0.64 65 101.90
Mencari panas sensibel (Q)

C₂H₆ = m x Cp x ΔT
= 2.42 lbmol x 15.80 Btu/lbmol °F x ( 127.40 - 60 ) °F
= 2575.5 Btu
Untuk nilai Q komponen lainnya dicari menggunakan cara yang sama dan dapat
mol Cp* ΔT Q
Komponen
(lbmol)(Btu/lbmol F) (°F) (Btu)
C₂H₆ 2.42 15.80 67.4 2575.49
C₃H₈ 941.52 34.08 67.4 2162966.67
i-C₄H₁₀ 187.45 70.19 67.4 886775.52
n-C₄H₁₀ 226.02 75.24 67.4 1146099.09
i-C₅H₁₂ 85.77 85.73 67.4 495590.81
n-C₅H₁₂ 46.93 86.98 67.4 275140.165
C₆H₁₄ 122.21 101.90 67.4 839280.472
Total 1612.3 469.91 5808428.21
b) Output Kolom De-Propanizer

Top Product (panas sensibel, Qs₂)
T input = 119.9 °F = 321.98 K = 579.57 R
T ref = 60 °F = 288.71 K
P = 271.1 psig = 19.442 atm

persamaan berikut :
Cp = a + b x T + c x T² + d x T³, T in K (Sherwood)
Dimana nilai a, b, c, dan d masing-masing komponen adalah sebagai berikut :

b c d
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10
Mencari Cp
C₂H₆ = a + b x T + c x T² + d x T³
= 1.292 + ( 0.043 x 322 K ) + -0.000017 x 103673 K
+ ( 2.80E-09 x 33381064 K )
= 13.36 cal/gmol K
= 13.36 Btu/lbmol F
Untuk nilai Cp komponen lainnya dicari menggunakan cara yang sama dan dapat
P T Cp
Komponen
(atm) (K) (Btu/lbmol F)
C₂H₆ 19.442 321.98 13.36
C₃H₈ 19.442 321.98 18.87
i-C₄H₁₀ 19.442 321.98 24.91
n-C₄H₁₀ 19.442 321.98 24.98

perpotongan antara Tr dan Pr sehingga didapatkan Cp-Cp*, dimana :

Tc (K) Pc (atm)
Pc Tc
Komponen
(atm) (K)
C₂H₆ 48.2 305.4
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1
n-C₄H₁₀ 37.5 425.2
Mencari Tr dan Pr
Tr C₂H₆ = 321.98 K Pr C₂H₆ = 19.442 atm
305.4 K 48.2 atm
= 1.054 = 0.403
Mencari Cp-Cp*
Mencari Cp*
C₂H₆ = (Cp - Cp*) + Cp
= 2.9 + 13.36 Btu/lbmol F
= 16.26 Btu/lbmol F
Pc Tc
(atm) (K)
C₂H₆ 48.2 305.4 0.403 1.054 3.2 16.56
C₃H₈ 41.9 369.8 0.464 0.871 40 58.87
i-C₄H₁₀ 36 408.1 0.540 0.789 46 70.91
n-C₄H₁₀ 37.5 425.2 0.518 0.757 49 73.98

= 2.39 lbmol x 16.56 Btu/lbmol F x ( 119.90 - 60 ) F
= 2369.7 Btu
mol Cp* ΔT Q
Komponen
C₂H₆ 2.39 16.56 59.9 2369.68
C₃H₈ 757.42 58.87 59.9 2670994.98
i-C₄H₁₀ 12.13 70.91 59.9 51544.57
n-C₄H₁₀ 0.95 73.98 59.9 4212.62
Total 772.9 220.33 2729121.84
c) Output Kolom De-Propanizer

Top Product (panas laten, Qs₃)
T input = 119.9 °F = 321.98 K = 579.57 R
T ref = 60 °F = 288.71 K
P = 271.1 psig = 19.442 atm
Untuk menghitung panas penguapan digunakan persamaan berikut :
ΔHn = 1.092 (ln Pc - 1.013)

(J. M. Smith, p. 125)
RTn 0.930 - Trn
dimana :
R = 1.987 Btu/lbmol R
Tn = dalam R
Pc = dalam bar
Trn = Tn/Tc, dalam R
dan
ƛ₂ 1 - Tr₂ ###
= (J. M. Smith, p. 125)
ƛ₁ 1 - Tr₁
dimana :
ƛ₁ = ΔHn, dalam Btu/lbmol
Tr₁ = Tn/Tc, dalam R
Tr₂ = T/Tc, dalam R
Pc Pc Tc Tc Tn Tn
Komponen
(atm) (bar) (K) (R) (K) (R)
C₃H₈ 41.9 42.46 369.8 665.64 231.1 416.0
i-C₄H₁₀ 36 36.48 408.1 734.58 261.4 470.5
n-C₄H₁₀ 37.5 38.00 425.2 765.36 272.7 490.9
Mencari ΔHn atau ƛ₁ C₃H₈

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 42.46 bar - 1.013 )
=
1.987 Btu/lbmol R x 416.0 R 0.930 - ( 416.0 / 665.64 ) R
ΔHn 1.092 ( 3.749 - 1.013 )
=
826.55 Btu/lbmol 0.930 - 0.6249
ΔHn 2.9877
=
826.55 Btu/lbmol 0.3051
ΔHn = 8094.9 Btu/lbmol
Untuk nilai ΔHn komponen lainnya dicari menggunakan cara yang sama dan dapat
Mencari ΔH₂ atau ƛ₂ C₃H₈

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 579.57 / 665.64 ###
=
8094.9 Btu/lbmol 1 - 416.0 / 665.64
ƛ₂ 0.1293 ###
=
8094.9 Btu/lbmol 0.3751
ƛ₂ = 5400.87 Btu/lbmol
Untuk nilai ΔH₂ komponen lainnya dicari menggunakan cara yang sama dan dapat
Mencari panas penguapan

C₃H₈ = m x ƛ
= 757.42 lbmol x5400.87 Btu/lbmol
= 4090722.46 Btu
Untuk nilai Qlaten komponen lainnya dicari menggunakan cara yang sama dan
mol ƛ Q
Komponen
(lbmol) (Btu/lbmol) (Btu)
C₃H₈ 757.42 5400.87 4090722.46
i-C₄H₁₀ 12.13 7443.48 90322.22
n-C₄H₁₀ 0.95 8340.93 7929.36
Total 770.5 21185.29 4188974.04
Menghitung ΔHn atau ƛ₁ i-C₄H₁₀

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn (J. M. Smith, p. 125)
dimana :
Tn = dalam R
Pc = dalam bar
Jadi,
ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 36.48 bar - 1.013 )
=
1.987 Btu/lbmol R x 470.5 R 0.930 - ( 470.5 / 734.58 ) R
ΔHn 1.092 ( 3.597 - 1.013 )
=
934.92 Btu/lbmol 0.930 - 0.6405
ΔHn 2.8217
=
934.92 Btu/lbmol 0.289
Menghitung ΔH₂ atau ƛ₂

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
dimana :
ƛ₁ = 9113.5 Btu/lbmol
Jadi,
ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 579.57 / 734.58 ###
=
=
9113.5 Btu/lbmol 1 - 470.5 / 734.58
ƛ₂ 0.211 ###
=
9113.5 Btu/lbmol 0.3595
Menghitung ΔHn atau ƛ₁ n-C₄H₁₀

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn (J. M. Smith, p. 125)
dimana :
Tn = dalam R
Pc = dalam bar
Jadi,
ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 38.00 bar - 1.013 )
=
1.987 Btu/lbmol R x 490.9 R 0.930 - ( 490.9 / 765.36 ) R
ΔHn 1.092 ( 3.635 - 1.013 )
=
975.34 Btu/lbmol 0.930 - 0.6413
ΔHn 2.8632
=
975.34 Btu/lbmol 0.2887

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
dimana :
Jadi,
ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 579.57 / 765.36 ###
=
9674.6 Btu/lbmol 1 - 490.9 / 765.36
ƛ₂ 0.2427 ###
=
9674.6 Btu/lbmol 0.3587
Mencari latent heat

mol ƛ Q
Komponen
C₃H₈ 757.42 5400.87 4090722.46
i-C₄H₁₀ 12.13 7443.48 90322.22
n-C₄H₁₀ 0.95 8340.93 7929.36
Total 770.5 21185.29 4188974.04
d) Output Kolom De-Propanizer

Bottom Product (Qs₄)
T input = 205 °F = 369.26 K = 664.67 R
T ref = 60 °F = 288.71 K

persamaan berikut :
Cp = a + b x T + c x T² + d x T³, T in K
Cp komponen diperoleh dari Sherwood ditunjukkan pada tabel berikut :

P T Cp
Komponen
C₃H₈ 16.163 369.26 0.00
i-C₄H₁₀ 16.163 369.26 0.00
n-C₄H₁₀ 16.163 369.26 0.00
i-C₅H₁₂ 16.163 369.26 0.00
n-C₅H₁₂ 16.163 369.26 0.00
C₆H₁₄ 16.163 369.26 0.00
Mencari panas sensibel

mol Cp ΔT Q
Komponen
C₃H₈ 214.05 0.00 145 0.00
i-C₄H₁₀ 115.30 0.00 145 0.00
n-C₄H₁₀ 171.72 0.00 145 0.00
i-C₅H₁₂ 73.29 0.00 145 0.00
n-C₅H₁₂ 36.85 0.00 145 0.00
C₆H₁₄ 120.90 0.00 145 0.00
Total 732.10 0.00 0.00

T input = 214.7 °F = 374.65 K
T ref = 60 °F = 288.71 K
P = 235.6 psig = 17.027 atm

persamaan berikut :

b c d
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹)
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08
Mencari Cp
C₃H₈ = a + b x T + c x T² + d x T³
= -1.009 + ( 0.073 x 375 K ) + -0.000038 x 140363 K
+ ( 7.68E-09 x 52586857 K )
= 21.48 cal/gmol K
= 21.48 Btu/lbmol F
P T Cp
Komponen
C₃H₈ 17.027 369.26 21.48
i-C₄H₁₀ 17.027 369.26 28.27
n-C₄H₁₀ 17.027 369.26 28.16
i-C₅H₁₂ 17.027 369.26 34.63
n-C₅H₁₂ 17.027 369.26 34.76
C₆H₁₄ 17.027 369.26 41.38


Tc (K) Pc (atm)
Pc Tc
Komponen
(atm) (K)
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1
n-C₄H₁₀ 37.5 425.2
i-C₅H₁₂ 33.4 460.4
n-C₅H₁₂ 33.3 469.6
C₆H₁₄ 29.3 507.4
Mencari Tr dan Pr
Tr C₃H₈ = 374.65 K Pr C₃H₈ = 17.027 atm
369.8 K 41.9 atm
= 1.013 = 0.406
Mencari Cp-Cp*
didapatkan nilai Cp - Cp* C₃H₈ = 5
Mencari Cp*
C₃H₈ = (Cp - Cp*) + Cp
= 5 + 21.48 Btu/lbmol F
= 26.48 Btu/lbmol F
Pc Tc
(atm) (K)
C₃H₈ 41.9 369.8 0.406 0.999 5 26.48
i-C₄H₁₀ 36 408.1 0.473 0.905 19 47.27
n-C₄H₁₀ 37.5 425.2 0.454 0.868 35 63.16
i-C₅H₁₂ 33.4 460.4 0.510 0.802 45 79.63
n-C₅H₁₂ 33.3 469.6 0.511 0.786 48 82.76
C₆H₁₄ 29.3 507.4 0.581 0.728 55 96.38

C₃H₈ = m x Cp x ΔT
= 174 lbmol x 26.48 Btu/lbmol F x ( 214.70 - 60 ) F
= 713589.4 Btu
mol Cp* ΔT Q
Komponen
C₃H₈ 174.18 26.48 154.7 713589.45
i-C₄H₁₀ 176.96 47.27 154.7 1294029.74
n-C₄H₁₀ 227.39 63.16 154.7 2221864.02
i-C₅H₁₂ 86.66 79.63 154.7 1067455.41
n-C₅H₁₂ 47.42 82.76 154.7 607169.71
C₆H₁₄ 123.47 96.38 154.7 1841027.18
Total 836.1 395.68 7745135.51
e) Hot Oil masuk (Qs₅)

ṁ = 250764 lb/hr
T = 400.1 °F
T ref = 60 °F
cp = 0.612 Btu/lb °F (pada 400.1 °F)
Mencari Q hot oil masuk

Q = m cp ΔT
= 250764 lb x 0.612 Btu/lb F x 340 °F
= 52194320 Btu
f) Hot Oil keluar (Qs₆)

ṁ = 250764 lb/hr
T = 306.8 °F
T ref = 60 °F
cp = 0.568 Btu/lb °F (pada 306.8 °F)
Mencari Q hot oil keluar
Q = m cp ΔT
= 250764 lb x 0.568 Btu/lb F x 247 °F
= 35152699 Btu

Input Output
Aliran
Btu % Btu %
Qs₁ 5808428 10.0 - -
Qs₂ - - 2729122 4.7
Qs₃ - - 4188974 7.2
Qs₄ - - 7745136 13.4
Qs₅ 52194320 90.0 - -
Qs₆ - - 35152699 60.6
Q loss - - 8186817 14.1
Total 58002748 100 58002748 100
Konsumsi Energi Spesifi = Energi yang dihasilkan

Produk yang dihasilkan
= 58002748 Btu
85545 lb
= 678.0 Btu/lb
Cp sensibel heat (Cp = a + b x T + c x T² + d x T³), T in K
= 127.4 °F = 326.15 K
= 106374 K
= 34693822 K
= 11315390113.3 K
= 200.4 psi
b c d Cp
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 13.50
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 19.08
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 25.19
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 25.24
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 30.73
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 30.98
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 36.90

= 119.9 °F = 321.98 K
= 103673 K
= 33381064 K
= 10748146278.9 K
= 200.4 psi
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 13.36
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 18.87
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 24.91
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 24.98
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 30.38
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 30.65
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 36.50

= 214.7 °F = 374.65 K
= 0 K
= 0 K
= 200.4 psi
b c d Cp
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 15.05
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 21.48
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 28.27
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 28.16
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 34.63
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 34.76
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 41.38
nakan cara yang sama dan
kan cara yang sama dan

ggi menggunakan grafik


n cara yang sama dan dapat


ara yang sama dan dapat

Komposisi Stream (5) Komposisi Stream (5)
C₂H₆ = 0.50 P = 196.2 psig C₂H₆
C₃H₈ = 93.59 T = 114.68 °F T = 111.38 °F C₃H₈
i-C₄H₁₀ = 4.42 (3) (4) i-C₄H₁₀
n-C₄H₁₀ = 1.44 n-C₄H₁₀ =
C₆H₁₄ = 0.05 C₆H₁₄
Total = 100 Total
ṁ = 41998 lb/hr P = 194.8 psig

P = 200.4 psi (6) T 104.80 °F
T = 137.36 °F ṁ = 65990 lb/hr
ṁ = 68383 lb/hr (5)
(1) (2) (7) (1)
T = 200.38 °F ṁ = 23992 lb/hr
Komposisi NGL masuk : (8) Komposisi NGL masuk
C₂H₆ = 0.18 C₂H₆
C₃H₈ = 56.46 C₃H₈
i-C₄H₁₀ = 10.97 (9) i-C₄H₁₀
n-C₄H₁₀ = 14.17 n-C₄H₁₀ =
i-C₅H₁₂ = 5.78 (10) T = 179.92 °F i-C₅H₁₂
n-C₅H₁₂ = 2.91 n-C₅H₁₂
C₆H₁₄ = 9.53 T = 205.00 °F C₆H₁₄
Total = 100 (11) ṁ = 43403 lb/hr Total

C₃H₈ = 19.07
i-C₄H₁₀ = 20.56
n-C₄H₁₀ = 29.06
i-C₅H₁₂ = 11.17
n-C₅H₁₂ = 7.20
C₆H₁₄ = 12.95
Total = 100
Gambar 2. Unit 03-C-4101 (kolom de-propanizer) Gambar 2. U

PERHITUNGAN
ṁ input = ṁ fuel gas + ṁ top product + ṁ bottom product ṁ input

ṁ input = (ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom producṁ input
• Input kolom De-Propanizer • Input kolom De-Propan

ṁ = 68383 lb/hr ṁ=
T = 137.36 °F
P = 200.4 psi
Mencari BM campuran Mencari BM campuran

BM BM campuran
C₂H₆ 0.18 0.002 30 0.05 C₂H₆
C₃H₈ 56.46 0.565 44 24.84 C₃H₈
i-C₄H₁₀ 10.97 0.110 58 6.36 i-C₄H₁₀
n-C₄H₁₀ 14.17 0.142 58 8.22 n-C₄H₁₀
i-C₅H₁₂ 5.78 0.058 72 4.16 i-C₅H₁₂
n-C₅H₁₂ 2.91 0.029 72 2.09 n-C₅H₁₂
C₆H₁₄ 9.53 0.095 86 8.20 C₆H₁₄

BM campuran
= 68383 lb/hr
53.93 lb/lbmol
= 1267.95 lbmol
Mencari massa komponen Mencari massa kompone

mol BM massa
Komponen fraksi mol fraksi berat Komponen
C₂H₆ 0.002 2.24 30 67 0.001 C₂H₆
C₃H₈ 0.565 715.90 44 31500 0.461 C₃H₈
i-C₄H₁₀ 0.110 139.14 58 8070 0.118 i-C₄H₁₀
n-C₄H₁₀ 0.142 179.65 58 10419 0.152 n-C₄H₁₀
i-C₅H₁₂ 0.058 73.29 72 5277 0.077 i-C₅H₁₂
n-C₅H₁₂ 0.029 36.85 72 2653 0.039 n-C₅H₁₂
C₆H₁₄ 0.095 120.90 86 10397 0.152 C₆H₁₄
Total 1 1267.96 - 68383 1 Total
• Output kolom De-Propanizer (top produk) • Output kolom De-Prop
1. Top Product 1. Top Product
ṁ = 23992 lb/hr ṁ=

BM BM campuran
C₂H₆ 0.50 0.0050 30 0.15 C₂H₆
C₃H₈ 93.59 0.9359 44 41.18 C₃H₈
i-C₄H₁₀ 4.42 0.0442 58 2.56 i-C₄H₁₀
n-C₄H₁₀ 1.44 0.0144 58 0.84 n-C₄H₁₀
C₆H₁₄ 0.05 0.0005 86 0.04 C₆H₁₄

BM campuran
= 23992 lb/hr
44.77 lb/lbmol
= 535.87 lbmol

mol BM massa
C₂H₆ 0.0050 2.66 30 80 0.003 C₂H₆
C₃H₈ 0.9359 501.53 44 22067 0.920 C₃H₈
i-C₄H₁₀ 0.0442 23.69 58 1374 0.057 i-C₄H₁₀
n-C₄H₁₀ 0.0144 7.74 58 449 0.019 n-C₄H₁₀
C₆H₁₄ 0.0005 0.26 86 22 0.001 C₆H₁₄
Total 1 535.87 - 23992 1 Total
2. Bottom Product 2. Bottom Product
ṁ = 43403 lb/hr ṁ=
T = 205.00 °F

BM BM campuran
C₃H₈ 19.07 0.191 44 8.39 C₃H₈
i-C₄H₁₀ 20.56 0.206 58 11.92 i-C₄H₁₀
n-C₄H₁₀ 29.06 0.291 58 16.85 n-C₄H₁₀
i-C₅H₁₂ 11.17 0.112 72 8.04 i-C₅H₁₂
n-C₅H₁₂ 7.20 0.072 72 5.18 n-C₅H₁₂
C₆H₁₄ 12.95 0.129 86 11.14 C₆H₁₄

BM campuran
= 43403 lb/hr
61.52 lb/lbmol
= 705.45 lbmol

mol BM massa
C₃H₈ 0.191 134.54 44 5920 0.136 C₃H₈
i-C₄H₁₀ 0.206 145.03 58 8412 0.194 i-C₄H₁₀
n-C₄H₁₀ 0.291 204.99 58 11889 0.274 n-C₄H₁₀
i-C₅H₁₂ 0.112 78.77 72 5671 0.131 i-C₅H₁₂
n-C₅H₁₂ 0.072 50.76 72 3655 0.084 n-C₅H₁₂
C₆H₁₄ 0.129 91.34 86 7855 0.181 C₆H₁₄
Total 1 705.43 - 43403 1 Total
Neraca Massa Neraca Massa
Input Output (lb)
Komponen Komponen
C₂H₆ 67 80 - C₂H₆
C₃H₈ 31500 22067 5920 C₃H₈
i-C₄H₁₀ 8070 1374 8412 i-C₄H₁₀
n-C₄H₁₀ 10419 449 11889 n-C₄H₁₀
i-C₅H₁₂ 5277 - 5671 i-C₅H₁₂
n-C₅H₁₂ 2653 - 3655 n-C₅H₁₂
C₆H₁₄ 10397 22 7855 C₆H₁₄
23992 43403
Total 68383 Total
67394
C₂H₆ = 0.42 % P = 196.2 psig
C₃H₈ = 93.66 % T = 114.68 °F T = 111.38 °F
i-C₄H₁₀ = 4.45 % (3) (4)
n-C₄H₁₀ = 1.48 %
Total = 100 %
ṁ = 41998 lb/hr P = 194.8 psig

P = 200.4 psi (6) T 104.80 °F
T = 137.36 °F ṁ = 65990 lb/hr
ṁ = 68383 lb/hr (5)
(1) (2) (7)
T = 200.38 °F ṁ= 23992 lb/hr
C₂H₆ = 0.18 %
C₃H₈ = 56.46 %
i-C₄H₁₀ = 10.97 % (9)
n-C₄H₁₀ = 14.17 %
i-C₅H₁₂ = 5.78 % (10) T = 179.92 °F
n-C₅H₁₂ = 2.91 %
C₆H₁₄ = 9.53 % T = 205.00 °F
Total = 100 % (11) ṁ= …?

C₃H₈ = …?
i-C₄H₁₀ = … ?
n-C₄H₁₀ = … ?
i-C₅H₁₂ = … ?
n-C₅H₁₂ = … ?
C₆H₁₄ = … ?
PERHITUNGAN

ṁ = 68383 lb/hr
T = 137.36 °F
P = 200.4 psi
Mencari BM campuran
BM BM campuran
C₂H₆ 0.18 0.002 30 0.05
C₃H₈ 56.46 0.565 44 24.84
i-C₄H₁₀ 10.97 0.110 58 6.36
n-C₄H₁₀ 14.17 0.142 58 8.22
i-C₅H₁₂ 5.78 0.058 72 4.16
n-C₅H₁₂ 2.91 0.029 72 2.09
C₆H₁₄ 9.53 0.095 86 8.20
Total 100 1 - 53.93
Mencari mol total

mol total= ṁ
BM campuran
= 68383 lb/hr
53.93 lb/lbmol
= 1267.95 lbmol

mol BM massa
Komponen fraksi mol
Komponen fraksi mol
C₂H₆ 0.002 2.24 30 67
C₃H₈ 0.565 715.90 44 31500
i-C₄H₁₀ 0.110 139.14 58 8070
n-C₄H₁₀ 0.142 179.65 58 10419
i-C₅H₁₂ 0.058 73.29 72 5277
n-C₅H₁₂ 0.029 36.85 72 2653
C₆H₁₄ 0.095 120.90 86 10397
Total 1 1267.96 - 68383

1. Top Product
ṁ = 23992 lb/hr
Mencari BM campuran
BM BM campuran
C₂H₆ 0.42 0.0042 30 0.13
C₃H₈ 93.66 0.9366 44 41.21
i-C₄H₁₀ 4.45 0.0445 58 2.58
n-C₄H₁₀ 1.48 0.0148 58 0.86
Total 100 1 - 44.78
Mencari mol total

mol total= ṁ
BM campuran
= 23992 lb/hr
44.78 lb/lbmol
= 535.82 lbmol

mol BM massa
Komponen fraksi mol
C₂H₆ 0.0042 2.25 30 68
C₃H₈ 0.9366 501.85 44 22081
i-C₄H₁₀ 0.0445 23.84 58 1383
n-C₄H₁₀ 0.0148 7.93 58 460
Total 1 535.87 - 23992
2. Bottom Product
ṁ bottom product = ṁ input - ṁ top product
ṁ bottom product = 68383 lb/hr - 23992 lb/hr
ṁ bottom product = 44392 lb/hr

Massa (lb)
Komponen
Input Top Product Bottom Product
C₂H₆ 67 68 -
C₃H₈ 31500 22081 9418
i-C₄H₁₀ 8070 1383 6687
n-C₄H₁₀ 10419 460 9960
i-C₅H₁₂ 5277 - 5277
n-C₅H₁₂ 2653 - 2653
C₆H₁₄ 10397 - 10397
Total 68316 23924 44392

massa BM mol mol
Komponen
(lb) (lb/lbmol) (lbmol) (%)
C₂H₆ - 30 - -
C₃H₈ 9418 44 214.05 29
i-C₄H₁₀ 6687 58 115.30 16
n-C₄H₁₀ 9960 58 171.72 23
i-C₅H₁₂ 5277 72 73.29 10
n-C₅H₁₂ 2653 72 36.85 5
C₆H₁₄ 10397 86 120.90 17
Total 44392 - 732.10 100
Neraca Massa
Input Output (lb)
Komponen
C₂H₆ 67 68 -
C₃H₈ 31500 22081 9418
i-C₄H₁₀ 8070 1383 6687
n-C₄H₁₀ 10419 460 9960
i-C₅H₁₂ 5277 - 5277
n-C₅H₁₂ 2653 - 2653
C₆H₁₄ 10397 - 10397
23992 44392
Total 68383
68384
C₂H₆ = 0.04 P = 193.3 psig C₂H₆
C₃H₈ = 93.80 T = 113.30 °F T = 110.70 °F C₃H₈
i-C₄H₁₀ = 4.56 (3) (4) i-C₄H₁₀
n-C₄H₁₀ = 1.55 n-C₄H₁₀ =
C₆H₁₄ = 0.05 C₆H₁₄
Total = 100 Total
ṁ = 43509 lb/hr P = 195.0 psig

P = 202.0 psi (6) T 108.00 °F
T = 143.50 °F ṁ = 67790 lb/hr
ṁ = 67824 lb/hr (5)
(2) (7) (1)
T = 197.50 °F ṁ = 24281 lb/hr
Komposisi NGL masuk : (8) Komposisi NGL masuk :
C₂H₆ = 0.00 C₂H₆
C₃H₈ = 54.60 C₃H₈
i-C₄H₁₀ = 11.25 (9) i-C₄H₁₀
n-C₄H₁₀ = 14.71 n-C₄H₁₀ =
i-C₅H₁₂ = 6.12 (10) T = 177.60 °F i-C₅H₁₂
n-C₅H₁₂ = 3.09 n-C₅H₁₂
C₆H₁₄ = 10.23 T = 205.00 °F C₆H₁₄
Total = 100 (11) ṁ = 43285 lb/hr Total

C₃H₈ = 19.11
i-C₄H₁₀ = 20.80
n-C₄H₁₀ = 29.59
i-C₅H₁₂ = 11.11
n-C₅H₁₂ = 7.15
C₆H₁₄ = 12.23
Total = 100
Gambar 2. Unit 03-C-4101 (kolom de-propanizer) Gambar 2. Unit

PERHITUNGAN P
ṁ input = ṁ fuel gas + ṁ top product + ṁ bottom product ṁ input

ṁ input = (ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom producṁ input
• Input kolom De-Propanizer • Input kolom De-Propanizer

ṁ = 67824 lb/hr ṁ=
T = 143.50 °F T=
P = 202.0 psi P=

BM BM campuran
C₂H₆ 0.00 0.000 30 0.00 C₂H₆
C₃H₈ 54.60 0.546 44 24.02 C₃H₈
i-C₄H₁₀ 11.25 0.112 58 6.52 i-C₄H₁₀
n-C₄H₁₀ 14.71 0.147 58 8.53 n-C₄H₁₀
i-C₅H₁₂ 6.12 0.061 72 4.41 i-C₅H₁₂
n-C₅H₁₂ 3.09 0.031 72 2.23 n-C₅H₁₂
C₆H₁₄ 10.23 0.102 86 8.79 C₆H₁₄

BM campuran
= 67824 lb/hr
54.51 lb/lbmol
= 1244.27 lbmol
Mencari massa komponen Mencari massa komponen

mol BM massa
C₂H₆ 0.000 0.00 30 0 0.000 C₂H₆
C₃H₈ 0.546 679.39 44 29893 0.437 C₃H₈
i-C₄H₁₀ 0.112 139.97 58 8118 0.119 i-C₄H₁₀
n-C₄H₁₀ 0.147 183.06 58 10617 0.155 n-C₄H₁₀
i-C₅H₁₂ 0.061 76.13 72 5481 0.080 i-C₅H₁₂
n-C₅H₁₂ 0.031 38.49 72 2771 0.041 n-C₅H₁₂
C₆H₁₄ 0.102 127.25 86 10943 0.160 C₆H₁₄
Total 1 1244.28 - 67824 1 Total
• Output kolom De-Propanizer (top produk) • Output kolom De-Propaniz
ṁ = 24281 lb/hr ṁ=

BM BM campuran
C₂H₆ 0.04 0.0004 30 0.01 C₂H₆
C₃H₈ 93.80 0.9380 44 41.27 C₃H₈
i-C₄H₁₀ 4.56 0.0456 58 2.64 i-C₄H₁₀
n-C₄H₁₀ 1.55 0.0155 58 0.90 n-C₄H₁₀
C₆H₁₄ 0.05 0.0005 86 0.04 C₆H₁₄

BM campuran
= 24281 lb/hr
44.87 lb/lbmol
= 541.13 lbmol

mol BM massa
C₂H₆ 0.0004 0.22 30 6 0.000 C₂H₆
C₃H₈ 0.9380 507.58 44 22334 0.931 C₃H₈
i-C₄H₁₀ 0.0456 24.68 58 1431 0.060 i-C₄H₁₀
n-C₄H₁₀ 0.0155 8.39 58 486 0.020 n-C₄H₁₀
C₆H₁₄ 0.0005 0.27 86 23 0.001 C₆H₁₄
Total 1 541.13 - 24281 1 Total
ṁ = 43285 lb/hr ṁ=
T = 205.00 °F T=

BM BM campuran
C₃H₈ 19.11 0.191 44 8.41 C₃H₈
i-C₄H₁₀ 20.80 0.208 58 12.06 i-C₄H₁₀
n-C₄H₁₀ 29.59 0.296 58 17.16 n-C₄H₁₀
i-C₅H₁₂ 11.11 0.111 72 8.00 i-C₅H₁₂
n-C₅H₁₂ 7.15 0.072 72 5.15 n-C₅H₁₂
C₆H₁₄ 12.23 0.122 86 10.52 C₆H₁₄

BM campuran
= 43285 lb/hr
61.30 lb/lbmol
= 706.12 lbmol

mol BM massa
C₃H₈ 0.191 134.94 44 5937 0.137 C₃H₈
i-C₄H₁₀ 0.208 146.87 58 8519 0.196 i-C₄H₁₀
n-C₄H₁₀ 0.296 208.94 58 12119 0.279 n-C₄H₁₀
i-C₅H₁₂ 0.111 78.45 72 5648 0.130 i-C₅H₁₂
n-C₅H₁₂ 0.072 50.49 72 3635 0.084 n-C₅H₁₂
C₆H₁₄ 0.122 86.36 86 7427 0.171 C₆H₁₄
Total 1 706.05 - 43285 1 Total
Input Output (lb)
Komponen Komponen
C₂H₆ 0 6 - C₂H₆
C₃H₈ 29893 22334 5937 C₃H₈
i-C₄H₁₀ 8118 1431 8519 i-C₄H₁₀
n-C₄H₁₀ 10617 486 12119 n-C₄H₁₀
i-C₅H₁₂ 5481 - 5648 i-C₅H₁₂
n-C₅H₁₂ 2771 - 3635 n-C₅H₁₂
C₆H₁₄ 10943 23 7427 C₆H₁₄
24281 43285
Total 67824 Total
67566
= 0.60 P = 189.6 psig C₂H₆ =
= 93.60 T = 112.20 °F T = 108.60 °F C₃H₈ =
= 4.36 (3) (4) i-C₄H₁₀ =
n-C₄H₁₀ = 1.35 n-C₄H₁₀ =
= 0.09 C₆H₁₄ =
= 100 Total =
ṁ = 41858 lb/hr P = 195.0 psig

P = 200.0 psi (6) T 106.00 °F P=
T = 128.70 °F ṁ = 67387 lb/hr T=
ṁ = 69223 lb/hr (5) ṁ=
(2) (7) (1)
T = 199.80 °F ṁ = 25529 lb/hr
= 0.05 C₂H₆ =
= 56.94 C₃H₈ =
= 10.95 (9) i-C₄H₁₀ =
n-C₄H₁₀ = 14.12 n-C₄H₁₀ =
= 5.74 (10) T = 179.30 °F i-C₅H₁₂ =
= 2.86 n-C₅H₁₂ =
= 9.35 T = 205.00 °F C₆H₁₄ =
= 100 (11) ṁ = 43817 lb/hr Total =

C₃H₈ = 18.67
i-C₄H₁₀ = 20.48
n-C₄H₁₀ = 29.07
i-C₅H₁₂ = 11.26
n-C₅H₁₂ = 7.27
C₆H₁₄ = 13.25
Total = 100
Gambar 2. Unit 03-C-4101 (kolom de-propanizer) Gambar 2. Unit 03-C

PERHITUNGAN PER
= ṁ fuel gas + ṁ top product + ṁ bottom product ṁ input =

= (ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom producṁ input =

69223 lb/hr ṁ = 68075 lb/hr
128.70 °F T = 143.40 °F
200.0 psi P = 200.0 psi

BM BM campuran
C₂H₆ 0.05 0.001 30 0.02 C₂H₆
C₃H₈ 56.94 0.569 44 25.05 C₃H₈
i-C₄H₁₀ 10.95 0.109 58 6.35 i-C₄H₁₀
n-C₄H₁₀ 14.12 0.141 58 8.19 n-C₄H₁₀
i-C₅H₁₂ 5.74 0.057 72 4.13 i-C₅H₁₂
n-C₅H₁₂ 2.86 0.029 72 2.06 n-C₅H₁₂
C₆H₁₄ 9.35 0.093 86 8.04 C₆H₁₄

= ṁ mol total=
BM campuran
= 69223 lb/hr =
53.84 lb/lbmol
= 1285.80 lbmol =

mol BM massa
C₂H₆ 0.001 0.65 30 19 0.000 C₂H₆
C₃H₈ 0.569 732.09 44 32212 0.471 C₃H₈
i-C₄H₁₀ 0.109 140.73 58 8162 0.119 i-C₄H₁₀
n-C₄H₁₀ 0.141 181.52 58 10528 0.154 n-C₄H₁₀
i-C₅H₁₂ 0.057 73.79 72 5313 0.078 i-C₅H₁₂
n-C₅H₁₂ 0.029 36.81 72 2650 0.039 n-C₅H₁₂
C₆H₁₄ 0.093 120.20 86 10337 0.151 C₆H₁₄
Total 1 1285.80 - 69223 1 Total
• Output kolom De-Propanizer (top produk) • Output kolom De-Propanizer (t
25529 lb/hr ṁ = 21959 lb/hr

BM BM campuran
C₂H₆ 0.60 0.0060 30 0.18 C₂H₆
C₃H₈ 93.60 0.9360 44 41.18 C₃H₈
i-C₄H₁₀ 4.36 0.0436 58 2.53 i-C₄H₁₀
n-C₄H₁₀ 1.35 0.0135 58 0.78 n-C₄H₁₀
C₆H₁₄ 0.09 0.0009 86 0.08 C₆H₁₄

= ṁ mol total=
BM campuran
= 25529 lb/hr =
44.75 lb/lbmol
= 570.44 lbmol =

mol BM massa
C₂H₆ 0.0060 3.42 30 103 0.004 C₂H₆
C₃H₈ 0.9360 533.93 44 23493 0.979 C₃H₈
i-C₄H₁₀ 0.0436 24.87 58 1443 0.060 i-C₄H₁₀
n-C₄H₁₀ 0.0135 7.70 58 447 0.019 n-C₄H₁₀
C₆H₁₄ 0.0009 0.51 86 44 0.002 C₆H₁₄
Total 1 570.44 - 25529 1 Total
43817 lb/hr ṁ = 44236 lb/hr
205.00 °F T = 205.00 °F

BM BM campuran
C₃H₈ 18.67 0.187 44 8.21 C₃H₈
i-C₄H₁₀ 20.48 0.205 58 11.88 i-C₄H₁₀
n-C₄H₁₀ 29.07 0.291 58 16.86 n-C₄H₁₀
i-C₅H₁₂ 11.26 0.113 72 8.11 i-C₅H₁₂
n-C₅H₁₂ 7.27 0.073 72 5.23 n-C₅H₁₂
C₆H₁₄ 13.25 0.133 86 11.40 C₆H₁₄

= ṁ mol total=
BM campuran
= 43817 lb/hr =
61.69 lb/lbmol
= 710.27 lbmol =

mol BM massa
C₃H₈ 0.187 132.61 44 5835 0.134 C₃H₈
i-C₄H₁₀ 0.205 145.46 58 8437 0.194 i-C₄H₁₀
n-C₄H₁₀ 0.291 206.48 58 11976 0.276 n-C₄H₁₀
i-C₅H₁₂ 0.113 79.98 72 5758 0.133 i-C₅H₁₂
n-C₅H₁₂ 0.073 51.64 72 3718 0.086 n-C₅H₁₂
C₆H₁₄ 0.133 94.11 86 8094 0.186 C₆H₁₄
Total 1 710.27 - 43817 1 Total
Input Output (lb)
Komponen Komponen
C₂H₆ 19 103 - C₂H₆
C₃H₈ 32212 23493 5835 C₃H₈
i-C₄H₁₀ 8162 1443 8437 i-C₄H₁₀
n-C₄H₁₀ 10528 447 11976 n-C₄H₁₀
i-C₅H₁₂ 5313 - 5758 i-C₅H₁₂
n-C₅H₁₂ 2650 - 3718 n-C₅H₁₂
C₆H₁₄ 10337 44 8094 C₆H₁₄
25529 43817
Total 69223 Total
69346
0.94 P = 200.9 psig C₂H₆ = 0.15
94.46 T = 115.10 °F T = 112.30 °F C₃H₈ = 91.95
3.88 (3) (4) i-C₄H₁₀ = 5.11
0.69 n-C₄H₁₀ = 2.77
0.03 C₆H₁₄ = 0.02
100 Total = 100
ṁ = 44572 lb/hr P = 190.0 psig

200.0 psi (6) T 96.00 °F P = 200.0 psi
143.40 °F ṁ = 66531 lb/hr T = 142.50 °F
68075 lb/hr (5) ṁ = 69083 lb/hr
(2) (7) (1)
T = 202.20 °F ṁ = 21959 lb/hr
0.26 C₂H₆ = 0.48
55.87 C₃H₈ = 57.57
11.04 (9) i-C₄H₁₀ = 10.80
14.29 n-C₄H₁₀ = 13.82
5.87 (10) T = 181.70 °F i-C₅H₁₂ = 5.56
2.96 n-C₅H₁₂ = 2.79
9.71 T = 205.00 °F C₆H₁₄ = 9.00
100 (11) ṁ = 44236 lb/hr Total = 100

C₃H₈ = 20.32
i-C₄H₁₀ = 20.51
n-C₄H₁₀ = 28.90
i-C₅H₁₂ = 10.75
n-C₅H₁₂ = 6.93
C₆H₁₄ = 12.59
Total = 100
Gambar 2. Unit 03-C-4101 (kolom de-propanizer) Gambar 2. Unit 03-C-41

PERHITUNGAN PERHIT
ṁ fuel gas + ṁ top product + ṁ bottom product ṁ input = ṁ fuel gas + ṁ top produ
(ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom producṁ input = (ṁ top vapor - (ṁ refluk

68075 lb/hr ṁ = 69083 lb/hr
143.40 °F T = 142.50 °F
200.0 psi P = 200.0 psi

BM BM campuran
mol (%) fraksi mol Komponen mol (%)
0.26 0.003 30 0.08 C₂H₆ 0.48
55.87 0.559 44 24.58 C₃H₈ 57.57
11.04 0.110 58 6.41 i-C₄H₁₀ 10.80
14.29 0.143 58 8.29 n-C₄H₁₀ 13.82
5.87 0.059 72 4.22 i-C₅H₁₂ 5.56
2.96 0.030 72 2.13 n-C₅H₁₂ 2.79
9.71 0.097 86 8.35 C₆H₁₄ 9.00
100 1 - 54.06 Total 100

ṁ mol total=
BM campuran BM campuran
68075 lb/hr = 69083 lb/hr
54.06 lb/lbmol 53.50 lb/lbmol
1259.21 lbmol = 1291.38 lbmol

mol BM massa
fraksi mol fraksi berat Komponen fraksi mol
0.003 3.22 30 97 0.001 C₂H₆ 0.005
0.559 703.51 44 30954 0.453 C₃H₈ 0.576
0.110 139.08 58 8067 0.118 i-C₄H₁₀ 0.108
0.143 179.97 58 10438 0.153 n-C₄H₁₀ 0.138
0.059 73.86 72 5318 0.078 i-C₅H₁₂ 0.056
0.030 37.27 72 2683 0.039 n-C₅H₁₂ 0.028
0.097 122.30 86 10518 0.154 C₆H₁₄ 0.090
1 1259.21 - 68075 1 Total 1
• Output kolom De-Propanizer (top produk) • Output kolom De-Propanizer (top p
21959 lb/hr ṁ = 28263 lb/hr

BM BM campuran
0.94 0.0094 30 0.28 C₂H₆ 0.15
94.46 0.9446 44 41.56 C₃H₈ 91.95
3.88 0.0388 58 2.25 i-C₄H₁₀ 5.11
0.69 0.0069 58 0.40 n-C₄H₁₀ 2.77
0.03 0.0003 86 0.03 C₆H₁₄ 0.02
100 1 - 44.52 Total 100

ṁ mol total=
21959 lb/hr = 28263 lb/hr
493.23 lbmol = 626.80 lbmol

mol BM massa
0.0094 4.64 30 139 0.006 C₂H₆ 0.0015
0.9446 465.91 44 20500 0.854 C₃H₈ 0.9195
0.0388 19.14 58 1110 0.046 i-C₄H₁₀ 0.0511
0.0069 3.40 58 197 0.008 n-C₄H₁₀ 0.0277
0.0003 0.15 86 13 0.001 C₆H₁₄ 0.0002
1 493.23 - 21959 1 Total 1
44236 lb/hr ṁ = 42390 lb/hr
205.00 °F T = 205.00 °F

BM BM campuran
20.32 0.203 44 8.94 C₃H₈ 19.75
20.51 0.205 58 11.90 i-C₄H₁₀ 20.10
28.90 0.289 58 16.76 n-C₄H₁₀ 28.42
10.75 0.108 72 7.74 i-C₅H₁₂ 11.48
6.93 0.069 72 4.99 n-C₅H₁₂ 7.29
12.59 0.126 86 10.83 C₆H₁₄ 12.96
100 1 - 61.16 Total 100

ṁ mol total=
44236 lb/hr = 42390 lb/hr
723.34 lbmol = 689.36 lbmol

mol BM massa
0.203 146.98 44 6467 0.149 C₃H₈ 0.198
0.205 148.36 58 8605 0.198 i-C₄H₁₀ 0.201
0.289 209.04 58 12125 0.279 n-C₄H₁₀ 0.284
0.108 77.76 72 5599 0.129 i-C₅H₁₂ 0.115
0.069 50.13 72 3609 0.083 n-C₅H₁₂ 0.073
0.126 91.07 86 7832 0.180 C₆H₁₄ 0.130
1 723.34 - 44236 1 Total 1
Input Output (lb) Input
Komponen
(lb) top product bottom product (lb)
97 139 - C₂H₆ 185
30954 20500 6467 C₃H₈ 32712
8067 1110 8605 i-C₄H₁₀ 8086
10438 197 12125 n-C₄H₁₀ 10350
5318 - 5599 i-C₅H₁₂ 5170
2683 - 3609 n-C₅H₁₂ 2589
10518 13 7832 C₆H₁₄ 9990
21959 44236
68075 Total 69083
66195
0.15 P = 205.4 psig C₂H₆ = 0.75
91.95 T = 121.70 °F T = 117.30 °F C₃H₈ = 94.15
5.11 (3) (4) i-C₄H₁₀ = 4.19
2.77 n-C₄H₁₀ = 0.86
0.02 C₆H₁₄ = 0.05
100 Total = 100
ṁ = 36430 lb/hr P = 199.0 psig

200.0 psi (6) T 96.00 °F P = 200.0 psi
142.50 °F ṁ = 64693 lb/hr T = 128.70 °F
69083 lb/hr (5) ṁ = 67712 lb/hr
(2) (7) (1)
T = 204.90 °F ṁ = 28263 lb/hr
0.48 C₂H₆ = 0.10
57.57 C₃H₈ = 57.33
10.80 (9) i-C₄H₁₀ = 10.83
13.82 n-C₄H₁₀ = 13.90
5.56 (10) T = 184.50 °F i-C₅H₁₂ = 5.62
2.79 n-C₅H₁₂ = 2.83
9.00 T = 205.00 °F C₆H₁₄ = 9.39
100 (11) ṁ = 42390 lb/hr Total = 100

C₃H₈ = 19.75
i-C₄H₁₀ = 20.10
n-C₄H₁₀ = 28.42
i-C₅H₁₂ = 11.48
n-C₅H₁₂ = 7.29
C₆H₁₄ = 12.96
Total = 100
Gambar 2. Unit 03-C-4101 (kolom de-propanizer) Gambar 2. Unit 03-C-4101 (

PERHITUNGAN PERHITUN
ṁ fuel gas + ṁ top product + ṁ bottom product ṁ input = ṁ fuel gas + ṁ top product +
(ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom producṁ input = (ṁ top vapor - (ṁ refluks + ṁ

69083 lb/hr ṁ = 67712 lb/hr
142.50 °F T = 128.70 °F
200.0 psi P = 200.0 psi

BM BM campuran
0.48 0.005 30 0.14 C₂H₆ 0.10
57.57 0.576 44 25.33 C₃H₈ 57.33
10.80 0.108 58 6.26 i-C₄H₁₀ 10.83
13.82 0.138 58 8.01 n-C₄H₁₀ 13.90
5.56 0.056 72 4.00 i-C₅H₁₂ 5.62
2.79 0.028 72 2.01 n-C₅H₁₂ 2.83
9.00 0.090 86 7.74 C₆H₁₄ 9.39
100 1 - 53.50 Total 100

ṁ mol total= ṁ
69083 lb/hr = 67712 lb/hr
1291.38 lbmol = 1259.56 lbmol

mol BM massa
0.005 6.17 30 185 0.003 C₂H₆ 0.001
0.576 743.46 44 32712 0.478 C₃H₈ 0.573
0.108 139.42 58 8086 0.118 i-C₄H₁₀ 0.108
0.138 178.45 58 10350 0.151 n-C₄H₁₀ 0.139
0.056 71.80 72 5170 0.076 i-C₅H₁₂ 0.056
0.028 35.97 72 2589 0.038 n-C₅H₁₂ 0.028
0.090 116.16 86 9990 0.146 C₆H₁₄ 0.094
1 1291.43 - 69083 1 Total 1
• Output kolom De-Propanizer (top produk) • Output kolom De-Propanizer (top produ
1. Top Product
28263 lb/hr ṁ = 19927 lb/hr

BM BM campuran
0.15 0.0015 30 0.05 C₂H₆ 0.75
91.95 0.9195 44 40.46 C₃H₈ 94.15
5.11 0.0511 58 2.96 i-C₄H₁₀ 4.19
2.77 0.0277 58 1.61 n-C₄H₁₀ 0.86
0.02 0.0002 86 0.02 C₆H₁₄ 0.05
100 1 - 45.09 Total 100

ṁ mol total= ṁ
28263 lb/hr = 19927 lb/hr
626.80 lbmol = 446.56 lbmol

mol BM massa
0.0015 0.94 30 28 0.001 C₂H₆ 0.0075
0.9195 576.35 44 25359 1.057 C₃H₈ 0.9415
0.0511 32.03 58 1858 0.077 i-C₄H₁₀ 0.0419
0.0277 17.36 58 1007 0.042 n-C₄H₁₀ 0.0086
0.0002 0.13 86 11 0.000 C₆H₁₄ 0.0005
1 626.80 - 28263 1 Total 1
42390 lb/hr ṁ = 43285 lb/hr
205.00 °F T = 205.00 °F

BM BM campuran
19.75 0.198 44 8.69 C₃H₈ 17.51
20.10 0.201 58 11.66 i-C₄H₁₀ 20.90
28.42 0.284 58 16.48 n-C₄H₁₀ 29.31
11.48 0.115 72 8.27 i-C₅H₁₂ 11.23
7.29 0.073 72 5.25 n-C₅H₁₂ 7.34
12.96 0.130 86 11.15 C₆H₁₄ 13.71
100 1 - 61.49 Total 100

ṁ mol total= ṁ
42390 lb/hr = 43285 lb/hr
689.36 lbmol = 698.29 lbmol

mol BM massa
0.198 136.15 44 5991 0.138 C₃H₈ 0.175
0.201 138.56 58 8037 0.185 i-C₄H₁₀ 0.209
0.284 195.92 58 11363 0.262 n-C₄H₁₀ 0.293
0.115 79.14 72 5698 0.131 i-C₅H₁₂ 0.112
0.073 50.25 72 3618 0.083 n-C₅H₁₂ 0.073
0.130 89.34 86 7683 0.177 C₆H₁₄ 0.137
1 689.36 - 42390 1 Total 1
Neraca Massa
Input Output (lb) Input
Komponen
(lb) top product bottom product (lb)
185 28 - C₂H₆ 37
32712 25359 5991 C₃H₈ 31771
8086 1858 8037 i-C₄H₁₀ 7915
10350 1007 11363 n-C₄H₁₀ 10155
5170 - 5698 i-C₅H₁₂ 5094
2589 - 3618 n-C₅H₁₂ 2567
9990 11 7683 C₆H₁₄ 10173
28263 42390
69083 Total 67712
70653
P = 191.9 psig
T = 111.10 °F T = 108.00 °F
(3) (4)
ṁ = 43621 lb/hr P = 195.0 psig

200.0 psi (6) T 118.00 °F
128.70 °F ṁ = 63548 lb/hr
67712 lb/hr (5)
(2) (7)
T = 197.50 °F ṁ= 19927 lb/hr
(9)
(10) T = 176.50 °F
T = 205.00 °F
(11) ṁ = 43285 lb/hr

C₃H₈ = 17.51
i-C₄H₁₀ = 20.90
n-C₄H₁₀ = 29.31
i-C₅H₁₂ = 11.23
n-C₅H₁₂ = 7.34
C₆H₁₄ = 13.71
Total = 100

PERHITUNGAN
ṁ fuel gas + ṁ top product + ṁ bottom product

(ṁ top vapor - (ṁ refluks + ṁ top product)) + ṁ bottom product
Mencari BM campuran
BM BM campuran
fraksi mol
0.001 30 0.03
0.573 44 25.22
0.108 58 6.28
0.139 58 8.06
0.056 72 4.04
0.028 72 2.04
0.094 86 8.08
1 - 53.76
ṁ
BM campuran
67712 lb/hr
53.76 lb/lbmol
1259.56 lbmol

mol BM massa
fraksi mol fraksi berat
0.001 1.24 30 37 0.001
0.573 722.08 44 31771 0.465
0.108 136.46 58 7915 0.116
0.139 175.09 58 10155 0.149
0.056 70.75 72 5094 0.074
0.028 35.65 72 2567 0.038
0.094 118.29 86 10173 0.149
1 1259.56 - 67712 1
Mencari BM campuran
BM BM campuran
fraksi mol
0.0075 30 0.23
0.9415 44 41.43
0.0419 58 2.43
0.0086 58 0.50
0.0005 86 0.04
1 - 44.62
ṁ
BM campuran
19927 lb/hr
44.62 lb/lbmol
446.56 lbmol

mol BM massa
0.0075 3.35 30 100 0.004
0.9415 420.44 44 18499 0.771
0.0419 18.71 58 1085 0.045
0.0086 3.84 58 223 0.009
0.0005 0.22 86 19 0.001
1 446.56 - 19927 1
Mencari BM campuran
BM BM campuran
fraksi mol
0.175 44 7.70
0.209 58 12.12
0.293 58 17.00
0.112 72 8.09
0.073 72 5.28
0.137 86 11.79
1 - 61.99
ṁ
BM campuran
43285 lb/hr
61.99 lb/lbmol
698.29 lbmol

mol BM massa
0.175 122.27 44 5380 0.124
0.209 145.94 58 8465 0.195
0.293 204.67 58 11871 0.274
0.112 78.42 72 5646 0.130
0.073 51.25 72 3690 0.085
0.137 95.74 86 8233 0.190
1 698.29 - 43285 1
Output (lb)
top product bottom product
100 -
18499 5380
1085 8465
223 11871
- 5646
- 3690
19 8233
19927 43285
63212
• Neraca Energi Cp sensibel heat
T
a) Input Kolom De-Propanizer (Qs₁) T²
T input = 137.36 °F = 331.68 K T³
T ref = 60 °F = 288.71 K T⁴
P = 200.4 psi = 13.633 atm P
Komponen
persamaan berikut : C₂H₆
C₃H₈
Cp = a + b x T + c x T² + d x T³, T in K (Sherwood) i-C₄H₁₀
n-C₄H₁₀
Dimana nilai a, b, c, dan d masing-masing komponen adalah sebagai berikut : i-C₅H₁₂
b c d
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08
Mencari Cp
C₂H₆ = a + b x T + c x T² + d x T³
= 1.292 + ( 0.043 x 332 K ) + -0.000017 x 110014 K
+ ( 2.80E-09 x 36489755 K )
= 13.68 cal/gmol K
P T Cp n-C₅H₁₂
Komponen
(atm) (K) (Btu/lbmol °F) C₆H₁₄
C₂H₆ 13.633 331.68 13.68
C₃H₈ 13.633 331.68 19.37
Komponen
i-C₄H₁₀ 13.633 331.68 25.55
n-C₄H₁₀ 13.633 331.68 25.58 C₂H₆
i-C₅H₁₂ 13.633 331.68 31.19 C₃H₈
n-C₅H₁₂ 13.633 331.68 31.42 i-C₄H₁₀
C₆H₁₄ 13.633 331.68 37.42 n-C₄H₁₀
i-C₅H₁₂

Tc (K) Pc (atm)
i-C₅H₁₂
Pc Tc n-C₅H₁₂
Komponen
(atm) (K) C₆H₁₄
C₂H₆ 48.2 305.4
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1 Cp sensibel heat
n-C₄H₁₀ 37.5 425.2 T
i-C₅H₁₂ 33.4 460.4 T²
n-C₅H₁₂ 33.3 469.6 T³
C₆H₁₄ 29.3 507.4 T⁴
Mencari Tr dan Pr
Tr C₂H₆ = 331.68 K Pr C₂H₆ = 13.633 atm
305.4 K 48.2 atm
= 1.086 = 0.283
Mencari Cp-Cp*
Mencari Cp*
C₂H₆ = (Cp - Cp*) + Cp
= 1.9 + 13.68 Btu/lbmol °F
Pc Tc
(atm) (K)
C₂H₆ 48.2 305.4 0.283 1.09 1.9 15.58
C₃H₈ 41.9 369.8 0.325 0.90 9 28.37
i-C₄H₁₀ 36 408.1 0.379 0.81 34 59.55
n-C₄H₁₀ 37.5 425.2 0.364 0.78 35 60.58
i-C₅H₁₂ 33.4 460.4 0.408 0.72 52 83.19
n-C₅H₁₂ 33.3 469.6 0.409 0.71 58 89.42
C₆H₁₄ 29.3 507.4 0.465 0.65 68 105.42

= 2697.5 Btu
P
mol Cp* ΔT Q
Komponen
(lbmol)(Btu/lbmol F) (°F) (Btu) C₂H₆
C₂H₆ 2.24 15.58 77.36 2697.50 C₃H₈
C₃H₈ 715.90 28.37 77.36 1570932.40 i-C₄H₁₀
i-C₄H₁₀ 139.14 59.55 77.36 640979.733 n-C₄H₁₀
n-C₄H₁₀ 179.65 60.58 77.36 841841.855 i-C₅H₁₂
i-C₅H₁₂ 73.29 83.19 77.36 471623.163 n-C₅H₁₂
n-C₅H₁₂ 36.85 89.42 77.36 254918.737 C₆H₁₄
C₆H₁₄ 120.90 105.42 77.36 985953.599
Total 1268.0 442.10 4768946.98
Komponen
b) Output Kolom De-Propanizer C₂H₆
Top Product (panas sensibel, Qs₂) C₃H₈
T input = 104.8 °F = 313.59 K = 564.47 R i-C₄H₁₀
T ref = 60 °F = 288.71 K n-C₄H₁₀
P = 194.8 psig = 14.252 atm i-C₅H₁₂
n-C₅H₁₂
Untuk menghitung harga kapasitas panas pada tekanan konstan digunakan C₆H₁₄
persamaan berikut :
Cp = a + b x T + c x T² + d x T³, T in K (Sherwood) Cp sensibel heat
T
b c d
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10
Mencari Cp
C₂H₆ = a + b x T + c x T² + d x T³
= 1.292 + ( 0.043 x 314 K ) + -0.000017 x 98341 K
+ ( 2.80E-09 x 30839340 K )
= 13.09 cal/gmol K
= 13.09 Btu/lbmol F
P T Cp T³
Komponen
(atm) (K) (Btu/lbmol F) T⁴
C₂H₆ 14.252 313.59 13.09 P
C₃H₈ 14.252 313.59 18.44
Komponen
i-C₄H₁₀ 14.252 313.59 24.36
n-C₄H₁₀ 14.252 313.59 24.46 C₂H₆


Tc (K) Pc (atm)
Pc Tc
Komponen
(atm) (K)
C₂H₆ 48.2 305.4
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1
n-C₄H₁₀ 37.5 425.2
C₃H₈
Mencari Tr dan Pr i-C₄H₁₀
Tr C₂H₆ = 313.59 K Pr C₂H₆ = 14.252 atm
305.4 K 48.2 atm
= 1.027 = 0.296
Mencari Cp-Cp*
Mencari Cp*
C₂H₆ = (Cp - Cp*) + Cp
= 2.9 + 13.09 Btu/lbmol F
= 15.99 Btu/lbmol F
Pc Tc n-C₄H₁₀
(atm) (K) i-C₅H₁₂
C₂H₆ 48.2 305.4 0.296 1.027 2.9 15.99 n-C₅H₁₂
C₃H₈ 41.9 369.8 0.340 0.848 17 35.44 C₆H₁₄
i-C₄H₁₀ 36 408.1 0.396 0.768 35 59.36
n-C₄H₁₀ 37.5 425.2 0.380 0.738 40 64.46
Komponen
Mencari panas sensibel (Q) C₂H₆
= 2.25 lbmol x 15.99 Btu/lbmol F x ( 104.80 - 60 ) F
= 1612.0 Btu
mol Cp* ΔT Q C₃H₈

Komponen
(lbmol)(Btu/lbmol F) (°F) (Btu) i-C₄H₁₀
C₂H₆ 2.25 15.99 44.8 1612.03 n-C₄H₁₀
C₃H₈ 501.85 35.44 44.8 796816.54
i-C₄H₁₀ 23.84 59.36 44.8 63410.75 i-C₅H₁₂
n-C₄H₁₀ 7.93 64.46 44.8 22899.62 n-C₅H₁₂
Total 535.9 175.25 884738.94 C₆H₁₄

T input = 104.8 °F = 313.59 K = 564.47 R
T ref = 60 °F = 288.71 K
P = 194.8 psig = 14.252 atm
Untuk menghitung panas penguapan digunakan persamaan berikut :
ΔHn = 1.092 (ln Pc - 1.013)

(J. M. Smith, p. 125)
RTn 0.930 - Trn
dimana :
Tn = dalam R
Pc = dalam bar
dan
ƛ₂ 1 - Tr₂ ###
= (J. M. Smith, p. 125)
ƛ₁ 1 - Tr₁
dimana :
ƛ₁ = ΔHn, dalam Btu/lbmol
Pc Pc Tc Tc Tn Tn
Komponen
(atm) (bar) (K) (R) (K) (R)
C₃H₈ 41.9 42.46 369.8 665.64 231.1 416.0
i-C₄H₁₀ 36 36.48 408.1 734.58 261.4 470.5
n-C₄H₁₀ 37.5 38.00 425.2 765.36 272.7 490.9
Mencari ΔHn atau ƛ₁ C₃H₈

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 42.46 bar - 1.013 )
=
1.987 Btu/lbmol R x 416.0 R 0.930 - ( 416.0 / 665.64 ) R
ΔHn 1.092 ( 3.749 - 1.013 )
=
826.552 Btu/lbmol 0.930 - 0.6249
ΔHn 2.9877
=
826.552 Btu/lbmol 0.3051
Untuk nilai ΔHn komponen lainnya dicari menggunakan cara yang sama dan dapat
Mencari ΔH₂ atau ƛ₂ C₃H₈

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 564.47 / 665.64 ###
=
8094.9 Btu/lbmol 1 - 416.0 / 665.64
ƛ₂ 0.152 ###
=
8094.9 Btu/lbmol 0.3751
Untuk nilai ΔH₂ komponen lainnya dicari menggunakan cara yang sama dan dapat
Mencari panas penguapan

C₃H₈ = m x ƛ
= 501.85 lbmol x 5743.02 Btu/lbmol
= 2882130.54 Btu
Untuk nilai Qlaten komponen lainnya dicari menggunakan cara yang sama dan
mol ƛ Q
Komponen
C₃H₈ 501.85 5743.02 2882130.54
i-C₄H₁₀ 23.84 7711.11 183863.83
n-C₄H₁₀ 7.93 8592.32 68138.31
Total 533.6 22046.44 3134132.68
Menghitung ΔHn atau ƛ₁ i-C₄H₁₀

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn (J. M. Smith, p. 125)
dimana :
Tn = dalam R
Pc = dalam bar
Jadi,
ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 36.48 bar - 1.013 )
=
1.987 Btu/lbmol R x 470.5 R 0.930 - ( 470.5 / 734.58 ) R
ΔHn 1.092 ( 3.597 - 1.013 )
=
934.923 Btu/lbmol 0.930 - 0.6405
ΔHn 2.8217
=
934.923 Btu/lbmol 0.289

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
dimana :
Jadi,
ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 564.47 / 734.58 ###
=
=
9113.5 Btu/lbmol 1 - 470.5 / 734.58
ƛ₂ 0.2316 ###
=
9113.5 Btu/lbmol 0.3595
Menghitung ΔHn atau ƛ₁ n-C₄H₁₀

ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn (J. M. Smith, p. 125)
dimana :
Tn = dalam R
Pc = dalam bar
Jadi,
ΔHn = 1.092 (ln Pc - 1.013)
RTn 0.930 - Trn
ΔHn 1.092 ( ln 38.00 bar - 1.013 )
=
1.987 Btu/lbmol R x 490.9 R 0.930 - ( 490.9 / 765.36 ) R
ΔHn 1.092 ( 3.635 - 1.013 )
=
975.339 Btu/lbmol 0.930 - 0.6413
ΔHn 2.8632
=
975.339 Btu/lbmol 0.2887

ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
dimana :
Jadi,
ƛ₂ 1 - Tr₂ ###
=
ƛ₁ 1 - Tr₁
ƛ₂ 1 - 564.47 / 765.36 ###
=
9674.6 Btu/lbmol 1 - 490.9 / 765.36
ƛ₂ 0.2625 ###
=
9674.6 Btu/lbmol 0.3587
Mencari latent heat

mol ƛ Q
Komponen
C₃H₈ 501.85 5743.02 2882130.54
i-C₄H₁₀ 23.84 7711.11 183863.83
n-C₄H₁₀ 7.93 8592.32 68138.31
Total 533.6 22046.44 3134132.68

T input = 205 °F = 369.26 K = 664.67 R
T ref = 60 °F = 288.71 K

persamaan berikut :
Cp = a + b x T + c x T² + d x T³, T in K
Cp komponen diperoleh dari Sherwood ditunjukkan pada tabel berikut :

P T Cp
Komponen
C₃H₈ 13.633 369.26 21.24
i-C₄H₁₀ 13.633 369.26 #REF!
n-C₄H₁₀ 13.633 369.26 27.86
i-C₅H₁₂ 13.633 369.26 34.23
n-C₅H₁₂ 13.633 369.26 34.37
C₆H₁₄ 13.633 369.26 40.92
Mencari panas sensibel

mol Cp ΔT Q
Komponen
C₃H₈ 214.05 21.24 145 659133.62
i-C₄H₁₀ 115.30 #REF! 145 #REF!
n-C₄H₁₀ 171.72 27.86 145 693706.86
i-C₅H₁₂ 73.29 34.23 145 363729.21
n-C₅H₁₂ 36.85 34.37 145 183663.09
C₆H₁₄ 120.90 40.92 145 717407.00
Total 732.10 #REF! #REF!

T input = 205 °F = 369.26 K
T ref = 60 °F = 288.71 K
P = 235.6 psig = 17.027 atm

persamaan berikut :

b c d
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹)
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08
Mencari Cp
C₃H₈ = a + b x T + c x T² + d x T³
= -1.009 + ( 0.073 x 369 K ) + -0.000038 x 136354 K
+ ( 7.68E-09 x 50350144 K )
= 21.22 cal/gmol K
= 21.22 Btu/lbmol F
P T Cp
Komponen
C₃H₈ 17.027 369.26 21.22
i-C₄H₁₀ 17.027 369.26 27.94
n-C₄H₁₀ 17.027 369.26 27.84
i-C₅H₁₂ 17.027 369.26 34.20
n-C₅H₁₂ 17.027 369.26 34.35
C₆H₁₄ 17.027 369.26 40.90


Tc (K) Pc (atm)
Pc Tc
Komponen
(atm) (K)
C₃H₈ 41.9 369.8
i-C₄H₁₀ 36 408.1
n-C₄H₁₀ 37.5 425.2
i-C₅H₁₂ 33.4 460.4
n-C₅H₁₂ 33.3 469.6
C₆H₁₄ 29.3 507.4
Mencari Tr dan Pr
Tr C₃H₈ = 369.26 K Pr C₃H₈ = 17.027 atm
369.8 K 41.9 atm
= 0.999 = 0.406
Mencari Cp-Cp*
didapatkan nilai Cp - Cp* C₃H₈ = 5
Mencari Cp*
C₃H₈ = (Cp - Cp*) + Cp
= 5 + 21.22 Btu/lbmol F
= 26.22 Btu/lbmol F
Pc Tc
(atm) (K)
C₃H₈ 41.9 369.8 0.406 0.999 5 26.22
i-C₄H₁₀ 36 408.1 0.473 0.905 19 46.94
n-C₄H₁₀ 37.5 425.2 0.454 0.868 30 57.84
i-C₅H₁₂ 33.4 460.4 0.510 0.802 45 79.20
n-C₅H₁₂ 33.3 469.6 0.511 0.786 48 82.35
C₆H₁₄ 29.3 507.4 0.581 0.728 55 95.90

C₃H₈ = m x Cp x ΔT
= 214 lbmol x 26.22 Btu/lbmol F x ( 205.00 - 60 ) F
= 813878.9 Btu
mol Cp* ΔT Q
Komponen
C₃H₈ 214.05 26.22 145 813878.93
i-C₄H₁₀ 115.30 46.94 145 784683.48
n-C₄H₁₀ 171.72 57.84 145 1440206.26
i-C₅H₁₂ 73.29 79.20 145 841686.75
n-C₅H₁₂ 36.85 82.35 145 440012.10
C₆H₁₄ 120.90 95.90 145 1681074.37
Total 732.1 388.45 6001541.89

ṁ = 330.5 gal/meni = 2651.3 ft³/hr
T = 368 °F
T ref = 60 °F
ρ = 47.3 lb/ft³ (pada 368 °F)
cp = 0.597 Btu/lb °F (pada 368 °F)
Mencari massa hot oil masuk

massa = ṁ x ρ
= 2651.27 ft³/hr x 47.3 lb/ft³
= 125405 lb

Q = m cp ΔT
= 125405 lb x 0.597 Btu/lb F x 308 °F
= 23058991.5 Btu

ṁ = 330.5 gal/meni = 2651.3 ft³/hr
T = 254.8 °F
T ref = 60 °F
ρ = 50.03 lb/ft³ (pada 254.8 °F)
cp = 0.544 Btu/lb °F (pada 254.8 °F)
Mencari massa hot oil keluar

massa = ṁ x ρ
= 2651.27 ft³/hr x 50.03 lb/ft³
= 132643 lb

Q = m cp ΔT
= 132643 lb x 0.544 Btu/lb F x 195 °F
= 14056347.2 Btu
Neraca Massa Kolom De-Propanizer Output kolom top produ

Input Output Output kolom top produ
Aliran
Btu % Btu % Output kolom bottom pr
Qs₁ 4768947 17.1 - - Panas yang hilang
Qs₂ - - 884739 3.2 Total
Qs₃ - - 3134133 11.3
Qs₄ - - 6001542 21.6
Qs₅ 23058991.5 82.9 - -
Qs₆ - - 14056347 50.5
Q loss - - 3751178 13.5
Total 27827939 100 27827939 100
Konsumsi Energi Spesifik = Energi yang dihasilkan

= 27827939 Btu
68383 lb
= 406.9 Btu/lb
Cp sensibel heat (Cp = a + b x T + c x T² + d x T³), T in K CP sensibel heat
= 137.36 °F = 331.68 K T =
= 110014 K T²
= 36489755 K T³
= 12103043585.8 K T⁴
= 200.4 psi P =
b c d Cp
Komponen a Komponen
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 13.68 C₂H₆
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 19.37 C₃H₈
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 25.55 i-C₄H₁₀
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 25.58
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 31.19
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 31.42 n-C₅H₁₂

C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 37.42 C₆H₁₄
Cp Cp
Komponen
(J/kmol K) (Btu/lbmol F)
C₂H₆ 57279.98 13.69
C₃H₈ 81078.97 19.38
i-C₄H₁₀ 106965.20 25.57
n-C₄H₁₀ #REF! #REF!
i-C₅H₁₂ #REF! #REF!
ilihat pada tabel dibawah

i-C₅H₁₂ #REF! #REF!
n-C₅H₁₂ 131566.47 31.45
C₆H₁₄ 156674.28 37.45
Cp sensibel heat (Cp = a + b x T + c x T² + d x T³), T in K CP sensibel heat

= 104.8 °F = 313.59 K T =
= 98341 K T²
= 30839340 K T³
= 9671045820.51 K T⁴
akan cara yang sama dan

= 200.4 psi P =
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K)
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 13.09 C₂H₆
C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 18.44 C₃H₈
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 24.36 i-C₄H₁₀
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 24.46 n-C₄H₁₀
i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 29.68 i-C₅H₁₂
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 29.97 n-C₅H₁₂
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 35.69 C₆H₁₄
Cp Cp
Komponen
(J/kmol K) (Btu/lbmol F)
C₂H₆ 54801.74 13.10
C₃H₈ 77209.03 18.45
i-C₄H₁₀ 101997.03 24.38
n-C₄H₁₀ 102395.91 24.47
i-C₅H₁₂ 124266.82 29.70
n-C₅H₁₂ 125463.08 29.99
C₆H₁₄ 149420.57 35.71
Cp sensibel heat (Cp = a + b x T + c x T² + d x T³), T in K Laten heat
= 205 °F = 369.26 K T =
= 50350144 K
Komponen
= 18592350096.6 K
= 200.4 psi C₂H₆
b c d Cp C₃H₈
Komponen a
(x10⁻²) (x10⁻⁵) (x10⁻⁹) (cal/gmol K) i-C₄H₁₀
C₂H₆ 1.292 4.25E-02 -1.66E-05 2.80E-09 14.88 n-C₄H₁₀

C₃H₈ -1.009 7.32E-02 -3.79E-05 7.68E-09 21.22 i-C₅H₁₂
i-C₄H₁₀ -0.332 9.19E-02 -4.41E-05 6.92E-09 27.94
n-C₄H₁₀ 2.266 7.91E-02 -2.65E-05 -6.74E-10 27.84 C₆H₁₄

i-C₅H₁₂ -2.275 1.21E-01 -6.52E-05 1.37E-08 34.20
n-C₅H₁₂ -0.866 1.16E-01 -6.16E-05 1.27E-08 34.35
Komponen
C₆H₁₄ -1.054 1.39E-01 -7.45E-05 1.55E-08 40.90
C₂H₆
Cp Cp C₃H₈
Komponen
(J/kmol K) (Btu/lbmol F) i-C₄H₁₀
C₂H₆ 62308.03 14.89
C₃H₈ 88854.76 21.24 i-C₅H₁₂

i-C₄H₁₀ #REF! #REF! n-C₅H₁₂
n-C₄H₁₀ 116570.61 27.86 C₆H₁₄
i-C₅H₁₂ 143209.41 34.23

n-C₅H₁₂ 143818.45 34.37 CP sensibel heat
C₆H₁₄ 171228.54 40.92 T =
T²
C₃H₈
i-C₄H₁₀
n-C₄H₁₀



Output kolom top product - #REF! #REF!
Output kolom top product - 0.00 #REF!
Output kolom bottom product - 0.00 #REF!
Panas yang hilang - #REF!
Total #REF! #REF! #REF!
CP sensibel heat (cp = C1 + C2 x T + C3 x T² + C4 x T³ + C5 x T⁴), T in K
137.36 °F = 331.68 K
= 110014 K
= 36489755 K
= 12103043585.8 K
200.4 psi
Cp
Komponen C1 C2 C3 C4 C5
(J/kmol K)
C₂H₆ 44.009 89718 918.770 -1886 - -68688842595
C₃H₈ 62.983 113630 633.210 -873.46 - -31764990342
i-C₄H₁₀ 172370 -1783.9 14.759 -0.048 0.00006 158768.277643
n-C₅H₁₂ 159080 -270.5 0.995 - - 178864.127895

C₆H₁₄ 172120 -183.8 0.887 - - 208782.912116
Cp
(Btu/lbmol F)
-16417038.644
-7592020.1051
37.9465550895
#REF!
#REF!
42.7495818652
49.900347815

104.8 °F = 313.59 K
= 98341 K
= 30839340 K
= 9671045820.51 K
200.4 psi
(J/kmol K)
C₂H₆ 44.009 89718 918.770 -1886 - -58044507691
C₃H₈ 62.983 113630 633.210 -873.46 - -26839025662
i-C₄H₁₀ 172370 -1783.9 14.759 -0.048 0.00006 148292.959279
n-C₄H₁₀ 64.730 161840 983.410 -1431.5 - -43999053606
i-C₅H₁₂ 108300 146 -0.292 0.002 - 171936.482025
n-C₅H₁₂ 159080 -270.5 0.995 - - 172138.857332
C₆H₁₄ 172120 -183.8 0.887 - - 201749.937947
Cp
(Btu/lbmol F)
-13872979.801
-6414685.4836
35.4428921962
41.0938336293
41.1422025217
48.2194254939
Laten heat (ΔHᵥ = C1 x (1 - Tr)^(C2 + C3 x Tr + C4 x Tr x Tr)), T in K
104.8 °F = 313.59 K
Tc Tr
Komponen C1 C2 C3 C4
(K) (K)
C₂H₆ 0.00000021091 0.60646 -0.5549 0.32799 305.4 1.209
C₃H₈ 0.00000029209 0.78237 0.77319 0.39246 369.8 0.999
i-C₄H₁₀ 0.00000031667 0.38550 - - 408.1 0.905
n-C₄H₁₀ 0.00000036238 0.83370 0.82274 0.39613 425.2 0.868
i-C₅H₁₂ 0.00000037700 0.39520 - - 469.6 0.786
C₆H₁₄ 0.00000044544 0.39002 - - 507.4 0.728
Tr x Tr ΔHᵥ ΔHᵥ
Komponen
(K) (J/kmol) (Btu/lbmol)
C₂H₆ 1.462 0.415 #VALUE! #VALUE!
C₃H₈ 0.997 1.946 8.8401349E-13 3.8031197E-16
i-C₄H₁₀ 0.819 0.386 1.2788475E-07 5.5017374E-11
i-C₅H₁₂ 0.618 0.395 2.0485901E-07 8.8132518E-11
n-C₅H₁₂ #REF! #REF! #REF! #REF!
C₆H₁₄ 0.530 0.390 2.6817263E-07 1.1537071E-10

205 °F = 369.26 K
= 136354 K
C₃H₈ 62.983 113630 633.210 -873.46 - #REF!
i-C₄H₁₀ 172370 -1783.9 14.759 -0.048 0.00006 #REF!
n-C₄H₁₀ 64.730 161840 983.410 -1431.5 - #REF!
#REF!
#REF!
#REF!
#REF!
#REF!
Kolom De-Propanizer secara Hysys
• Neraca Massa
a) Input kolom De-Propanizer

ṁ = 68380 lb/hr
T = 137.40 °F
P = 200.4 psi
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.18
100
= 0.002
Mencari BM campuran
= 0.002 x 30 lb/lbmol
= 0.05 lb/lbmol
BM BM campuran
C₂H₆ 0.18 0.002 30 0.05
C₃H₈ 56.46 0.565 44 24.84
i-C₄H₁₀ 10.97 0.110 58 6.36
n-C₄H₁₀ 14.17 0.142 58 8.22
i-C₅H₁₂ 5.78 0.058 72 4.16
n-C₅H₁₂ 2.91 0.029 72 2.10
C₆H₁₄ 9.53 0.095 86 8.20
Total 100 1 - 53.93
mol total= ṁ
BM campuran
= 68380 lb/hr
53.93 lb/lbmol
= 1267.94 lbmol

= 0.002 x 1267.94 lbmol
= 2.28 lbmol
pada tabel dibawah

= 68 lb
mol BM massa
Komponen fraksi mol
C₂H₆ 0.002 2.28 30 68
C₃H₈ 0.565 715.88 44 31499
i-C₄H₁₀ 0.110 139.09 58 8067
n-C₄H₁₀ 0.142 179.67 58 10421
i-C₅H₁₂ 0.058 73.29 72 5277
n-C₅H₁₂ 0.029 36.90 72 2657
C₆H₁₄ 0.095 120.83 86 10392
Total 1 1267.94 - 68380
b) Output Kolom De-Propanizer (top produk)

ṁ = 24000 lb/hr
Mencari fraksi mol

C₂H₆ = % mol
100
= 0.43
100
= 0.004
Mencari BM campuran
= 0.004 x 30 lb/lbmol
= 0.13 lb/lbmol
BM BM campuran
C₂H₆ 0.43 0.0043 30 0.13
C₃H₈ 93.66 0.9366 44 41.21
i-C₄H₁₀ 4.41 0.0441 58 2.56
n-C₄H₁₀ 1.50 0.0150 58 0.87
Total 100 1 - 44.77

mol total= ṁ
BM campuran
= 24000 lb/hr
44.77 lb/lbmol
= 536.11 lbmol

= 0.004 x 536.11 lbmol
= 2.31 lbmol
pada tabel dibawah

= 69 lb
mol BM massa
Komponen fraksi mol
C₂H₆ 0.0043 2.31 30 69
C₃H₈ 0.9366 502.12 44 22093
i-C₄H₁₀ 0.0441 23.64 58 1371
n-C₄H₁₀ 0.0150 8.04 58 466
Total 1 536.11 - 24000
c) Output Kolom De-Propanizer (bottom produk)

ṁ = 44390 lb/hr
Mencari fraksi mol

C₃H₈ = % mol
100
= 29.22
100
= 0.292
Mencari BM campuran
C₃H₈ = fraksi mol x BM
= 0.292 x 44 lb/lbmol
= 12.86 lb/lbmol
BM BM campuran
C₃H₈ 29.22 0.292 44 12.86
i-C₄H₁₀ 15.77 0.158 58 9.15
n-C₄H₁₀ 23.45 0.235 58 13.60
i-C₅H₁₂ 10.01 0.100 72 7.21
n-C₅H₁₂ 5.04 0.050 72 3.63
C₆H₁₄ 16.51 0.165 86 14.20
Total 100 1 - 60.64
Mencari mol total

mol total= ṁ
BM campuran
= 44390 lb/hr
60.64 lb/lbmol
= 732.04 lbmol

= 0.292 x 732.04 lbmol
= 213.90 lbmol
pada tabel dibawah

= 9412 lb
mol BM massa
Komponen fraksi mol
C₃H₈ 0.292 213.90 44 9412
i-C₄H₁₀ 0.158 115.44 58 6696
n-C₄H₁₀ 0.235 171.66 58 9956
i-C₅H₁₂ 0.100 73.28 72 5276
n-C₅H₁₂ 0.050 36.89 72 2656
C₆H₁₄ 0.165 120.86 86 10394
Total 1 732.04 - 44390
Input Output (lb)
Komponen
C₂H₆ 68 69 -
C₃H₈ 31499 22093 9412
i-C₄H₁₀ 8067 1371 6696
n-C₄H₁₀ 10421 466 9956
i-C₅H₁₂ 5277 - 5276
n-C₅H₁₂ 2657 - 2656
C₆H₁₄ 10392 - 10394
24000 44390
Total 68380
68390

Input Output (lb)
Komponen
C₂H₆ 68 69 -
C₃H₈ 31499 22093 9405
i-C₄H₁₀ 8067 1371 6696
n-C₄H₁₀ 10421 466 9954
i-C₅H₁₂ 5277 - 5277
n-C₅H₁₂ 2657 - 2657
C₆H₁₄ 10392 - 10392
24000 44381
Total 68380
68381
umsi Energi Spesifik pada

yang sama dan dapat dilihat


• Neraca Energi
a) Input Kolom De-Propanizer (Qs₁)

T input = 137.36 °F = 331.68 K
T ref = 60 °F = 288.71 K
P = 200.4 psi = 13.633 atm
Harga Cp total pada stream input diperoleh dari hysys, yaitu : 36.71 Btu/lbmol F
Mencari Cp
C₂H₆ = % mol
x Cp total
100
= 0.18
x 36.71Btu/lbmol °F
100
Cp
Komponen % mol
(Btu/lbmol F)
C₂H₆ 0.18 0.07
C₃H₈ 56.46 20.73
i-C₄H₁₀ 10.97 4.03
n-C₄H₁₀ 14.17 5.20
i-C₅H₁₂ 5.78 2.12
n-C₅H₁₂ 2.91 1.07
C₆H₁₄ 9.53 3.50
Total 100 36.71

= 11.7 Btu
mol Cp ΔT Q
Komponen
C₂H₆ 2.28 0.07 77.36 11.67
C₃H₈ 715.88 20.73 77.36 1147835.52
i-C₄H₁₀ 139.09 4.03 77.36 43332.24
n-C₄H₁₀ 179.67 5.20 77.36 72299.89
i-C₅H₁₂ 73.29 2.12 77.36 12029.67
n-C₅H₁₂ 36.90 1.07 77.36 3049.19
C₆H₁₄ 120.83 3.50 77.36 32702.71
Total 1267.9 36.71 1311260.87
b) Output Kolom De-Propanizer

Top Product (panas sensibel, Qs₂)
T input = 104.8 °F = 313.59 K = 564.47 R
T ref = 60 °F = 288.71 K
P = 194.8 psig = 14.252 atm
Harga Cp total stream output diperoleh dari hysys, yaitu : 33.79 Btu/lbmol F
Mencari Cp
C₂H₆ = % mol
x Cp total
100
= 0.43
100
Cp
Komponen % mol
(Btu/lbmol F)
C₂H₆ 0.43 0.15
C₃H₈ 93.66 31.65
i-C₄H₁₀ 4.41 1.49
n-C₄H₁₀ 1.50 0.51
Total 100 33.79

= 15.0 Btu
mol Cp ΔT Q
Komponen
C₂H₆ 2.31 0.15 44.8 15.01
C₃H₈ 502.12 31.65 44.8 711911.20
i-C₄H₁₀ 23.64 1.49 44.8 1578.32
n-C₄H₁₀ 8.04 0.51 44.8 182.60
Total 536.1 33.79 713687.12

T input = 104.8 °F = 313.59 K = 564.47 R
T ref = 60 °F = 288.71 K
P = 194.8 psig = 14.252 atm
Harga ΔHv total stream output diperoleh dari hysys, yaitu : 5880 Btu/lbmol
Mencari ΔHv
C₂H₆ = % mol
x ΔHv total
100
= 0.43
x 5880 Btu/lbmol
100
= 25.28 Btu/lbmol
Untuk nilai ΔHv komponen lainnya dicari menggunakan cara yang sama dan dapat
ΔHv
Komponen % mol
(Btu/lbmol)
C₂H₆ 0.43 25.28
C₃H₈ 93.66 5507.21
i-C₄H₁₀ 4.41 259.31
n-C₄H₁₀ 1.50 88.20
Total 100 5880
Mencari panas laten (Q)

C₂H₆ = m x ΔHv
= 2.31 lbmol x 25.28 Btu/lbmol
= 58.3 Btu
mol ƛ Q
Komponen
C₂H₆ 2.31 25.28 58.29
C₃H₈ 502.12 5507.21 2765266.18
i-C₄H₁₀ 23.64 259.31 6130.64
n-C₄H₁₀ 8.04 88.20 709.27
Total 533.8 5880 2772106.09

T input = 205 °F = 369.26 K
T ref = 60 °F = 288.71 K
P = 235.6 psig = 17.027 atm
Harga Cp total pada stream bottom diperoleh dari hysys, yaitu : 45.03 Btu/lbmol F
Mencari Cp
C₃H₈ = % mol
x Cp total
100
= 29.22
100
Cp
Komponen % mol
(Btu/lbmol F)
C₃H₈ 29.22 13.16
i-C₄H₁₀ 15.77 7.10
n-C₄H₁₀ 23.45 10.56
i-C₅H₁₂ 10.01 4.51
n-C₅H₁₂ 5.04 2.27
C₆H₁₄ 16.51 7.43
Total 100 45.03
= 214 lbmol x 13.16 Btu/lbmol °F x ( 205.00 - 60 ) °F
= 408097 Btu
mol Cp ΔT Q
Komponen
C₃H₈ 213.90 13.16 145 408097.08
i-C₄H₁₀ 115.44 7.10 145 118868.41
n-C₄H₁₀ 171.66 10.56 145 262838.37
i-C₅H₁₂ 73.28 4.51 145 47892.91
n-C₅H₁₂ 36.89 2.27 145 12141.27
C₆H₁₄ 120.86 7.43 145 130285.84
Total 732.0 45.03 980123.87

ṁ = 330.5 gal/meni = 2651.3 ft³/hr
T = 368 °F
T ref = 60 °F
ρ = 47.3 lb/ft³ (pada 368 °F)
cp = 0.597 Btu/lb °F (pada 368 °F)
Mencari massa hot oil masuk

massa = ṁ x ρ
= 2651.3 ft³/hr x 47.3 lb/ft³
= 125405 lb

Q = m cp ΔT
= 125405 lb x 0.597 Btu/lb F x 308 °F
= 23058992 Btu

ṁ = 330.5 gal/meni = 2651.3 ft³/hr
T = 254.8 °F
T ref = 60 °F
ρ = 50.03 lb/ft³ (pada 254.8 °F)
cp = 0.544 Btu/lb °F (pada 254.8 °F)
Mencari massa hot oil keluar
massa = ṁ x ρ
= 2651.3 ft³/hr x 50.03 lb/ft³
= 132643 lb

Q = m cp ΔT
= 132643 lb x 0.544 Btu/lb F x 195 °F
= 14056347 Btu

Input Output
Aliran
Btu % Btu %
Qs₁ 1311261 5.4 - -
Qs₂ - - 713687 2.9
Qs₃ - - 2772106 11.4
Qs₄ - - 980124 4.0
Qs₅ 23058992 94.6 - -
Qs₆ - - 14056347 57.7
Q loss - - 5847988 24.0
Total 24370252 100 24370252 100
Konsumsi Energi Spesifi = Energi yang dihasilkan

= 24370252 Btu
68380 lb
= 356.4 Btu/lb
yaitu : 36.71 Btu/lbmol F


, yaitu : 45.03 Btu/lbmol F

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BAB V

5.1 Data/diagram Pengamatan Proses

Stream (5) Fuel output from akumulator

Stream (6) Output akumulator

Komposisi Stream (6)

(9) Komposisi NGL masuk

Gambar 1. Unit 03-C-4101 (kolom de-propanizer)

Tabel 1. Data laju aliran massa NGL masuk - Stream (2)

Tabel 2. Komposisi NGL masuk - Stream (2) • Neraca Massa

Mencari mol total stream

Untuk mol komponen la

Mencari massa kompone

Untuk massa komponen

Untuk fraksi mol kompo

Tabel 7. Kondisi operasi pada unit de-propanizer colomn

Untuk mol komponen la

Mencari massa kompone

Untuk massa komponen

Untuk massa komponen

Mencari mol komponen

Untuk mol komponen la

Untuk % mol komponen

Neraca Massa Kolom De

Komposisi Stream (6)

ṁ = 41998 lb/hr P = 194.8 psig

Komposisi Stream (10)

Gambar L1. Unit 03-C-4101 (kolom de-propanizer)

a) Input kolom De-Propanizer

Mencari fraksi mol

Mencari mol total stream 1

Mencari mol komponen

Mencari massa komponen

b) Output Kolom De-Propanizer (top produk)

Mencari fraksi mol

Mencari mol total stream 6

Mencari mol komponen

Mencari massa komponen

c) Output Kolom De-Propanizer (bottom produk)

Mencari massa komponen

Mencari mol komponen

Neraca Massa Kolom De-Propanizer

(9) Komposisi NGL masuk

Gambar 1. Unit 03-C-4101 (kolom de-propanizer)

Tabel 1. Data laju aliran massa NGL masuk - Stream (2)

ṁ = 41998 lb/hr P = 194.8 psig

Komposisi Stream (12)

Gambar 2. Unit 03-C-4101 (kolom de-propanizer)

ṁ input = ṁ fuel gas + ṁ top product + ṁ bottom product

• Input kolom De-Propanizer

Mencari mol total

Mencari massa komponen

Mencari mol total

Mencari massa komponen

Mencari mol total

Mencari massa komponen

Komposisi Stream (6)

Komposisi Stream (10)

Gambar 1. Unit 03-C-4101 (kolom de-propanizer)

a) Input kolom De-Propanizer • Input kolom De-Prop

Mencari fraksi mol

Mencari mol total stream 1 Mencari mol total

Mencari mol komponen