BEC Multi Choice Chem and Physics

CHEMISTRY passes through a tube and displaces water in an inverted,
DRILL 1 water-filled bottle. Which of the following items may be

determined after the experiment is completed?"
Question 1 2 points vapor pressure of water
Ima Chemist found the density of Freon-11 (CFCl3) to be 5.58 temperature of the displaced water
g/L under her experimental conditions. Her measurements barometric pressure in the room
showed that the density of an unknown gas was 4.38 g/L under mass of the solid used
the same conditions. What is the molar mass [g/mol] of the
unknown? Question 8 1 points
175 108 What is the term for a quantity of a substance to which a
96.7 127 chemical formula can be assigned and whose mass is equal to
its formula weight?
Question 2 2 points a. an equivalent b. a one-normal solution c. a
Silicon, which makes up about 25% of Earth's crust by mass, molecule d. a mole
is used widely in the modern electronics industry. It has three
naturally occurring isotopes, 28Si, 29Si, and 30Si. Calculate Question 9 2 points
the atomic mass of silicon. The executioner in charge of the lethal gas chamber at the
Isotope Isotopic Mass (amu) Abundance % state penitentiary adds excess dilute sulfuric acid to 196 g of
28Si 27.976927 92.23 sodium cyanide. What volume [L] of HCN gas is formed at
29Si 28.976495 4.67 STP?
30Si 29.973770 3.10 The reaction is: H2SO4 + 2 NaCN --> 2 HCN + Na2SO4
29.2252 amu 28.7260 amu 45 180
28.0855 amu 27.9801 amu 90 5
Question 3 1 points Question 4 2 points

"A sealed, rigid container is filled with three ideal gases: A, B, Copper(II) sulfate pentahydrate, CuSO4·5H2O, is used as a
and C. The partial pressure of each gas is known. The fungicide and algicide. Calculate the mass of oxygen in 1.000
temperature and volume of the system are known. What mol of CuSO4·5H2O.
additional information is necessary to determine the masses of 249.7 g 96.00 g
the gases in the container?" 144.0 g 64.00 g
the molar masses of the gases the total pressure
the intermolecular forces the average distance Question 5 1 points
traveled between What is the percentage (by mass) of hydrogen in glucose
molecular collisions (C₆H₁₂O₆)?
a. 0.067 b. 0.4
Question 4 1 points c. 0.17 d. 0.093
Which of the following elements has the largest first
ionization energy? Question 6 1 points
a. Kr (krypton) b. H (hydrogen) A steel tank containing argon gas has additional argon gas
c.Ar (argon) d. CI (chlorine) pumped into it at constant temperature. Which of the
following is true for the gas in the tank?
Question 5 1 points The gas atoms travel with the same average speed.
Structural isomers have the same molecular formula but There is a decrease in the pressure exerted by the gas.
different structural formulas There is an increase in the volume of the gas.
True There is no change in the number of gas atoms.
False
Question 7 1 points
Question 6 1 points Which of the following elements does not exists as a diatomic
"For a given isotope of an element, the atomic number plus the molecule under normal (ambient) conditions?
atomic weight is 148, and their difference is 58. How many a. sulfur b. chlorine
protons does an atom of the isotope contain?" c. iodine d. oxygen
a. 148 b. 45
c. 58 d. 90 Question 8 1 points
This element may form a compound with the formula
Question 7 1 points CaXO4.
"An experiment to determine the molar mass of a gas begins Se Cl
by heating a solid to produce a gaseous product. The gas P Na
Question 9 1 points a. 0.33 b. 0.57
"As the pressure of a gas increases, the solubility of that gas in c. 0.42 d. 0.66
a liquid"
Answers: Question 8 2 points
a. always increases. b. cannot be determined. A flask containing neon gas is connected to an open-ended
c. is not changed. d. always decreases. mercury manometer. The open end is exposed to the
atmosphere, where the prevailing pressure is 745 torr. The
Question 10 1 points mercury level in the open arm is 50. mm below that in the arm
Which sample demonstrate particles arranged in regular connected to the flask of neon. What is the neon pressure, in
geometric pattern? torr?
a. CO₂(aq) b. CO₂(g) 695 torr -50 torr
c. CO₂(l) d. CO₂(s) 795 torr 50 torr

“The rate of effusion of a gas is inversely proportional to the Lead (II) nitrate is a poisonous substance which has been used
square root of its molar mass” is a statement of in the manufacture of special explosives and as a sensitizer in
_________________ Law. photography. Calculate the mass of lead in 139 g of
Graham's Charles' Pb(NO3)2.
Dalton's Avogadro's 107 g 62.6 g
87.0 g 90.8 g
Question 2 1 points
At STP the volume of 1.5 mole N2 as compared to 1.0 mole Question 2 2 points
O2 is Assume that one cubic foot of air near a thermonuclear
a.different by about 11.2 L b. higher to about three explosion is heated from 0°C to 546,000°C. To what volume
fourths in ft3 does the air expand?
c. differ by a factor of 1.25 d. "the same, 22.4L" 2001 273
2000 1
Question 3 1 points
What should you do if you spill sulfuric acid on the Question 6 1 points
countertop? Which of the following represents the correct formula for
neutralize the acid with NaHCO3 solution potassium trioxalatoferrate(III)?
neutralize the acid with vinegar K3[Fe(C2O4)3] P3[Fe(C2O4)3]
sprinkle solid NaOH on the spill KFe3(C2O4)3 K3[Fe3(C2O4)3]
neutralize the acid with an Epsom salt (MgSO4) solution
Question 7 1 points
Question 4 1 points Which of the following substances will produce a colorless
"The total pressure in a mixture of unreacting gases is equal to aqueous solution?
the sum of the partial pressures of the individual gases" is a Zn(NO3)2 CuSO4
statement of __________________ Law. K2Cr2O7 Co(NO3)2
Dalton's Boyle's
Charles' Graham's Question 8 1 points
Which atom is not paired with its correct ion and ionic charge?
Question 5 1 points a. F / F1- b. Rb / Rb1-
A book is lifted off of the floor and placed on a table that is c. Li / Li1+ d. Mg / Mg2-
one meter above the floor. The book has
a. gained sound energy b. lost chemical energy Question 10 1 points
c. gained kinetic energy d. gained potential energy "The reaction shown occurs in a gaseous phase. Once
equilibrium has been achieved in a particular reaction vessel,
Question 6 1 points additional HI gas is injected directly into the reaction vessel.
Uranium-235 and uranium-238 have the same number of Compared to the initial conditions, which of the following
which of the following? statements is correct after the new equilibrium has been
a. protons b. Protons and electrons achieved?"
c. electrons d. neutrons a. The partila pressure of HI will have decreased.
b. The amount of I2 will have increased.
Question 7 2 points c. The amount of H2 will have decreased.
What is the gravimetric (i.e.m.,mass) percentage of oxygen in d. The partial pressure of H2 will have decreased.
K₂CrO₄?
In an average year the American chemical industry produces Nitrogen dioxide is a red-brown gas that is responsible for the
more than 9.5 million metric tons of sodium carbonate. Over color of photochemical smog. A sample of nitrogen dioxide
half of this is used in the manufacture of glass while another has a volume of 28.6 L at 45.3°C and 89.9 kPa. What is its
third is used in the production of detergents and other volume at STP?
chemicals. How many pounds of sodium carbonate are 21.8 L 29.6 L
produced annually? 153 L 27.6 L
4.3 X 109 lb 2.2 X 106 lb
2.1 X 1010 lb 1.1 X 107 lb Question 2 2 points
Calculate the pressure required to compress 2 liters of a gas at
Question 2 2 points 700 mm Hg and 20°C into a container of 0.1 liter capacity at a
Joseph Priestley discovered oxygen in 1774 by heating temperature of -150°C.
mercury(II) oxide. The compound decomposes into its 15 7167 mm Hg
elements. How much oxygen, O2, is produced by the 717 mm Hg 5877 mm Hg
decomposition of 25 g of HgO?
5.5 3.7 g Question 6 1 points
0.9 g 1.8 g "If a sample of methane gas effuses at a rate of 9.0 mole per
hour at 35 deg C, which of the gases below will effuse at
Question 3 1 points approximately twice the rate under the same conditions?"
The true volume of a real gas is larger than that calculated helium gas carbon monoxide gas
from the ideal gas equation. This occurs because the ideal gas oxygen gas fluorine gas
equation does consider which of the following?
the volume of the molecules Question 7 1 points
the attraction between the molecules Choose the gas that probably shows the greatest deviation
the shape of the molecules from ideal gas behavior.
the mass of the molecules SF4 He
O2 SiH4
Question 4 1 points
What are the conditions of STP? Question 8 1 points
273 °C and 760 torr 0 K and 1 atm Which of the following has the lowest electronegativity?
273 K and 760 torr 0 °C and 760 atm Ba F
I Al
Question 5 1 points
"The volume of an ideal gas is directly proportional to its Question 10 1 points
absolute temperature at constant pressure and number of "Consider a solution of water and a nonvolatile solute
moles" is a statement of ________________ Law. at some temperature. What combination of conditions would
Dalton's Charles' be sure to increase the vapor pressure of the solution?
Avogadro's Boyle's _____""" a. Lower the
temperature and add more solute
Question 6 1 points b. Lower the temperature and add more water
Which units could be used to express the account absorbed or c. Raise the temperature and add more water
released during chemical reaction? d. Raise the temperature and add more solute
a. Calorie and joule b. Gram and liter
c. Degree and gram d. Torr and mmHg Question 1 1 points
Which is the symbol for the element that forms a protective
Question 7 1 points oxide coating?
Which sample represent a homogeneous mixture? Mg Al
a. CH₃OH(aq) b. CH₃OH(l) Ga K
c. CH₃OH(g) d. CH₃OH(s)
Question 3 1 points
Question 8 1 points "What are the chemical formulas for the following
Sodium sulfate froms a number of hydrates. A sample of a compounds: aluminum nitrate, magnesium hydroxide, calcium
hydrate is heated until all the water is removed. What is the oxide, and cupric carbonate?"
formula of the original hydrate if it loses 43% of its mass a. AINO3Mg(HO)2,CaO,Cu(CO3)2
when heated? b. AINO3,Mg(OH),Ca2O3,CuCO3
Na2SO4 *6H2O Na2SO4 *H2O c. "AI(NO3)3,Mg(OH)2,CaO,CuCO3"
Na2SO4 *8H2O Na2SO4 *2H2O d. AL2NO3,Mg(HO),CaO2,CuCO3
Question 5 1 points 2. They readily accept an electron from another atom to form
Potassium metal will react with water to release a gas and compounds.
form a potassium compound. Which of the following is true? 3. They have a high electrical conductivity.
The final solution is basic. 4. "Next to the noble gases, they are the most chemically
The gas is oxygen. inactive group."
The potassium compound precipitates.
The potassium compound will react with strong bases. Question 4 1 points
Aqueous solutions of this ion are blue.
Question 6 1 points Cu2+ (CO3)2+
Which of the following gases will be the slowest to diffuse Fe3+ Al3+
through a room?
Methane hydrogen sulfide Question 5 1 points
Neon carbon dioxide Which of the following statements pertaining to acids and
bases is incorrect?
Question 7 2 points a. Bases have a sour taste.
All of the substances listed below are fertilizers that b. Acids conduct electricity in aqueous solutions.
contribute nitrogen to the soil. Which of these is the richest c. Bases have a pH between 7 and 14.
source of nitrogen on a mass percentage basis? d. Acids turn blue litmus paper red.
Ammonia, NH3
Ammonium nitrate, NH4NO3 Question 6 1 points
Urea, (NH2)2CO Guanidine, HNC(NH2)2 This ion will generate gas bubbles upon the addition of
hydrochloric acid.
Question 4 2 points (CO3)2- Cu2+
A sample of methane gas was collected over water at 35degC. Fe3+ Al3+
The sample had a total pressure of 756 mm Hg. Determine the
partial pressure of the methane gas in the sample. The vapor Question 7 1 points
pressure of water at this temperature is 41 mm Hg. What is the valence (oxidation state) of carbon in sodium
715 mm Hg 760 mm Hg carbonate (Na2CO3)?
41 mm Hg 797 mm Hg a. 2 b. 4
c. -4 d. -2
Question 5 1 points
Which sentence below is incorrect? Question 8 1 points
a. Sand and water make heterogeneous mixture. This element is a liquid at room temperature.
b. Milk is a homogeneous mixture. Hg Th
c. Pure iron is a heterogeneous mixture. Na Cl
d. Salads are heterogeneous mixtures.
Question 9 2 points
Question 7 1 points Terephthalic acid, used in the production of polyester fibers
A liquid will boil when and films, is composed of carbon, hydrogen, and oxygen.
a. it is heated to a temperature that is below the boiling point. When 0.6943 g of terephthalic acid was subjected to
b. a salt has been added to the liquid combustion analysis it produced 1.471 g CO2 and 0.226 g
c. its vapor pressure is equal to the melting point H2O. What is its empirical formula?
d. its vapor pressure is equal to the surrounding pressure C2H2O C5H12O4
C2H3O4 C4H3O2
Question 8 1 points
The ozone layer is important because Question 3 2 points
ozone purifies the atmosphere by reacting with excess 0.72 g of O2 has a greater mass than 0.0011 mol of
fluorocarbons chlorophyll (C55H72MgN4O5)
ozone absorbs low energy radiation which warms the True
troposphere False
ozone absorbs ultraviolet radiation
ozone reflects high energy radiation such as X-rays and Question 7 1 points
gamma rays "Manganese, Mn, forms a number of oxides. A particular
oxide is 63.2% Mn. What is the simplest formula for this
Question 3 1 points oxide?"
What is a distinguishing characteristic of the halogens? MnO2 Mn3O4
1. They are phosphorescent. Mn2O3 MnO
"Aluminum metal reacts with HCl to produce aluminum At which temperature does a water sample have the highest
chloride and hydrogen gas. How many grams of aluminum average kinetic energy?
metal must be added to an excess of HCl to produce 33.6L of a. 100 degrees Celcius b. 0 K
hydrogen gas, if the gas is at STP?" c. 100 K d. 0 degrees Celcius
27g 18g
35g 45g Question 7 1 points
Which gas under a high temperature and a low pressure
Question 3 1 points behaves most like an ideal gas?
"By decreasing the pressure of an ideal gas at constant a. He b. NH₃
temperature and amount of substance 1/3 times the original c. O₂ d. Ne
pressure, the volume of gas will"
a. decreases three times the original Question 10 2 points
b. multiply by a factor of 1/3 Which of the following equations is balanced?
c. expands two thirds the original Be2C + H2O → 2Be(OH)2 + CH4
d. increases three times the original CH4 + 2O2 → CO2 + 2H2O
CO2 + 2KOH → K2CO3 + 2H2O
Question 4 1 points Cu + 2HNO3 → Cu(NO3)2 + NO + H2O
Which of the following elements is a reactive gas?
Chlorine gold Question 1 2 points
Radon sodium Peroxyacylnitrate (PAN) is one of the components of smog. It
is a compound of C, H, N, and O. Determine the empirical
Question 5 1 points formula from the following percent composition by mass: 19.8
"A sample of argon gas is sealed in a container. The volume of percent C, 2.50 percent H, 11.6 percent N, 66.1 percent O.
the container is doubled. If the pressure remains constant, What is its molecular formula given that its molar mass is
what happens to the absolute temperature?" about 120 g?
It is doubled. It does not change. CH5N2O C2HNO6
It is halved. It is squared. C2H3NO5 C3H6N4O3

A carbon dioxide sample weighing 44.0 g occupies 32.68 L at Aluminum sulfate, Al2(SO4)3, is used in tanning leather,
65°C and 645 torr. What is its volume at STP? purifying water, and manufacture of antiperspirants. Calculate
34.3 L 35.2 L its molar mass (g/mol).
22.4 L 31.1 L 342.15 278.02
315.15 74.98
Question 7 2 points
"In the following reaction, which elements are the reducing Question 5 1 points
and oxidizing agents?" What is the mass of an object that has a density of 13 g/mL
a. Mg is the reducing agent; MgO is the oxidizing agent. and a volume of 10 mL?
b. MgO is the reducing agent; Mg is the oxidizing agent. a. 1.3 g/mL b. 130 g/mL
c. O₂ is the reducing agent; Mg is the oxidizing agent. c. 1.3 g/L d. 0.77 g/Ml
d. Mg is the reducing agents; O₂ is the oxidizing agent.
Question 6 1 points
Question 8 2 points What is the oxidation number for chromium (Cr) in the
An unknown quantity of hydrogen gas has a volume of 2.5 L compound BaCrO4?
at STP (0° and 1 atm). What is the mass of hydrogen? a. 2 b. 1
a. 0.22 g b. 0.19 g c. 4 d. 6
c. 0.51 g d. 0.073 g
Question 10 1 points
Question 5 1 points "The group of metals that includes lithium, sodium, potassium,
"The pressure of an ideal gas is directly proportional to its rubidium, and cesium forms a closely related family known as
absolute temperature at constant volume and number of the"
moles" is a statement of ________________ Law. a. alkaline earth metals. b. rare earth group.
Avogadro's Boyle's c. alkali metals. d. halogens.
Charles' Amonton's
Question 1 2 points c. CO d. I?
Sulfur trioxide can react with atmospheric water vapor to form
sulfuric acid that falls as acid rain. Calculate the mass in grams Question 8 1 points
of 3.65 × 1020 molecules of SO3. Which of the following elements is present in chlorophyll?
2.91 × 10-2 g 20.6 g Mg Al
6.06 × 10-4 g 4.85 × 10-2 g Ga K

Increasing the temperature of an ideal gas from 50 deg C to 75 "In most of its compounds, this element exists as a monatomic
deg C at constant volume will cause which of the following to cation."
increase for the gas? Ca F
the average speed of the molecules S N
the density of the gas
the average distance between the molecules Question 5 1 points
the average molecular mass of the gas Which of the following is not a conclusion Rutherford made
from his experiment with alpha particles being shot at a thin
Question 4 1 points sheet of gold foil?
Which of the following chemical formulas is incorrect? a. An atom's mass is concentrated in the nucleus.
a. Na₂CO₃ b. CaCI b. An atom is mainly empty space
c. KOH d. Ca(OH)₂ c. "An atom has a very small, compact nucleus"
Correctd. An atom has a negatively charged nucleus.
Question 6 1 points
The mole (mol) is the amount of a substance that contains as Question 6 1 points
many elementary entities as there are atoms in exactly "The volume of an ideal gas is directly proportional to the
a. average atomic mass of isotopes of C. number of moles of the gas at constant temperature and
b. 12.00 grams of C. pressure" is a statement of _____________ Law.
c. 12.00 grams of ^12 C. Dalton's Amonton's
d. 12.01 grams/mol of C. Charles' Avogadro's

"Which of the following best represents the balanced net ionic There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The
equation for the reaction of lead (II) carbonate with ZnS is roasted in excess air to form zinc oxide (ZnO) and
concentrated hydrochloric acid? In this reaction, all lead sulfer dioxide (S)?. How many grams of zinc can be
compounds are insoluble." subsequently recovered if 5% of the zinc is lost in the roasting
PbCO3 + 2 H+ + 2 Cl- --> PbCl2 + CO2 + H2O process?
PbCO3 + 2H+ --> Pb2+ + CO2 + H2O a. 380 g b. 320 g
Pb2CO3 + 2H+ + Cl- --> Pb2Cl + CO2 + H2O c. 400 g d. 340 g
PbCO3 + 2Cl- --> --> Pb2Cl + CO2 + H2O
Question 3 1 points
Question 1 2 points How many grams of nitrogen are in 25.0g of (NH4)2SO4?
How many milliliters of 0.100M H2SO4 are required to 5.30 g 1.30 g
neutralize 50.0 mL of 0.200M KOH? 0.19 g 2.65 g
50.0 mL 20.0 mL
30.0 mL 25.0 mL Question 1 1 points
"A reaction produces a gaseous mixture of carbon dioxide,
Question 2 2 points carbon monoxide, and water vapor. After one reaction, the
Aluminum metal reacts with gaseous HCl to produce mixture was analyzed and found to contain 0.60 mol of carbon
aluminum chloride and hydrogen gas . What volume of dioxide, 0.30 mol of carbon monoxide, and 0.10 mol of water
hydrogen gas, at STP, is produced when 13.5 g of aluminum is vapor. If the total pressure of the mixture was 0.80 atm, what
mixed with an excess of HCL? was the partial pressure of the carbon monoxide?"
16.8 L 11.2 L 0.24 atm 0.13 atm
33.6 L 22.4 L 0.34 atm 0.080 atm

"Which of the following compounds would be ionic, Calculate the pressure of a helium sample at -207.3°C and 768
considering the electro negativities of the elements?" mL if it exerts a pressure of 175 kPa at 25.0°C and 925 mL.
a. NO b. KCI not possible, since the pressure would have to be negative
32.1 kPa 48 L 36 L
953 kPa 6.0 L 4.0 L
46.6 kPa
Question 6 1 points
Question 6 1 points Which phase change is described correctly?
Which of the following occurs when table salt (NaCI) is added a. Solid to liquid is called vaporization
to continuously heated boiling water? b. Liquid to solid is called freezing
a. The water momentarily stops boiling. c. Gas to solid is called sublimation.
b. The temperature of the water decreases but boiling d. Solid to gas is called deposition
continues uninterrupted.
c. The water continues to boil. Question 9 2 points
d. The water boils even more agitatedly. "Nitroglycerin is made by combining glycerol, nitric acid, and
sulfuric acid. What are the minimum coefficients needed to
Question 4 2 points balance the equation of this reactions?"
Determine the molecular mass of iron (III) bromide a. "1,3,1,1,3,1" b. "2,6,2,2,6,2"
hexahydrate, a substance used as a catalyst in organic c. "4,2,1,1,3,1" d. "1,3,3,1,3,2"
reactions.
355.54 317.61 Question 10 2 points
295.56 403.65 It is known that ozone (O₃) will decompose into oxygen (O₂)
at a temperature of 100°. One mole of ozone is sealed in a
Question 7 1 points container at STP (0°C and 1 atm). What will be pressure of the
"Which of the following elements is important in the container once it is heated to 100°C?
semiconductor industry to improve the conductivity of a. 1.4 kPa b. 210 kPa
germanium, Ge?" c. 2.1 kPa d. 37 kPa
Ga K
Al Mg Question 10 1 points
Two moles of sodium react with 2 moles of water to produce
Question 9 2 points which of the following?
Two balloons are at the same temperature and pressure. One a. 2 moles of sodium hydroxide and 1 mole of hydrogen
contains 14g of nitrogen and the other contains 20.0g of argon. b. 1 mole of sodium hydroxide and 2 moles of hydrogen
Which of the following is true? c. 2 moles of sodium hydroxide and 2 mole of hydrogen
The average speed of the nitrogen molecules is greater than d. 1 mole of sodium hydroxide and 1 mole of hydrogen
the average molecules of the argon molecules.
The density of the nitrogen sample is greater than the density Question 8 1 points
of the argon sample. Oxygen reacts stoichimetrically with methane to form 14 g of
The average kinetic energy of the nitrogen molecules is carbon monoxide. How many moles of methane are
greater than the average kinetic energy of the argon molecules. consumed?
The volume of the nitrogen container is less than the volume a. 2 mol b. 0.5 mol
of the argon container. c. 1.5 mol d. 1 mol

A sample of propane, a component of LP gas, has a volume of Dimethyl hydrazine (CH₃)₂NNH₂ has been used as a fuel in
35.3 L at 315 K and 922 torrs. What is its volume at STP? space, with nitrogen tetraoxide (N₂O₄) as the oxidizer. The
37.1 L 30.6 L products of the reaction between these two in an engine are
49.2 L 25.2 L H₂O, CO₂, and N₂. What is the mass of nitrogen tetraoxide
required to burn 50 kg of dimethyl hydrazine?
Question 3 2 points a. 50 kg b. 100 kg
"When 50.0 mL of 1.0M AgNO3 is added to 50 mL of 0.50M c. 128 kg d. 153 kg
HCl, a precipitate of AgCl forms. After the reaction is
complete, what is the concentration of silver ions in the Question 10 2 points
solution?" _____ KClO3 --> _____ KCl + _____O2
0.25M 1.0M After the above equation is balanced, how many moles of O2
0.0M 0.50M can be produced from 1.0 mol of KClO3 ?
1.5 mol 3.0 mol
Question 4 2 points 1.0 mol 2.0 mol
A sample of the inert gas krypton has its pressure tripled while
its temperature remained constant. If the original volume is 12
L, what is the final volume?
Question 4 1 points 273 °C 273 K
Which of the following best explains why a hot air balloon
rises? Question 7 2 points
Hot air has a lower density than cold air. 3 Cu(s) + 8 HNO3(aq) --> 3 Cu(NO3)2(aq) + 2 NO(g) + 4
The temperature difference between the inside and outside air H2O(l) Copper metal reacts with nitric acid according to the
causes convection currents. above equation. A 0.30 mol sample of copper metal and 10.0
The cool outside air pushes the balloon higher. mL of 12 M nitric acid are mixed in a flask. How many moles
The heating of the air causes the pressure inside the balloon to of NO gas will form?
increase. 0.030 mol 0.060 mol
0.010 mol 0.20 mol
Question 2 2 points
The molar mass of caffeine is 194.19 g/mol and the empirical Question 7 2 points
formula is C4H5N2O; therefore the molecular formula of A sample of oxygen gas has its absolute temperature halved
caffeine is C8H10N4O2. while the pressure of the gas remained constant. If the initial
True volume is 400 mL, what is the final volume?
False 20 mL 133 mL
400 mL 200 mL
Question 6 1 points
Which gas is expected to have the highest rate of effusion? Question 8 2 points
a. He b. H?O Mammalian hemoglobin contains about 0.33% iron (Fe,
c. F? d. O? atomic weight = 56) by weight. If the molecular weight of
hemoglobin is 68,000 g/mol, how many iron atoms are there in
Question 2 1 points each molecule of hemoglobin?
Assuming ideal behavior, what is the density of argon gas at 1 4
STP, in g/L? 16 8
0.0176 g/L 0.0250 g/L
181 g/L 1.78 g/L Question 8 2 points
"When the following equation is balanced, it is found that 1.00
Question 1 1 points mol of C8H18 reacts with how many moles of O2(g)?
Which of the following elements may occur in the greatest ___C8H18(g) + ___O2(g) --> ___CO2(g) + ___H2O(g)"
number of different oxidation states? 12.5 mol 10.0 mol
C F 25.0 mol 37.5 mol
O Ca
Question 2 2 points
Question 7 2 points Which of the following is the correct electron configuration of
"Gold(III) oxide, Au2O3, can be decomposed to gold emtal, Pb?
Au, plus oxygen gas, O2. How many moles of oxygen gas will a. [Xe]6s24f146s2 b. [Xe]6s25d104f145d106p2
form when 221 g of solid gold(III) oxide is decomposed? The c. [Xe]5d104f146p2 d. [Xe]6s25d104f146p2
formula mass of gold(III) oxide is 442."
0.750 mol 0.250 mol Question 2 2 points
0.500 mol 1.00 mol 1.3625 g of unknown metal X reacts with oxygen to form
1.4158 g of the oxide X2O. What is the atomic mass of X?
Question 8 2 points 8 4
A flask has a mass of 78.23 g when empty and 593.63 g when 146 206
filled with water. When the same flask is filled with
concentrated sulfuric acid, H2SO4, its mass is 1026.57 g. Question 4 2 points
What is the density [g/cc] of concentrated sulfuric acid? "A solution is prepared by mixing 50.0 mL of 0.20M arsenic
(Assume water has a density of 1.00 g/cm3 at the temperature acid, H3AsO4, and 50.0 mL of 0.20M sodium hydroxide,
of the measurement.) NaOH. Which anion is present in the highest concentration?"
0.543 1.729 H2AsO4- HAsO42-
1.992 1.840 OH- Na+

Charles's Law relates the volume and temperature of a gas Macro Vee collected hydrogen gas using water displacement
sample at constant pressure. What would be the temperature method. He measured the temperature of water using a
of a gas sample when its volume is 0 L? thermometer and found out that it is 230C with the
0 °C - 273°C
correponding pressure of 21.1 mmHg. Calculate the pressure Question 1 2 points
of hydrogen gas under standard atmospheric pressure. The carat is the unit of mass used by jewelers. One carat is
a. 98.15 Kpa b. 95.18 Kpa exactly 200 mg. How many carbon atoms are present in a 24-
c. 95.81 Kpa d. 98.51 Kpa carat diamond?
4.8 x 1023 atoms 3.0 x 1023 atoms
Question 7 2 points 2.4 x 1023 atoms 6.0 x 1023 atoms
A given sample of radioactive material has 80% of the original
substance remaining after 10 years. How much will remain Question 9 2 points
after 90 additional years? A 0.850-mole sample of nitrous oxide, a gas used as an
a. 0.017 b. 0.001 anesthetic by dentists, has a volume of 20.46 L at 123°C and
c. 0.13 d. 0.11 1.35 atm. What would be its volume at 468°C and 1.35 atm?
19.0 L 5.38 L
Question 8 2 points 38.3 L 77.9 L
A compound composed of carbon, hydrogen, and chlorine
effuses through a pinhole 0.411 times as fast as neon. Select
the correct molecular formula for the compound.
CHCl3 CH2Cl2
CCl4 C2H3Cl
Question 5 1 points
"In order to separate two substances by fractional
crystallization, the two substances must differ in which of the
following? "
Solubility specific gravity
vapor pressure viscosity
Question 6 1 points
Which of the following gases effuses most rapidly?
carbon monoxide ammonia
nitrogen oxygen
Question 1 2 points
"A sample of oxalic acid, H2C2O4, is titrated with standard
sodium hydroxide, NaOH, solution. A total of 45.20 mL of
0.1200M NaOH is required to neutralize20.00 mL of the acid.
What is the concentration of the acid?"
0.1356 M 0.2712 M
0.1200 M 0.2400 M
Question 1 2 points
There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The
ZnS is roasted in excess air to form zinc oxide (ZnO) and
sulfer dioxide (S)?. How many grams of zinc can be
subsequently recovered if 5% of the zinc is lost in the roasting
process?
a. 400 g b. 340 g
c. 320 g d. 380 g
Question 2 2 points
Gadolinium oxide, a colorless powder which absorbs carbon
dioxide from the air, contains 86.76 mass % Gd. Determine its
empirical formula.
Gd3O2 Gd3O4
Gd2O3 GdO
DRILL 2 c.diffraction
d.deflection
Question 1 5 points Question 7 1
The solubility constant of stronyium sulfate, SrSO4, is 2.8 x points
10-7. How many grams of SrSO4 must be dissolved in water "In which one of the following reactions would you expect ?H
to produce 1 L saturated solution? to be substantially greater than ?E (i.e., ?H > ?E)?"
Answers: b Answers: a
a. 0.00005 g a. CO2(s) ?CO2(g)
b. 0.1 g b.H2(g) + Br2(g) ? 2HBr(g)
c. 0.0005 g c.H2O(s) ?H2O(l)
d. 2 g d.HCl(aq) + NaOH(aq) ? NaCl(aq) + H2O(l)

What is the molar mass of toluene if 0.85 g of toluene "An ideal gas (the system) is contained in a flexible balloon at
depresses the freezing point of 100.g of benzene by 0.47°C? a pressure of 1 atm and is initially at a temperature of 20.°C.
Kf of benzene is 5.12°C/m. The surrounding air is at the same pressure, but its temperature
Answers: b. is 25°C. When the system has equilibrated with its
a.81.8 g/mol surroundings, both systems and surroundings are at 25°C and
b.92.6 g/mol 1 atm. In changing from the initial to the final state, which one
c.927 g/mol of the following relationships regarding the system is correct?
d.78.0 g/mol "
Answers: a.
Question 3 1 points a. q > 0
The elements from Groups 1A(1) and 2A(2) are b.?E< 0
Answers: a. c.w> 0
a.strong reducing agents. d.?H = 0
b.strong oxidizing agents.
c.amphoteric Question 9 2 points
d.strong bases. Which of the following aqueous solutions will have the lowest
osmotic pressure?
Question 4 1 points Answers: a
Raoult's Law relates the vapor pressure of the solvent above a.0.05 m CaSO4
the solution to its mole fraction in the solution. Which of the b.0.10 m KOH
following is an accurate statement? c.0.10 m RbCl
Answers: a. d.0.05 m BaCl2
a.Raoult's Law works best when applied to dilute solutions.
b.Raoult's Law applies exactly to all solutions. Question 10 2 points
c.Raoult's Law works best when applied to concentrated "A solution is prepared by mixing 50.0 mL of 0.20M arsenic
solutions. acid, H3AsO4, and 50.0 mL of 0.20M sodium hydroxide,
d.Raoult's Law applies only to non-ideal solutions. NaOH. Which anion is present in the highest concentration?"
Answers: a
Question 5 1 points a.H2AsO4-
"A solution of sucrose (sugar) in water is in equilibrium with b.HAsO42-
solid sucrose. If more solid sucrose is now added, with c.OH-
stirring, " d.Na+
Answers: a
a.the concentration of the solution will remain the same. Question 11 2
b.the concentration of the solution will increase. points
c.the concentration of the solution will decrease. When 50.0 mL of 1.0M AgNO3 is added to 50 mL of 0.50M
d.the volume of solution will increase. HCl, a precipitate of AgCl forms. After the reaction is
complete, what is the concentration of silver ions in the
Question 6 1 points solution?
Which word best describes the phenomenon which gives rise Answers: a
to a rainbow? a.0.25M
Answers: a b.1.0M
a.dispersion c.0.0M
b.reflection d.0.50M
a.Rb
Question 12 2 points b.Na
Consider a 0.90 M Al(NO3)3 solution. This solution has a c.Mg
nitrate ion concentration of d.Sr
Answers: a
a. 2.7 M Question 18 1 points
b.0.3 M "In a single atom, what is the maximum number of electrons
c.0.9 M which can have quantum number n = 4? "
d.8.1 M Answers:a
a.32
Question 13 5 points b.16
A 0.1326 g sample of magnesium was burned in an oxygen c.18
bomb calorimeter. The total heat capacity of the calorimeter d.36
plus water was 5,760 J/°C. If the temperature rise of the
calorimeter with water was 0.570°C, calculate the enthalpy of Question 19 1 points
combustion of magnesium. Who proposed the principle which states that one cannot
Mg(s) + 1/2 O2(g) -->MgO(s) simultaneously know the exact position and velocity of a
Answers: b. particle?
a.106 kJ/mol Answers:a
b.-602 kJ/mol a. Heisenberg
c.435 kJ/mol b.Planck
d.-24.8 kJ/mol c.Bohr
d.de Broglie
Question 14 5
points Question 20 1
What is the boiling point of an aqueous solution of a points
nonelectrolyte that has an osmotic pressure of 10.50 atm at Which scientist demonstrated that photons transferred
25°C? Kb of water is 0.52°C/m. Assume the density of the momentum during collisions with matter?
solution is the same as that of pure water. Answers: a
Answers: a a. Compton
a.100.22°C b.Planck
b.99.78°C c.Bohr
c.100.43°C d.de Broglie
d.0.429°C
Question 15 1 points Styrene, C8H8, is one of the substances used in the production
"A system absorbs 21.6 kJ of heat while performing 6.9 kJ of of synthetic rubber. When styrene burns in oxygen to form
work on the surroundings. If the initial internal energy, E, is carbon dioxide and liquid water under standard-state
61.2 kJ, what is the final value of E? " conditions at 25°C, 42.62 kJ are released per gram of styrene.
Answers: a Find the standard enthalpy of formation of styrene at 25°C.
a.75.9 kJ (Given: [CO2(g)] = -393.5 kJ/mol, [H2O(l)] = -285.8 kJ/mol,
b.32.7 kJ [H2O(g)] = -241.8 kJ/mol)
c.46.5 kJ Answers: b
d.82.8 kJ a.-8730 kJ/mol
b.146 kJ/mol
Question 16 1 points c.324 kJ/mol
Select the correct electron configuration for sulfur (Z = 16). d.-637 kJ/mol
Answers:a
a. 1s2 2s2 2p6 3s2 3p4 Question 22 5 points
b.1s2 2s2 2p8 3s2 3p2 Lysine is an amino acid that is an essential part of nutrition but
c.1s2 2s2 2p8 3s2 3p4 which is not synthesized by the human body. What is the
d.1s2 1p6 2s2 2p6 molar mass of lysine if 750.0 mL of a solution containing 8.60
g of lysine has an osmotic pressure of 1.918 atm? T = 25.0°C
Question 17 1 points Answers: b
Which one of the following elements is likely to exhibit the a.1780 g/mol
most violent and rapid reaction with water? b.146 g/mol
Answers: a c.220 g/mol
d.1340 g/mol Question 29 2 points
Question 23 1 points What is the percent CdSO4 by mass in a 1.0 molal aqueous
"A system initially has an internal energy E of 501 J. It CdSO4 solution?
undergoes a process during which it releases 111 J of heat Answers: a
energy to the surroundings, and does work of 222 J. What is a.17.2
the final energy of the system, in J? " b.0.1
Answers: a c.20.8
a.168 J d.24.4
b.390 J
c.692 J Question 30 5 points
d.834 J The mole fraction of oxygen molecules in dry air is
0.2029.What volume of dry air at 1.00 atm and 25°C is
Question 24 1 points required for burning 1.00 L of hexane (C6H14, density =
The modern periodic table is arranged based upon atomic 0.660 g/mL) completely, yeilding carbon dioxide and water?
Answers: d Answers: b
a.radius a. 8499 L
b. isotopes b. 8490 L
c. density c. 8409 L
d. number d. 8495 L

How many valence electrons are in a atom with the Aqueous ammonia is commercially available in a solution that
configuration 1s²2s²2p?3s²3p² is 28% (w/w) ammonia. What is the mole fraction of ammonia
Answers: c in such a solution?
a. 5 Answers: d
b. 6 a. 0.012
c. 4 b.0.023
d. 2 c.0.24
d.0.29
The energy of an electron in the hydrogen atom is determined Question 32 2 points
by "A sample of oxalic acid, H2C2O4, is titrated with standard
Answers: a sodium hydroxide, NaOH, solution. A total of 45.20 mL of
a.the principal quantum number (n) only. 0.1200M NaOH is required to neutralize20.00 mL of the acid.
b.the angular momentum quantum number (l ) only. What is the concentration of the acid?"
c.the principal and angular momentum quantum numbers (n & Answers: a
l ).
d.the principal and magnetic quantum numbers (n & ml). a.0.1356 M
b.0.2712 M
Question 27 1 points c.0.1200 M
"A system receives 575 J of heat and delivers 425 J of work. d.0.2400 M
Calculate the change in the internal energy, ?E, of the system."
Answers: a Question 33 2 points
a. 150 J Calculate the percent by mass of potassium nitrate in a
b-150 J solution made from 45.0 g KNO3 and 295 mL of water. The
c.1000 J density of water is 0.997 g/mL.
d.575 J Answers: a
a.13.3
Question 28 2 points b.1.51
At 10°C one volume of water dissolves 3.10 volumes of c.7.57
chlorine gas at 1.00 atm pressure. What is the Henry's Law d.15.2
constant in mol/L·atm?
a.0.13 Which atom is not paired with its correct ion and ionic charge?
b.3.1 Answers:b.
c.0.043 a. Li / Li1+
d.3.8 b. Rb / Rb1-
c. F / F1- Question 40 1 points
d. Mg / Mg2- Which of the following isotopes has the greatest number of
neutrons?
Question 35 1 points Answers: c
Which electron configuration demonstrates an atom in the a. 41Ca
excited state? b. 31P
Answers: d c. 40AR
a. 1s²2s²2p4 d. 35Cl
b. 1s²2s1
c. 1s²2s² Question 41 1 points
d. 1s²2s²3s1 Which of the following ions and atoms has the greatest radius?
Answers: a
Question 36 1 points a. Se2-
Which of the following elements has the largest first b. Br-
ionization energy? c. Rb+
Answers: c d. Kr
a. CI (chlorine)
b. Ar (argon) Question 42 1 points
c. H (hydrogen) In which of these substances are the atoms held together by
d. Kr (krypton) polar covalent bonding?
Answers: a
Question 37 1 points a. ClF
Calculate q when 28.6 g of water is heated from 22.0°C to b.SrCl2
78.3°C. c.CsCl
Answers: a d.S8
a.6.74 kJ
b.0.385 kJ Question 43 1 points
c.1.61 kJ For which one of the following reactions will ?H be
d.9.37 kJ approximately (or exactly) equal to ?E?
Answers:a
Question 38 5 points a.H2(g) + Br2(g) ? 2HBr(g)
Dimethylglyoxime, DMG, is an organic compound used to test b.H2O(l) ? H2O(g)
for aqueous nickel(II) ions. A solution prepared by dissolving c.2H(g) + O(g) ? H2O(l)
65.0 g of DMG in 375 g of ethanol boils at 80.3°C. What is d.CH4(g) + 2O2(g) ? CO2(g) + 2H2O(l)
the molar mass of DMG?
Kb = 1.22°C/m, boiling point of pure ethanol = 78.5°C Question 44 1 points
Answers: d "The group of metals that includes lithium, sodium, potassium,
a.44.1 g/mol rubidium, and cesium forms a closely related family known as
b.131.6 g/mol the"
c.65.8 g/mol Answers: d
d.117 g/mol a. halogens.
b. rare earth group.
Question 39 5 points c. alkaline earth metals.
From the following list of aqueous solutions and water, select d.alkali metals.
the one with the lowest freezing point.
a.0.75 M (NH4)3PO4 Octane is a component of fuel used in internal combustion
b.pure water engines. The dominant intermolecular forces in octane are
c.l.0 M CaSO4 Answers: a
d.1.5 M CH3OH, methyl alcohol a.London dispersion forces.
b.dipole-dipole forces.
c.hydrogen bonding.
d.covalent bonds.
6 g of a substance are dissolved in 1000 g of water. The "The interference pattern seen when light passes through
solution freezes at -0.16°C. What is the molecular weight of narrow, closely spaced slits, is due to "
the substance? Answers: a
Answers: c a.diffraction
a. 75 g/mol b.reflection
b. 60 g/mol c.diffraction
c. 70 g/ mol d.deflection
d. 100 g/mol
Question 47 2 points Which one of the following statements about orbital energies
Which of the following aqueous solutions has the highest is incorrect?
osmotic pressure at 25°C? Answers: a
Answers : a a.The energy of a given orbital increases as the nuclear charge
a. 0.2 M Na2SO4 Z increases.
b.0.2 M KBr b."In the hydrogen atom, the energy of an orbital depends only
c.0.2 M ethanol on the value of the quantum number n."
d.0.2 M KCl c.Inner electrons shield outer electrons more effectively than
do electrons in the same orbital.
Question 48 1 points d.In many-electron atoms the energy of an orbital depends on
Select the correct formula for a compound formed from both n and l.
barium and nitrogen.
a. Ba3N2 Safrole is used as a topical antiseptic. Calculate the vapor
b.Ba2N pressure [torr] of a solution prepared by dissolving 0.75 mol of
c.Ba2N3 safrole in 950 g of ethanol ( MW = 46.07 g/mol).
d.BaN2 P°ethanol = 50.0 torr at 25°C.
Answers: d
Question 49 1 points a.11
Which of the following statements describes the correct b.1.8
method of preparation of 1.00 L of a 2.0 M urea solution? c.40
(MW urea = 60.06 g/mol ) d.48
Answers: a
a.Dissolve 120 g of urea in enough distilled water to produce Question 55 5 points
1.00 L of solution. A common laboratory reaction is the neutralization of an acid
b.Dissolve 120 g of urea in 1.00 kg of distilled water. with a base. When 50.0 mL of 0.500 M HCl at 25.0°C is
c.Dissolve 120 g of urea in 880 g of distilled water. added to 50.0 mL of 0.500 M NaOH at 25.0°C in a coffee cup
d.Dissolve 120 g of urea in 1.00 liter of distilled water. calorimeter, the temperature of the mixture rises to 28.2°C.
What is the heat of reaction per mole of acid? Assume the
Question 50 1 points mixture has a specific heat capacity of 4.18 J/(g·K) and that
Electromagnetic radiation of 500 nm wavelength lies in the the densities of the reactant solutions are both 1.00 g/mL.
________ region of the spectrum.
Answers: a Answers: a
a.visible a.54 kJ
b.infrared b.27 kJ
c.X-ray c.670 kJ
d.ultraviolet d.1300 kJ

Which one of the following properties is least characteristic of "When Mr. Bean adds chilled grog to his new granite mug, he
typical ionic compounds? removes 10.9 kJ of energy from the mug. If it has a mass of
Answers: a 625 g and was at 25°C, what is its new temperature? Specific
a. poor electrical conductor when molten heat capacity of granite = 0.79 J/(g·K) "
b.high melting point Answers: a
c.brittleness
d.high boiling point
a.3°C Question 62 1 points
b.14°C """Each electron in an atom must have its own unique set of
c.22°C quantum numbers"" is a statement of "
d.47°C Answers: a
a.the Pauli exclusion principle.
Question 57 2 points b.the Aufbau principle.
A sugar solution was prepared by dissolving 9.0 g of sugar in C,Hund's rule.
500 g of water. At 27 deg C, the osmotic pressure was d.Heisenberg's principle.
measured as 2.46 atm. Determine the molecular weight of
sugar. Question 63 1 points
Answers: a A solution of potassium hydroxide is in equilibrium with
a.180 g/mol undissolved solute at 45°C. What will happen if the
b.18 g/mol temperature is raised to 50°C? (?Hsoln = -57.6 kJ/mol)
c.342 g/mol Answers: a
d.150 g/mol a.The mass of dissolved KOH will decrease.
b.The mass of dissolved KOH will increase.
Question 58 5 points c.The mass of dissolved KOH will be unchanged.
Calculate the molality of a 20.0% by mass ammonium sulfate d.The mass of water in the solution will increase.
(NH4)2SO4 solution. The density of the solution is 1.117
g/mL. Question 64 1 points
Answers: c Which of the following substances will have hydrogen bonds
a.2.10 between molecules?
b.1.51 Answers: a
c.1.89 a.CH3CH2-OH
d.0.15 b.(CH3)3N
c.CH3CH2-F
Question 59 2 points d.HI
"Aluminum metal reacts with HCl to produce aluminum
chloride and hydrogen gas. How many grams of aluminum Question 65 1 points
metal must be added to an excess of HCl to produce 33.6L of Predict the products for the reaction of the following set of
hydrogen gas, if the gas is at STP?" reactants. CaO(s) + H2O(l) ?
a. The average speed of the nitrogen molecules is greater than a.Ca(OH)2(s)
the average molecules of the argon molecules. b.Ca2+(aq) + OH-(aq) + H2(g)
b.The density of the nitrogen sample is greater than the density c.Ca2+(aq) + H2(g) + O2(g)
of the argon sample. d.CaH2(s) + O2(g)
c.The average kinetic energy of the nitrogen molecules is
greater than the average kinetic energy of the argon molecules. Question 66 5 points
d.The volume of the nitrogen container is less than the volume Sodium hydroxide is a common ingredient in drain cleaners
of the argon container. such as Drano. The mole fraction of sodium hydroxide in a
saturated aqueous solution is 0.310. What is the molality of the
Question 60 2 points solution?
How many moles of solute particles are present in 100.0 mL Answers: d
of 2.50 M (NH4)3PO4? a.1.24 m
Answers: a b.0.690 m
a.1 c.0.310 m
b.0.75 d.12.4 m
c.0.5
d.0.1 Question 67 5 points
When solid iron(II) hydroxide is added to water, the resulting
Question 61 1 points solution contains 1.4 x 10-3 g of dissolved iron(II) hydroxide
The shape of an atomic orbital is associated with per liter of solution. What is the hydoxide ion concentration in
Answers: a this solution?"
a.the angular momentum quantum number (l). Answers : a
b.the principal quantum number (n). a. 3.1 x 10-5 M
c.the magnetic quantum number (ml). b. 3.2 x 10-5 M
d.the spin quantum number (ms). c. 3.4 x 10-5 M
d. 3.3 x 10-5 M Question 74 2 points
What volume of concentrated (14.7 M) phosphoric acid is
Question 68 1 points needed to prepare 25.0 L of 3.0 M H3PO4?
The elements that display the greatest non-metallic character Answers: a
are located toward which corner of the periodic table? a.5.1 L
Answers: d b.3.6 L
a. Lower right c.1.8 L
b. Dead center d.0.57 L
c. Upper left
d. Upper right Question 75 2 points
"What is the molarity of a solution of 10% by mass cadmium
Question 69 1 points sulfate, CdSO4 (molar mass = 208.46 g/mol) by mass? The
The most basic oxides contain elements from the density of the solution is 1.10 g/mL."
________________ ____________ region of the periodic Answers: a
table. a. 0.528 M
Answers : a b. 0.436 M
a.lower left c. 0.479 M
b.upper right d. 0.048 M
c.upper left
d.lower right Question 76 5 points
Ethanol, C2H5OH, is being promoted as a clean fuel and is
Question 70 1 points used as an additive in many gasoline mixtures. Calculate the
A liquid will boil when ΔH°rxn for the combustion of ethanol.
Answers: a ΔH°f [C2H5OH(l)] = -277.7 kJ/mol; ΔH°f [CO2(g)] = -393.5
a. its vapor pressure is equal to the surrounding pressure kJ/mol; ΔH°f [H2O(g)] = -241.8 kJ/mol
b. it is heated to a temperature that is below the boiling point. Answers: b
c. a salt has been added to the liquid a. -751.1 kJ
d. its vapor pressure is equal to the melting point b. -1234.7 kJ
c. 1234.7 kJ
Question 71 1 points d. -357.6 kJ
"Sulfur hexafluoride, SF6, is "
a.an inert gas that is used as an electrical insulator. Predict the products for the following set of reactants. Li(s) +
b. a reactive gas that decomposes when exposed to moisture. H2O(l) ?
c.a reactant in the process of manufacturing non-stick Answers: a
coatings. a. Li+(aq) + H2(g) + OH-(aq)
d.used in the manufacture of sulfuric acid. b. Li+(aq) + H2(g) + O2(g)
c. LiH(s) + O2(g)
Question 72 1 points d. Li+(aq) + H2O2(aq)
The smallest ionization energies are found in the
____________ ___________ region of the periodic table. Question 78 1 points
Answers: a Which of the following is the strongest acid?
a.lower left Answers: a
b.upper right a. HClO3
c.upper left b. HBrO3
d.lower right c. HIO3
d. HClO
"2.3 g ethanol (C2H5OH) is added to 500 g water. Determine Question 79 1 points
the molality, m, of the resulting solution." Xenon forms several compounds with oxygen and fluorine. It
Answers: a is the most reactive non-radioactive noble gas because
a.0.1 Answers: a
b.1 a. it has the lowest ionization energy of these noble gases.
c.0.01 b. its effective nuclear charge is lower than the other noble
d.0.001 gases.
c. it has the highest electron affinity of these noble gases.
d. it has the highest electronegativity of these noble gases.
Question 80 1 points c Einstein
Which two elements will display the most similar chemical d Heisenberg
properties?
Answers: b Question 85 1 points
a. Nickel and phosporus "Which of the following statements about the effective nuclear
b. Litium and potassium charge, Zeff, is correct? "
c. Chlorine and sulfur Answers: a
d. Aluminum and calcium a Zeff increases across a period and is relatively constant
down a group.
Question 81 1 points b Zeff increases with the size of the atom.
"When elements from a group exhibit more than one oxidation c Zeff decreases across a period and increases down a group.
state, " d Zeff increases as the value of the principal quantum number
Answers: a increases.
a. the lower oxidation state is more important as one goes
down a group. Question 86 1 points
b. the higher oxidation state is more important as one goes Which of the following elements is the least electronegative?
down a group. Answers: a
c. both oxidation states are equally important throughout the a Sr
group. bS
d. the oxidation state will be affected by the elements on either c Si
side of it in the period. d Se

Nitric acid, which is among the top 15 chemicals produced in Which of the following oxides will give the most basic
the United States, was first prepared over 1200 years ago by solution when dissolved in water?
heating naturally occurring sodium nitrate (called saltpeter) Answers: a
with sulfuric acid and collecting the vapors a K2O
produced.Calculate ΔH°rxn for this reaction.NaNO3(s) + b SO2
H2SO4(l) → NaHSO4(s) + HNO3(g) c CO2
ΔH°f [NaNO3(s)] = -467.8 kJ/mol; ΔH°f [NaHSO4(s)] = - d SO3
1125.5 kJ/mol; ΔH°f [H2SO4(l) = -814.0 kJ/mol; ΔH°f
[HNO3(g)] = -135.1 kJ/mol Question 88 1 points
Answers: b "Select the correct set of quantum numbers (n, l, ml, ms) for
a. -644.2 kJ the highest energy electron in the ground state of potassium,
b. 21.2 kJ K. "
c. -291.4 kJ Answers: a
d. -21.2 kJ a "4, 0, 0, ½"
b "4, 1, -1, ½"
Question 83 5 points c "4, 1, 0, ½"
The highly exothermic thermite reaction, in which aluminum d "4, 0, 1, ½"
reduces iron(III) oxide to elemental iron, has been used by
railroad repair crews to weld rails together. Question 89 1 points
2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s) ΔH = -850 kJ In period 3 of the periodic table the atom with the largest
What mass [g] of iron is formed when 725 kJ of heat are atomic radius is located in group
released? Answers: a
Answers: b a. 1
a. 112 b. 3
b. 95 c. 17
c. 47 d. 18
d. 65
Question 84 1 points Copper(II) bromide is used as a wood preservative. What mass
Which scientist first proposed that the electron in the hydrogen of CuBr2 is needed to prepare 750.0 mL of a 1.25 M solution?
atom can have only certain energies? Answers: a
Answers: a a 209 g
a Bohr b 134 g
b Planck c 372 g
d 938 g Question 97 2 points
How many grams of MgSO4 (MW 120.4) are in 100.0 mL of
Question 91 1 points a 5.0 molar solution?
Select the strongest electrolyte from the following set. Answers: a
Answers: a a 60.0 g
a LiNO3 b. 12 g
b "CH3CH2OH, ethanol" c 5.0 g
c CCl4 d 600 g
d HF
Question 92 1 points Hexachlorophene is used as a disinfectant in germicidal soaps.
Which of the following sets of conditions could exist when What mass of hexachlorophene ( MW = 406.9 g/mol) must be
two liquids which are completely miscible in one another are added to 125 g of chloroform to give a solution with a boiling
mixed? point of 62.60°C?Kb = 3.63°C/m, boiling point of pure
Answers: a chloroform = 61.70°C
a "?Hsoln ? 0, entropy of system increases" Answers: a
b "?Hsoln > 0, entropy of system decreases" a 12.6 g
c "?Hsoln ? 0, entropy of system decreases" b 31.0 g
d "?Hsoln ? 0, entropy change of system ? 0" c 17.2 g
d 101 g
Which of the following contains covalent bonds? Question 99 5 points
Answers: a What volume [mL] of water should be added to 600. mL of
a IBr ethanol in order to have a solution that boils at 95.0°C?
b BaO [For ethanol, Kb = 1.22°C/m, density = 0.789 g/cm3, boiling
c Mg point = 78.4°C]
d LiBr Answers: a
a 116
Question 94 1 points b 186
Atomic orbitals developed using quantum mechanics c 322
Answers: a d 245
a. describe regions of space in which one is most likely to find
an electron. Question 100 2 points
b. describe exact paths for electron motion. Calculate the molality of 6.0 M H2SO4 solution. The density
c allow scientists to calculate an exact volume for the of the solution is 1.34 g/mL.
hydrogen atom. Answers: a
d are in conflict with the Heisenberg Uncertainty Principle. a. 7.98
Question 95 1 points b. 4.48
The ____________________ quantum numbers are associated c. 8.1
with the energy of an electron in a many-electron atom. d. 8.43
Answers: a
a n and l Question 101 5 points
b n and ml A 2.0% (w/v) solution of sodium hydrogen citrate,
c l and ml Na2C6H6O7, which also contains 2.5% (w/v) of dextrose,
d n and ms C6H12O6, is used as an anticoagulant for blood which is to be
used for transfusions. What is the molarity of the sodium
Question 96 2 points hydrogen citrate in the solution?
What is the freezing point of a solution prepared from 50.0 g Answers: d
ethylene glycol (C2H6O2) and 85.0 g H2O? Kf of water is a. 0.19 M
1.86°C/m. b. 1.2 M
Answers: a c. 0.53 M
a. -17.6°C d. 0.085 M
b. 17.6°C
c. -1.50°C Question 102 5 points
1.50°C Galena is the ore from which elemental lead is extracted. In
the first step of the extraction process, galena is heated in air
to form lead(II) oxide.
2PbS(s) + 3O2(g) → 2PbO(s) + 2SO2(g) ΔH = -827.4 kJ c. 84.64 mm Hg
What mass [g] of galena is converted to lead oxide if 975 kJ of d. 84.30 mm Hg
heat are liberated?
Answers: c Question 108 1 points
a. 282 Which of the following elements does not exists as a diatomic
b. 406 molecule under normal (ambient) conditions?
c. 564 Answers: b
d. 478 a. chlorine
b. sulfur
Question 103 1 points c. iodine
"Arrange oxygen, sulfur, calcium, rubidium and potassium in d. oxygen
order of decreasing electronegativity. "
a. O > S > Ca > K > Rb Tin reacts to form several organic compounds. Which of the
b. O > S > Ca > Rb > K following is a use for organotin compounds?
c. O > S > Rb > K > Ca Answers: a
d. O > S > Rb > Ca > K a. They can be used as fungicides.
b. They are starting materials for polymers.
Question 104 1 points c. They can be used to prepare semiconductors.
"Which one of the following properties is least characteristic d. They are used as protective coatings to prevent corrosion of
of substances composed of small, covalently-bonded metals.
molecules? "
a. weak bonds If a solute dissolves in an endothermic process
b. low melting point Answers: a
c. low boiling point a. the entropy of the solution must be greater than that of its
d. poor electrical conductor when molten pure components.
b. H bonds must exist between solvent and solute.
Question 105 1 points c. strong ion-dipole forces must exist in the solution.
Which sample demonstrate particles arranged in regular d. the solute must be a gas.
geometric pattern?
Answers: b Question 111 1 points
a. CO₂(s) Two aqueous solutions are prepared: 1.00 m Na2CO3 and
b. CO₂(g) 1.00 m LiCl. Which of the following statements is true?
c. CO₂(aq) Answers: a
d. CO₂(l) a. The Na2CO3 solution has a higher osmotic pressure and
higher boiling point than the LiCl solution.
Question 106 1 points b. The Na2CO3 solution has a higher osmotic pressure and
An atom in the ground state has seven valence electrons. higher vapor . pressure than the LiCl solution.
Which electron configuration could represent the valence c. The Na2CO3 solution has a lower osmotic pressure and
electron configuration of this atom in the ground state? lower vapor pressure than the LiCI solution.
Answers: a d. The Na2CO3 solution has a lower osmotic pressure and
a. 3s²3p5 higher boiling point than the LiCl solution.
b. 3s63p1
c. 3s23p1 Question 112 1 points
d. 3s13p6 Which of the following is a correct set of quantum numbers
for an electron in a 5f orbital? Answers: a
Question 107 5 points a. "n = 5, l = 3, ml = +1"
A solution is 40.0% by volume benzene (C6H6) in carbon b. "n = 5, l = 2, ml = +3"
tetrachloride at 20°C. The vapor pressure of pure benzene at c. "n = 4, l = 3, ml = 0"
this temperature is 74.61 mmHg and its density is 0.87865 d. "n = 4, l = 2, ml = +1"
g/cm3; the vapor pressure of pure carbon tetrachloride is 91.32
mmHg and its density is 1.5940 g/cm3. If this solution is ideal, Question 113 2 points
its total vapor pressure at 20°C is 6 g of a substance are dissolved in 1000 g of water. The
Answers: d solution freezes at -0.16°C. What is the molecular weight of
a. 82.96 mm Hg the substance?
b. 81.63 mm Hg Answers: b
a. 60 g/mol Question 118 1 points
b. 70 g/ mol Which one of the following statements about orbital energies
c. 75 g/mol is incorrect?
d. 100 g/mol Answers: a
a. The energy of a given orbital increases as the nuclear charge
Question 113 2 points Z increases.
A gas is compressed in a cylinder from a volume of 20 L to b. "In the hydrogen atom, the energy of an orbital depends
2.0 L by a constant pressure of 10.0 atm. Calculate the amount only on the value of the quantum number n."
of work done on the system. c. Inner electrons shield outer electrons more effectively than
Answers: a do electrons in the same orbital.
a. 1.81 x10 4 J d. In many-electron atoms the energy of an orbital depends on
b. -180 J both n and l.
c. 180 J
d. 1.01 x 104 J Question 119 5 points
Arrange the following aqueous solutions in order of increasing
Question 114 1 points boiling points.
"Dinitrogen monoxide, N2O, is " 0.050 m Mg(NO3)2; 0.100 m ethanol; 0.090 m NaCl
Answers: a Answers: c
a. a colorless gas used as a propellant in canned whipped a. Mg(NO3)2 < ethanol < NaCl
cream. b. NaCl < ethanol < Mg(NO3)2
b. a brown poisonous gas that is one of the chemicals involved c. ethanol < Mg(NO3)2 < NaCl
in the production of photochemical smog. c. a colorless d. ethanol < NaCl < Mg(NO3)2
gas used in the production of nitric acid.
d. a colorless gas that disproportionates into nitrogen and Question 120 5 points
oxygen. Barbiturates are synthetic drugs used as sedatives and
hypnotics. Barbital ( MW = 184.2 g/mol) is one of the
Question 115 1 points simplest of these drugs. What is the boiling point of a solution
Which of the following is an ionic compound? prepared by dissolving 42.5 g of barbital in 825 g of acetic
Answers: a acid?
a. KI Kb = 3.07°C/m, boiling point of pure acetic acid = 117.9°C
b. H2S Answers: b
c. I2 a. 118.1°C
d. CCl4 b. 118.8°C
c. 117.7°C
Question 116 2 points d. 117.0°C
A chemist dropped a 200 g object into a tank of water. It
displaced 60 mL of the water when it sunk to the bottom of the Question 121 2 points
tank. In a similar experiment, it displaced only 50 g of oil into How many mL of concentrated nitric acid (16 M) are needed
which it was dropped. Calculate the density of the oil [g/mL]. to prepare 0.500 L of 6.0 M nitric acid?
a. 0.833 a. 190 mL
b. 3.33 b. 375 mL
c. 50 c. 250 mL
d. 200 d. 0.19 mL

Cadmium bromide is used in photography and lithography. Which of the following is the correct electron configuration of
Calculate the molality [m] of a solution prepared by dissolving Pb?
45.38 g of CdBr2 in 375.0 g of water. Answers: a Answers: a
a. 0.4446 a. [Xe]6s25d104f146p2
b. 0.121 b. [Xe]6s24f146s2
c. 0.03035 c. [Xe]5d104f146p2
d. 0.016 d. [Xe]6s25d104f145d106p2
Question 123 2 points c. 0.145
How many moles of Pb(NO3)2 must be added to 0.10L of a d. 0.0197
solution that is 1.0M in MgCl2 and 1.0M in KCl to precipitate
all of the chloride ion? The compound PbCl2 precipitates. Question 129 5 points
Answers: a Solid sodium peroxide (Na2O2) reacts with liquid water
a. 0.15 mol yielding aqueous sodium hydroxide and oxygen gas. How
b. 0.50 mol much heat is released when 250.0 L of oxygen gas is produced
c. 0.20 mol from the reaction of sodium peroxide and water if the reaction
d. 1.0 mol is carried out in an open container at 1.000 atm pressure and
25°C?
Question 124 2 points (Given: heat of formation
A 0.100 m K2SO4 solution has a freezing point of -0.43°C. [Na2O2(s)] = -510.9 kJ/mol; [NaOH(aq)] = -469.2 kJ/mol;
What is the van't Hoff factor for this solution? Kf = 1.86°C/m [H2O(l)] = -285.8 kJ/mol)
Answers: a Answers: b.
a. 2.3 a. 3330 kJ
b. 0.77 b. 2900 kJ
c. 1 c. 1740 kJ
d. 3 d. 141.7 kJ

"Ethylene glycol, used as a coolant in automotive engines, has A 275-g sample of nickel at l00.0°C is placed in 100.0 mL of
a specific heat capacity of 2.42 J/(g·K). Calculate q when 3.65 water at 22.0°C. What is the final temperature of the water?
kg of ethylene glycol is cooled from 132°C to 85°C. " Assume that no heat is lost to or gained from the surroundings.
Answers: a Specific heat capacity of nickel = 0.444 J/(g·K)
a. -420 kJ Answers: a
b. -1900 kJ a. 39.6°C
c. -99 kJ b. 40.8°C
d. -0.42 kJ c. 61.0°C
d. 79.2°C
Which of the following aqueous solutions has the lowest Question 131 2 points
freezing point? 0.102 g of an unknown compound dissolved in 100. mL of
Answers: b water has an osmotic pressure of 28.1 mmHg at 20°C.
a. 0.18 m KCl Calculate the molar mass [g/mol] of the compound.
b. 0.15 m Na2SO4 Answers: a
c. 0.12 m Ca(NO3)2 a. 663
d. pure water b. 872
c. 115
Question 127 5 points d. 727
For the reaction C(graphite) + O2(g) → CO2(g), ΔH° = -393
kJ/mol. Question 132 2 points
How many grams of C(graphite) must be burned to release "A chemist dropped a 200 g object into a tank of water. It
275 kJ of heat? displaced 60 mL of the water when it sunk to the bottom of the
Answers: d tank. In a similar experiment, it displaced only 50 g of oil into
a. 22.3 g which it was dropped. Calculate the density of the oil [g/mL]."
b. 0.70 g Answers: a
c. 12.0 g a. 0.833
d. 8.40 g b. 3.33
c. 50
Question 128 5 points d. 200
Diethyl ether has a vapor pressure of 400.0 torr at 18°C. When
a sample of benzoic acid is dissolved in ether, the vapor Question 133 2 points
pressure of the solution is 342 torr. What is the mole fraction What is the osmotic pressure of a solution that contains 13.7 g
of benzoic acid in the solution? of propyl alcohol (C3H7OH) dissolved in enough water to
Answers: c make 500. mL of solution at 27°C?
a. 0.855 Answers: a
b. 0.0169 a. 11.2 atm
b. 0.014 atm c. 32.9 kJ/°C
c. 0.037 atm d. 7.8 kJ/°C
d. 0.01 atm
Question 134 2 points What is the molar mass of toluene if 0.85 g of toluene
What is the freezing point of a solution that contains 10.0 g of depresses the freezing point of 100. g of benzene by 0.47°C?
glucose (C6H12O6) in 100. g of H2O? Kf for water is Kf of benzene is 5.12°C/m.
1.86°C/m. Answers: b
Answers: a a. 81.8 g/mol
a. -1.03°C b. 92.6 g/mol
b. +0.10°C c. 927 g/mol
c. -0.10°C d. 78.0 g/mol
d. +0.186°C
Question 135 5 points When 0.7521 g of benzoic acid was burned in a calorimeter
Procaine hydrochloride ( MW = 272.77 g/mol) is used as a containing 1,000. g of water, a temperature rise of 3.60°C was
local anesthetic. Calculate the molarity of a 4.666 m solution observed. What is the heat capacity of the bomb calorimeter,
which has a density of 1.1066 g/mL. excluding the water? The heat of combustion of benzoic acid
Answers: b is -26.42 kJ/g.
a. 4.216 M Answers: d
b. 2.272 M a. 4.18 kJ/°C
c. 4.056 M b. 5.52 kJ/°C
d. 4.666 M c. 15.87 kJ/°C
d. 1.34 kJ/°C
The solubility constant of stronyium sulfate, SrSO4, is 2.8 x Question 141 2 points
10 -7. How many grams of SrSO4 must be dissolved in water How many moles of bromide ions are present in 750.0 mL of
to produce 1 L saturated solution? 1.35 M MgBr2?
Answers: d Answers: a
a. 0.08 g a. 2.03
b. 0.09 g b. 0.506
c. 0.11 g c. 1.01
d. 0.10 g d. 3.04

The combustion of butane produces heat according to the How many milliliters of 0.100M H2SO4 are required to
equation neutralize 50.0 mL of 0.200M KOH?
2 C4H10(g) + 13 O2(g) → 8 CO2(g) + 10 H2O(l) ΔHrx = Answers: a
-5,314 kJ a. 50.0 mL
How many grams of butane must be burned to release 6,375 kJ b. 20.0 mL
of heat? c. 30.0 mL
Answers: b d. 25.0 mL
a. 69.7
b. 139 Question 143 5 points
c. 1.20 Isoamyl salicylate ( MW = 208.25 g/mol) has a pleasant
d. 97.8 aroma and is used in perfumes and soaps. Which of the
following combinations gives a 0.75 m solution of isoamyl
Question 138 5 points salicylate in ethyl alcohol (ρ = 0.7893 g/mL)?
Naphthalene combustion can be used to calibrate the heat Answers: b
capacity of a bomb calorimeter. The heat of combustion of a. 117.2 g isoamyl salicylate in 750.0 mL of ethyl alcohol
naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was b. 117.2 g isoamyl salicylate in 950.0 mL of ethyl alcohol
burned in a calorimeter containing 1,000. g of water, a c. 117.2 g isoamyl salicylate in 750.0 mL of solution
temperature rise of 4.21°C was observed. What is the heat d. 117.2 g isoamyl salicylate in 592.0 g of ethyl alcohol
capacity of the bomb calorimeter excluding the water?
Answers: b.
a. 1.76 kJ/°C
b. 3.64 kJ/°C
An average home in Colorado requires 20. GJ of heat per a. 5.8
month. How many grams of natural gas (methane) must be b. 103
burned to supply this energy? c. 0.245
CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) ΔHr = -890.4 d. 0.0058
kJ/mol
a. 3.6 x 105 Calculate the molarity of a solution prepared by diluting 1.85
b. 1.4 x 103 L of 6.5 M KOH to 11.0 L.
c. 7.1 x 104 Answers: a
d. 2.2 x 104 a. 1.1 M
b. 0.28 M
Question 145 5 points c. 0.91 M
Calcium nitrate tetrahydrate dissolves in cold water to the d. 3.9 M
extent of 266 g per 100 cm3. What is the concentration of
nitrate ions in this slution? Question 151 5 points
Answers: c When 24.0 g of glucose (a nonelectrolyte) are dissolved in
a. 20.5 M 500. g of water, the solution has a freezing point of -0.47°C.
b. 23.5 M What is the molar mass of glucose? Kf of water is
c. 22.5 M 1.86°C/m. Answers: a
d. 21.5 M a. 190
b. 48
Question 146 2 points c. 55
Calcium nitrite is used as a corrosion inhibitor in lubricants. d. 178
What is the molality [m] of a solution prepared by dissolving
18.5 g of calcium nitrite in 83.5 g of distilled water? Question 152 2 points
Answers: a How much water must be added to 100 mL of a 0.75 molar
a. 1.68 solution of KCI to make a 0.04 molar solution?
b. 0.444 Answers: a
c. 0.222 a. 1.78 L
d. 0.0342 b. 1.88 L
c. 1.98 L
Question 147 5 points d. 0.188 L
Use Hess's Law to calculate the enthalpy change for the
reaction Question 153 2 points
WO3(s) + 3H2(g) → W(s) + 3H2O(g) "Given the thermochemical equation 2SO2 + O2 --> 2SO3,
from the following data: dHr= -198 kJ/mol, what is the standard enthalpy change for
2W(s) + 3O2(g) → 2WO3(s) ΔH = -1685.4 kJ the decomposition of one mole of SO3?"
2H2(g) + O2(g) → 2H2O(g) ΔH = -477.84 kJ Answers: a
Answers: c a. 99 kJ/mol
a. 1207.6 kJ b. -99 kJ/mol
b. 364.9 kJ c. -198 kJ/mol
c. 125.9 kJ d. 198 kJ/mol
d. 252.9 kJ
Question 148 5 points How many milliters of 1 M NaOH solution will 25 mL of 2
From the following list of aqueous solutions and water, select H₂SO₄ neutralize?
the one with the highest boiling point. Answers: d
Answers: d a. 25 mL
a. 1.0 M KNO3 b. 75 mL
b. 0.75 M NaCl c. 50 mL
c. pure water d. 100 mL
d. 0.75 M CuCl2
Question 149 2 points Which of the following aqueous liquids will have the lowest
Calculate the molality of a solution containing 14.3 g of NaCl freezing point?
in 42.2 g of water. Answers: a
a. 0.5 m Li3PO4 Question 161 2 points
b. pure water What is the molarity of a solution that is 26.0% by mass
c. 0.5 m C12H22O11 (sucrose) phosphoric acid (H3PO4) and that has a density of 1.155
d. 0.5 m Ca(NO3)2 g/mL?
Answers: a
Question 156 5 points a. 3.06
Calculate the vapor pressure [torr] of a solution prepared by b. 300
dissolving 0.500 mol of a non-volatile solute in 275 g of c. 2.3
hexane ( MW = 86.18 g/mol) at 49.6°C. d. 0.3
P°hexane = 400.0 torr at 49.6°C.
Answers: c Question 162 5 points
a. 54 The chemist, Anna Lytic, must prepare 1.00 kg of 15.0%
b. 246 (w/w) acetic acid using a stock solution which is 36.0% (w/w)
c. 346 acetic acid (ρ = 1.045 g/mL). Which of the following
d. 400 combinations will give her the solution she wants?
Answers: d
Question 157 2 points a. 360 mL of 36% acetic acid in 640 mL of distilled water
How many grams of water are needed to dissolve 27.8 g of b. 150 g of 36% acetic acid in 850 g of distilled water
ammonium nitrate NH4NO3 in order to prepare a 0.452 m c. 417 mL of 36% acetic acid in 583 mL of distilled water
solution? d. 417 g of 36% acetic acid in 583 g of distilled water
Answers: a
a. 769 Question 163 2 points
b. 36.2 Ethanol boils at 78.5 °C. If 10 g of sucrose (C12H22O11) is
c. 100 dissolved in 150g of ethanol, at what temperature [ °C] will
d. 0.157 the solution boil? Assume Kb=1.20 ° C/m for the alcohol.
Answers: a
Question 158 5 points a. 78.73
Use the following data to calculate the standard heat b. 78.5
(enthalpy) of formation, ΔH°f , of manganese(IV) oxide, c. 0.23
MnO2 (s). d. 100.23
2MnO2(s) → 2MnO(s) + O2(g) ΔH = 264 kJ
MnO2(s) + Mn(s) → 2MnO(s) ΔH = -240 kJ Question 164 2 points
Answers: d The vapor pressure of water at 20°C is 17.5 mmHg. What is
a. 504 kJ the vapor pressure [in mm Hg] of water over a solution
b. -24 kJ prepared from 2.00 ´ 102 g of sucrose (C12H22O11) and 3.50
c. -372 kJ ´ 102 g water?
d. -504 kJ Answers: a
a. 17
"A sugar solution was prepared by dissolving 9.0 g of sugar in c. 16
500 g of water. At 27 deg C, the osmotic pressure was d. 19.4
measured as 2.46 atm. Determine the molecular weight of
sugar." Question 165 2 points
Answers: a "A reaction produces a gaseous mixture of carbon dioxide,
a. 180 g/mol carbon monoxide, and water vapor. After one reaction, the
b. 18 g/mol mixture was analyzed and found to contain 0.60 mol of carbon
c. 342 g/mol dioxide, 0.30 mol of carbon monoxide, and 0.10 mol of water
d. 150 g/mol vapor. If the total pressure of the mixture was 0.80 atm, what
was the partial pressure of the carbon monoxide?"
What is the molarity of a solution obtained by dis-solving 25 g a. 27g
of NaCI in enough water to produce 4 L of solution? b. 18g
Answers: c c. 35g
a. 0.365 d. 45g
b. 6.25
c. 0.107
d. 0.428
Question 166 5 points b. -118.7°C
What mass of ethanol, C2H5OH a nonelectrolyte, must be c. -119.0°C
added to 10.0 L of water to give a solution that freezes at - d. -120.6°C
10.0°C?
Assume the density of water is 1.0 g/mL. Kf of water is Question 171 2 points
1.86°C/m. "Ethanol undergoes combustion in oxygen to produce carbon
Answers: b dioxide gas and liquid water. The standard heat of combustion
a. 24.8 kg of ethanol, C2H5OH(l), is -1366.8 kJ/mol. Given that
b. 2.48 kg [CO2(g)] = -393.5 kJ/mol and [H2O(l)] = -285.8 kJ/mol, what
c. 5.38 kg is the standard enthalpy of formation of ethanol?"
d. 85.7 kg Answers: a
a. -277.6 kJ/mol
Question 167 2 points b. "3,010 kJ/mol "
A glass containing 200. g of H2O at 20°C was placed in a c. -687.6 kJ/mol
refrigerator. The water loses 11.7 kJ as it cools to a constant d. 687.6 kJ/mol
temperature. What is its new temperature? The specific heat of
water is 4.184 J/g·°C. Question 172 2 points
Answers:a "Ethanol boils at 78.5 deg C. If 10 g of sucrose (C12H22O11)
a. 6°C is dissolved in 150g of ethanol, at what temperature [deg C]
b. 0.013°C will the solution boil? Assume Kb=1.20 deg C/m for the
c. 14°C alcohol."
d. 34°C Answers: a
a. 78.73
The Starship Enterprise is caught in a time warp and Spock is c. 0.23
forced to use the primitive techniques of the 20th century to d. 100.23
determine the specific heat capacity of an unknown mineral.
The 307-g sample was heated to 98.7°C and placed into a Question 172 2 points
calorimeter containing 72.4 g of water at 23.6°C. The heat What is the percent CsCl by mass in a 0.711 M CsCl solution
capacity of the calorimeter was 15.7 J/K. The final that has a density of 1.091 g/mL?
temperature in the calorimeter was 32.4°C. What is the Answers:
specific heat capacity of the mineral? a. 11
Answers: a b. 1.1
a. 0.138 J/(g·K) c. 0.387
b. 0.124 J/(g·K) d. 0.065
c. 0.131 J/(g·K)
d. 0.145 J/(g·K) Question 173 5 points
A 250. mL sample of 0.0328 M HCI is partially neutralized by
Question 169 5 points the addition of 100. mL of 0.0245 M NaOH. Find the
Given H2(g) + (1/2) O2(g) → H2O(l), ΔH° = -286 kJ/mol, concentration of hydrochloric acid in the resulting solution.
determine the standard enthalpy change for the reaction Answers: b
2 H2O(l) → 2 H2(g) + O2(g). a. 0.0174 M
Answers: b b. 0.0164 M
a. ΔH° = -286 kJ/mol c. 0.0163 M
b. ΔH° = +572 kJ/mol d. 0.0173 M
c. ΔH° = -572 kJ/mol
d. ΔH° = +286 kJ/mol Question 174 5 points
The first step in the Otswald process for producing nitric acid
Question 170 5 points is 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g). If the reaction of
Benzaldehyde ( MW = 106.1 g/mol), also known as oil of 150 g of ammonia with 150 g of oxygen gas yeilds 87 g of
almonds, is used in the manufacture of dyes and perfumes and nitric oxide (NO), what is the percent yeild of this reaction?"
in flavorings. What would be the freezing point of a solution Answers: b
prepared by dissolving 75.00 g of benzaldehyde in 850.0 g of a. 0.44
ethanol? b. 0.33
Kf = 1.99°C/m, freezing point of pure ethanol = -117.3°C. c. 0.11
Answers: c d. 0.22
a. -117.5°C
Question 175 2 points a. 7.02 g
Determine the freezing point of a solution which contains 0.31 b. 4.83 g
mol of sucrose in 175 g of water. Kf = 1.86°C/m Answers: a c. 2.34 g
a. -3.3°C d. 0.146 g
b. 3.3°C
c. 0.0°C Question 181 5 points
d. -1.1°C A 350. mL sample of 0.276 M HNO3 is partially neutralized
by 125mL of 0.0120 M Ca(OH)2. Find the concentration of
Question 176 2 points nitric acid in the resulting solution.
A 0.100 m MgSO4 solution has a freezing point of -0.23°C. Answers: d
What is the van't Hoff factor for this solution? Kf = 1.86°C/m a. 0.187 M
Answers: a b. 0.157 M
a. 1.2 c. 0.167 M
b. 0.62 d. 0.197 M
c. 1
d. 2 Question 182 5 points
Cinnamaldehyde ( MW = 132.15 g/mol) is used as a flavoring
Question 177 2 points agent. What mass of cinnamaldehyde must be added to 175 g
Human blood has a molar concentration of solutes of 0.30 M. of ethanol to give a solution whose boiling point is 82.7°C?
What is the osmotic pressure of blood at 25°C? Kb = 1.22°C/m, boiling point of pure ethanol = 78.5°C
Answers: a Answers: d
a. 7.3 atm a. 78.5 g
b. 6.8 atm b. 67.8 g
c. 0.62 atm c. 62.4 g
d. 0.012 atm d. 79.6 g

Carbon tetrachloride, once widely used in fire extinguishers Potassium hydrogen phosphate is used in the preparation of
and as a dry cleaning fluid, has been found to cause liver non-dairy powdered creamers. Calculate the molarity of a
damage to those exposed to its vapors over long periods of solution prepared by dissolving 238 g of K2HPO4 in enough
time. What is the boiling point of a solution prepared by water to produce 275 mL of solution.
dissolving 375 g of sulfur (S8)? Answers: a
MW = 256.5g/mol) in 1250 g of CCl4 a. 4.97 M
Kb = 5.05°C/m, boiling point of pure CCl4 = 76.7°C b. 2.66 M
Answers: d c. 0.865 M
a. 75.2°C d. 0.732 M
b. 78.2°C
c. 70.8°C Question 184 2 points
d. 82.6°C A chemist discovered a new compound and wished to
determine its molecular weight. He placed 2.00 grams of the
Question 179 2 points unknown compound in 10 g of water and found that the
The Henry's Law constant (k) for carbon monoxide in water at normal freezing point of the water was depressed to -1.22 deg
25°C is 9.71 × 10-4 mol/(L·atm). How many grams of CO will C. What is the molecular weight of the new compound?
dissolve in 1.00 L of water if the partial pressure of CO is 2.75 Answers: a
atm? a. 305
Answers: a b. 503
a. 7.48 × 10-2 g c. 180
b. 9.89 × 10-3 g d. 150
c. 2.67 × 10-3 g
d. 3.53 × 10-4 g Question 185 2 points
"What is the molality [m] of a solution prepared by dissolving
Question 180 2 points 86.9 g of diethyl ether, C4H10O, in 425 g of benzene, C6H6?
Methane has a Henry's Law constant (k)of 9.88 × 10-2 "
mol/(L·atm) when dissolved in benzene at 25°C. How many Answers: a
grams of CH4 will dissolve in 3.00 L of benzene if the partial a. 2.76
pressure of CH4 is 1.48 atm? b. 2.01
Answers: a c. 0.362
d. 0.498 d. 0.0194 M
In how many grams of water should 25.31 g of potassium Question 192 2 points
nitrate (KNO3) be dissolved to prepare a 0.1982 m solution? "If 325 g of water at 4.2°C absorbs 12.28 kJ, what is the final
Answers: a temperature of the water? The specific heat of water is 4.184
a. 1263 J/g·°C."
b. 7917 Answers: a
c. 1000 a. 13.2°C
d. 792 b. 4.21°C
c. 4.8°C
Question 187 2 points d. 9.0°C
By how much [in deg] will 50 grams of water have its freezing
point depressed if you add 30 g (MW=80) of glucose to it? Question 193 2 points
Answers: a It has been determined that 1.0 L of solution contain 52.7 g
a. -6.2 H₂SO₄, 240.8 g KMnO₄, 11.3 g K₂SO₄, and 5.5 g Mn₂O₇.
b. -1.86 The reaction equation is The molecular weights of the
c. -100 compounds are What is the equilibrium constant for the
d. 0 reaction?
Answers: d
Question 188 2 points a. 6.9 x 10-3
Which of the following bonds would you expect to be the b. 5.2 x 10-3
most polar? c. 2.6 x 10-3
Answers: a d. 1.3 x 10-3
a. N-Bi
b. N-P Question 194 2 points
c. N-Sb "A piece of copper metal is initially at 100.0°C. It is dropped
d. N-As into a coffee cup calorimeter containing 50.0 g of water at a
temperature of 20.0°C. After stirring, the final temperature of
Question 189 5 points both copper and water is 25.0°C. Assuming no heat losses, and
A 0.89% (w/v) sodium chloride solution is referred to as that the specific heat (capacity) of water is 4.18 J/(g·K), what
physiological saline solution because it has the same is the heat capacity of the copper in J/K? "
concentration of salts as human blood. What is the molarity of Answers: a
a physiological saline solution? a. 13.9 J/K
Answers: b b. 2.79 J/K
a. 0.0028 M c. 3.33 J/K
b. 0.15 M d. 209 J/K
c. 0.30 M
d. 0.015 M Question 195 2 points
Which of the following aqueous solutions should demonstrate
Question 190 2 points the most ideal behavior?
Potassium fluoride is used for frosting glass. Calculate the Answers: a
molarity of a solution prepared by dissolving 78.6 g of KF in a. 0.1 M NaCl
enough water to produce 225 mL of solution. b. 0.1 M K2SO4
Answers: a c. 0.1 M CaCl2
a. 6.01 M d. 0.1 M MgSO4
b. 3.29 M
c. 1.35 M Question 196
d. 0.349 M 2 points
"Benzene is a starting material in the synthesis of nylon fibers
Question 191 5 points and polystyrene (styrofoam). Its specific heat capacity is 1.74
The mole fraction of potassium nitrate in an aqueous solution J/(g·K). If 16.7 kJ of energy is absorbed by a 225-g sample of
is 0.0194. The solution's density is 1.0627 g/mL. Calculate the benzene at 20.0°C, what is its final temperature? "
molarity of the solution. Answers: a
Answers: c a. 62.7°C
a. 0.981 M b. -22.7°C
b. 1.96 M c. 36.7°C
c. 1.05 M d. 42.7°C
"The osmotic pressure of a 0.010 M MgSO4 solution at 25°C c. 1.58
is 0.318 atm. Calculate i, the van't Hoff factor, for this MgSO4 d. 0.0134
solution."
Answers: a Question 203 (1point)
a. 1.3 "A system which undergoes an adiabatic change (i.e., q = 0)
b. 1.5 and has work done on it by the surroundings has "
c. 2 Answers: a
d. 76.8 a. w = ?E
b. "w > 0, ?E < 0"
Questions 198 (2points) c. "w < 0, ?E > 0"
Electronegativity is a measure of d. w > ?E
Answers: a
a. the attraction by an atom for electrons in a chemical Question 204 (1 point)
bond. Which of the following elements has the smallest atomic
b. the energy needed to remove an electron from an radius?
atom. Answers: a
c. the energy released when an electron is added to an a. Ne
atom. b. Li
d. the magnitude of the negative charge on an c. Rb
electron. d. Xe
Question 205 (1 point)

Question 199 Select the correct electron configuration for Te (Z = 52).
Interference of light waves Answers: a
Answers: a a. [Kr]5s2 4d10 5p4
a. creates a pattern of light and dark regions. b. [Kr]5s2 4f14
b. separates light into its component colors. c. [Kr]5s2 4d10 5p6
c. bends light as it passes the edge of an object. d. [Kr]5s2 5d10 5p4
d. creates a laser beam.
Question 200 Colligative properties depend on
In hydrogen iodide __________________ are the most Answers: a
important intermolecular forces. a. the number of particles dissolved.
Answers: a b. the chemical properties of the solute.
a. dipole-dipole forces c. the masses of the individual ions.
b. London dispersion forces d. the molar mass of the solute.
c. hydrogen bonding
d. covalent bonds
Question 207 (2 points)
Calculate the concentration [molality] of an alcohol-water
Question 201 mixture which will not freeze above a temperature of -10 deg
A system that does no work but which receives heat from the C. MW of alcohol = 46; kf water = 1.86 deg C/m
surroundings has Answers: a
Answers: a a. 5.4
a. q = ?E b. 10.86
b. "q < 0, ?E > 0" c. 1.86
d. 250
c. "q > 0, ?E < 0"
d. w = ?E
Silicon carbide is an important industrial chemical. Which of
the following statements about silicon carbide is true?
Question 202 (5 points)
Answers: a.
Calculate the molality of a 15.0% by mass solution of MgCl2
a. It can be doped to form a high temperature
in H2O. The density of this solution is 1.127 g/mL.
Answers: b semiconductor.
a. 0.157 b. It will react with water to form acetylene.
c. It is the hardest known substance. DRILL 3
d. It is a naturally occurring mineral source of silicon.
1) A given sample of radioactive material has 80% of the
Question 209 (1point) original substance remaining after 10 years. How much
"When a deliquescent substance is exposed to air, it" will remain after 90 additional years?
Answers: a
a. becomes moist 0.11
b. crystallizes.
c. loses water of hydration. 2) The decay of U-238 to Pb-206 can be used to estimate
d. oxidizes. the age of inorganic matter. The half-life of U-238 is 4.5 x
10^9 years. In a particular rock sample, the ratio of the
Question 210 (1point) numbers of Pb-206 to U-238 atoms is 0.66. Assume all of
The orientation in space of an atomic orbital is associated with the Pb-206 present is due to the decay of U-238. What is
Answers: a the age of the rock?"
a. the magnetic quantum number (ml). 3.3x 109 yr
b. the principal quantum number (n).
c. the angular momentum quantum number (l). 3) Which of the following equilibria is not affected by
d. the spin quantum number (ms). pressure?
a) solid <==> liquid
b) A(s) <==> B(g)
c) 2A(g) + B(g) <==> 2C(g)
d) A(g) <==> 2B(g)
4) The reaction system

POCl3(g) ↔ POCl(g) + Cl2(g)
is at equilibrium. Which of the following statements
describes the behavior of the system if POCl is added to
the container?
a) The reverse reaction will proceed to
establish equilibrium.
b) The partial pressures of POCl3and POCl will
remain steady while the partial pressure of
chlorine increases.
c) The forward reaction will proceed to
d) The partial pressure of chlorine will increase
while the partial pressure of POCl decreases
5) Complete the following statement: A catalyst

a) alters the reaction mechanism
b) increases the activation energy.
c) increases the average kinetic energy of the
reactants.
d) increases the concentration of reactants.
6) The following reaction is at equilibrium at one

atmosphere, in a closed container.
NaOH(s) + CO2(g) ↔ NaHCO3(s)
Which, if any, of the following actions will decrease the

total amount of CO2 gas present at equilibrium?
a. removing half of the solid NaHCO3
b. decreasing the volume of the container c) As equilibrium is reestablished, the partial
c. adding N2 gas to double the pressure pressure of carbon disulfide increases.
d. adding more solid NaOH d) As equilibrium is reestablished, the partial
pressure of methane, CH4, decreases.
7) A reaction mechanism usually is

a. difficult, if not impossible, to prove"
b. the same as the balanced chemical 14) Which of the following statements is false?
equation a) A catalyst increases the rate of the forward
c. obvious if the reaction order is known reaction, but does not alter the reverse rate.
d. obvious if the activation energy is known b) A catalyst alters the mechanism of reaction.
c) A catalyst alters the activation energy.
d) A catalyst increases the rate of reaction, but is
not consumed.
8) Alpha particles are identical to
15)
helium nuclei A student adds 0.1 mol of oxalic acid and 0.1 mol of
sodium dihydrogen phosphate to enough water to make
9) Which of the following acids has the lowest pH? 1.0 L of solution. The following equilibrium is established
a) 0.1M HBO, pKa = 2.43 with the concentrations of the products greater than the
b) pure water concentrations of the reactants. Which of the statements
c) 0.20 mol about the equilibrium system is correct?
d) 0.1M HST, pKa = 11.89 - -
H2C2O4(aq) + H2PO4 (aq) ↔ HC2O4 (aq) + H3PO4(aq)
10) The half-life of radioactive carbon is approximately 5700 a)
-
The hydrogen oxalate anion, HC2O4 , is a
years. If a sample is found to have 7000 atoms after 6000 stronger base than the dihydrogen phosphate
years, how many atoms were presents initially? -
anion, H2PO4 .
14500 atoms b) Phosphoric acid is a weaker acid than oxalic
11) acid.
-
In order to write the correct mass-action expression for a c) The dihydrogen phosphate anion, H2PO4 , is a
reaction one must stronger acid than oxalic acid.
d) Oxalic acid is a weaker acid than phosphoric
a) know the kinetic rate law for the reaction acid.
b) have a properly balanced chemical equation. 16) The number of faradays required to deposit one mole of
c) know the limiting reactant Cr metal from Cr2O72- is
d) know the mechanism for the reaction
12) The Arrhenius equation is k = A e-(Ea/RT). The slope of a 6
plot of ln k vs. 1/T is equal to 17) As a result of beta decay, the product nucleus is
a) -Ea /R a) one atomic number higher than the original
b) -k element.
c) Ea b) one atomic number lower than the original
d) A element
13) The reaction system c) two atomic numbers higher than the original
element
CS2(g) + 4H2(g) ↔ CH4(g) + 2H2S(g) d) two atomic numbers lower than the original
element
is at equilibrium. Which of the following statements 18)
describes the behavior of the system if the partial The position of the equilibrium 2CO(g) + O2(g) <==> 2
pressure of hydrogen is doubled? CO2(g) can be shifted to the left by the addition of _____
a) As equilibrium is reestablished, the partial at constant pressure.
pressure of hydrogen decreases. a) He
b) CO
b) As equilibrium is reestablished, the partial
c) O2
pressure of hydrogen sulfide decreases.
d) KCl
19) Which of the following has an effect on the magnitude of c) nobelium-245
the equilibrium constant? d) californium-245
a) concentrations of the reactants and products
b) presence of a catalyst 28) When the reaction Cu + HNO3 --> Cu2+ + NO + H2O is
c) change in temperature balanced in acidic solution, the coefficient of H+ is _____.
d) change in volume of container 6
20) Write the mass-action expression, Qc , for the following 29) Which one of the following changes would alter the rate
chemical reaction. constant (k) for the reaction 2A + B ® products?
a) increasing the temperature
+ 2+
Zn(s) + 2Ag (aq) ↔ Zn (aq) + 2Ag(s) b) increasing the concentration of A
c) increasing the concentration of B
a) 2+ 2 + 2
[Zn ] / [Ag ] d) measuring k again after the reaction has run for
b) 2+ + 2
[Zn ] / [Ag ] a while
+ 2 2+
c) [Ag ] / [Zn ]
30) The equilibrium 2SO2(g) + O2(g) <==> 2 SO3(g) can
21) The following reaction is at equilibrium in a sealed shifted to the reactant side by _____. DH = –198.2 Kj
container. a) Decreasing pressure
b) Decreasing temperature
N2(g) + 3H2(g) ↔ 2NH3(g); ΔH°rxn < 0 c) Decreasing volume
d) Increasing the concentration of SO2
Which, if any, of the following actions will increase the
value of the equilibrium constant, Kc? 31)
a) increasing the pressure A typical radius of an atomic nucleus is about
b) adding more N2 a) 5 ´ 10-3 pm
c) adding a catalyst b) 100 µm
d) lowering the temperature c) 5000 mm
d) 500 pm
22) _____ faradays of electricity are required to reduce one
mole of MnO4– to Mn2+. 32) The equilibrium pressure of NO2 in the equilibrium
5 N2O4(g) <==> 2 NO2(g) is 1.56 atm. Its pressure on the
addition of a catalyst will be _____.
23) The standard potential for the reduction of Cu+ to Cu is 1.56 atm
0.52V. E° at 25 °C for 2Cu+(aq) --> Cu2+(aq) + Cu(s) is
_____. 33)
0.37V What is the pH of a 0.20 M HCl solution?
0.7
24) The substance HCl is considered
a) a weak Arrhenius acid
b) a strong Arrhenius acid. 34) Which of the following does a catalyst change?
c) a weak Arrhenius base a)
d) a neutral compound the heat of reaction of a reaction
b) the concentration of product at equilibrium
25) The pH of a 0.001 M HCI solution is c) the equilibrium constant of a reaction
3 d) the activation energy of a reaction
26) 35)
For what order reaction does the half-life get longer as The following reaction is at equilibrium at a pressure of 1
the initial concentration increases? atm, in a closed container.
zeroth order
NaOH(s) + CO2(g) ↔ NaHCO3(s); ΔH°rxn < 0
27) Which isotope, when bombarded with oxygen-18, yields
the artificial isotope seaborgium-263 plus 4 neutrons? Which, if any, of the following actions will decrease the
concentration of CO2 gas present at equilibrium?
a) increasing the volume of the container
a) radium-259 b) lowering the temperature
b) californium-249 c) adding N2 gas to doubmle the pressure
d) adding more solid NaOH d) in the reaction equation, the number of moles
of gaseous products is smaller than the number
36) What role does cadmium metal (Cd) play in a nuclear of moles of gaseous reactants.
reactor?
a) controls chain reaction (control rods) 43) The reaction system
b) slows down the fission neutrons (moderator)
c) transfers heat from the reactor to the heat POCl3(g) ↔ POCl(g) + Cl2(g)
exchanger (primary coolant)
d) transfers heat from the condenser to the is at equilibrium. Which of the following statements
environment (cooling tower) describes the behavior of the system if the partial
pressure of chlorine is reduced by 50%?
37) When the concentrations of reactant molecules are a) POCl will be consumed as equilibrium is
increased, the rate of reaction increases. The best established.
explanation for this phenomenon is that as the reactant
concentration increases b) Chlorine will be consumed as equilibrium is
a) the frequency of molecular collisions increases established.
b) the average kinetic energy of molecules
increases c) The partial pressure of POCl will decrease while
c) the rate constant increases the partial pressure of Cl2 increases as
d) the activation energy increases equilibrium is established.
44) For a second order reaction, the half-life is equal to
38) Which one of the following substances will give an t1/2 = 1/k[A]o
aqueous solution of pH < 7?
a) Na2CO3 45) Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) +
b) CH3COONa O2(g) Starting with NO2 (g) only, the partial pressure of
c) KI O2 at equilibrium is 0.25 atm. Calculate the partial
d) NH4Br pressure [atm] of NO2 at equilibrium.
0.02
39) For the reaction N2(g) + 3H2(g) <==> 2NH3(g) Kc = 1.2 at
375 C. Kc for the reverse reaction is 46)
0.83 The value of Kc for the equilibrium 2SO2(g) + O2(g) <==>
2SO3(g) is 5.6x10^4 at 350 C. The initial pressures of SO2
40) Kc for the formation of one mole of NH3 from H2 and N2 and O2 are 0.35 and 0.762 atm. The total pressure at
is _____. equilibrium will be
1.1 Less than 1.112
41) What element is the stable end-product of the uranium 47) Which statement is correct with respect to the above
radioactive decay series? equilibrium when 0.30 moles of CO and 0.30 moles of
a) Pb H2O are heated to 700°C and allowed to reach
b) Th equilibrium.
c) Ra a) [H2O] = [CO]
d) Au b) [H2O] = [CO2]
c) [CO2] = [CO]
42) The two equilibrium constants for the same d) [H2O] = [H2]
reaction, Kc and Kp, will always equal one another when
a) 48) Sodium hydrogen carbonate decomposes above 110°C to
in the reaction equation, the number of moles form sodium carbonate, water, and carbon dioxide.
of gaseous products equals the number of
moles of gaseous reactants. 2NaHCO3(s) ↔ Na2CO3(s) + H2O(g) + CO2(g)
b) all of the reactants and products are gases. One thousand grams of sodium hydrogen carbonate are
c) added to a reaction vessel, the temperature is increased
in the reaction equation, the number of moles to 200°C, and the system comes to equilibrium. What
of gaseous products is greater than the number happens in this system if another 50 g of sodium
of moles of gaseous reactants. carbonate are now added?
a) The amounts of all products will be greater
when equilibrium is reestablished.
b) The partial pressure of carbon dioxide will the reactants when the system is at
increase. equilibrium.
c) The partial pressure of carbon dioxide will d. The concentrations of the products will be
decrease. about the same as the concentrations of the
d) The partial pressure of carbon dioxide will be reactants when the system is at equilibrium.
unchanged.
49) Which of the following statements concerning reversible 56) A radioisotope decays to give an alpha particle and Pb-
reactions is false? 208. What was the original element?
a. Po
a. Concentration have no effect on the b. Se
direction of the reaction c. Bi
b. Both reactants and products are always d. Hg
present.
-2
c. Temperature affects the direction of the 57) The acid dissociation constant Ka equals 1.26 × 10 for
- -10 +
reaction. HSO4 and is 5.6 × 10 for NH4 . Which statement about
d. Concentration remain constant once the following equilibrium is correct?
equilibrium is reached.
- 2- +
HSO4 (aq) + NH3(aq) ↔ SO4 (aq) + NH4 (aq)
50) Which of the following is the strongest acid?
a. H2SO3 a) The reactants will be favored because
b. CH3COOH ammonia is a stronger base than the sulfate
c. HI anion.
d. H3PO4 b) Neither reactants or products will be
favored because all of the species are weak
51) acids or bases.
Gamma-rays cause radiation damage when they interact c) The products will be favored because the
with matter by producing hydrogen sulfate ion is a stronger acid than
a. ions and free radicals the ammonium ion.
b. isotopes d) This reaction is impossible to predict, since
c. daughter products the strong acid and the weak base appear
d. oxidation on the same side of the equation.
52) The substance H2SO3 is considered
a) a strong Arrhenius acid 58) Which one of the following is a strong acid?
b) a weak Arrhenius base a) H2CO3
c) a weak Arrhenius acid b) H2SO3
d) a neutral compound c) H3PO4
d) H2SO4
53) Which of the following will shift the equilibrium to the
right? CaCO3(s) <==> CaO(s) + CO2(g) 59) The standard potential of the cell consisting of the
a. Addition of NaOH solution Zn2+/Zn half-cell and the SHE is _____.
b. Addition of CO2 a. 0.76V
c. Addition of KCl b. 1.76V
d. Decrease of temperature c. 1.018V
d. 1.18V
54) What is the pH of a 0.050 M HBr solution?
1.3 60) The reaction A → B is first-order overall and first-order
with respect to the reactant A. The result of doubling the
55) The reaction quotient, Qc, for a reaction has a value of 75 initial concentration of A will be to
while the equilibrium constant, Kc, has a value of 195. a.
Which of the following statements is accurate? double the initial rate
a. The reaction must proceed to the right to b. shorten the half-life of the reaction
establish equilibrium. c. increase the rate constant of the reaction
b. The reaction must proceed to the left to d. decrease the rate constant of the reaction
c. The concentrations of the products will be 61) The pH of a 0.001 M HCI solution is
much smaller than the concentrations of 3
+ +
H + H2O2 H2O -OH (rapid equilibrium)
+ -
62) The relation connecting DG° and E° is _____. H2O -OH + Br → HOBr + H2O (slow)
+ -
a. DG° = –nFE° HOBr + H + Br → Br2 + H2O (fast)
b. DG° = – RTnFE Which of the following rate laws is consistent with the
c. E° = DG°/RT mechanism?
d. DG° = nFE°
Rate = k[H2O2][H+]2[Br-]
63) In the electrolysis of water, _____. Rate = k[H2O2][H+][Br-]
Rate = k[HOBr][H+][Br-][H2O2]
a. oxygen is liberated at the anode Rate = k[Br-]
b. hydrogen is liberated at the anode
c. oxygen is liberated at the cathode 70) The equilibrium constant Kc for the equilibrium A + B
d. water is oxidized to hydrogen <==> C + D is X. The equilibrium constant for the reaction
2C + 2D <==> 2A + 2B is
64) a. X^(-2)
The standard emf of the cell involving Mg/Mg2+ and b. -2X
Cu/Cu2+ half-cell reactions is _____. c. 1/2X
a. 2.71V d. X^2
b. 1.18V
c. 3.71V 71) Which of the following is an advantage of nuclear power
d. 2.03V plants over coal-burning plants? Nuclear power plants
a. do not pollute the air with SO2, soot, and
65) Ammonium chloride is used as an electrolyte in dry cells. fly-ash
Which of the following statements about a b. form numerous radioactive fission products.
0.10 M solution of NH4Cl, is correct? c. produce more thermal pollution than coal
a. The solution is acidic. plants.
d. use more fuel
b. The values for Ka and Kb for the species in
solution must be known before a prediction 72) What is the pH of a 0.75 M HNO3 solution?
can be made. 0.12
c. The solution is strongly basic. 73) The cathode in the Daniell cell is _____.
Cu
d. The solution is weakly basic.
74) For the reaction whose rate law is rate = k[X], a plot of
66) The correct statement is: _____. which of the following is a straight line?
a. Oxidation occurs at the anode a. log [X] versus time
b. Oxidation occurs at the cathode b. [X] versus time
c. Anions travel to the cathode in an c. 1/[X] versus time
electrochemical cell. d. log [X] versus 1/time
d. Reduction occurs at the anode.
75) Which can alter the value of the equilibrium constant?
67) Which of the following affects the activation energy of a a. Temperature
reaction? b. Catalyst
c. Concentration
a. temperature of the reactants d. Pressure
b. concentrations of reactants
c. presence of a catalyst 76) Consider the reaction
d. reaction progress
2NH3(g) → N2(g) + 3H2(g)
-1 -1
68) What is the pH of a 0.00200 M HClO4 solution? If the rate Δ[H2]/Δt is 0.030 mol L s , then Δ[NH3]/Δt is
2.699
-1 -1
a) -0.045 mol L s
-1 -1
69) Consider the following mechanism for the oxidation of b) -0.030 mol L s
-1 -1
bromide ions by hydrogen peroxide in aqueous acid c) -0.010 mol L s
d) -1 -1
solution. -0.020 mol L s
2
77) An electrochemical reaction will be spontaneous if d. (K1K2)
_____. 83) How many grams of copper will be deposited at an
a. the standard emf of the cell is positive. electrode if a current of 1.5 A is supplied for 2 hours to a
b. the standard emf of the cell is negative. CuSO₄?
c. resistance is positive. a) 48 g
d. DG is positive b) 3.6 g
c) 7.1 g
78) The substance Ba(OH)2 is considered d) 2.4 g
a. a weak Arrhenius acid
b. a weak Arrhenius base 84) The concentration of H+ in pure water at 25°C is _____.
c. a strong Arrhenius acid a. 10^-7 M
d. a strong Arrhenius base b. 10^-14 M
c. 10^-10 M
79) Which is the most penetrating of the three types of d. 10^-8 M
nuclear radiation? 85) When a chemical system is at equilibrium,
a. Gamma a) the concentrations of the reactants are
b. Alpha equal to the concentrations of the products.
c. Beta
d. None of the choices b) the concentrations of the reactants and
products have reached constant values.
80) A solution is adjusted from pH 8 to pH 9. The relative
concentration of the hydrogen [H?] ion has changed by a c) the forward and reverse reactions have
factor of what? stopped.
a) 10
b) 1100 d) the reaction quotient, Q, has reached a
c) 5 maximum.
d) 110
86) The energy released by the sun is the result of
81) The reaction shown occurs in a gaseous phase. Once a. nuclear fusion
equilibrium has been achieved in a particular reaction b. natural radioactivity
vessel, additional HI gas is injected directly into the c. combustion of hydrogen
reaction vessel. Compared to the initial conditions, which d. nuclear fission
of the following statements is correct after the new
equilibrium has been achieved? 87) Methanol can be synthesized by combining carbon
monoxide and hydrogen.
a. The partial pressure of H2 will have 88) CO(g) + 2H2(g) ↔ CH3OH(g)
decreased.
b. The amount of I2 will have increased. A reaction vessel contains the three gases at equilibrium
c. The partial pressure of HI will have with a total pressure of 1.00 atm. What will happen to
decreased. the partial pressure of hydrogen if enough argon is added
d. The amount of H2 will have decreased. to raise the total pressure to 1.4 atm?
82) About half of the sodium carbonate produced is used in
making glass products because it lowers the melting a. The partial pressure of hydrogen will
point of sand, the major component of glass. When decrease.
sodium carbonate is added to water it hydrolyses b. Both Kp and the temperature need to be
according to the following reactions. known before a prediction can be made.
CO32-(aq) + H2O(l) ↔ HCO3-(aq) + OH-(aq); K1 c. The partial pressure of hydrogen will be
HCO3-(aq) + H2O(l) ↔ H2CO3(aq) + OH-(aq); K2 unchanged.
d. The partial pressure of hydrogen will
These can be combined to yield increase.
CO32-(aq) + 2H2O(l) ↔ H2CO3(aq) + 2OH-(aq); K3 89) Tarnished silver is coated with _____.
a. Ag2S
What is the value of K3? b. AgCl
a. K1 × K2 c. ZnS
b. K1 + K2 d. Ag2O
c. K1 ÷ K2
90) The equilibrium position of the reaction SO2(g) + Cl2(g) 94) Kp is 158 for the equilibrium 2NO2(g) <==> 2 NO(g) +
<==> SO2Cl2(g) can be shifted in the forward direction by O2(g) Starting with NO2 (g) only, the partial pressure of
_____. NO at equilibrium is 0.25 atm. Calculate the partial
a. Adding Cl2 pressure [atm] of NO2 at equilibrium.
b. Removing SO2 a. 0.5
c. Removing Cl2 b. 0.125
d. Removing SO2 and Cl2 c. 0.02
95) The equilibrium PCl5(g) <==> PCl3(g) + Cl2(g) can be
91) Write the mass-action expression, Qc, for the following shifted toward more product formation by _____. DH =
chemical reaction equation. 92.5 kJ
a. Increasing temperature
2C6H6(g) + 15O2(g) 12CO2(g) + 6H2O(g) b. Increasing pressure
c. Decreasing temperature
d. Increasing the concentration PCl3
96) Galvanized iron is steel coated with _____.

a) a. Zn
b. Sn
c. Hg
d. Na
b)
97) The dose unit of ionizing radiation is called the rad. The
rad is defined in terms of
a. the energy deposited per gram of an object.
b. the half-life of a radioisotope
c) c. the biological damage produced.
d. the accumulation of fission products
98) When the reaction A → B + C is studied, a plot of
ln[A]t vs. time gives a straight line with a negative slope.
What is the order of the reaction?
a. More info is needed to determine order
d) b. First
92) The kinetics of the decomposition of dinitrogen c. Second
pentaoxide is studied at 50°C and at 75°C. Which of the d. zero
following statements concerning the studies is correct? 99) _____ Faradays are required to liberate 32 g of O2 in the
a. The rate at 75°C will be greater than at 50°C electrolysis of H2O.
because the concentration of a gas a. 4
increases with increasing temperature. b. 2
b. The rate at 75°C will be less than the rate at c. 8
50°C because the molecules at higher d. 6
speeds do not interact as well as those at 100) Methanol can be synthesized by combining carbon
lower speeds monoxide and hydrogen.
c. The rate at 75°C will be greater than the
rate at 50°C because the activation energy CO(g) + 2H2(g) ↔ CH3OH(g); ΔH°rxn = -90.7 kJ
will be lower at 75°C than at 50°C.
d. The rate at 75°C will be greater than the A reaction vessel contains these compounds at
rate at 50°C because the number of equilibrium. What effect will be seen when equilibrium is
molecules with enough energy to react re-established after decreasing the temperature by 45°C?
increases with increasing temperature. a) The partial pressure of methanol will decrease
b) The partial pressures of hydrogen and
93) The unit of electromotive force is the _____. methanol will decrease
a. Volt c) The partial pressure of carbon monoxide will
b. Erg decrease.
c. Ohm d) All the partial pressures will decrease.
d. Ampere
101) The substance H2SO3 is considered 108) Which isotope, when bombarded with nitrogen-15,
a. a neutral compound yields the artificial isotope dubnium-260 plus 4
neutrons?
b. a strong Arrhenius acid
c. a weak Arrhenius base a. californium-249
d. a weak Arrhenius acid b. thorium-257
c. dubnium-249
102) What is the pH of a 0.00200 M HClO4 solution? d. nobelium-245
6.125
109) The substance NH3 is considered
103) What is the half-life of a substance that decays to a. A weak acid
25% of its original amount in six days? b. A neutral compound
a. 8 days c. A strong base
b. 0.08 days d. A weak base
c. 3 days
d. 12 days 110)
The reaction _____ is spontaneous.
104) a. MnO4– oxidizing Fe to Fe2+
At 450°C, tert-butyl alcohol decomposes into water and b. NO3– oxidizing Mn2+ to MnO4–
isobutene. c. Ag reducing Cu2+ to Cu
105) (CH3)3COH(g) ↔ (CH3)2CCH2(g) + H2O(g) d. Br2 oxidizing F– to F2
A reaction vessel contains these compounds at 111) Which one of the following substances will give an
equilibrium. What will happen if the volume of the aqueous solution of pH closest to 7?
container is reduced by 50% at constant temperature? a) NH3
b) NH4I
a) No change occurs. KNO3
b) c) CO2
The reverse reaction will proceed to
reestablish equilibrium.
112) The process _____ occurs spontaneously under standard
c) The equilibrium constant will increase. state conditions.
a. Fe3+ oxidizes I–
d) The forward reaction will proceed to b. Cu reduces Mg2+
reestablish equilibrium. c. Fe3+ reduces I2
d. Ag reduces Fe2+
106) Hydrogen bromide will dissociate into hydrogen and
bromine gases. 113) One ampere-hour (1A·hr) is _____.
a. 3600 C
2HBr(g) ↔ H2(g) + Br2(g); ΔH°rxn = 68 kJ b. 360 F
c. 36 F
What effect will a temperature increase of 50°C have on d. 36000 C
this system at equilibrium?
a. high temperature, low pressure 114) Consider the equilibrium reaction: N2O4(g) ↔ 2NO2(g)
b. high temperature, high pressure Which of the following correctly describes the
c. low temperature, high pressure relationship between Kc and Kp for the reaction?
d. low temperature, low pressure a. Kp = Kc /RT
b. Kp = Kc
107) Which type of nuclear process requires an extremely c. Kp = RT/Kc
high temperature (millions of degrees)? d. Kp = RT × Kc
a. Fusion reaction 115) Consider the equilibrium reaction: H2(g) +

b. Beta decay Br2(g) ↔ 2HBr(g)
c. Fission reaction Which of the following correctly describes the
d. Alpha decay relationship between Kc and Kp for the reaction?
a. 2
Kp = Kc/(RT)
2
b. Kp = (RT) Kc
c. Kp = (RT)Kc b. 0.012
d. Kp = Kc c. 0.12
d. 0.35
The reaction system
CS2(g) + 4H2(g) ↔ CH4(g) + 2H2S(g)
is at equilibrium. Which of the following statements describes

the behavior of the system if the partial pressure of carbon
disulfide is reduced?
a) As equilibrium is reestablished, the partial pressure
of hydrogen decreases.
b) As equilibrium is reestablished, the partial
pressures of hydrogen and hydrogen sulfide
decrease.
c) As equilibrium is reestablished, the partial pressure
of methane, CH4, increases.
d)
As equilibrium is reestablished, the partial pressure
of carbon disulfide increases.
What is the value of Kc for the reaction CO2(g) + H2(g) <==>
H2O(g) + CO(g) when the equilibrium concentrations of CO,
H2, CO2, and H2O are 0.050 M, 0.045 M, 0.086 M and 0.040
M respectively?
a. 0.52
b. 0.074
c. 0.063
d. 0.24
Two balloons are at the same temperature and pressure.
One contains 14g of nitrogen and the other contains
20.0g of argon. Which of the following is true?
a. The average speed of the nitrogen molecules is
greater than the average molecules of the argon
molecules.
b. The density of the nitrogen sample is greater
than the density of the argon sample.
c. The average kinetic energy of the nitrogen
molecules is greater than the average kinetic
energy of the argon molecules.
d. The volume of the nitrogen container is less than
the volume of the argon container
Which one of the following statements about fission and

fusion is false?
a. For a fission reaction the mass defect (Dm) is
negative, whereas for fusion Dm is positive."
b. Fission occurs among the heaviest isotopes,
whereas fusion occurs more readily for light
isotopes.
c. The fission of Pu-239 atoms produces a great
number of isotopes of a large number of
elements.
d. In order for fusion reactions to occur,
temperatures must be in the millions of
degrees.
The emf of the concentration cell Cu/Cu2+(0.08
M)||Cu2+(1.2 M)/Cu is _____.
a. 0.035
PHYSICS
Basic Engineering Correlation (Physics Reviewer)

(A Collaborative work of GaMbit, jay729, and airsWTP)
1. The system shown is in static equilibrium. Find W.
4. The structure shown is formed of three separate solid aluminum cylindrical

rods, each with a 1 cm diameter. What is the -coordinate of the centroid of
volume for the structure?
Select one:
a. 15.2 cm
b. 16.0 cm
Select one: c. 15.9 cm
a. 1000 N d. 14.0 cm
b. 1700 N
c. 1500 N 5. A projectile has an initial velocity of 110 m/s and a launch angle of 20o
d. 830 N from the horizontal. The surrounding terrain is level, and air friction is to be
disregarded. What is the maximum elevation achived by the projectile?
2. What is the force in member AF?
Select one:
a. 350 m
b. 72 m
c. 140 m
d. 620 m
6. What are R1 and R2? (insert question #11)

Select one:
a. 1250 N
b. 1250 N; R2 /
c. 1000 N; R2 /
d. R1 /
Select one:
e. 3750 N
a. 5000 N
f. 4000 N
b. 15 000 N
g. 2500 N; R2 /
c. 10 000 N
h. 1250 N
d. O
i. R1 /
j. R1 /
3. A ball is dropped from rest at a point 12 m above the ground into a
k. 3750 N; R2 /
smooth, frictionless chute. The ball exist the chute 2 m above the ground and
l. R1 /
at angle 45o from the horizontal. Air resistance is negligible. Approximately
how far will the ball travel in the horizontal direction before hitting the
7. What is the reaction at point A?
ground?
Select one: Select one:

a. 22 m a. 710 N
b. 20 m b. O
c. 24 m c. 500 N
d. 12 m d. 290 N
8. A turntable capable of angularly accelerating at 12 rad/s2 needs to be

given an initial angular velocity if it is to rotate through a net 400 radians in 6
seconds. What must its initial angular velocity be?
Select one:
a. 33 rad/s
b. 21 rad/s
c. 200 rad/s
d. 28 rad/s
9. A 550 kg mass initially at rest acted upon by a force of 50 et N. What are

the acceleration, speed, and displacement of the mass at t = 4 s?
Select one:
a. 4.96 m/s2,4.87 m/s,19.5 m
b. 4.96 m/s2,135.5 m/s,2466 m
c. 4.96 m/s2,271 m/s,3900 m
d. 4.96 m/s2,4.96 m/s,19.8 m
10. A constant force of 750 N is applied through a pulley system to lift a mass Select one:
of 50 kg as shown. Neglecting the mass and friction of the pulley system, a. 3500 N
what is the acceleration of the 50 kg mass? b. 2500 N
Select one: c. O
a. 20.2 m/s2 d. 550 N
b. 16.2 m/s2
c. 8.72 m/s2 16. Link AB of the linkage mechanism shown in the illustration rotates with
d. 5.20 m/s2 an instantaneous counterclockwise angular velosity of 10 rad/s. What is the
instantaneous angular velocity of link BC when link AB is horizontal and link
11. A child keeps a 1 kg toy airplane flying horizontally in a circle by holding CD is vertical?
onto a 1.5 m long string attached to its wing tip. The string is always in the
plane of the circular flight path. If the plane flies at 10 m/s, what is the
tension in the string?
Select one:
a. 15 N
b. 28 N
c. 7 N
d. 67 N
12. One newton is the force required to

Select one:
a. give a 1 g mass an acceleration of 1m/s2.
b. accelerate a 10 kg mass at a rate of 0.10 m/s2.
c. accelerate a 1 kg mass at a rate of 9.81 m/s2
d. accelerate a 1 kg mass at a rate of 1.00 cm/s2.
Select one:
13. What is the approximate centroidal polar moment of inertia of the area? a. 3.25 rad/s (counterclockwise)
b. 2.25 rad/s (clockwise)
c. 12.5 rad/s (clockwise)
d. 5.50 rad/s (clockwise)
17. Why does a spinning ice skater's angular velocity increase as she brings
her arms in toward her body?
Select one:
a. Her angular momentum is constant
b. Her radius of gyration is reduced.
c. Her mass moment of inertia is reduced.
Select one: d. all of the above
a. 27.3cm4
b. 25.6 cm4 18. A flywheel rotates at 7200 rev/min when the power is suddenly cut off.
c. 16.2 cm4 The flywheel decelerates at a constant rate of 2.1 rad/s2 and comes to rest 6
d. 21.4 cm4 min later. How many revolutions does the flywheel make before coming to
rest?
14. A 4-A current is maintained in a simple circuit with a total resistance of 2 Select one:
. How much energy is delivered in 3 seconds a. 390 000 rev
Select one: b. 18 000 rev
a. 3J c. 22 000 rev
b. 12J d. 72 000 rev
c. 6 J
d. 96J 19. Two 2 kg block are linked as shown. Assuming that the surfaces are
frictionless, what is the velocity of block B if block A is moving at a speed of 3
15. In the pin-jointed truss shown, what is the force in member DE? m/s?
d. 1.1
24. If the sum of the forces on a particle is not equal to zero,the particle is
Select one:
a. moving with a constant velocity opposite to the direction of the resulatnt
force.
b. accelerating in a direction opposite to the resultant force.
c. accelerating in the same direction as the resultant force.
d. moving with constant velocity in the direction of the resultant force.
Select one: 25. What is the -coordinate of the centroid of the perimeter line?
a. 1.30 m/s
b. 0 m/s
c. 5.20 m/s
d. 1.73 m/s
20. Find the distance between position B and C.
Select one:
a. 1.66 cm
b. 1.56 cm
c. 1.75 cm
Select one:
d. 1.80 cm
a. 3.23 m
b. 10.1 m
26. An angle bracket is subjected to the forces and couple shown. Determine
c. 4.78 m
the equivalent force-couple system at point A
d. 7.78 m
21. A weekend plumber, unable to loosen a pipe fitting, slips a piece of scrap
pipe (a "cheater") over his wench handle. He then applies his full mass of 100
kg to the end of the cheater by standing on it. The distance from the center
of the fitting on the point where the weight acts is 0.80 m and the wrench
handle and cheater make an angle of 19° with the horizontal. Find the
magnitude and direction of the torque he applies about the center of the
pipefitting.
Select one:
a. 740 N
b. 120 N
c. 360 N
d. 520 N Select one:
a. 292 N at -5.9o ; 103 N.m
22. A 1530 kg car is towing a 300 kg trailer. The coefficient of friction b. 333 N at 42.9o ; 53 N.m
between all tires and the road is 0.80. How fast can the car and trailer travel c. 114 N at 15.3o ; 50 N.m
around an unbanked curve of radius 200 m without either the car or trailer d. 307 N at 10.4o ; 110 N.m
skidding?
Select one: 27. In the figure, a very small toy race car of mass m is released from rest on
a. 143 km/h the loop-the-loop track. If it is released at a height 2R above the floor, how
b. 75.2 km/h high is it above the floor when it leaves the track, neglecting friction?
c. 40.0 km/h Select one:
d. 108.1 km/h a. 1.33 R
b. 2.00 R
23. A rope passes over a fixed sheave as shown. The two rope ends are c. 1.67 R
parallel. A fixed load on one end of the rope is supported by a constant force d. 1.50 R
on the other end. The coefficient of friction between the rope and the sheave
is 0.30. What is the ratio of tensile forces in the two rope ends? 28. Find the acceleration of block A after the blocks are released.
Select one:
Select one: a. 2.5 m/s
a. 2.6 b. 0 m/s
b. 1.6 c. 1.4 m/s
c. 1.2 d. 5.6 m/s
35. A single force (not shown) is applied at point B in the y-direction, in line
29. Where can a couple be moved on a rigid body to have an equivalent with points A and B. What should this force bein order for the frame to be in
effect? equilibrium in that direction?.
Select one:
a. along the perpendicular bisector joining the two original forces
b. along the line of action
c. anywhere on the rigid body
d. in a parallel plane
30. What is the reaction at point B?
Select one:
Select one: a. -280 N (down)
a. 20 000 N b. 120 N (down)
b. 10 000 N c. 180 N (down)
d. -250 N (down)
An isolated parallel-platd. 5000 N 36. A cable passes over a stationary sheave and supports a 60 kg bucket, as
shown. The coefficient of friction between the cable abd the sheave is 0.10.
31. Find the -and y-coordinates of the centroid of wire ABC
The cable has a uniform mass per unit length of 0.4 kg/m. The cable is in the
shape of a catenary due to its own weight. The tension o fthe cable at the
pulley is given by T = wy, where w is the weight per unit lenght and the
constant y (for this configuration) is known to be 151 m. How much more
mass can be added to the4 bucket before the cable slips over the pulley?
Select one:
a. 0.43 m ; 1.29 m
b. 2.71 m ; 1.49 m
c. 3.33 m ; 2.67 m
d. 0.64 m ; 2.83 m
32. For a force to do work it must be ____ the displacement

Select one:
a. shorter than
b. equal in magnitude to
Select one:
c. paralllel or antiparallel to
a. 12.1 kg
d. perpendicular to
b. 11.6 kg
c. 10.0 kg
33. For which of the following situation is the net force acting on a particle
d. 0
necessarily equal to zero?
Select one:
37. The moment of inertia about the -axis o fthe cross section shown is
a. The particle has constant loinear momentum.
245833 cm4. If the cross-sectional area is 250 cm2 and the thickness of the
b. The particle has constant angular momentum.
web and the flanges are the same, what is the moment of inertia about the
c. The particle has constant kinetic energy.
centroidal axis?
d. The particle is traveling at constant velocity around a circle.
34. A perfect sphere moves up a frictionless incline. Which of the following

quantities increases?
Select one:
a. potential energy
b. total energy
c. angular velocity
d. linear momentum
Select one:
a. 2.1 x 104 cm4
b. 1.5 x 105 cm4
c. 2.5 x 105 cm4
d. 8.0 x 104 cm4
38. Assume that the centroidal moment of inertia of area A2 with respect to
the composite centroidal -axis is 73.94 cm4. The moment of inertia of area
A2 with respect to the composite centroidal horizontal axis is 32.47 cm4.
What is the moment of inertia o fthe composite area with respect to its
centroidal -axis?
Select one:
a. 4130 N (tension)
b. 0
c. 2320 N (compression)
d. 3840 N (tension)
42. What is the period of a pendulum that passes the center point 20 times a
minute.
Select one:
a. 0.2 s
b. 3 s
c. 6 s
d. 0.3 s
Select one:
a. 560 cm4 43. A 2kg block rests on 34o incline. If the coefficient of static friction is 0.2,
b. 460 cm4 how much additional force, F, must be applied to keep the block from sliding
c. 480 cm4 down the incline?
d. 350cm4
39. Find the tension, T, that must be applied to pulley A to lift the 1200 N
weight.
Select one:
a. 14 N
b. 9.1 N
c. 7.7 N
d. 8.8 N
44. A uniform rod (AB) of length L and weight W is pinned at point C. An

initial impulse starts the rod accelerating with an initial angular acceleration
(in rad/s2) of g/L. What is the initial reaction at point C?
Select one:
a. 600 N
b. 300 N
c. 100 N
d. 400 N
40. What are the - and y-coordinates of the centroid of the area?
Select one:
a. w/3
b. w/4
c. 4w/7
Select one: d. 4w/7
a. 3.0 cm ; 4.0 cm
b. 2.4 cm ; 3.4 cm 45. What is the radius of gyration about a horizontal axis passing through the
c. 3.0 cm ; 3.6 cm centroid?
d. 3.0 cm ; 3.8 cm Select one:
a. 1.7 cm
41. Determine the force in member FH for the pi-connected truss shown. b. 0.86 cm
c. 3.7 cm
d. 2.3 cm
46. A 153 kg car is towing a 300 kg trailer. The coefiicient of friction between
all tires and the road is 0.80. The car and trailer are traveling at 100 km/h
around a banked curve of radius 200 m. What is the necessary banking angle d. 25 N s (gain)
such that tire friction will not be necessary to prevent skidding?
Select one: 51. What is the magnitude o fthe couple that exactly replaces the moment
a. 36o that is removed?
b. 78o
c. 21o
d. 8o
47. A 47.2-kg child is standing on the outer edge of a merry-go-round that

has moment of inertia 543 kg · m2 and radius 2.40 m. The entire system is
initially rotating at 0.180 rev/s. Find the angular velocity if the child moves to
a final position 1.10 m from the center of the merry-go-round. Select one:
Select one: a. 2.5 N m
a. 4.123 rev/s b. 0.16 N m
b. 0.132 rev/s c. 15 N m
c. 0.244 rev/s d. 0.08 N m
d. 1.324 rev/s
52. Refer to a particle for which the position is defined by s(t) = 2 sin tj [tin
48. A hollow cylinder has a mass of 2 kg, a height of 1 m, an outer diameter radians]. What is the magnitude of the particles velocity at t = 4 rad?
of 1 m, and an inner diameter of 0.8 m. What is the cylinders mass moment Select one:
of inertia about an axis perpendicular to the cylinders longitudinal axis and a. 3.30
located at the cylinders end? b. 4.12
c. 2.75
d. 2.61
53. A 2 kg mass swings in a vertical plane at the end of a 2 m cord. When =

30o, the magnitude of the tangential velo9city of the mass is 1 m/s. What is
the tension in the cord at this position?
Select one:
a. 0.79 kg m2
b. 0.87 kg m2
c. 1.49 kg m2
d. 0.41 kg m2
49. Rigid link AB is 12 m long. It rotates counterclockwise about point A at 12

rev/min. A thin disk with radius 1.75 m is pinned at its center to the link at
point B. The disk rotates counterclockwise at 60 rev/min with respect to
point B. What is the maximum tangetial velocity seen by any point on the
disk?
Select one:
a. 19.6 N
b. 29.4 N
c. 18.0 N
d. 24.5 N
54. What total torque is apllied to the pulley?
Select one:
a. 45 m/s
b. 28 m/s
c. 33 m/s
d. 6 m/s
Select one:
50. A car is pulling a trailer at 100 km/h. A 5 kg cat riding on the roof of the a. O
car jumps from the car to the trailer. What is the change in the cat's b. 230 N m
momentum? c. 300 N m
Select one: d. 280 N m
a. -25 N s (loss)
b. 0 N s
c. 1300 N s(gain)
55. A fisherman cuts his boats engine as it is entering a harbor. The boat d. 11 N
comes to a dead stop with its front end touching the dock. The fisherman's
mass is 80 kg. He moves 5 m from his seat in the back to the front of the boat 60. If the car described in Prob.72 moves along a track that is banked 5o,
in 5 s, expecting to be able to reach the dock. if the empty boat has a mass of what is the smallest radius it can travel without skidding?
300 kg, how far will the fisherman have to jump to reach the dock? Select one:
Select one: a. 47 m
a. 1.3 m b. 6 m
b. 0.0 m c. 26 m
c. 5.0 m d. 18 m
d. 1.9 m
61. Find the force in member BC.
56. A cannonball of mass 10 kg is fired from a cannon of mass 250 kg. The
initial velocity of the cannonball is 1000 km/h. All of the cannon's recoil is
absorbed by a spring with a spring constant of 250 N/cm. What is the
maximum recoil distance of the cannon?
Select one:
a. 0.59 m
b. 0.35 m
c. 0.92 m
d. 0.77 m
57. The cylinder shown is acted on by couple M. Wall A is frictionless (&#181s

= 0), but the coefficeint of static friction between the cylinder and wall B is
&#181s = 0.3. The cylinder has a weigh of 200 N. What is the largest value of
the couple M for which the cylinder will not turn?
Select one:
a. 50 000 N (compression)
b. 50 000 N (tension)
c. 52 700 N (compression)
d. 16 700 N (tension)
Select one:
a. 96 N m 62. A projectile is fired from a cannon with an initial velocity of 1000 m/s and
b. 31 N m at an angle of 30o from the horizontal. What distance from the cannon will
c. 72 N m the projectile strike the ground if the point of impact is 1500 m below the
d. 48 N m point of release?
58. Whatb is the polar radius of gyration?
Select one:
a. 4.2 m Select one:
b. 4.9 m a. 90 800 m
c. 3.6 m b. 78200 m
d. 4.0 m c. 67300 m
d. 8200 m
59. Three concurrent forces act as shown.
63. Quantity of inertia possessed by an object or the proportion between
force and acceleration
Select one:
a. Mass
b. Moment of inertia
c. Velocity
d. Momentum
64. A varying force acts on a 40 kg weight as shown in the following force

versus time diagram. What is the object's velocity at t = 4 s if the object start
from
If the forces are in equilibrium, and F2 is 11 N, what is the magnitude of F1?
Select one:
a. 10 N
b. 8 N
c. 12 N
70. A 100 kg block is pulled along a smooth, flat surface by an external 500 N
force. If the coefficient of friction between the block and the surface is 0.15,
what acceleration is experienced by the block due to the external force?
Select one:
Select one: a. 4.33 m/s2
a. 0.30 m/s b. 3.23 m/s2
b. 0.075 m/s c. 5.00 m/s2
c. 0.15 m/s d. 3.80 m/s2
d. 0 m/s
71. A motorist is travelling at 70 km/h when he sees a traffic light in an
65. A I kg uniform rod 1 m long is suspended from the ceiling by a frictionless intersection 250 m ahead turn red. The light's red cycle is 15 s. The motorist
hinge. The rod is free to pivot. What is the product of inertia of the about the wanst to enter the intersection without stopping his vehicle, just as the light
pivot point? turns green. What uniform deceleration of the vehicle will just put the
Select one: motorist in the intersection when the light turns greens?
a. 0 kg m2 Select one:
b. 0.045 kg m2 a. 0.18 m/s2
c. 0.13 kg m2 b. 1.3 m/s2
d. 0.33 kg m2 c. 0.37 m/s2
d. 25 m/s2
66. Three forces act on a hook. Determine the magnitude of the resultant of
the forces. Neglect hook bending. 72. The nuts on a collar are each tightened to 18 N m torque. 17% of this
torque is used to overcome screw thread friction. The bolts have a nominal
diameter of 10 mm. The threads are a simple square cut with a pitch abgle of
15o. The coefficient of friction in the threads is 0.10. What is the
approximate tensile force in each bolt?
Select one:
a. 1250 N
b. 989 N
c. 1510 N Select one:
d. 1140 N a. 203 N
b. 1620 N
67. The support force exerted on an object in contact with another stable c. 405 N
object d. 132 N
Select one:
a. Normal force 73. During the time a compact disc (CD) accelerates from rest to a constant
b. Weight rotational speed of 477 rev/min, it rotates through an angular displacement
c. Tension of 0.250 rev. What is the angular acceleration of the CD
d. Gravity Select one:
a. 358 rad/s2
68. Refer to a particle whose curvilinear motions is represented by the b. 794 rad/s2
equation s = 20t + 4t2 - 3t3. What is particles initial velocity? c. 126 rad/s2
Select one: d. 901 rad/s2
a. 25 m/s
b. 20 m/s 74. A 6.0-kg block is released from rest 80m above the ground. When it has
c. 32 m/s fallen 60m its kinetic energy is approximately:
d. 30 m/s Select one:
a. 4800 J
69. What is the tension in cable AB? b. 1176 J
c. 3528 J
d. 120 J
75. A particle starting from rest experienced an acceleration of 3 m/s2 for 2 s.

The particle then returned to rest in a distance of 8 m. Assuming all
accelerations were uniform, what was the total time elapsed for the particles
motion?
Select one:
a. 5.33 s
Select one: b. 4.67 s
a. 250 N c. 2.67 s
b. 430 N d. 4.00 s
c. 870 N
d. 500 N
76. A rope passes over a fixed sheave as shown. The two rope ends are Select one:
parallel. A fixed load on one end of the rope is supported by a constant force a. 4.43 rad /s
on the other end. The coefficient of friction between the rope and the sheave b. 1.98 rad/s
is 0.30. What is the ratio of tensile forces in the two rope ends? c. 3.92 rad /s
d. 1.40 rad/s
83. A rigid body is subjecyed to three cfoncurrent, coplanar forces. What is

the minimum number of independent equations that are necessary to
establish the equilibrium conditions?
Select one:
a. 3
b. 2
Select one:
c. 1
a. 1.6
d. 0
b. 1.2
c. 1.1
84. Two meshing spur gears are arranged such that neither gear is turning
d. 2.6
and both are in equilibrium. Gear 1 has a radius of 4 cm. Gear 1's shaft carries
a torsional moment of 65 N m from an external motor. Gear 2 has a radius of
77. In an isolated system it does not change with time when there are no
6 cm. Assuming a 100% transmission efficiency, what torque is transmitted
forces acting on the system
by the shaft of gear 2?
Select one:
Select one:
a. displacement
a. 97.5 N m
b. force
b. 65 N m
c. momentum
c. 107 N m
d. position
d. 101 N m
78. The coeffecicient of friction between the brqake pad and drum is 0.3.
85. Determine the force in member AG for the pin-conneted truss shown.
Assuming that the beam supporting the cable drum is more than adequate
for the loads involved, what load,W, can be held stat5ionary?(Insert question
#12)
Select one:
a. 100 N
b. 180 N
c. 33 N
d. 90 N
79. The elevator in a 12--story building has a mass of 1000 kg. Its maximum
velocity and maximum acceleartion ar 2 m/s and 1 m/s2, respectively. A
paasenger with a mass of 75 kg stands on a bathroom scale in the elevator as Select one:
the elevator ascends at its maximum acceleration. what is the scale reading a. 37 500 N (tension)
just as the elevator reaches its maximum velocity? b. 31 500 N (compression)
Select one: c. 25 000 N (compression)
a. 886 N d. 50 000 N (tension)
b. 150 N
c. 75 N 86. What are the -and y-coordiantes of the centroid of the area?
d. 811 N
80. The braced frame shown is constructed with pin-connected members and
supports. All applied forces are horizontal. What is the force in the diagonal
member AB?(Insert question #10)
Select one:
a. 160 N
b. 250 N
c. 0
d. 200 N
81. An automobile travels on a perfectly horizontal, unblanked circular track

of radius r. The coefficient of friction between the tires and the track is 0.3. If
the car's velocity is 10 m/s, what is the smallest radius it may travel without
skidding?
Select one:
Select one:
a. 10 m
a. 3.50 cm ; 5.50 cm
b. 50 m
b. 3.93 cm ; 4.79 cm
c. 34 m
c. 4.00 cm ; 5.00 cm
d. 68 m
d. 3.40 cm ; 5.60 cm
82. A 10 kg block is resting on a horizontal circular disk (e.g., turntable) at a
87. An ideal spring is hung vertically from the ceiling. When a 2.0-kg block
radius of 0.5 m form the center. The coefficient of friction between the block
hangs at rest from it the spring is extended 6.0 cm from its relaxed length. A
and disk is 0.2. the disk begins to rotate with a uniform angular acceleration.
upward external force is then applied to the block to move it upward a
What is the minimum angular velocity of the plate that will cause the block to
distance of 16 cm. While the block is moving upward the work done by the
slip?
spring is
Select one:
a. -2.09 J
b. -1.75 J
c. -1.05 J
d. -0.52 J
88. Refer to a particle for which the position is defined by s(t) = 2 sin tj [tin
radians]. What is the magnitude of the particle's acceleartion at t = π?
Select one:
a. 2.00 Select one:
b. 2.56 a. 18 000 N (compression)
c. 4.00 b. 8000 N (tension)
d. 3.14 c. 8000 N (compression)
89. A satellite is placed in a circular orbit to observe the surface of Mars from
an altitude of 144 km. The equatorial radius of Mars is 3397 km. If the speed
of the satellite is 3480 m/s, what is the magnitude of the centripetal 94. A projectile whose mass is 10 g is fired directly upward from ground level
acceleration of the satellite? with an initial velocity of 1000 m/s. Neglect the effects of air resistance, what
Select one: will be speed of the projectile when it impacts the ground?
a. 2.99 m/s2 Select one:
b. 2.17 m/s2 a. 981 m/s
c. 3.42 m/s2 b. 1414 m/s
d. 2.60 m/s2 c. 1000 m/s
d. 707 m/s
intersection 250 m ahead turn red. The light's red cycle is 15 s. The motorist 95. The 285 kg plate shown is suspended horizontally by four wires of equal
wanst to enter the intersection without stopping his vehicle, just as the light loenght, and the tension of each wire is equal. If wire D snaps, the tension in
turns green. What uniform deceleration of the vehicle will just put the the three remaining wires is redistributed. Determined the tension in each
motorist in the intersection when the light turns greens? wire after wire D snaps.
Select one:
a. 0.37 m/s2
b. 25 m/s2
c. 0.18 m/s2
d. 1.3 m/s2
91. The location of a particle moving in the -y plane is given by the

parametric equations = t2 + 4t and y =(1/4)t4 - 60t, where and y are in
meters and t is in seconds. What I sthe particles velocity at t = 4 s?
Select one:
a. 16.0 m/s
b. 8.95 m/s
c. 11.3 m/s
d. 12.6 m/s
92. The two cables shown carry a 100 N vertical load. What is the tension in Select one:
cable AB? a. TA /= 699 N ; TB /= 699 N ; TC /= 1398 N
b. TA /=1398 N ; TB /= 1398 N ; TC /= 0 N
c. TA /
d. TA /= 1398 N ; TB /= 0 N ; TC /= 1398 N
e. TA = 699 N ; TB = 1398 N ; TC = 699 N
96. Identfy the zero-force members in the truss shown.
Select one:
a. 80 N
b. 60 N
c. 50 N
d. 40 N
93. The pedestrian bridge truss shown has 10 000 N applied loads at points
Select one:
I,J, and K. What is the force in member IJ?
a. AB,GH,GI,HI,EG
b. AB,GH
c. AB,HI,GI
d. GI,HI
97. Three coplanar forces are in equilibrium on the surface of a steel plate, as
shown. Two of the forces are known to be 10 N. What is the angle, , of the
third force?
Select one:
a. 82.5o Select one:
b. 26.7o a. 300 000N (tension)
c. 53.8o b. 50 000 N (tension)
d. 7.50o c. 37 500 N (tension)
98. A signal arm carries two traffic signals and a sign, as shown. The siognals
and sign are rigidly attached to the arm. Each traffic signal is 0.2 m2 in frontal 101. A projectile has an initial velocity of 110 m/s and a launch angle of 20o
area and weighs 210 N. The sign weighs 60 N/m2. The design wind pressure from the horizontal. The surrounding terrain is level, and air friction is to be
is 575 N/m2. The maximum moment that the connection between the arm disregarded. What is the horizontal distance traveled by the projectile?
and pole can withstand due to wind is 6000 N m , and the maximum Select one:
permitted moment due to the loads is 4000 N m. As limited by moment on a. 1200 m
the connection, what is the maximum area of the sign? b. 80 m
c. 800 m
d. 400 m
102. QUEST032::Figure shows a uniform disk, with mass M = 2.5 kg and

radius R = 20 cm, mounted on a fixed horizontal axle. A block with mass m =
1.2 kg hangs from a massless cord that is wrapped around the rim of the disk.
Find the acceleration of the falling block. The cord does not slip, and there is
no friction at the axle.
Select one:
a. -4.8 m/s2
b. 4.8 m/s2
Select one: c. -3.2 m/s2
a. 5.65 m2 d. 3.2 m/s2
b. 1.15 m2
c. 8.03 m2 103. Find the velocity of block A 2.5 s after the blocks are released.
d. 1.04 m2
99. A uniform thin disk has a radius of 30 cm and a mass of 2 kg. A constant
force of 10 N is applied tangentially at a varying, but unknown, distance from
the center of the disk. The disk accelerates about its axis at 3t rad/s2. What is
the distance from the center of the disk at which the force is apllied at t = 12
s? Select one:
a. 3.5 m/s
b. 0 m/s
c. 4.4 m/s
d. 4.9 m/s
104. A box has uniform density and a total weight of 600 N. It is suspended
by three equal-length cables, AE,BE, and CE, as shown. Point E is 0.5 m
directly above the center of the box's top surface. What is the tension in
cable CE?
Select one:
a. 108 cm
b. 32.4 cm
c. 54.0 cm
d. 36.0 cm
100. Four bolts (not shown) connect support A to the ground. Determine the
design load for each o fthe four bolts.
Select one: Select one:
a. 400 N a. 720 N to 1360 N
b. 200 N b. 560 N to 1360 N
c. 128 N c. 720 N to 1510 N
d. 370 N d. 670 N to 1440 N
105. The five forces shown act at point A. What is the magnitude of the 109. A model T-beam is constructed from five balsa boards. Refer to the
resultant force? illustration for the as-built dimensions. What is the approximate centroidal
Select one: moment of inertia about an axis parallel to the -axis?
a. 234 N
b. 182 N
c. 156 N
d. 32 N
106. Determine the reaction at point C.
Select one:
a. 660 cm4
b. 600 cm4
c. 500 cm4
d. 560 cm4
Select one:
a. -417 N (down) 110. A 3 kg disk with a diameter of 0.6 m is rigidly attached at point B to 1 kg
b. + 83 N (down) rod 1 m in length. The rod-disk combination rotates around point A. What is
c. +333 N (up) the mass moment of inertia about A for the combinanation
d. -83 N (down)
107. A 50 kg cylinder has a height of 3 m and a radius of 50 cm. The cylinder

sits on the -axis and is oriented with its major axis parallel to the y-axis. What
is the mass moment of inertia about the -axis?
Select one:
a. 41 kg mo
b. 16 kg mo
c. 150 kg mo
d. 4.1 kg mo
108. A rope is wrapped over a 6 cm diameter pipe to support a bucket of

tools being lowered. The coefficient of friction between the rope and the Select one:
pipe is 0.20. The combined mass of bucket and tools is 100 kg. What is the a. 0.56 kg m2
range of force that can be applied to the free end of the rope such that the b. 0.87 kg m2
bucket remains stationary? c. 047 kg m2
d. 3.7 kg m2
111. A 2.5-kg ball and a 5.0-kg ball have an elastic collision. Before the
collision, the 2.5-kg ball was at rest and the other ball had a speed of 3.5 m/s.
What is the kinetic energy of the 2.5-kg ball after the collision?_____"
Select one:
a. 27 J
b. 14 J
c. 5.8 J
d. 8.1 J
112. A spring has a constant of 50 N/m. The spring is hung vertically, and a
mass is attached to its end. The spring end displaces 30 cm from its
equilibrium position. The same mass is removed from the first spring and
attached to the end of a second (different) spring, and the displacement is 25
Select one:
cm. What is the spring constant of the second spring?
a. -6500 N m (counterclockwise)
Select one:
b. 12 000 N m (clockwise)
a. 63 N/m
c. 3500 N m (clockwise)
b. 56 N/m
d. -9000 N m (counterclockwise)
c. 60 N/m
d. 46 N/m
117. What is the magnitude of the forces that constitute the moment?
113. An isolated parallel-platmoment of nertia about the composite

centroid?
Select one:
a. 8.3 N
b. 6.3 N
Select one: c. 4.2 N
a. 1530 m4 d. 2.1 N
b. 1020 m4
c. 2410 m4 118. A 28 mm diameter circuit area is reduced by a 21 mm diameter circular
d. 1260 m4 area that is cut out. Both circles are tangent to the y-axis. What is the
moment of inertia about the y-axis of the remaining (shaded) area?
114. An area is a composite of a semicircle and a triangle, as shown. What is
the distance between the -axis an dthe centroid? Select one:
a. 103 000 mm4
b. 330 000 mm4
c. 1340 000 mm4
d. 20 600 mm4
119. What is the coefficient of friction between the plane and the block?
Select one:
a. 0.15
b. 0.78
c. 0.22
d. 0.85
Select one: 120. Two blocks are connected over a pulley. The mass of block A is 10 kg and
a. 3.46 mm the coefficient of kinetic friction between A and the incline is 0.20. Angle θ of
b. 3.68 mm the incline is 30°. Block A slides down the incline at constant speed. What is
c. 5.35 mm the mass of block B
d. 4.28 mm
115. Find the velocity at position B.
Select one:
Select one: a. 2.1 kg
a. 9.83 m/s b. 5.0 kg
c. 3.7 kg
b. 6.95 m/s
c. 2.41 m/s d. 3.3 kg
d. 4.12 m/s
121. The center of gravity of a roller coaster car is 0.5 m above the rails. The
116. In the structure shown, the beam is pinned at point B. Point E is a roller rails are 1 m part. What is the maximum speed that the car can travel around
support. The beam is loaded with a distributed load from point A to point B an unbanked curve of radius 15 m without the inner wheel losing contact
of 400 N/m, a 500 N m couple at point C, and a vertical 900 N force at point with the top of the rail?
D. If the distributed load and the vertical load are removed and replaced with Select one:
a vertical upward force of 1700 N at point F, what moment at point F would a. 8.58 m/s
be necessary to keep the reaction at point E at the same?. b. 17.2 m/s
c. 24.2 m/s d. 7.2 m
d. 12.1 m/s
127. The maximum kinetic and potential energy of a spring when stretched at
122. Two particles are fixed to an x axis : particle 1 of charge -2.00 x 10-7 C at various displacements is equal to
x=6.00 cm and particle 2 of charge +2.00 x 10-7 C at x=21.0 cm. Midway Select one:
between the particles, what is their net electric field in unit vector notation?
a. 1 /2Kx2
Select one:
a. -3.20 X 105 N/C i ̂ b. mg
b. -6.39 x 105 N/C i ̂ c. –mx2
c. -4.00 x 105 N/C i ̂ d. None of the choices
d. -2.40 x 105 N/C i ̂
123. Find the force in member DE.

128. A car with a mass of 1530 kg tows a trailer (mass of 200 kg) at 100 km/h.
What is the total momentum of the car-trailer combination?

Select one:
a. 46 000 N s
b. 22 N s
c. 37 N s
d. 48 000 N s
Select one: 129. If W = 80 N, what are the reactions

a. 8800 N (tension)
at pont A?
b. 10 000 N (compresiion)
c. 0
d. 6300 N (tension)
124. A force is defined by the vector A = 3.5 i - 1.5 j + 2.0k. i,j, and k are unit
vectors in the -,y-, and z-direction, respectively. What is the angle that the
force makes with the positive y-axis?
Select one:
a. 69.6o Select one:
b. 20.4o a. 27 i N - 100j N
c. 110o
b. -27 i N - 100j N
d. 66.4o
c. 0 i N+ 180j N
125. The position (in radians) of a car travelling around a curve is described d. 0 i N + 100j N
by the following function of time (in seconds). What is the angular velocity at
t = 3 s?
130. A parallel-plate air capacitor is made from two plates 0.070 m square,
Select one:
a. -16 rad/s spaced 6.3 mmapart. What must the potential difference between the plates
b. -4 rad /s be to produce an energydensity of 0.037 J/m3?
c. 15 rad/s Select one:
d. 11 rad/s
a. 470 V
126. A stone is dropped down a well. 2.47 s after the stone is realeased, a b. 370V
splash is heard. If the velocity of sound in air is 342 m/s, find the distance to c. 270 V
the surface of the water in the well. d. 570 V
Select one:
a. 38 m
b. 2.4 m
c. 28 m
131. Block d side freely on the homogeneous bar and experiences a c. 0.40 rad/s2
gravitation force of 50 N. Homogeneous bar AB experiences a gravitational d. 16 rad/s2
force of 25 N. What is the force between the bar and block D?
135. A 6 kg sphere moving at 3m/s collides with a 10 kg sphere traveling 2.5
m/s in the same direction. The 6 kg ball comes to a complete stop after the
collision. What is the new velocity of the 10 kg ball immediately after the
collision?
Select one:
a. 0.5 m/s
b. 5.5 m/s
c. 2.8 m/s
d. 4.3 m/s
136. Which type of load is not resisted by a pinned joint?

Select one:
Select one:
a. 21 N
a. compression
b. 19 N
b. moment
c. 15 N
c. shear
d. 28 N
d. axial

137. What is the resultant R of the system of forces shown?
intersection 250 m ahead turn red. The light's red cycle is 15 s. The motorist
wanst to enter the intersection without stopping his vehicle, just as the light
turns green. If the vehicle decelerates at a constant rate of 0.5 m/s2, what
will be its speed when the light turns green?
Select one:
a. 52 km/h
b. 63 km/h
c. 43 km/h
d. 59 km/h
133. Which of the structures shown is statically determinant and stable?

Select one:
Select one:
a.
a. I and III
b. I and IV
c. I only b.
d. II and III
134. The rotor of a steam turbine is rotating at 7200 rev/min when the steam
supply is suddenly cut off. The rotor decelerates at a constant rate and comes
to rest after 5 min. What was the angular deceleration of the rotor?
Select one:
a. 2.5 rad/s2
b. 5.8 rad/s2 c.
142. A disk-shaped bofy with a 4 cm radius has a 320 N force acting through
the center at an unknown angle , and two 40 N loads acting as a couple, as
shown. All of these forces are removed and replaced by a single 320 N force
at point B, parallel to the original 320 N force. What is the angle ?
d.
138. If the frame is pinned so that it rotates around point B, what

counteracting moment must be applied at point A to put the frame in
equilibrium?
Select one:
a. 0o
b. 7.6o
c. 15o
d. 29o
143. A block with a mass of 150 kg is pulled over a horizontal surface by a

cable guided by a pulley as shown. The coefficients of friction are 0.58
between the surface and the block, and 0.90 between the cable and the
pulley. What force,F, must be applied to the cable for the block to move?
Select one:
a. 1150 N m
b. 1240 N m
c. 650 N m
d. 890 N m
140. An isolated parallel-plate capacitor (not connected to a battery) has a

charge of Q = 2.9 × 10-5 C. The separation between the plates initially is d =
1.2 mm, and for this separation the capacitance is 3.1 × 10-11 F. Calculate the Select one:
work that must be done to pull the plates apart until their separation a. 2500 N
becomes 5.3 mm, if the charge on the plates remains constant. The capacitor b. 900 N
plates are in a vacuum c. 1700 N
Select one: d. 2200 N
a. 5 J
b. 46 J 144. Refer to a particle whose curvilinear motions is represented by the
c. 48 J equation s = 20t + 4t2 - 3t3. What is the acceleration of the particle at time t
d. 47 J = 0?
Select one:
141. A wheel with a radius of 80 cm rolls along a flat surface at 3 m/s. If arc a. 2 m/s2
AB on the wheels perimeter measures 90o, what is the velocity of point A b. 5 m/s2
when point B contacts the ground? c. 3 m/s2
Select one: d. 8 m/s2
a. 3.39 m/s
b. 3.75 m/s 145. A playground merry-go-round has a radius of 3.0m and a rotational
c. 4.24 m/s inertia of 600 kg m2.It is initially spinning at 0.80 rad/s when a 20-kg child
d. 3.00 m/s crawls from the center to the rim. When the child reaches the rim the
angular velocity of the merry-go-round is
Select one:
a. 0.80 rad/s radius of 1 m. What is the instantaneous angular velocity ( in rad/s) of the
particle?
b. 1.04 rad/s
Select one:
c. 0.73 rad/s a. t2+cost+ 3 In |csct|
d. 0.62 rad/s b. t2-cost+ 3 In |csct|
c. t2-cost+ 3 In |sint|
146. Traffic travels at 100 km/h around a banked high-way curve with a d. t2+cost+ 3 In |sint|
radius of 1000m. What banking angle is necessary such that friction will not 152. A golfer on level ground attempts to drive a gof ball across a 50 m wide
be required to resist the centrifugal force? pond, hitting the ball so that it travels initially at 25 m/s. The ball travels at an
Select one: initial angle of 45o to the horizontal plane. How far will the golf ball travel,
a. 46o and does it clear the pond?
Select one:
b. 2.8o
a. 58 m; the ball clears the pond
c. 4.5o b. 32 n; the ball does not clear the pond
d. 1.4o c. 45 m; the ball does not clear the pond
d. 64 m ; the ball clears the pond
147. Resolve the 300 N force into two components, one along line p and the
153. A 2000 kg car pulls a 500 kg trailer. The car and trailer accelerates from
other along line Q. (F, P and Q are coplanar.) 50 km/h to 75 km/h at rate of 1 m/s2. What linear impules does the car
Select one: impart on the trailer?
a. Fp = 126 N ; FQ /= 272 N Select one:
b. Fp = 226 N ; FQ = 135 N a. 12 500 N s
b. 3470 N s
c. Fp = 186 N ; FQ /= 232 N
c. 17400 N s
d. Fp = 226 N ; FQ /=212 N d. 8680 N s
148. Determine the force in member BC. 154. What are R1 and R2? (insert question #11)
Select one:
a. 1250 N
b. 4000 N
c. R1 /
d. 1000 N; R2 /
e. R1 /
f. R1 /
g. 3750 N; R2 /
h. 1250 N
155. QUEST029::Two blocks are connected over a pulley. The mass of block A
is 10 kg and the coefficient of kinetic friction between A and the incline is
0.20. Angle θ of the incline is 30°. Block A slides down the incline at constant
speed. What is the mass of block B
Select one:
a. 1000 N (compression)
b. 2500 N (tension)
c. 1500 N (tension)
d. 0
149. The statement “An object with constant momentum is in a state of

equilibrium” is
Select one:
a. Insufficient data
b. False Select one:
c. Partly true a. 3.7 kg
d. True b. 3.3 kg
c. 2.1 kg
150. The velocity (in m/s) of a falling ball is described by the equation v = 32 + d. 5.0 kg
t + 6t2. What I sthe acceleration at time t = 2 s?
Select one: 156. A mass of 10 kg is suspended from a vertical spring with a spring
a. 25 m/s2
b. 9.8 m/s2 constant of 10 N/m. What is the period of vibration?
c. 58 m/s2 Select one:
d. 32 m/s2 a. 6.3 s
b. 0.30 s
c. 0.60 s
151. A particle has a tangential acceleration of at (represented by the
equation given) when it moves around a point in a curve with instantaneous d. 0.90 s
157. What is the reaction at point A for the simply supported beam shown? service stations, this force is usually generated with the use of compressed
air.)
Select one:
Select one:
a. 1.00 X 102 N
b. 40 N
c. 1.00 x 103 N
a. d. 225 N
b. None of the choices 162. A disk rolls along a flat surface at a constant speed of 10 m/s. Its
diameter is 0.5 m. At a particular instant, point P on the edge of the disk is
45o from the horizontal. What is the velocity of point P at that instant?
Select one:
a. 10.0 m/s15.0 m/s16.2 m/s
b. 18.5 m/s
163. For the reciprocating pump shown, the radius of the crank is r = 0.3 m,
c. and the rotational speed is n = 350 rpm. What is the tangetial velocity of
point A on the crank corresponding to an angle of = 35o from the horizontal?
Select one:
a. 10 m/s
b. 1.1 m/s
c. 0 m/s
d. d. 11 m/s
158. A bent beam is acted upon by a moment and several concentrated 164. What is the -coordinate of the centroid of the curve y = cos between = 0
forces, as shown. Find the missing force F and distance that will maintain = /2?
equilibrium on the member shown. a. pi/4
b. pi/6
c. 1 – 2/pi
d. pi/2 – 1
165. QUEST031::Two particles are fixed to an x axis : particle 1 of charge -

2.00 x 10-7 C at x=6.00 cm and particle 2 of charge +2.00 x 10-7 C at x=21.0
cm. Midway between the particles, what is their net electric field in unit
vector notation?
Select one:
a. -6.39 x 105 N/C i ̂
b. -2.40 x 105 N/C i ̂
c. -4.00 x 105 N/C i ̂
d. -3.20 X 105 N/C i ̂
166. Refer to a particle whose curvilinear motions is represented by the

Select one:
equation s = 20t + 4t2 - 3t3. What is the maximum speed reached by the
a. F = 20 N ; = 0.2 m particle?
b. F = 10 N ; = 0.6 m Select one:
c. F = 20 N ; = 0.4 m a. 34.6 m/s
b. 27.9 m/s
d. F = 5 N ; = 0.8 m
c. 48.0 m/s
d. 21.8 m/s
159. A car travels around an unbanked 50 m radius curve without skidding.
167. A torsional pendulum consists of a 5 kg uniform disk with a diameter of
The coefficient of friction between the tires and road is 0.3. What is the car's
50 cm attached at its center to a rod 1.5 m in length. The torsional spring
maximum speed?
constant is 0.625 N.m/rad. Disregarding the mass of the rod, what is the
Select one:
natural frequency of the torsional pendulum?
a. 54 km/h
Select one:
b. 25 km/h
a. 1.0 rad/s
c. 44 km/h
b. 1.4 rad/s
d. 14 km/h
c. 1.2 rad/s
d. 2.0 rad/s
160. A force that is directed away or towards the origin
168. The position (in radians) of a car travelling around a curve is described
Select one:
by the following function of time (in seconds). What is the angular
a. Frictional force
acceleration at t = 5 s?
b. Uniform force
Select one:
c. Central force
a. 4 rad/s2
d. Normal force
b. 26 rad/s2
c. 30 rad/s2
d. 6 rad/s2
161. QUEST030::The small piston of a hydraulic lift has a cross-sectional area
of 3.00 cm2, and its large piston has a cross-sectional area of 200 cm2 . What
«May the odds be ever in your favor.»
force must be applied to the small piston for it to raise a load of 15.0 kN? (In

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CHEMISTRY passes through a tube and displaces water in an inverted,

DRILL 1 water-filled bottle. Which of the following items may be

Question 3 1 points Question 4 2 points

Question 1 1 points Question 1 2 points

Question 6 1 points Question 2 2 points

Question 2 2 points Question 10 1 points

Question 8 1 points Question 9 2 points

Question 1 2 points Question 4 2 points

Question 10 2 points Question 9 2 points

Question 3 2 points Question 3 1 points

Question 2 5 points Question 8 1 points

Question 25 1 points Question 31 5 points

Question 51 1 points Question 56 2 points

Question 82 5 points Question 87 1 points

Question 117 2 points Question 122 2 points

Question 125 2 points Question 130 2 points

Question 137 5 points Question 142 2 points

Question 178 5 points Question 183 2 points

Question 205 (1 point)

4) The reaction system

5) Complete the following statement: A catalyst

6) The following reaction is at equilibrium at one

NaOH(s) + CO2(g) ↔ NaHCO3(s)

Which, if any, of the following actions will decrease the

7) A reaction mechanism usually is

96) Galvanized iron is steel coated with _____.

a. Fusion reaction 115) Consider the equilibrium reaction: H2(g) +

CS2(g) + 4H2(g) ↔ CH4(g) + 2H2S(g)

is at equilibrium. Which of the following statements describes

Which one of the following statements about fission and

Basic Engineering Correlation (Physics Reviewer)

1. The system shown is in static equilibrium. Find W.

4. The structure shown is formed of three separate solid aluminum cylindrical

6. What are R1 and R2? (insert question #11)

Select one: Select one:

8. A turntable capable of angularly accelerating at 12 rad/s2 needs to be

9. A 550 kg mass initially at rest acted upon by a force of 50 et N. What are

12. One newton is the force required to

20. Find the distance between position B and C.

30. What is the reaction at point B?

32. For a force to do work it must be ____ the displacement

34. A perfect sphere moves up a frictionless incline. Which of the following

44. A uniform rod (AB) of length L and weight W is pinned at point C. An

47. A 47.2-kg child is standing on the outer edge of a merry-go-round that

53. A 2 kg mass swings in a vertical plane at the end of a 2 m cord. When =

49. Rigid link AB is 12 m long. It rotates counterclockwise about point A at 12

54. What total torque is apllied to the pulley?

57. The cylinder shown is acted on by couple M. Wall A is frictionless (&#181s

58. Whatb is the polar radius of gyration?

64. A varying force acts on a 40 kg weight as shown in the following force

75. A particle starting from rest experienced an acceleration of 3 m/s2 for 2 s.

83. A rigid body is subjecyed to three cfoncurrent, coplanar forces. What is

81. An automobile travels on a perfectly horizontal, unblanked circular track

91. The location of a particle moving in the -y plane is given by the

96. Identfy the zero-force members in the truss shown.

102. QUEST032::Figure shows a uniform disk, with mass M = 2.5 kg and

106. Determine the reaction at point C.

107. A 50 kg cylinder has a height of 3 m and a radius of 50 cm. The cylinder

108. A rope is wrapped over a 6 cm diameter pipe to support a bucket of

113. An isolated parallel-platmoment of nertia about the composite

115. Find the velocity at position B.

123. Find the force in member DE.

What is the total momentum of the car-trailer combination?

Select one: 129. If W = 80 N, what are the reactions