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Mathcad Vle Eos Svna7
Mathcad Vle Eos Svna7
Mathcad Vle Eos Svna7
⎯⎯→
a
Preliminary values: q := (14.34) (Used for initial iteration)
b⋅ R⋅ T
⎛ 11.9832 ⎞
q=⎜
⎝ 15.5722 ⎠
Updated values used in iteration:
⎯⎯→
b⋅ Psat ⎛ 2.8275 × 10− 3 ⎞
β := (14.33) β =⎜
R⋅ T ⎜ 4.4078 × 10− 4
⎝ ⎠
Solve blocks with initial estimates: Zliq := β 1 Zvap := 1
(Species 1)
Zvap − β 1
Given Zvap = 1 + β 1 − q1⋅ β 1⋅ (14.36)
( Zvap + ε ⋅ β 1) ⋅ ( Zvap + σ ⋅ β 1)
zvap1 := Find ( Zvap)
1 + β 1 − Zliq
Given Zliq = β 1 + ( Zliq + ε ⋅ β 1) ⋅ ( Zliq + σ ⋅ β 1) ⋅ (14.35)
q1⋅ β 1
zliq1 := Find ( Zliq)
Zvap − β 2
Given Zvap = 1 + β 2 − q2⋅ β 2⋅ (14.36)
( Zvap + ε ⋅ β 2) ⋅ ( Zvap + σ ⋅ β 2)
zvap2 := Find ( Zvap)
1 + β 2 − Zliq
Given Zliq = β 2 + ( Zliq + ε ⋅ β 2) ⋅ ( Zliq + σ ⋅ β 2) ⋅ (14.35)
q2⋅ β 2
zliq2 := Find ( Zliq)
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
⎛ 1 ⋅ ln ⎛ zvap + σ ⋅ β ⎞ ⎞ ⎛ 2.9125 × 10− 3 ⎞
Ivap := ⎜ ⎜ (6.65b) Ivap = ⎜
⎝ σ − ε ⎝ zvap + ε ⋅ β ⎠ ⎠ ⎜ 4.4343 × 10− 4
⎝ ⎠
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
⎛
( zvap − zliq) + ln ⎜
zliq − β ⎞ ⎛ 12.0364 ⎞ FINAL
⎝ zvap − β ⎠ (14.37) q = ⎜
q := ⎝ 15.4551 ⎠ VALUES
Ivap − Iliq
_________________________________________________________
Subsequent calculations require values of Z and I for the PURE
LIQUID species at system pressure P. Because P is to be
determined, an iterative procedure is initiated by a starting value for
P. A logical initial choice is the sum of the pure-species vapor
pressures at the known temperature T, each weighted by its known
liquid-phase mole fraction.
CURRENT VALUE OF PRESSURE: P := 1.3576 (Shown is the final
converged value)
⎯→
b⋅ P ⎛ 2.4311 × 10− 3 ⎞
β := (14.40) β =⎜
R⋅ T ⎜ 8.5335 × 10− 4
⎝ ⎠
Solve block with initial estimate: Zliq := β 1
(Species 1)
1 + β 1 − Zliq
Given Zliq = β 1 + ( Zliq + ε ⋅ β 1) ⋅ ( Zliq + σ ⋅ β 1) ⋅ (14.35)
q1⋅ β 1
zliq1 := Find ( Zliq)
Solve block with initial estimate: Zliq := β 2
(Species 2)
1 + β 2 − Zliq
Given Zliq = β 2 + ( Zliq + ε ⋅ β 2) ⋅ ( Zliq + σ ⋅ β 2) ⋅ (14.35)
q2⋅ β 2
zliq2 := Find ( Zliq)
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
⎛
Iliq := ⎜
1 ⎛
⋅ ln ⎜
zliq + σ ⋅ β ⎞⎞ (6.65b)
⎝ σ − ε ⎝ zliq + ε ⋅ β ⎠ ⎠
⎛ 3.0556 × 10− 3 ⎞ ⎛ 0.5203 ⎞
zliq = ⎜ Iliq = ⎜ (At pressure P)
⎜ 1.0047 × 10− 3 ⎝ 0.5476 ⎠
⎝ ⎠
bliq⋅ P −3
β liq := (14.40) β liq = 1.2421 × 10
R⋅ T
qliq := x1⋅ q1 + x2⋅ q2 qliq = 14.6127 (initial estimate)
Must update qliq as calculation progresses:
1 ⎛ zliq + σ ⋅ β liq ⎞
Iliq := ⋅ ln ⎜ (6.65b) Iliq = 0.5374
σ−ε ⎝ zliq + ε ⋅ β liq ⎠
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯→
⎡ 1 ⎡ ⎛ zliq − β liq ⎞ ⎤⎤
⋅ ( zliq − 1) − ln ⎜
b
qbarliq := ⎢ ⋅ ⎢1 − zliq + + q⋅ Iliq − lngam⎥ ⎥ (14.57)
⎣ Iliq ⎣ bliq ⎝ zliq − β ⎠ ⎦⎦
⎛ 10.3080 ⎞
qbarliq = ⎜ qliq := x1⋅ qbarliq + x2⋅ qbarliq (14.58)
⎝ 15.0975 ⎠ 1 2
y2 := 1 − y1
blv⋅ P −3
β lv := (14.40) β lv = 1.7205 × 10
R⋅ T
1 ⎛ zlv + σ ⋅ β lv ⎞
Ilv := ⋅ ln ⎜ (6.65b) Ilv = 0.5258
σ−ε ⎝ zlv + ε ⋅ β lv ⎠
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯→
⎡ 1 ⎡ ⎛ zlv − β lv ⎞ ⎤⎤
⋅ ( zlv − 1) − ln ⎜
b
qbarvap := ⎢ ⋅ ⎢1 − zliq + + q⋅ Iliq − lngam⎥ ⎥ (14.59)
⎣ Ilv ⎣ blv ⎝ zliq − β ⎠ ⎦⎦
bvap⋅ P −3
bvap := y1⋅ b1 + y2⋅ b2 β vap := β vap = 1.7205 × 10
R⋅ T
Given
Zvap − β vap
Zvap = 1 + β vap − qvap⋅ β vap⋅ (14.39)
( Zvap + ε ⋅ β vap) ⋅ ( Zvap + σ ⋅ β vap)
zvap := Find ( Zvap) zvap = 0.9798
1 ⎛ zvap + σ ⋅ β vap ⎞ −3
Ivap := ⋅ ln ⎜ (6.65b) Ivap = 1.7529 × 10
σ−ε ⎝ zvap + ε ⋅ β vap ⎠
______________________________________________________
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯→
lnφhatvap := ⎡⎢ ⋅ ( zvap − 1) − ln zvap − β vap − qbarvap⋅ Ivap⎤⎥
( )
b
(14.50)
⎣ bvap ⎦
⎯⎯⎯→
lnφhatvap ⎛ 0.9752 ⎞
φhatvap := e φhatvap = ⎜
⎝ 0.9862 ⎠
⎯⎯⎯ →
φhatliq ⎛ 2.2305 ⎞
K := (14.53) K =⎜
φhatvap ⎝ 0.5977 ⎠
Σ := x1⋅ K1 + x2⋅ K2 Σ = 1.0000 (converged value) (14.52)
y1 = 0.5496 P = 1.3576
P ( exp) = 1.3564