July, 2008 - Which ofthe faliowing postulates concerning 5, Dalion's Atomic Theory is knowa to be correct by moder theory? (A) Atoms are small, (B) Atoms of en elernent are identical, (©) Atoms of one element have the same mass. (D) Atoms are indivisible particles of elements, ‘What is the average relative atomic mass of bromine, given the following isotopic messes and relativeabundance? ™Br-505% — Br «49.5% 7899 @) 79.90 © 199 ©) 8001 ‘When an isotope, X, is bombarded with a nevtronthe isotoge FLiandanalpka particls — ; are produced, Theequationis as follows: ~ a Xt jn ti do Isotope X is MOST tikely 8, 4B 8 YB © te ©) sui Which of the folowing characteristics of ‘esygen BEST explains why the frst onisation energy of oxygen is lower than that of nitrogen? (A) Asmatteratomie radius (B) — Greatershielding by inner cleeteons (©) Greater effective nuoteat chexge (©) Reputsion between the paired 2p electrons Which of the following pairs of efements Would be expetted to form the compound with ths MOST ionié character? @) Lisner ) Lieier ©: ‘RbadF ©) RoandI ‘The van der Wail” forces consist oF (A) permnent dipole- permanent dipole interactions . ®) induced dipote - induced dipole intnracfons (©) _ remanent dipole - induced dipole covalent interactions () dipole-dipole; dipole - induced dipoie Tonic interactions vo ‘The bond angles in the PH, molecule ars the same as that of NCI,. Its shape would therefore be A) fineae @) octehedral ©) pyramidal ©) tetrahedral ‘The following equation shows the preduction of emrhonia, N.@ +38,@ = 2H) 1f 10 era’ of nitrogen reacts with 30 em of hydrogen at s.tp., what volume of NEL, is produced? ) lcm? ®) Sem? © Wom? ©) 40cm10. a. ae Sodium azide, NoN, is used in air bags for vars, Onheating, it decomposes into sodiyma. andnitrogon, ‘What -volyme of nitfogen, ¢t room temperature, would be produced by heating ‘one mole of sodiym azide? A) 244m B 36cm © 48dm ©) Rem ‘The simplest formula fora compound that contains 50% $ and 50% O by mass is A $0 ® 39 ©) 80, ©) so Which ofthe following conversions requiea > reducingagent? 1 NO,-+N,0> Te Fe sper IL H,0,+0; NONE, : @ Land If only ®) — TandIVonly (© thandiiloniy ©) TMandiVoniy 12, Which ofthe following diagrims correctly represents the behieviout ofa fixed mess of ‘en ideal gas at constant tempersture? a a Ls o . « ¥ . P © v RB oea4. Which of thie following is NOT an 15, What is the standard heat of reaction endothermic process? (jeg) at 101.325 kPa of pressure and 298 forthe equation given below? ® — Ieomelting (8) Waterbolling Zoot Cy** (oq) + 24 aa) + Gu) (©) Waterevaporating ©) Water vapoyreondensing BE ace, = PEA KF mol for CH . + OHNE 152.4 by mol fer Za 14, The equation which represents the enthalpy AR amma 9 foro en ofatorisation of bromine is (@) }aI7KImok 1 ®B) — +88.0kF mol A FB, > B® ( -88.0kimot! 4 (0) -217kKimot* . ©) Fer) +Br@) . . ©) Brg) + 2Brée) ©) Br) > 2Br(@) ‘Toni 16 refers tothe following reaction which ogeus in the presence of dilute acid, CH,COCH, (aq) +I, (aq) + CHL COCK, (aq) +H" (2a) + Fea) 16. Iftherate equation forthereactionis . / me k[CH,COCH, (aq)] {H'Gq)], which of the following BEST illustrates the slow ° on il I (A) CH, —C— CH, + H + CH.— C—CH, : @ 2 1 _ ll ®) cic —cu, + scun¢ CK e ° ; I i | () CH-O--CH, + F + CH,~ C—cH, ® ° on Il . i = (©) CH. C—CH, + L+H'» CH C—CH, i