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CAPE Chemistry 2014 U1 P1 PDF
CAPE Chemistry 2014 U1 P1 PDF
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CAPE Chemistry U1 P1
1. Which of the following factors increases the Ilem ? refers to the following graph which
first ionization energY of an dtom? shows the log of successive ionization
energies for ten electrons of an element, P.
(A) Greater nuclear charge
$o
(B) Larger atomic radius L
q)
E5
(C) Larger number ofvalence electrons
(D) Increased screening bY inner E+
6l
electrons N
EJ
h0t
:l
2 3 4,5 6 7 8 9 l0
Number of electrons lost
(A) chlorine
(B) magnesium
(C) neon
(D) sodium
q)
ql
q)
c)
30 35 40 45 50 55 60 65 70 7s E0
mJe
Item 4 refers to the following sketch which 6. The bond angles in the PH, molecule are
shows the variation of the boiling points of the same as that of NClr. Its shape would
the hydrides of Group V. BEST be described as
(A) bipyramidal
U
(B) pyramidal
(c) tetrahedral
c (D) trigonal
00
4. Ammonia has the highest boiling point (A) They react to produce 5 dm3 of
because water.
(B) They react completely with each
(A) the N-H bond is the shortest and other.
strongest (c) They possess the same amount of
(B) there are more van der Waals forces kinetic energy.
between NH, molecules (D) They contain the same number of
(c) there is hydrogen bonding between molecules.
NH, molecules
(D) the eletronegativity of nitrogen is
much higher than that of the other The following equation represents the
elements in the group reaction of magnesium with hydrochloric
acid.
(A) .
so
(B) So,
(c) S,o
(D) SrOo
10. When 86 g of the ionic salt, CaSOo.xHrO, 12. In which of the following chemical
is heated so that all of its water of reactions is sulfur reduced?
crystallization is driven off and 68.0 g
- of
Caso. remain, the value of x is (A) S + Oz
- SOz
14. The standard enthalpy changes for two reactions are as follows:
+r
?
2Fe(s) Or(C)
- FerOr(s), AH* = -822 kJ mol-'
2
I -- CO(B), AII* :
1
(A) -e32
(B) -7r2
(c) 4e2
(D) +492
-\t
L Attractive forces are strong between (A) Nr(e) + rHr(s) t==i zNH,(e)
molecules.
IL Average kinetic energy of the
(B) SOr(e) + Or(B);:::izSO,(e)
molecules is proportional to the
absolute temperature.
III. Volume of molecules is negligible (C) 2cHClFr(g)a-" C,Fo(g; + 2HCl(g)
compared to that ofthe container.
(D) CH4G) + H,Q(g);=: CO(g) + 3H,(g)
(A) Ill only
(B) I and III only
(C) II and III only
(D) I,ll and III 19. Which of the following statements about
dynamic equilibrium is NOT true?
16. The activation energy of a reaction (A) The forward reaction proceeds
at the same rate as the reverse
(A) is unaffected by a catalyst reaction.
(B) is an energy barrier to the reaction (B) The concentrations of the reactants
(C) is affected by temperatures and products are constant
(D) reduces the speed of the reactant throughout the course ofthe
molecules reaction.
(C) Dynamic equilibrium can only be
achieved in a sYstem where no
Item 17 refers to the table which shows materials are added or
removed.
the rate results for the reaction A + B + C (D) There is no aPParent change
but both forward and reverse
IAI IBI Rate of reaction reactions continue to take Place
Experiment (moldm'3) (moldm'3 s'r;
(mol dm-r) at equal rates.
L7 . What is the OVERALLorder ofthe reaction? What is the value of K" at 25 'C for the
following equi libri um?
(A) Zero
(B) First
(c)
L nr<e) * lr(g) ff Hl(g)
Second +
(D) Third
(A) 2e
(B) zts
(c) 430
(D) 1720
(D) rLPb"J
^,t2 rr-]2
LI'J
t 6A tF a lrrt'F
-t
-7 -
28. Precipitation of a sparingly soluble salt Item 30 refers to the following diagram of
occurs on addition of a common ion ONLy an electrochemical cell.
if the ionic product is
Wire
(A) less than K,o
(B) greater than K_-
(Ci Jqualto K,o
sP
(A) Aluminium
(B) Magnesium
(C) Sodium
(D) Sulfur
Bonding and structure in Ionic lattice Giant covalent Covalent molecular Covalent molecular
oxide
Match each oxide below with an option, A, B, C or D, above. Each option may be used once, more
than once or not at all.
a) Oxide of silicon
?? Oxide of sulfur
34. Silicon carbide has a structure similar to 35. Which of the following statements about
that of diamond. What are the advantages oxides of the elements in Period 3, sodiurn
of using silicon carbide ceramics to chlorine, is NOT true?
compared with steel?
(A) Across the Period, the oxides
I. Silicon carbide is less likely to change from basic to amPhoteric
deform under comPression' to acidic character'
II. Silicon carbide has a higher melting (B) The oxides react with water to form
alkaline solutions.
Point.
III. Silicon carbide is more resistant to (C) The oxidation number of the
oxidation. element in the oxide increases
across the Period.
(A) I and II onlY (D) The structure ofthe oxides changes
(B) I and III onlY from giant ionic to simPle
(C) II and III onlY covalent molecules.
(D) I, II and lll
36. Which of the following properties belong to
Group II elements of the periodic table?
GO ON TO THF.NtrXT PArltr
-9 -
42. The equation for the reaction between 44. Which of the following elements gives a
chlorine and cold dilute aqu€ous sodium green flaf'ne when heated?
hydroxide is as follows:
(A) Magnesium
Cl"(g) + 2NaOH(a9) * NaCl(aq) + (B) Calcium
NaCIO(aq) + H.O(l) (C) Sodium
(D) Copper
This reaction can BEST be described as an
example of
Item 45 refers to the following information.
(A) decomposition
2+
(B) displacement
(C) disproportionation
(D) dissociation
\
43. Which ofthe following transition elements
has an unpaired electron in an s-orbital? White precipitate White precipitate
soluble in excess insoluble in excess
(A) Chromium
(B) Manganese 45. Which of the following reagents does NOT
(C) Nickel aid in the identification of X2*?
(D) Titanium
(A) Aqueous KI
(B) Dilute HCI
(c) Dilute HNo3
(D) Dilute H,SO4
END. OF TEST
IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.
o|t12olO/CAPE 2014