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Griswold 1949
Griswold 1949
10
VAPOR-LIQUID EQUILIBRI.\
\Yi,ii.!rt Ratio.
\\t.(? \Vatvr: (:loiirl I'oiiit,
I n the remaining figures, compositioiis are giveii iri mole pcr 1 :'wtatc' '':t'l) 1 - A h J h d 0 c. K
cent, converted from weight per cent analytical data. Thc 8 111 301.1
8 , (iB 1 312.7
tie line data are givvn in Table 1- and are plotted in Figure 6. < , I , Jti , 327.7
I ( 1 (ill 346.0
These were correlated by thc method of Ot,hmer and Tobias 11. 1:s 4 02 2 0 (i 293.7
(14), which permits estmpolation t o locate t,he plait point. The 1.1 O(i 1 ti.' 32 0 303.1
data all fell on a smooth curve on the Othnier plot, the fivc t#ic- 14.0: 1, li2 39 (1 312.1
14 31 4.n2 41 0 314.1
line points highest in ethyl alcohol forming a straight line. Tht' 1.5 !I(! 4 ,(il' .i1 , !I 325.0
other two points which include the et,hyl acet8ate-\vatcr binary 17.2,i 4 ti2 fi0,7 333.8
did not fall on the straight h e portion of the Othnier plot. I!, , 3!l 3 . 2!) 2:. 1 '298.5
21.8'1 3.2!1 24.3 307.6
The resulting conjugate curvc is shown in Figure ti wit,h the 25.10 R 20 18 (I 321.1
28 6 3 3 . ?!I 6 3 , :i 336.4
extrapolated portion dashed. A4smight have been anticipated, 32.00 3.29 i8.2 351.3
the plait point has the higheat boiling point of any composition I!). 87 3.12 20.6 293.9
on the boundary curve. This observation may soinetinie prove 23.24 3.12 :j2.0 305.1
2G. 9i ?,I2 46 , 4 319.5
useful for determination of plait point compositions. Another 81.33 3. I:! 66.4 33'3.5
noteworthy observation is that the tw+phase mixture con-
October 1949 INDUSTRIAL AND ENGINEERING CHEMISTRY 2355
100 79 I i
BO
P
F 'C.
E 60
0
-I
z
U
x 40
I-
W
se
-I 20
W
0 20 40 60 BO 100
0 FURNL1S 8 LEIGH
I MOLE % ETHANOL
0
Figure 8. Sornial Boiling Point
MOLE% E T H A N O L IN LIQUID Diagram (760 Rlni.) for Ethyl
tlcohol-Ethj 1 Acetate
E'igure 7 . \ apor-I,irpirl Equilib-
rium (760 T l n i . ) for Ethyl .tlcohol-
EthJl i c e t a t e
4
V A N L A A R EQUATION
alcohol-water activity cocfIicients correlate better by the four- 3 I 1 -___ 4.0372 8~0384
__
6S,!l 88.4
-
13.8 7.0 17.3 4.6 0 , __ - ~ _ ~ ~ _ ~ ~ _ _.J~~-
!
;,,--+--;-->-I
I i
----I
EXPERI-ENTIL
I - -
i
I I
I'
SL'
S::
s'4
S3
0 20 40 60 80 IW
MOLE % ETHYL ACETATE
WATER
E T H Y L AGETATE-
i(:KSOW-LEI)G\l k : R T
70.3” C. ~ : i found
s
-