Vidyamandir Classes

Solutions to JEE Advanced-4 | JEE-2018

CHEMISTRY PAPER-2
SINGLE CORRECT ANSWERS TYPE
ZM 0 ZM 0
1.(A) ρTh = 3
⇒ ρobs = × 0.96 = 2.56 g / cc ⇒ (A)
NA a NAa 3
2.(B)

3.(A) ∆Tb = i × k f × m
m / 60
⇒ 0.5 = 1 × 1.86 × × 1000
(500 − 128)
⇒ m = 6 ⇒ (A)
4 3 2 1
1 1 1 1
4.(B) Mass left = 16 ×   + 16 ×   + 16 ×   + 16 ×   + 16 = 31 mg ⇒ (B)
2 2 2 2
5.(B)

6.(D) Iodination of alkane is not possible by using I − Cl and AlCl3

7.(C) This reaction proceed by NGP reaction mechanism.

MULTIPLE CORRECT ANSWERS TYPE

8.(ABC) (A) Water will flow out of plant cell placed in hypertonic solution ⇒ Cell will shrink.
(B) ∆Tb = ik b m
Hg 2 Cl 2 → Hg 22 + + 2Cl− ; i = 3 ⇒ im ≃ 3 × 0.1 = 0.3
NaCl → Na + + Cl− ; i = 2 ⇒ im ≃ 2 × 0.2 = 0.4
(C) Only gas pressure will change
(D) As molarity is decreased ⇒ degree of dissociation of HF increases.

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9.(ABD) Mechanism of nitration is :

HNO3 + 2 H 2SO 4 ↽ ⇀ NO +2 + 2 HSO −4 + H 3O +
If a large amount of KHSO 4 is added then conc. of HSO −4 ion increases and the reaction will be shifted
in backward direction hence, the rate of nitration will be slower.
10.(AC) Formula = A 4 B
4rA = 2a . . . .(i)
2(rA + rB ) = a . . . .(ii)
4 4
4 × πrA3 + πrB3
P.F. = 3 3 = 0.754
a3
and void space = (1 − 0.754) × 100 = 24.6%

5400
11.(ABCD) P=
(60 + 30y A )
5400
For p oA put y A = 1 ⇒ p oA = = 60 mmHg
60 + 30
5400
For p oB put y B = 1 ⇒ yA = 0 ⇒ p B = = 90 mmHg
60
For ideal solution → p oA < p T < poB ; No azeotrope

12.(ABC) Hint : All are carbocation mechanism and carbocation is planar. So attack from both sides
equally gives a stereocentre. Hence A, B and C are correct.

(B)

(C)

13.(D) Meso compound are those compound having symmetry with chiral carbon atom and
superimposable mirror image.

14.(AC) (4n + 2)π , Cyclic, planar are known as Aromatic.

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LINK COMPREHENSION TYPE

dx k f 2 × 107
15.(A) = k f [Ag + ][NH 3 ]2 − k b [Ag(NH3 ) 2 ]+ = 0 at eqm ⇒ k eqm = = = 2 × 109
dt k b 1 × 10−2
Ag + + e− ↽ ⇀ Ag

Ag + 2NH3 ↽ ⇀ [Ag(NH3 ) 2 ]+ + e−

Ag + + 2NH3 ↽ ⇀ [Ag(NH3 )2 ]+

E 0cell = E 0( Ag + /Ag
− E0
[Ag(NH3 ) 2 ]+ /Ag, NH3 ) = 0.061 log(2 ×10 ) 9

⇒ E0 = (0.8 − 0.06 × 9.3) = 0.24 volts

[Ag(NH3 )2 ]+ /Ag, NH3

0.06
16.(B) E 0 − E0 = log(k sp ) AgBr ⇒ (k sp ) AgBr = 10−12
Br − /AgBr/Ag Ag + /Ag 1
AgBr ↽ ⇀ Ag + + Br − ; k sp = 10−12
(s − x) s

Ag + + 2NH3 ↽ ⇀ [Ag(NH 3 )2 ]+ ; k eq = 2 × 109

(s − x) (1− 2x) x x ≃ s; sin ce k eq is very l arg e

 x   s 2
k sp .k eq = [(s − x)s]  =
2  
 (s − x)(1 − 2x)   1 − 2s 
2
 s 
⇒ 
−12
(
 = 10 × 2 × 10 = 20 × 10
 1 − 2s 
9 −4
)
⇒ s ≃ 20 × 10−2 M

17-18. 17.(D) 18.(B)

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Solutions to JEE Advanced-4 | JEE-2018

PHYSICS PAPER-2

SINGLE CORRECT ANSWERS TYPE

I
1.(D) Time period physical pendulum T = 2π
Mgd
1 3
2.(B) v= v= v
4 ( 0.1 + e ) 4 ( 0.35 + e )
⇒ 0.35 + e = 0.3 + 3e
∴ e = 0.025m

3.(C) E=
1 2ɵi
+
1 ( −3ɵj )
4π ∈0 23 4π ∈0 23
7k
E=
8

4.(D) Potential of sphere B is zero. Then after closing of switch, charges do not flow.

 ℓ0   ℓ0   ℓ0 
5.(B) r = R  − 1 ⇒ r = 5  − 1 = 10  − 1
ℓ 
 1   2   3 
⇒ ℓ 0 = 6m
∴ r = 10n

6.(D) Magnetic moment of cos ℓ is µ = iAℓɵ = ℓɵ

∴ τ = µ × B = ℓɵ × 2 ɵj = 2kɵ N − m

7.(C) B = µ0 ni

MULTIPLE CORRECT ANSWERS TYPE

(
8.(BCD) r = (1 + 2 cos 2ωt ) ɵi + 3 sin 2 ωt ɵj + ( 3t ) kɵ )
 3   3 
=  ɵi + ɵj  +  2ɵi − ɵj  cos 2ωt ɵj + 3tkɵ
 2   2 
The motion of particle in S.H.M in frame moving with 3kɵ m / s
 3   3 
r =  ɵi + ɵj  +  2ɵi − ɵj  cos 2ωt ɵj
 2   2 
2
 −3 
2 5
A= 2 +  = m
 2  2
3 4 3
Direction of S.H.M. is 2ɵi − ɵj i.e. ɵi − ɵj
2 5 5

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T ( 2 + 2.25t ) g 10 t
9.(AB) Velocity of wave in string at t is v =
µ
=
0.1
⇒ ∫ dx = 10 ∫ 2 + 2.25t dt
0 0
∴ t = 0.6125
T = ( 2 + 2.25 × 0.612 ) × 10 = 33.77 N

10.(ACD) The correct through cross section of radius r is

r
2π kr 4
i= ∫ ( J 2π rdx ) = 4
0

According Amphere’s circuital law ( r1 < a )

∫ B ⋅ d ℓ = µ0 iℓn
π kr 4 µ0 kr 3
B 2π r = µ0 ∴ B=
2 4
For r>a
π ka 4 µ ka 4
B 2π r = µ0 ∴ B=
2 4r
( )
2
11.(ABCD) ( r − 5) 2
+ 5 3 =r 2

∴ r = 10m
5 3 3
sin θ = =
10 2
∴ θ = 60°
rqB 10 × 156 × 10
v= = = 2m / s
m 5 × 15−5
Magnetic force is perpendicular to velocity WF = 0

12.(CD) B1 − B2 = 0 ⇒ B1 = B2 ⇒ µ0 n1i1 = µ0 n2i2

13.(AC) B=0 ; 0<r <a
µ0i
= ; r >a
2π r

14.(BC) V = (100 + R ) × 50 × 10−6

For R = 10kΩ, V = 0.505 volt
For R = 200 kΩ, V = 10 volt
100 × ig = R × i − ig ( )
⇒ (100 + R ) ig = Ri

 100 + R 
i=  ig
 R 
For R = 1Ω
i = 5mA

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LINK COMPREHENSION TYPE

15.(C) Since, during propagation of sound wave medium particles execute SHM, therefore, displacement of a
particle due to a wave frequency n is given by y = a sin ( 2π nt ) . Hence, displacements of medium
particles caused by these waves will be
y1 = a sin ( 2π n1t ) or y1 = a sin 800 π t ......(1)
y2 = a sin ( 802π t ) .....( 2 )
According to principle of superposition, y = y1 + y2
∴ Resultant displacement of a medium particle at time t is
y = a [ sin 800π t + sin 802π t ] = 2a sin ( 801π t ) cos (π t ) with time
or y = 2a cos (π t ) ⋅ sin ( 801 π t ) (varying with time)
Resultant amplitude = 2a cos (π t )
Since, resultant amplitude A varies with time, therefore, resultant intensity also varies with time.
Since, intensity ∝ A2 , therefore, intensity is maximum when A is maximum. A is maximum when
cos π t = 1
∴π t = 0 , π ,2π , or t = 0 ,1, 2,3,....
Hence, period of one complete cycle of intensity is one second.
1
16.(A) 2a cos (π t ) = a ⇒ cos ( π t1 ) = + ⇒ π t1 = π
2 3

t1 = 1 sec .
3
 1 
Detector will receive signal in  0 → sec 
 3 
−1 2π
And cos (π t2 ) = ⇒ π t2 = ⇒ t2 = 2 sec .
2 3 3

 2 
It again receive signal between  t2 = sec ⇒ 1 sec 
 3 
1 2 1
The time interval for which detector remains idle is between sec to sec i.e. ∆ t = sec .
3 3 3
17-18.
17.(C) Charge on capacitor at t = 0 is q0 = 0
Charge on capacitor at t = RC during charging
 −
t 

q = CE 1 − e RC  = CE 1 − e −1

  ( )
 
Charge at t = 2 RC during discharging from t = RC to t = 2RC
t
− 1 1 
q = q1e RC
( )
= CE 1 − e −1 e −1 = CE  − 2 
e e 
18.(C) Charge on capacitor in each 2RC cycle of time goes on increasing and each cycle contains exponential
grow or exponential delay of current.

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Solutions to JEE Advanced-4 | JEE-2018

MATHEMATICS PAPER-2
SINGLE CORRECT ANSWERS TYPE
1.(D) y – 4x – 8y + 40 = 0 and x2 – 8x – 4y + 40 = 0 are curves image of each other with respect to the
2

line y = x.
So, tangents with slope M = 1 exist for both and shortest distance is the distance between those two
tangents.
(y – 4)2 = 4(x – 6) . . . (1)
⇒ Equation of tangent y – 4 = x – 6 + 1
⇒ y=x–1
Or x – y –1 = 0 . . . .(A)
(x – y)2 = 4(y – 6) . . . . (2)
⇒ Equation of tangent
(y – 6) = (x – 4) –1 ⇒ y = x +1
⇒ x–y+1=0 . . . . (B)
2
Dist = = 2
2
2
2.(D) Equation of tangent to y2 = 8x is y = mx + . . . .(i)
m
 2
So, xy = −1 ⇒ x  mx +  = −1
 m
2
⇒ Mx 2 + x +1 = 0
M
(i) is tangent to hyperbola also
4
⇒ D = 0 so, 2
− 4m = 0 ⇒ M 3 =1 ⇒ M = 1
M
So, equation y = x + 2

3.(C) Since by definition PS = PM.

So, need to equate PM = SM for value of t if
P = (t2, 2t) ⇒ M = (–1, 2t) and S(1, 0)
So, PM = 1 + t2 and SM = 2 1 + t 2

⇒ (1 + t2) = 2 1 + t 2

⇒ (1 + t 2 ) = 2 ⇒ 1+ t 2 = 4
3
⇒ Side length = 4 So, area = k = × 16
4
⇒ K = 4 3 = 4 ×1.7 ≃ 6.8
⇒ [K]=6

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4.(B) Since f ( x) = | x = 2 | = 2 − x x<2

x −2 x≥2
So, left hand derivative = –1
lim g ( x) = − 1
x →2+

Let x = 2 + h ⇒ h → 0+ as x → 2+
hm
So lim = −1
h → 0+ ℓn cos n x
mh m −1 m h m − 2 cos h
⇒ lim = −1 ⇒ lim − = −1
−n cosn −1 h sinh
h → 0+ h → 0+ n sin h
cos n h h
⇒ M=2=n

5.(B) f(x) = [x2 – 3x] + 2015

 9 
Range of (x2 – 3x) for x ∈ (0, 3) is  − , 0 
 4 
Discontinuous at each integral point

6.(B) Equation of circle passing through

x2 y2  x2 y 2 
Intersection of x2 − y2 = 0 and + = 1 is ( x 2
− y 2
) + λ  2 + 2 −1 = 0
a2 b 2
a b 
 λ  λ 
⇒ x 2  2 + 1  + y 2  2 − 1 = λ
a  b 
Since it is a circle
λ λ 2a 2 b 2
⇒ +1 = −1 ⇒ λ =
a2 b2 a2 − b2
λ 2ab
So, Radius = =
λ a + b2
2
2
+1
a
2
2  1 3
7.(C) x − x +1 =  x −  +
 2 4
⇒ x∈ (0,1)
⇒ [x2 – x + 1] =0
1 0
⇒ ∫ ∫
[ x 2 − x + 1] dx = [ x 2 − x +1] dx
−1 −1
1− 5
0
2
1 − 5   5 −1 
=2 ∫ dx + 1 ∫ dx = 2 
 2
+ 1 + 1 
  2 

−1 1− 5
2

5 −1 6 − 2 5 + 5 − 1 5 − 5
=3 − 5+ = =
2 2 2

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MULTIPLE CORRECT ANSWERS TYPE

8.(ABCD) (A) lim f ( x ) = lim − x − 2 x = lim − 3 x = 3

x →−1− x →−1− x →−1−

lim f ( x ) = lim − 2 x − x lim − 3 x = 3

x →1+ x →−1+ x →−1+

lim f ( x) = lim x = 1
x →1+ x →1+ 
(B)  = But f (1) = 2
lim f ( x) = lim x =1
x →1− x →1− 
(C) lim f ( x) = lim 2 x = 4
x → 2+ x → 2+

lim f ( x) = lim x = 2
x → 2− x →2−
(D) Let λ = positive integer
lim λ x = λ 2 and lim (λ − 1) x = λ (λ − 1)
x →λ + x→λ −

9.(ABCD) (A) y = sin −1 (sin x)

(B) y = sin −1 | sin x |

(C) y = max {2sin x, 1– cos x}

(D) y = max {sec–1x, cosec–1x}

10.(D) Equation of normal to y2 = 4ax with slope m is y = mx – 2am – am3

⇒ am3 + m(2a − h) + k = 0 ….. (1) [Since it passes through (h, k)]
Where the point of contact is (ami2 , − 2ami ), i = 1, 2, 3
Let equation of circle be x 2 + y 2 + 2 gx + 2 fy + c = 0
It is passes through (am 2 , − 2am)
⇒ a 2 m 4 + 4a 2 m 2 + 2 gam 2 − 4 afm + c = 0 . . .(ii)
It passes through m1 , m2 , m3
⇒ c=0

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So, (2) changes to am3 + m(2 g + 4a) − 4 f = 0 . . . .(iii)

−k
Comparing (1) and (3), we get : 2 g = − (2a + h) and 2 f =
2
ky
So, equation of circle is x2 + y2 – (2a + h)x − =0
2
1 1
11.(ABD) Let ∫ tf (t )dt = A and ∫ f (t )dt = B
−1 −1

⇒ f ( x) = x (1 + A) + x3 B
2
. . .(1)
1 1 1

∫ t[(1 + A)t 2 + t 3 B ]dt = ∫ (1 + A)t 3 + ∫ Bt

4
Now, A= dt
−1 −1 −1
1
2B
∫
A = 2 B t 4 dt =
5
0
1 1
2(1 + A)
∫
B = (t (1 + A) + t B ) dt = 2(1 + A) t 2 dt ∫
2 3
Again ⇒ B=
3
−1 0

2 2
So, A= × (1 + A) ⇒ 15 A = 4 + 4 A
5 3
4 2 15 10 15 10
⇒ A= So, B = × = ⇒ f ( x) = x 2 + .
11 3 11 11 11 11

1 + cos 4 x (2 cos2 2 x ) (sin x cos x) cos 2 2 x sin 2 x

12.(BCD) f ( x) = ∫ (cot x − tan x )
dx = ∫(cos2 x − sin 2 x)
dx =
cos 2 x ∫ dx

1
∫
f ( x) = cos 2 x sin 2 x dx =
2∫sin 4 x dx

1
⇒ f ( x) = − cos 4 x + λ ,
8
π  1
Now, since f   = 0 ⇒ λ = 0 ⇒ f ( x) = − cos 4 x
8 8
 c
13.(ABCD) Let the parametric point of xy = c 2 be  ct , 
 t
 c
So, the equation of tangent at the point is  y −  = t 2 ( x − ct )
 t
yt − c = xt 3 − ct 4
Passes through (α , β )

So, ct 4 − α t 3 + β t − c = 0 . . . . (i)
Let t1 , t2 , t3 , t4 are roots of equation . . . . (i)
c
So, xi , = cti , yi = ∀ i =1, 2,3, 4
ti
1 1 1 1 c4
So, c(t1 + t2 + t3 + t4 ) = α , c  + + +  = β . Also, c 4 (t1t2t3t4 ) = − c 4 and = − c4
 t1 t2 t3 t4  t1t2t3t4

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x2 y2
14.(ABCD) Let us take equation of ellipse as + = 1 ( a > b)
a2 b2

Given NQ = PS = PM
Again, x = a cosθ , y = ± (a ± ae cos θ )
⇒ y − ex − a = 0 or y + ex − a = 0 or y + a + ex = 0 or y + a − ex = 0

LINK COMPREHENSION TYPE

− sin h + tan h + cos h − 1

15-16. LHD = lim −0 =0
h →0 2h 2 ln(2 − h) − tan h
−h
2 2
eh − 1 − 0 eh − 1
RHD = lim =h × =0
h→0 h h2
⇒ L1 : y = 0 and L2 : x = 0

15.(A) ( x − r )2 + ( y − r )2 = r 2 (Family of circle)

x 2 + y 2 − 2rx − 2ry + r 2 = 0
2(r1r2 + r1r2 ) = r12 + r22 or 4r1r2 = r12 + r22
2
 r2   r2  r2 4 ± 12
  − 4   +1 = 0 ⇒ = =2 ± 3
 r1   r1  r1 2
1  θ 
16.(C) ∆ = 2 ×  cot (π / 4 − θ / 2 ) + cot + 1
2  2 

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π θ 
cos  −  cos θ 2 sin
π
∆=  4 2 + 2 + 1 = 1+ 4
π θ θ θ  π θ
sin  −  sin 2 sin sin  − 
4 2 2 2  4 2
2 π
⇒ ∆ =1 + ⇒ ∆ is minimum it θ =
 π π 4
cos  θ −  − cos
 4 4
2
⇒ ∆ min = 1 + =3 + 2 2
1
1−
2
17-18. 17.(A) 18.(D)
r
 n
1  1  
n n
1   1  
n
lim f ( r , n) = e r −1 = lim 1 +  1 + 1 + 1 +  
n →∞ n →∞ 
 r  rn    
r 2n   r n −1n  

So, lim f (3, n) = e3 / 2

n →∞

∏ ln ( nlim )
100 100
r 2 3 100
→∞
f ( r , n) = ∏ r − 1 = 1 × 2 × ..... × 99
= 100
r =2 r =2

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