Basic Concepts of Colour Measurement

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Basic concepts of colour measurement

Dr. A. K. Roy Choudhury,

Retired Professor and HOD (textile)

Govt. College of Engineering and Textile Technology,

Serampore - 712201, Hooghly (W.B.), India

e-mail: akrc2008@yahoo.in

Colour in our Daily Life

From time immemorial, man must have watched inquisitively the wonder-work of sunlight in

creating blue colour of zenith sky, glowing scarlet of rising and setting sky and various hues of

rainbow. Colour is also an integral part of our daily life, be it textiles, paints, plastics or printing.

We can’t even imagine a colourless world around us. All our daily necessities are packed in

attractive colourful packaging that tempts us to buy even if we do not need it. We can’t even

imagine our television without colour. We choose our garments primarily by colour, which projects

our personality. We select paints and furniture for our house by colour, which gives us pleasing

atmosphere. The colour depicts the nature and inner personality of the car owner. Colour of a

gem or precious stone also guides a person to overcome obstacles in his life. Colour has become

a focal point of what we do every day.

Despite being so important and so close to everyone’s day-to-day life, it is not possible to express

colour in unique or in specific language. We remember colour till we look at it. The moment we

take away our sight from it, it gets erased from our memory. The colour scientists attempted to

specify colour in explicit universal language so that it could be understood by everyone involved

with colour and colour reproduction. This led to express colour numerically which is unique and

unambiguous specification of colour.

Visual Perception of Colour

Colour may be viewed in two modes (Figure 1) namely:

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1) Illuminant mode - when the light stimulus comes directly from a source of light, say, an

incandescent lamp or a candle.

2) Object mode - when stimulus comes from Light source


Eye
an object either from its surface (surface Illuminant mode

mode) or through the object (volume

mode). In this mode, the perception of an


Object mode
object is mostly in reference to the

surrounding objects. Three ingredients

are required to visualise the colour of an

object, namely a light source, object itself Object

and the human observer.

A light source illuminates the object and is


Fig. 1 Two modes of viewing colours
characterised by the energy at different

wavelengths, which is denoted by the term spectral power distribution (SPD). When a light beam

falls on an object, it is modified by absorption, scattering and other physical processes depending

on the physical and chemical construction of the object. The light (colour stimulus) that reaches

the eye of the observer in the form of reflected light interacts with the photosensitive pigments

present in the eye. This gives rise to nerve impulses which are transmitted to brain. The human

eye-brain mechanism makes rapid and continuous evaluation of object appearance and colour.

The light, which enters our eyes, contains the characteristic imprints of the light source and the

object. Light can also fall directly (without interaction with object) on our eyes creating nerve

impulses.

Colour Perception

The Committee on Colorimetry of the Optical Society of America in 1922 defined colour as the

general name for all sensations arising from the activity of the retina of the eye and its attached

nervous mechanisms, this activity being, in nearly every case in the normal individual, a specific

response to radiant energy of certain wavelength and intensity (OSA, 1953).

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Colour is sometimes used as a name for materials such as dyes and pigments, but the name

Colorant will be more appropriate in these cases. The spectral composition of radiant energy and

the spectral transmittance or reflectance of substances is also called colour, but it is again an

inappropriate name for these purely physical concepts. Psychophysical concept of colour as

characteristics of light dependant on human vision is most appropriate.

Perception of colour which is solely a prerogative of human beings is purely individualistic and

hence subjective. As a result, objective communication of a particular colour becomes difficult.

For expressing colour objectively one must measure and quantify it. The colour can be objectively

expressed either by creating calibrated coloured physical samples or by an instrumental colour

measuring devise and expressing it by numbers.

Colour Mixing

According to one reliable estimate, we can distinguish among ten million different colours (Judd

and Wyszecki, 1975). Kuehni further estimated that the humans with normal colour vision can

distinguish among some two million colours when viewed against a mid-grey background and

perhaps double when the background is widely varied (Kuehni, 2005).

Newton explicitly stated that colour is a perceptual property, not a physical attribute, which meant

that the light mixtures occurred in the eye, not in the light. Newton recognised three aspects of

colour perception: brightness, hue and intensity. Painters and dyers already from before Newton’s

time believed in three fundamental chromatic colours that they sometimes equated with pigments

or dyes: yellow, red and blue, from which all other hues can be created. With long experience

with paints and dyes they also affirmed that material colour mixtures and light mixtures behaved

very differently.

Colour perception for humans is three-dimensional, a fact almost certainly stems from the

existence in the retina of three different classes of light-receptive cells. LeBlon (1756) was first to

make clear distinction between mixing pigment colours and mixing colours of light. He stated that

all visible objects can be represented by three colours, yellow, red and blue and mixture of these

three colours makes black or all other colours. He named those as material colours or those used

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by painters. He further added that for a mixture of spectral colours those proposed by Sir Isaac

Newton cannot produce black, but the very contrary, white.

Primary colours are sets of colours that can be combined to make a useful range of colours. For

human applications, three primary colours are usually used, since human colour vision is

trichromatic.

Primary colours are not a fundamental property of light but are often related to the physiological

response of the eye to light. Fundamentally, light is a continuous spectrum of

the wavelengths that can be detected by the human eye in an infinite-

dimensional stimulus space. However, the human eye normally contains only three types of

colour receptors, called cone cells. Each colour receptor responds to different ranges of the

colour spectrum. Humans and other species with three such types of colour receptors are known

as trichromats. These species respond to the light stimulus via a three-dimensional sensation,

which generally can be modelled as a mixture of three primary colours (Sobel, 1989).

Many birds and marsupials are tetrachromats (Backhaus and Werner, 1998), and it has been

suggested that some human females are tetrachromats as well (Mollon and Jordan,

1993), having an extra variant version of the long-wave (L) cone type.

Most mammals other than primates have only two types of colour receptors and are, therefore,

dichromats; to them, there are only two primary colours.

Any choice of primary colours is essentially arbitrary; for example, an early colour photographic

process, autochrome, typically used orange, green, and violet primaries. However, unless

negative amounts of a colour are allowed the gamut of colour generated will be restricted by the

choice of primaries (http://en.wikipedia.org/wiki/Primary_color, accessed on 16.7.15).

Fundamental laws of colour mixing can, therefore, be classified into two types namely

1) Additive colour mixing (Figure 2 a) occurs when two or more lights mix together.

2) Subtractive colour mixing (Figure 2 b) occurs when colorants are mixed together.

Virtually all our visible colours can be produced by utilizing some combination of the three primary

colours, either by additive or subtractive processes.

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For additive combination of colours, as in overlapping projected lights or in CRT displays, the

primary colours normally used are red (R), green (G), and blue (B). The result of additive mixing

of the primaries are listed below,

R + G = Y (Yellow),

G + B = C (Cyan or blue-green)

B + R = M (Magenta)

R + G + B = W (white)

For subtractive combination of

colours, as in mixing

of pigments or dyes, such as in

dyeing or printing, the primaries

normally used are cyan

(C), magenta (M), and yellow (Y), though the set of red, yellow, blue is popular among artists.

The subtractive primaries can be obtained by removing red, green and blue from white light using

respective coloured filters namely

W - R = C (- R)

W - G = M (- G),

W – B = Y (- B),

The mixing of subtractive primaries yellow, magenta and cyan can be predicted mathematically

as follows:

Y + M = (W - B) + (W - G) = W - B - G = R,

Y + C = (W - B) + (W - R) = W - B – R = G

M+ C = (W - G) + (W - R) = W - G - R = B,

Y + M + C = W - R - G - B = K (Black)

When the three subtractive primaries are mixed in proper proportions as in case of mixing

colorants, the mixture is unable to reflect light anymore and appear black (K) in colour. Similarly

when white light is passed through filters of three subtractive colours, the whole of white light will

be removed. Mixture of two primaries is called secondary. The most commonly used additive

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colour primaries are the secondary colours of the most commonly used subtractive

colour primaries, and vice versa.

The age-old belief that three primary colours are required to make white was also proved false

(Helmholtz, 1852). The idea of complimentary spectral colours came into existence and was

subsequently defined by Grassman (1853) as follows:

To every colour belongs another homogeneous colour, which when mixed with it, gives colourless

light.

Subsequently Helmholtz confirmed that every spectral colour does not have a spectral

complement as proposed by Grassman. A range of green colours ranging from about 484 nm to

about 570 nm, has complimentary colours in the non-spectral purple range.

Colour Communication

In colorant production and application industries, colours are to be communicated, compared,

recorded and formulated on regular basis. This necessitates systematic classification of colours.

The objects can be classified in various ways in terms of colour. The classification may be based

on visually or instrumentally-assessed colour parameters (Roy Choudhury, 2000) .

While communicating or talking about colour, a language which is understandable by both the

parties must be followed. A logical scheme for ordering and specifying colours on the basis of

some clearly defined attributes is known as colour notation system. The attributes are generally

three in number as our vision is trichromatic and they constitute the coordinates of the resultant

‘colour space’. Colour notation systems also encompass ‘colour order systems’ which are

typically comprised of material standards in the form of colour atlas. Due to constraints of colorant

gamut, the atlases may depict only a physically realisable subset of a colour order system.

Colour notations can be classified into three categories (Rhodes, 2002):

1) Device dependant systems – the most common imaging devices used for reproducing colour

are the computer controlled CRT displays and the colour printers. The associated colour

order system and colour spaces are hardware-oriented and they lack perceptually based

attributes.

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2) Mathematical systems – uniform colour spaces based on mathematical transformation of CIE

tristimulus values such as CIELUV and CIELAB belong to this category.

3) Systems based on database of aim points – colour order systems existing principally in

physical form, the colour samples of which can be measured to establish a database of aim

points. Using interpolation techniques among limited available samples, many more colours

can be defined.

The monitors and printers follow device-dependant specification systems. In cathode ray tube

(CRT) displays, colour television, and most computer video displays, colour stimuli are generated

with three different types of phosphors after activated by electron beams. The three additive

primary colours generated by such activation are orange-red, leaf green, and violet. A large

number of colours can be created by their mixture.

Two most common additive systems used in connection with computer display are RGB (based

on mixing of three additive primary colour red, green and blue produced by the phosphors of the

display unit in cubic space) and HSB (hue, saturation and brightness in cylindrical form).

For instrumental colour measurement of an object, additive primaries are used to predict the

quantity of subtractive colours required to reproduce that colour. This entails the use of standard

source of light, viewing geometry and a standard observer. The expression of colour as numerals

has been standardized by Commission Internationale de l’Eclairage (CIE) set up in 1931 for

standardisation of measurement of colour. Thus the instrumental measurement of colour is

helpful in, communication of colour across the entire supply chain as well as comparing samples

and setting pass-fail criterion for sourcing and supply of products. In this form it is a useful tool for

quality control.

It is very convenient, easily understandable and memorable when the colours are called by

names similar to common objects orange, ultramarine, olive, malachite green, bottle-green,

peanut-green, sea-green etc. But such colour names are very approximate, unreliable and

temporary. Their meaning also changes with observer, time, place, style, technology, language,

culture etc.

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When we deal with a reasonable number of specimen, say a few thousands, to cover the whole

range of possible colours (1millions or more), the specimen must be selected according to a

system or plan. It is well known that the colours are three-dimensional. However, the dimensions

of colour are expressed in various ways in different fields. For systematic arrangements, the

dimensions should be independent of each other.

Visual Description of Colour

Wright (1984) identified two sets of visual attributes namely:

Group A attributes are lightness, hue and chroma

Group B attributes are whiteness, blackness and chromaticness.

According to him, group B attributes are more useful because it is most easily understood and is

more fundamental for observers to represent colour appearance. However they are less studied

in psychometric (equal perception) terms.

A colour order system is a systematic and rational method of arranging all possible colours or

subsets by means of material samples. Once the colours are arranged systematically they are

named in some descriptive terms and/or are numbered (Graham, 1985).

The colour order systems are of three types (Wyszecki, 1986):

1) Colorant-mixture system based on subtractive mixture of colorants e.g. Pantone

2) Colour-mixture system based on additive mixture of colour stimuli e.g. Ostwald system.

3) Colour appearance system based on the principles of colour perception or colour appearance

e.g. Munsell.

Examples of colorant-mixture systems are the colour atlases developed by different dye

manufacturers. ICI colour atlas (1969) was a collection of 1379 original colours and 27,580

variations printed on papers.

Pantone Colour System (Figure 3) is basically a colourant mixture system. The Pantone system

(www.pantone.co.uk) began life in 1963 in the USA, for defining colours for printers, but

expanded into other fields later, e.g. textiles in 1984, plastics in 1993, and architecture and

interiors (1925 colours) in 2002, each of which has a 6-digit numerical notation (e.g. # 19-1764)

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and an inspirational colour name. This is widely used in graphic art and also in textile industry

mainly because of its low cost, though the colours are not equally spaced. The shades are

prepared on paper using printing inks. It is not a colour order system since it does not include a

continuous scale. It is more

appropriately considered a colour

naming system.

Colour appearance systems are

based on the perception of

colours by an observer with

normal colour vision. The scales

of these systems are chosen to

represent attributes of perceived

colours. However, attributes

represented in various systems are different.

The main emphasis of appearance-based systems is the uniform visual spacing. The systems

thus allow easy interpolation between the samples represented and extrapolation of colours not

illustrated in a given collection. The collections of samples are generally represented in pages of

constant hue.

Six popular colour order systems, country of origin and their respective colour attributes are as

follows (Roy Choudhury, 2010) :

1) Munsell (USA) – Hue, Value and Chroma

2) Natural Colour System (Sweden) – Hue, Blackness and Chromaticness

3) Ostwald system (Germany) – Hue, Lightness and Saturation

4) DIN system (Germany) – Hue, Saturation degree and Darkness degree

5) OSA-UCS (USA) - no separate scaling of three attributes

6) Coloroid System (Hungary) – Hue, Saturation and Lightness.

Most popular appearance-based colour order system is Munsell system. The system (Figure 4,

https://en.wikipedia.org/wiki/Albert_Henry_Munsell) consists of the following three independent

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dimensions which can be represented cylindrically in three dimensions as an irregular colour

solid.

1) Hue (H), measured along circumference of the horizontal circles

2) Chroma (C) or purity of colour, measured radially outward from the neutral (grey) vertical

axis

3) Value (V), measured vertically from 0 (black) to

10 (white).

The complete Munsell specification of a sample is

expressed as H V/C (e.g. 5R 4/8).

Munsell system divides each horizontal hue circle into

five unique or principal hues: Red (5R), Yellow (5Y),

Green (5G), Blue (5B), and Purple (5P), along with 5

intermediate hues (5YR, 5GY, 5BG, 5PB, 5RP) halfway

between adjacent principal hues.

The Munsell atlas is usually available on painted paper in glossy (1488 chips) and matt forms

(1277 chips). A method for specifying opaque object colours such as textiles, painted panel etc.

by Munsell colour system has been described by ASTM (1980).

SCOTDIC, a textile version of Munsell created by fusion of two quite different systems - Standard

Colour of Textile (Japan) and Dictionnaire Internationale de la Couleur (France), is adopted by

over 8,000 companies worldwide. Textile standard colours of the SCOTDIC colour system are

widely used as colour tools by fashion colour professionals. The system has three versions -

glossy (2468 colours on polyester crepe fabric), matt (2038 colours on cotton poplin fabric) and

yarn (1100 colours on wool yarns). It has incorporated many bright colours and the number of

constant hue chart has been increased to 54 (20 for Wool). SCOTDIC system uses a six digit

code for each standard colour – the first two digits for hue, the second two digits for value and the

third two digits for chroma. The prefix corresponds to the material of textile bases – P for

Polyester, C for Cotton, W for Wool. Therefore, the notation C-155010 means cotton Standard

sample having hue = 15, value = 50 and chroma = 10 (Roy Choudhury, 2008).

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Most of the material based atlases are now available in digitised form e.g. NCS Digital Atlas

(www.ncscolour.com), Digital Colour Atlas 3.0 (www. dtpstudio.de) etc.

Figure 5 shows two pages from the Munsell Book of Colours. Figure 5 (a) shows hue circle

having samples of 100 hues in two depths (moderate and dark shades) (samples of some hues

are missing). Figure 5 (b) shows constant hue page of hue = 05. In these pages, rows represent

constant values samples, while columns represent constant chroma samples.

Instrumental Measurement of Colour

Newton said that (light) rays are not coloured, but merely

has the power to simulate certain sensations in the mind

of the observer. Human eye is a highly versatile detector

of light and colour. An observer can perceive chromatic

attributes and various geometric factors (direction, texture,

shape and many others) simultaneously. An instrument till

date is far behind in versatility. It can measure only one

attribute at time. In other words, we need several

instruments to measure various aspect of visual

perception.

Basically there are three types of colorimetric instruments in use - colorimeter, spectrophotometer

and spectroradiometer. They are available in the market with varying degrees of sophistication

and specialisation. While the spectroradiometer measures in illuminant-mode, the other two

generally measure in object mode. The recent trend on instrumental process control has resulted

in use of on-line instruments. However majority of the colorimetric instruments till date are off-line

and mostly used in laboratories. Laboratory instruments should be highly accurate and

standardised, while on-line instruments should be rugged under various environments and should

have good precision and firmness.

The colorimeters measure colour in terms of the quantities of the three primaries required to

match the colour. On the other hand, spectrophotometer measures percent reflectance or

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transmittance of the object plotted against wavelength at regular intervals of 1 nm, 5 nm, 10 nm,

20 nm throughout the visible range of light i.e. 380-750 nm or for practical purposes 400-700 nm.

Colour by Numbers!

The colour of an object depends on the relative quantity of the light reflected at different

wavelengths within the visible range (400-700 nm), but our colour sensation is not analytical in

nature. We cannot judge the existence of lights of different wavelengths individually. We get the

sensation from cumulative effect. As this cumulative quantity can be matched by mixing three

primary lights it is proved that our eyes have three types of colour-detecting cones, the stimuli

generated by them are mixed before reaching to brain. Various other phenomena of colour have

also lead to the conclusion that our eyes have three types of cones only. Each object colour is

sensed by each type of cone separately and each type sends a stimulus to the brain.

So, for each object colour, the brain receives three separate stimuli. Keeping similarity with colour

mixing experiment, we can consider the three types of cones as red-sensitive r, green-sensitive g

and blue-sensitive b equivalent to the three additive primaries. The spectral sensitivity of the three

colour-detecting cones has been measured and named as colour matching data

r (), g (), b () (bar stands for statistical average data of a number of colour normal observers)

and subsequently transformed into more usable CIE standard observer functions,

x ( ), y ( ), z ( ). The area under the functions signifies the amounts of three stimuli to be

transmitted to the brain for the incidence of light having one unit of energy at each of visible

wavelength. These three stimuli are represented by three numbers called CIE tristimulus values

(X, Y, Z) which may be calculated as follows:

700
100
X=
K 
 = 400
R(  )E(  )x( )

100 700
Y=  R(  )E(  ) y(  )
K  = 400
100 700
Z=  R(  )E(  )z(  )
K  = 400

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Where E(λ) is the relative spectral energy distribution of the illuminant, R(λ) is the spectral

reflectance factor of the object and x (), y (), z () are the colour matching functions of the CIE

standard observer. K is a normalising constant.

A light source is an essential component of visualisation and measurement of colour. Various

light sources, such as daylight (D65), tungsten lamp (A), fluorescent lamp (F1 to F12),

departmental lamp (TL84) etc., emit different amounts of energy in the visible region of the

spectrum that can be expressed in the form of its relative spectral power distribution (SPD) curve.

An illuminant is an ideal form of a light source with defined SPD. The SPD of light source may

vary, but that of illuminant is constant or defined and hence, it is used for quantification of colour

as mentioned above.

In the visual observing situation, the observer is the human eye that receives the light reflected

from or transmitted through an object and the brain which perceives the vision. Since different

human perceive colour in different ways, subjectively, attempts have been made to standardise

the human observer as a numerical representation of what the average person sees. This

standard observer could then be used in lieu of a human observer when assessments are made

instrumentally. In 1931 CIE published the 2 CIE Standard Observer function based on colour

matching by viewing through a hole of 2 field of view. Later it came to know that cones present in

a larger area of the eye. Hence, in 1964, the 10 Standard Observer function was developed

which is now universally used.

When two objects have equal tristimulus values under a particular illuminant, they will look alike in

colour under the said illuminant. If their reflectance curves are same they will look alike in colour

under any illuminant (universal match). Otherwise they may or may not differ in colour when the

illuminant is changed. On the other hand, two alike colours with different lightness may have

different tristimulus values. To express colours in two-dimensional space independent of

lightness, chromaticity coordinates may be calculated as follows:

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X Y Z
x = ————, y = ————, z = ————
X+Y+Z X+Y+Z X+Y+Z

As x + y + z = 1, only two chromaticity coordinates x and y have been recommended by CIE to

specify chromaticity. Instead of tristimulus values (X, Y, Z), colours can also be specified by a

luminance parameter Y and two colour coordinates x and y (Yxy colour space).

However, none of the chromaticity coordinates is correlated with any meaningful visual attribute

of colour.

When the chromaticity coordinates of spectral colours are plotted in such diagram, a horse-shoe

shaped curve called chromaticity diagram is obtained. Chromaticity diagram is of great help in

finding colours generated by additive colour mixing. If two lights are represented by two points on

the chromaticity diagram, any additive mixture of the two will correspond to a point on the straight

line joining the two points. Since the locus of spectral colours is concave, all real colours must fall

within the area bounded by the spectrum locus and joining the ends.

Figure 6 shows CIE 1976 chromaticity diagram along with location of different spectral colours

(i.e. monochromatic lights of different wavelengths in nm). The figure also shows the regions of

locations of different surface colours viewed under daylight. Approximately in the centre of the

curve is the neutral point, which represents the

chromaticities of white, grey or blacks. The

illuminant C having chromaticity co-ordinates x

= 0.310 and y = 0.317 also lies at the centre of

the curve (point C). The locations of other

illuminants depend on their colour temperatures.

The chromaticity diagram is closed by line

indicating the locations of non-spectral purple

colours.

CIE system is very successful for colour

specification and is universally used for colour

measurement. The system is unchanged since 1931 except some minor change in 1964. CIE

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tristimulus values are related only to the colour. It ignores all other aspects like surface texture,

gloss etc. which influence colour appearance significantly. It does not take into account

geometrical arrangements for illumination and viewing and the instrumental measures will match

visual assessments only if the above geometries are similar.

The main limitation of CIE system is its visual non-uniformity. Equal changes in Yxy colour space

do not correspond to equal colour perception. In other words, the distribution of colours in CIE

colour space is non-uniform with regard to visual perception.

Uniform Colour Scales

CIE tristimulus values or chromaticity coordinates are not very convenient for identifying colour of

the objects, because these were designed for colour stimuli of different modes. None of the

values are directly correlated with any visual attributes of colour. Only Y value has high

correlation with luminance and object lightness. The spacing of colours in chromaticity diagram is

not visible uniform. A number of uniform colour scales are, therefore, developed which can

represent colours with equal visual spacing and are directly related to meaningful attributes of

colour appearance.

In 1976 CIE recommended CIELUV and CIELAB uniform colour spaces. Colorant industries were

in favour of a formula similar to Adam-Nickerson (AN40) formula, popular at that time. The

CIELAB formula was acceptable as colour-difference values were about 1.1 times those

produced by AN40 formula. On the other hand, television industries preferred a colour space

(CIELUV) associated with a chromaticity diagram because of its simple way of presentation of

additive mixture which also occur in television and other display devices. No simple relation exists

between the two colour scales.

Both CIELUV and CIELAB formulae are plotted on rectangular coordinates. Lightness L* function

is same for both colour spaces and is represented by the formula,

L* = 116(Y/Yn)1/3 - 16 if Y/Yn 0.008856

For CIELAB Colour Space, Red-green attribute, a* = 500[f(X/Xn) - f(Y/Yn)]

Yellow-blue attribute, b* = 200[f(Y/Yn) - f(Z/Zn)]

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Subscript n represent nominally white object colour stimulus given by a perfect reflecting diffuser

as reference surface illuminated by standard illuminant. For standard daylight illuminant D65, the

values are: Xn = 95.047, Yn = 100.000, Zn =108.883. White object has been taken into account

because we perceive colours in relation to surrounding colours.

In recent years efforts have been made to define CIE correlates for perceptual attributes like

lightness, chroma and hue. Hence, two new attributes corresponding to visual attributes have

been derived from a* and b* values namely:

Metric chroma, C*ab = [(a*)2 + (b*)2] 1/2

Hue angle, h = tan -1 (b*/a*).

CIELAB colour space is shown in the Figure 7.

Lightness L* is represented in vertical axis with white

(L* = 100) at the top and black (L* = 0) at the bottom.

Chromatic colours are represented by two opponent a*

and b* axes. Red and green are represented by a* axis

– the positive values are for red and negative for green. Similarly positive b* values are for yellow

and negative b* values are blue.

Colour Difference

Measurement of difference in colour between two objects is one of the most complicated aspects

of colour vision. The colour discrimination may be general/overall or of specific psychophysical

attribute like hue, chroma or lightness. For colorant users like textile, leather, paper or paint

industries, the difference in colour of two specimens namely a standard and a sample or of

different portions of a coloured specimen may be more important than the measurement of

absolute colour (Luo, 1986). The prime difficulty is that the perception of colour-difference by an

individual is not a precise phenomenon and may vary on successive assessment (Zeller and

Hemmendinger, 1978). Colour-difference perception and evaluation may also vary widely among

individuals.

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The colour-difference evaluation is necessary for day to day colour control and for colour

matching in colouration industries like textile, paint etc. Colour-difference formulae have

accelerated the instrumental pass-fail device a success.

The colour differences are calculated by subtracting values of the standard from the respective

values of the sample. The total colour-difference (ΔE) is intended to be single number metric for

pass/fail decisions and in the CIELAB system ΔE is given by the following equation:

ΔE = [ (ΔL*)² + (Δa*)² + (Δb*)² ]1/2

In addition to the overall colour difference (ΔE), the difference in individual parameters of the

standard and a sample are also estimated e.g. ΔL = L (sample) - L (standard).

These may indicate some specific visual difference such as

if ΔL < 0 or > 0, the sample is darker or lighter respectively,

if Δa* < 0 or > 0, the sample is greener or redder respectively,

if Δb* < 0 or > 0, the sample is bluer or yellower respectively.

ΔE (CIELAB) values are not always reliable in predicting perceptible differences between object

colours, especially when the variations are in different visual attributes. This is due to the fact that

the visual spacing along L, a* and b* axes are unequal.

The formulae based on surface-mode colour discrimination data mainly aimed at single number

shade-passing. Much of the available visual data related to physical samples are supplied by the

textile and dye industries, where prime criteria is that whether the colours will be acceptable

against the respective standards.

Main reason for poor correlation with visual data of the earlier formulae was equal weighting of

the colour parameters. The weighted values of lightness, chroma and hue showed significant

improvement in performance of colour-difference equations. The weights can be determined by

empirical fitting to experimental data-sets. These formulae are optimized by visual acceptability/

perceptibility scaling. They represent most closely the average visual results of judgments of

colour difference of textile and other physical samples under normal evaluation conditions

(Kuehni, 1984)

A few colour-difference formulae based on surface-mode colour discrimination data are:

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1) JPC79 colour-difference Formula

2) CMC (l:c) colour-difference Formula

3) BFD (l:c) colour-difference Formula

4) CIE 94 colour-difference Formula

5) CIE 2000 colour-difference Formula

However, none of the above formulae is completely satisfactory and acceptability of a particular

formula is decided mutually by producers and users/salers.

Colorimetry is the science of quantitative measurement of colour. Even though study on colour

science started as far back as the Newtonian age, research continues even today. Colour

Science is a vast field. Hunt (1977) identified three phases of development of colorimetry - colour

matching, colour difference evaluation and lastly, prediction of colour appearance. It is now

possible to predict colour appearance of an object under a test illuminant from the colour

appearance data under a reference illuminant with the help of complex mathematical

transformations.

References

Judd D.B. and Wyszecki G. (1975). Color in business, science and industry, 3rd Ed., John Wiley

& sons, New York, p388.

Kuehni R. G. (1984). Colour Technology in the Textile Industry, AATCC, U.S.A., pp.123.

Kuehni R. G. (2005), Colour: an introduction to practice and principles, New Jersey, Wiley-

Interscience.

Leblon C. Jacob (1756). Coloritto or the harmony of colouring in painting, English and French

Edition reprinted in Paris.

Luo M.R. (1986). New Colour Difference Formula for Surface Colours, Ph.D Thesis, University of

Bradford, Bradford, U.K.

Jordan G. and Mollon J. D. (1993). A Study of Women Heterozygous for Colour

Deficiencies, Vision Research Vol. 33, No. I I, pp. 1495-1508.

Optical society of America (OSA) (1953). The science of color, Committee on Colorimetry,

Thomas Y. Cromwell, New York.

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Rhodes P A (2002), Colour notation systems. In Colour Engineering, P Green and L MacDonald

(ed.), pp 307-331, John Wiley, Chichester, England.

Roy Choudhury A.K. (2000). Modern concepts of colour and appearance, Science publishers

(USA) and Oxford & IBH, New Delhi,.

Roy Choudhury A.K. (2008), ‘Colorimetric Study of SCOTDIC Colour Specifier’, Color.

Technology, 124, 273–284.

Roy Choudhury A.K. (2010). Chapter 2. Scales for communicating colour in Colour Measurement:

Principles, advances and industrial applications. Edited by M L Gulrajani, Woodhead Publishing

Series in Textiles No. 103, ISBN 1 84569 559 3.

Sobel Michael I. (1989). Light, University of Chicago Press. pp. 52–62. ISBN 0226767515.

Wright W D (1984), ‘The basic concepts and attributes of colour order systems’, Col. Res. Appl.,

9, 229-233.

Wyszecki G (1986), Colour Appearance, Chapter 9 in Handbook of Perception and Human

Performance, New York, Wiley.

Zeller R.C. and Hemmendinger H. (1978). Evaluation of Color-difference equations: a new

approach, AIC Color 77, Bristol: Adam Hilger.

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