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Excess Naoh (Alkalinity) Hydrosulphite & Leuco Indigo in Indigo Dyebath
Excess Naoh (Alkalinity) Hydrosulphite & Leuco Indigo in Indigo Dyebath
Excess Naoh (Alkalinity) Hydrosulphite & Leuco Indigo in Indigo Dyebath
ION ANALYSIS
Apparatus: Titrino 801 Stirrer , 800 Dosino ( 20 ml & 10 ml ) Separate Pt. ring Electrode6.0351.0
0.125 gm Setamaol EWS, 1 gm Indigo Dye sample, 1.25 gm NaOH , 2.25 gm Hydro added gradually &
Kept Stirring for 1 hr. Whem greenish ORANGE col.observed make 250 ml. with water . Keep for Setting.
Solution turn ORANGE col.
Analysis : Take 20 ml water in beaker .Add 1 ml. Setamol 10ml NaOH purged with N2 for 5 min inside the
soln. Pipetted out 10ml dyebath sample &continue purging N2 while titration.
Two End points observed (1) HYDRO Content (2) Diff.between Ist & IInd EP- Indigo Content
Reagent : 0.1 mol / ltr HCl , K 3 Fe ( CN ) 6 0.01 mol/ltr , N2 gas from Pressuring Flask ,
Apparatus : Titrino /Titro processor ,Magnetic Stirrer, Exchange units, Pt. titrode with Electrode cable , Titration
vessel & its head , Gas inlet & overflow tube.
(A) Alkalinity : Take 20 ml dist. Water & deareate it by bubbling thro’ N2 for 2 to 3 min.
Add 0.5 ……5 ml sample & Titrate with 0.1 mol/ltr HCl Note Endpoint EP1
0.1 mol / ltr = 1 ml HCl = 4.0 mg NaOH gpl NaOH = EP 1 x C 01 / C 00 COO-Col.sample 4 ml
(B) Hydro & Leuco Indigo Take 20 ml dist.water in beaker & deareate it by bubbling thro’ N2 for 2 min.
Add 0.5 ……….5 ml sample dye solution & titrate in MET –mode for titrator .
0.2 ml steps 5 sec waiting time with cyanoferrate ( III) using Pt. Titrode. There are two endpoints .
Gpl Hydrosulphit = EP 1 x CO 1 / CO 0
Gpl Leuco Indigo = ( EP2-EP1) x CO2 / CO0 CO0- Sample size ml , CO1-8.705 ,CO2-13.114
1Mol. Indigo= 1 Mol. Hydro : 272/193 , 1 gm Hydro = 1.41 gm Indigo , 1gm Indigo =0.71 gm Hydro
K3[Fe(CN)6] Mol.Wt = 329 0.5 N or Molar =16.4 gpl , 0.1 N or Molar = 32.9 gpl
Indigo Testing Spectrophotometer
Bausch & Lomb UV-VIS Spectronic – 21
Chem.Required : 30 % H 2 O2
Vatg. Temp:50- 60 o C,
Time : 45 min
6 Volumetric Flask each of 1 ltr capacity charged with 5 ml. 30 % H2O2 solution
The procedure ensures 100% colloidal solution of indigo with no tendency to settle
Calculation :
Titration Method
Take 50 ml conditioner in 100 ml beaker , Place in the redox probe , place oil over the surface .
Take 5 or 10 ml dyebath thro’ pipette & introduce it under the layer of oil in the beaker
From burette add K3 Fe (CN)6 at slow flow rate
End Point col. Change - Honey Yellow ------> Dark Blue
Note Burette reading & Redox Potential
Draw titration curve & Find the concentration .
Calculation of Concentration :
Factor 136
Resulting Value
Conc of K3 [ Fe ( CN ) 6 ]
Hydro