Professional Documents
Culture Documents
(4104) DPP 32 50 B
(4104) DPP 32 50 B
(A) (B)
(C) (D)
Br2 / Fe
6.
(1 eq.)
(A) (B)
(C) (D)
Br
2
7. ____________
CHCl 3
8. The most stable carbocation is formed when the electrophile ( E ) attacks upon position
E
10. Three dibromobenzenes X, Y, Z melt at 87°, 6° and – 7°C respectively. Number of mononitration
products obtained by X, Y and Z are respectively.
(A) 3, 2 and 1 (B) 1, 2 and 3 (C) 2, 3 and 4 (D) 1, 3 and 2
H
p
15. Which one of the following compounds will be most radily attacked by an electrophile ?
(A) Chlorobenzene (B) Benzene (C) Phenol (D) Toluene
16. Benzene reacts with acetyl chloride in presence of anhydrous aluminium chloride to form :
(A) acetophenone (B) phenyl acetate (C) chlorobenzene (D) benzoic acid
18. A
A can be :
20. The reaction of biphenyl with HOCl in presence of a strong acid gives (Major)
(A) (B)
(C) (D)
21. A B
(B) is
22. Which of the following structures correspond to the product expected when excess of C6H6 react
with CH2Cl2 in presence of anh. AlCl3
(A) (B)
(C) (D)
23. The ortho-para (o/p) ratio of the percentage yield of product isomers formed on mononitration is
minimum with
(I)
(II)
(III)
(IV)
(B) m, s m, s m, s p, f
(C) m, s p, f m, s p, f
(D) p, s m, f m, f p, s
25. o/p ratio of the products formed during nitration of alkylbenzene will be nearly one when the alkyl
group attached to benzene ring is
(A) – CH3 (B) – CH2Me (C) – CHMe2 (D) – CMe3
(i ) Cl / Fe
26. 2 Identify the product
( ii) H O, , H
2
Br Br
Cl Br
Cl Cl Cl
(A) (B) (C) (D)
SO3H OH SO3H
Cl Cl OH
NO2
O
||
29. + Cl C Cl X
(A) (B)
(C) (D)
140C
30. + CH3CH2CH2CH2NH2 X
(A) X is (B) X is
(C) X is (D) X is
gives :
(A) (B)
(C) (D)
(A) (B)
(C) (D)
34. The given product can not be formed by which set of reactants in the presence of AlCl3 catalyst.
(A) + (B)
36. Compound Y, C7H8O is insoluble in water, dil HCl and aqueous NaHCO3. It dissolves in dilute
NaOH. When Y is treated with bromine water it is converted rapidly into a compound of formula
C7H5OBr3. Identify the structure of Y
37. X Y
39. Observe the following reaction carefully. Select the correct answer regarding the major product
formed and the relative reactivity of compound X with respect to ethene for the following reaction.
Br (1eq.) / CCl
X= 2
4
41. Which of the following is not the correct route to prepare compound 'X'
X =
(B)
(C) +
(D)
42. The major product of the following reaction has substitution at position
Br / Fe
2
44. n-propyl benzene will be the final major product in the reaction.
(B) + CH3CH2CH2Cl
(C)
(D)
(A) (B)
(C) (D)
HNO
3
H2SO4
(A) (B)
(C) (D)
(A) (B)
(A)
(B)
(C)
(D)
53. Major product formed by SE reaction in disubstituted benzene has been given. Which is not the
correct formation ?
(A) (B)
(C) (D)
55. Consider following -complex of SE reaction on the benzene and its compounds.
+ E+
+ E+
+ E+
56. SE reaction product has been given in each case. In which case orientation is incorrect ?
(A) +
(B)
(C)
(D)
Free energy change associated with addition product and electrophilic substitution has been given
in the diagram. Answer the questions based on this :
(A) (B)
59.
In monosubstituted benzene derivatives, if the substituent group provides electron density to the
ring by its resonance effect, it is always ortho para directing. The arenes (alkyl benzenes) stabilize
the arenium ion by + I and hyperconjugative effect so are also activating and ortho para directing.
If the substituent group withdraws electron density by resonance effect then it is meta directing. In
case of disubstituted benzenes, the strongly activating group dominates over weakly activating or
deactivating groups in deciding the orientation of major product. There is often little substitution
between two group that are meta to each other due to steric crowding.
61. ;
62.
63. Which of the following aromatic ring is most basic with DF / BF3.
HCl Br2 / Fe
H
64. +
(1) ( 2) (3)
(A) (B)
(C) (D)
(C) (D)
(A) (B)
(C) (D)
67. Which of the following structures correspond to the product expected when excess of C6H6 react
with CH2Cl2 in presence of anh. AlCl3
(A) (B)
(C) (D)
(A) Benzene
(B) Benzene
(C) Benzene
(D) Benzene
69. + CO + HCl
C or D cannot be
70. A B
(B) is
71. A
‘A’ is
The main factor for such observation with different halogens can be
(A) Polar factor (B) Steric factor
(C) Ionisation of X2 (D) Ionisation of phenol
73. Three dibromobenzenes X, Y, Z melt at 87°, 6° and – 7°C respectively. Number of mononitration
products obtained by X, Y and Z are respectively.
(A) 3, 2 and 1 (B) 1, 2 and 3 (C) 2, 3 and 4 (D) 1, 3 and 2
75. The most stable and the least stable resonating structures are respectively
(A) I and IV (B) I and III (C) II and III (D) III and II
(A) C6H6 and C6D6 react with almost same rate for most of the electrophiles
(B) II is an aromatic species
(C) rate of first step (r1) is faster than rate of second step (r2) in most of aromatic electrophilic
substitution reactions
(D) Electrophilic addition is more favoured than electrophilic substitution in benzene
77. The correct order of resonance energy of the following compounds would be
(A) > > > V (B) V > > > (C) > > > V (D) > > > V
(A) (B)
(C) (D)
79. Where the nitration will take place in the following compound ?
80. 1, 2, 4-Tribromo benzene on nitration gives all possible isomers mono nitration products
(A) 1 (B) 2 (C) 3 (D) 4
3. C, D 4. C
5. A 6. B 7. B 8. A