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1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

PRODUCT NAME : SEA GRANDPRIX 880 HS, COLORS


Product Type : Special Syntethic Resin Paints
MANUFACTURER : PT. CHUGOKU PAINTS INDONESIA
Midplaza I,8th Floor. Jalan Jendral Sudirman Kav. 10-11 Jakarta 10220, Indonesia
Charge Section : Technical Department
Telephone Number : +62 21 5700515 Fax Number : (021)57337887
Emergency Call : +62 21 5902005
Issued : May. ,2018

2. HAZARD(S) IDENTIFICATION

GHS CLASSIFICATION :
Flammable liquids Category 3 Acute Toxicity ( Inhalation ) Category 4
Skin Corrosion / Irritation Category 1 Acute Toxicity ( Oral ) Category 4
Eye Corrosion / Irritation Category 2 Aquatic Environmental Hazard Category 1
Carcinogenicity Category 2

GHS-Labeling

Symbol(s) :

Signal Word : Danger

Hazard Statements :
H226: Flammable liquid and vapor.
H302: Harmful if swallowed.
H332: Harmful if inhaled
H319: Causes serious eye irritation
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
H317: May cause an allergic skin reaction
H351: Suspected of causing cancer
H360: May damage fertility or the unborn child
H370: Causes damage to the kidneys/ liver/ eyes/ brain/ respiratory system/ central nervous system if inhaled.
H372: Causes damage to organs (Central nervous system, Hematopoietic system) through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
H401: Toxic to aquatic life.

Precautionary Statements :
Prevention:
P201: Obtain special instructions before use.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapor/spray.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed: Get Medical advice / attention.
P331: Do NOT induce vomiting.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/ attention.
P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P391: Collect spillage.
Storage: P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Disposal: P501: Dispose of contents/ container to an approved waste disposal plant.
3. COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS No. Content ( % )


Zinc Oxide (ZnO) 1314 – 13 – 2 1–5
Diiron Trioxide 1309 – 37 – 1 1–5
Titanium Dioxide 13463 – 67 – 7 1–5
Cuprous oxide 1317 – 39 – 1 30 – 40
Coper (II) Oxide (CuO) 1317 – 38 – 0 0.1 – 1
4,5-Dichloro-2-N-Octyl-4-isothiatzolin-3-one 64359 – 81 – 5 0.1 – 1
Xylene 1330 – 20 – 7 1 – 10
Ethyl Benzene 100 – 41 – 4 1 – 10
Tritolyl Phosphate 1330 – 78 – 5 1–5
MIBK 108 – 10 – 1 1–5
Rosin 8050 – 09 – 7 5 – 10

4. FIRST-AID MEASURES
# INHALATION Move the exposed person to fresh air at once. Rinse nose and mouth with water.
Get medical attention if any discomfort continues.
# INGESTION If swallow accidentally keep a patient in quit place and consult doctor immediately
Do not induce vomiting unless directed by medical personnel!
# SKIN CONTACT Remove affected person from source of contamination. Remove contaminated clothing.
Wash the skin immediately with soap and water. Get medical attention if any discomfort continues.
# EYE CONTACT Remove victim immediately from source of exposure. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.

5. FIRE-FIGHTING MEASURES
This product is flammable liquid.
EXTINGUISHING MEDIA : Carbon Dioxide Fire Extinguisher Foam Fire Extinguisher
Powder Fire Extinguisher Dry Sand Fire Extinguisher.
Do not use water-jet for fire extinguishing.
Use fire-extinguishing media appropriate for surrounding materials.

Special hazards arising from the substance or mixture


Hazards from the substance or Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with mixture : the risk of a
subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Hazardous combustion products :


Decomposition products may include the following materials: carbon oxides nitrogen oxides sulfur oxides halogenated compounds metal oxide/oxides

Advice for firefighters


Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without
suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Cool closed containers exposed to fire with
water. Do not release runoff from fire to drains or watercourses. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.

6. ACCIDENTAL RELEASE MEASURES


# PERSONAL PRECAUTIONS & PROTECTIVE EQUIPMENT :
Wear protective clothing as described in Section 8 of this safety data sheet.
Clear away all sources of ignition, heat, and flammable materials immediately
# ENVIRONMENTALLY PRECAUTIONS :
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
# MATERIALS AND SPILL CLEAN UP METHODS
Stop leak if possible without risk. Do not let spills to drain, river and sea and other water sources.
Absorb spills with noncombustible materials such as dry sand and soil and collect in vermiculite and place in closed containers.

7. HANDLING AND STORAGE


# PRECAUTIONS FOR SAFE HANDLING.
Wear overall clothes and goggles to protect skin, membrane and eyes. Handle carefully in a well ventilated place.
Use adequate tools to prevent spark. Keep container closed tightly.
Provide earthing leads and an explosion-prevention for electrical equipments and installation.
Prevent unauthorized access.
# SAFETY STORAGE :
Store in accordance with local regulations for flammable liquids. Keep out of the reach of children
Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking.
Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Containers that are opened must be carefully resealed and kept upright to prevent leakage
8. EXPOSURE CONTROL AND PERSONAL PROTECTION

Nama Bahan ACGIH OSHA


TWA (mg/m3) TWA (ppm) PEL (Mg / m3) PEL (ppm)
Zinc Oxide (ZnO) 2 - - -
Diiron Trioxide 5 (Fe, Fume) - - -
Titanium Dioxide 10 - - -
Cuprous oxide 0.2 (fume) - - -
Xylene - 100 - -
Ethyl Benzene - 100 435 100
MIBK - 50 - -

PROTECTIVE EQUIPMENT

Individual protection measures


General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be worn when soiling is so great that
regular work clothes do not adequately protect skin against contact with the product. Safety eyewear should be used when there is a likelihood
of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to
liquid splashes, mists or dusts.
Hand protection : Wear chemical-resistant gloves in combination with 'basic' employee training. The quality of the chemical-resistant protective gloves must be
chosen as a function of the specific workplace concentrations and quantity of hazardous substances. Since the actual work situation is
unknown. Supplier of gloves should be contacted in order to find the appropriate type.
Body protection : Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at the neck and wrists through
contact with the product are avoided. Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product. Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : If working areas have insufficient ventilation, wear half or totally covering mask equipped with gas filter of type Organic Vapor, when grinding
use particle filter of type P95, P99 or P100. When spraying use a combined filter (organic vapor / HEPA or organic vapor / P100 type). Be sure to
use approved/certified respirator or equivalent. Always wear an air-fed respirator when spraying in a continuous and prolonged work situation
(e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter).

9. PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE Liquid
COLOUR Brown and Light Brown
ODOUR Solvent smell
BOILING POINT 117 – 144.4 °C
FLASH POINT 23°C
DENSITY 1.91 – 2.01
SOLUBILITY Insoluble in water
EXPLOSION LIMIT 1.1 – 8.0% ( LEL - UEL )

10. STABILITY AND REACTIVITY


# REACTIVITY : No specific test data related to reactivity available for this product or its ingredients.
# CHEMICAL STABILITY The product is stable.
# POSSIBILITY of HAZARDOUS REACTIONS
Under normal conditions of storage and use, hazardous reactions will not occur.
# CONDITIONS TO AVOID Avoid all possible sources of ignition (spark or flame).
Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
# INCOMPATIBLE MATERIALS Highly reactive or incompatible with the following materials: oxidizing materials, reducing materials and acids.
Reactive or incompatible with the following materials: organic materials, alkalis and moisture.
# HAZARDOUS DECOMPOSITION PRODUCTS
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed.

11. TOXICOLOGICAL INFORMATION


Materials elements categorized as “Not Classified” or “Classification Not Possible” by GHS are not described.
Harmful information on substance :
ACUTE TOXICITY
INGREDIENT NAME LD / LC TYPE DOSE
LD50 rat, oral 7950 mg / kg
ZINC OXIDE LD50 rat, dermal 8437 mg / kg
LC50 rat, inhalative 2500 mg/m3
LD50 rat, oral 4300 mg/kg
XYLENE LD50 rat, dermal > 1700 mg/kg
LC50 rat, inhalative 5000 ppm (4H)
LD50 rat, oral 2525 mg / kg
ETHYL BENZENE LD50 rat, dermal 15415 mg / kg
LC50 rat, inhalative 17 mg / L
LD50 rat, oral 2,080 mg/kg
MIBK LD50 rabbit, dermal 3000 mg/kg
LC50 rat, inhalative 100000 mg/m3

12. ECOLOGICAL INFORMATION


ECOTOXICITY Do not allow to enter drains or watercourses.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national
requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the
material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material
generated to determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7 and Section 8 for additional handling information and protection of employees.

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul
sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers
or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.

14. TRANSPORT INFORMATION


Make sure there are no damage, corrode and leak on the product container . Products should be also prevented from falling, loosening or tumbling during transit.
Packing, labeling and transport take place according to appropriate regulation.

Flammable Liquid
UN Number : 1263 Class Number : 3 Packaging Group : III
Proper Shipping Name : Paint Technical Name : Anti Fouling Paint EMS Code : FE - SE

15. REGULATORY INFORMATION


Product related hazard information : The product has been classified and marked in accordance with directives on hazardous materials.
Related Regulation :
1. GHS Purple Book (Revision 5, 2013 )
2. Government Regulation of the Republic of Indonesia no. 74 year 2001, Concerning the Management of Hazardous and Toxic Materials.
3. Republic of Indonesia Minister of Industry Regulation, No. 23/M-IND/PER/4/2013, concerning Global Harmonization System Classification and Labels on
Chemicals.
4. Minister of Manpower Decree of the Republic of Indonesia no. 187 year 1999 Concerning Managing of Hazardous Chemicals in the Workplace.
5. General Director Regulation of Basic Industrial Manufacture No. 04/BIM/PER/1/2014 for Technical Guidance and Monitoring of Global Harmonization
System Implementation, Classification, and Label for Chemical Goods.

16. OTHER INFORMATION

This data is based on our present knowledge.


However, it shall not constitute a guarantee for any specific product feature and shall not establish a legally valid contractual relationship.

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