Resource section 4 Character tables ‘The character tables that follow are for the most common point groups encountered in inorganic chemistry. Each one is labelled with the symbol adopted in the Schoenfles system of nomenclature (such as C,.). Point groups that qualify as crystallographic point groups (because they are also applicable co unit cells) are also labelled with the symbol adopted in the International System (or the Hermann-Mauguin system, stich as 2/m). In the latter syscem, a number # represents an r-fold axis and a letcer mm represents 8 mieror plane. A diagonal line indicates that a mirror plane lies perpendicular to the symmetry axis and a bar over the number indicates that the rotation is combined with an inversion. ‘The symmetry species of the p and d orbitals are shown on the right of the tables. Thus, in C,, ap, orbital (which is proportional to x) has B, symmetry. The functions x, y, and 2 also show the transformation properties of translations and of the electric dipole moment. ‘The set of functions that span a degenerate representation (such as x and y, which joinely span E in C,,) are enclosed in parentheses. The transformation properties of roration are shown by the letters K on the right of the tables, The value of b is the order of the group. The groups 6,6, 6, ea fe > z EG & aft x 1 1 faxR, Bay 1 ADRK, BoP x 1 at fark, yer 1 alane “The groups ¢, 62 [kc G8) [EGG [esepianvs) bs a > afraid fer Faye ee tee E tee fp emMBeR Yo) bez) Ga lz G&G bea aA froa a afar eae Bott aa oy ian E pai af fRMRRY beeResource section4 SOT rd ©,,(2mm) [EC 0,(x2) of (v2) bad C,Gm) [E 20, 30, b= 5 at 4 Jeg 2 Efe 0 [rem gy wees entense) Talon [E20 6, Fe, ts, ie alee, Sia aa de ta 0a alk e ofaaaa e 2 ewe deorta 0 JoesNRLR) lene ©, eum) |B 26, 20, C, 40, 30, h eae enc) =, A, Toaoto1ai1 tile svat pou lide moira aaa] 2 rare o oa BR j2ta200 7 meow, ER EEGeLen ae Dea fe 26, 3a, ie To a fa a a rn A ft oa a fee802 Resource section 4 Tesoro, Dim [Bea eGo tae) oa) oe |e = aoa 4 rr are Puede a6 3 @ ™ 1 1114 wane Be for aaa al, ” : tad al ” ta aaa ifs Di Wee [eae ea aga ee, bate aoa ad 14 wane jor a a a taialy fat a 4 ta a a a] ey for doa ot 4 4 4 4 a} fDtoi a 44 4 4 4 Gh Diy Rug aa, u [2 tenta tore 02 dete tema | a) ela 4 tad a | eloioot aaa 4 tle tt [2 tena doe 0 2 aeola tema 0