REFERENCES

1. M.A Fahim, Fundamentals of Petroleum Refining, 1st edition, Elsevier ,2010

2. J.H Gray, Petroleum Refining Technology and Economics, 4th edition, Marcel
Dekker 2001
3. Serge Raseev, Thermal and Catalytic Processes in Petroleum Refining, Marcel
Dekker 2003

4. Ludwig, E.E, ‖ Applied process design‖ , 3rd ed, vol. 2, Gulf

Professional Publishers, 2002.

5. Ludwig, E.E, ―Applied Process Design, 3rd ed, vol. 3, Gulf

Professional Publishers, 2002.
6. McKetta, J.J., ―Encyclopedia of chemical Processing and Design‖, Executive
ed, vol. 1, Marcel Dekker Inc, New York, 1976.
7. Peters, M.S. and Timmerhaus ,K.D., ―Plant Design and Economics for

Chemical Engineering ―, 5th ed, McGraw Hill, 1991.

8. Rase, H.F., ―Fixed Bed Reactor Design and Diagnostics, Butterworth
Publishers, 1990.
9. Frank L., Evans Jr. ―Equipment Design Hand Book For Refineries &

Chemical Plants‖ Vol 2, 2nd Ed., 1980,

10. Peacock, D.G.,‖ Coulson & Richardson‘s Chemical engineering‖,

3rded,vol,Butterworth Heinenann, 1994.

11. Kern D.Q., ―Process Heat Transfer‖, McGraw Hill Inc.,2000.

12. Mcabe, W.L, ―Unit Operations of Chemical Engineering ―,5th ed, McGraw
Hill, Inc,1993.
13. Perry, R.H and D.W. Green (eds): Perry‘s Chemical Engineering Hand Book,

7thed. McGraw Hill New York, 1997.

14. Sinnot, R.K.,‖Coulson & Richardson’s Chemical Engineering‖, 2nd ed,

vol.6, Butterword Heinenann, 1993.
15. Rohsenow,Hartnett,Ganic ―Hand Book of Heat Transfer Application‖ 2nd
edition.

16. W.L.Nelson. ―Petroleum Refinery Engineering‖4 th Ed ,McGraw Hill.

17. Kern, Donald Q:―Process Heat Transfer‖ , McGraw-Hill International Edition
,New York
18. W.L. Nelson: ―Petroleumner Refiy Engineering‖ Fourth Edition, McGraw-Hill,
New York.
19. Kirk: ―Encyclopedia of Chemical Technology ― John Willey and Sons, New
York
20. Macketta, John J: ―Encyclopedia of chemical Processing and Design
Marceer Dekker, INC., New York
21. Warren M. Rohenson: ―Hand book of Heat Transfer ―, McGrawHill, New York
A Components Properties

B Thermodynamic Properties

C Equilibrium Constants

D Graphs used in the designing of Compressor, pump,

heat exchanger and Distillation column

 Boiling Critical Critical Temp
Components Mol Wt
Temperature C Pressure Kpa C

Hydrogen -252.595 2.016 1315.5 -239.71

Methane -161.525 16.0429 4640.68 -82.451
Ethane -88.6 30.0699 4883.85 32.278
Propane -42.102 44.097 4256.66 96.748
n-Butane -0.50199 58.124 3796.62 152.049
n-Pentane 36.059 72.151 3375.12 196.45
n-Hexane 68.73 86.1779 3031.62 234.748
n-Heptane 98.429 100.205 2736.78 267.008
i-Butane -11.73 58.124 3647.62 134.946
i-Pentane 27.878 72.151 3333.59 187.248
2-Mpentane 60.261 86.1779 3010.36 224.347
3-Mpentane 63.27 86.1779 3123.84 231.299
22-Mbutane 49.731 86.1779 3880.62 231.299
23-Mbutane 57.977 86.1779 3126.87 226.83
2-Mhexane 90.049 100.205 2733.62 257.219
3-Mhexane 91.847 100.205 2813.79 262.1
22-Mpentane 79.191 100.205 2773.26 247.35
23-Mpentane 89.778 100.205 2908.02 264.198
24-Mpentane 80.493 100.205 2736.78 246.639
33-Mpentane 86.059 100.205 2945.51 263.248
3-Epentane 93.472 100.205 2890.8 267.49
Benzene 80.089 78.11 4924.39 288.948
Toluene 110.649 92.1408 4100.04 318.649
Cyclopentane 49.248 70.135 4508.95 238.45
Mcyclopentan 71.809 84.1619 3789.55 259.55
Cyclohexane 80.73 84.16 4053 280.05
Ecyclopentan 103.467 98.189 3397.62 296.37
Mcyclohexane 100.929 98.189 3475.37 298.948
223-Mbutane 80.876 100.205 2953.62 258.019
H2 O 99.998 18.0151 22120 374.149
CCl4 76.748 153.822 4559.99 283.25
 Heat of Heat of
Combustion Formation MON RON Flash point Freez point
kJ/Kmol kJ/Kmol

-241942 0 130 -259.25

-802703 -74900 120 -182.75
-1.43E+06 -84738 100.789 111.378 -182.75
-2.04E+06 -103890 97.1 112.135 -187.65
-2.66E+06 -126190 89.6 93.8 -138.15
-3.27E+06 -146490 62.6 61.7 -40.15 -130.15
-3.89E+06 -167290 26 24.8 -21.15 -95.15
-4.50E+06 -187890 0 0 -4.15 -90.15
-2.65E+06 -134590 97.6 101.426 -159.15
-3.27E+06 -154590 90.3 92.3 -56.15 -160.15
-3.85E+06 -174390 73.5 73.4 -35.15 -153.15
-3.88E+06 -171690 74.3 74.5 -32.15 -163.15
-3.87E+06 -185690 93.4 91.8 -48.15 -99.15
-3.88E+06 -177890 94.3 100 -29.15 -128.15
-4.50E+06 -195090 46.4 42.4 -23.15 -118.15
-4.50E+06 -192390 55.8 52 -4.15 -119.15
-4.49E+06 -206290 95.6 92.8 -15.15 -124.15
-4.49E+06 -199390 88.5 91.1 -15.15
-4.49E+06 -202090 83.8 83.1 -12.15 -119.15
-4.49E+06 -201690 86.6 80.8 -19.15 -134.15
-4.50E+06 -189790 69.3 65 -12.15 -118.15
-3.17E+06 82977 101 106 -11.15 5.85
-3.77E+06 50029 103.524 120.083 3.85 -95.15
-3.10E+06 -77288 84.9 101.426 -40.15 -94.15
-3.71E+06 -106790 80 91.3 -27.15 -142.15
-3.69E+06 -123190 77.2 83 -20.15 6.85
-4.32E+06 -127190 61.2 67.2 -4.15 -138.15
-4.29E+06 -154890 71.1 74.8 -6.15 -126.15
-4.49E+06 -204890 101 100 -24.15 -24.15
- -241814
-258069 -100488
 APPENDIX B

Antoine Equation ln(P) = a + b/(T + c) + d*ln(T) + e*T^f

Tmin Tmax Default Q a b c d e f

Hydrogen 13 32 101.3 9.183 -107.9 0 0.1641 6.02E-04 2

Methane 91 190.4 101.3 31.35 -1308 0 -3.261 2.94E-05 2
Ethane 133 305.4 101.3 44.01 -2569 0 -4.976 1.46E-05 2
Propane 145 369.8 101.3 52.38 -3491 0 -6.109 1.12E-05 2
n-Butane 170 425.2 101.3 66.94 -4604 0 -8.255 1.16E-05 2
i-Butane 165 408.1 101.3 58.78 -4137 0 -7.017 1.04E-05 2
n-Pentane 195 469.6 101.3 63.33 -5118 0 -7.483 7.77E-06 2
i-Pentane 220 460.4 101.3 66.76 -5059 0 -8.089 9.25E-06 2
22-Mpropane 260 433.8 101.3 69.98 -4845 0 -8.701 1.11E-05 2
n-Hexane 220 507.5 101.3 70.43 -6056 0 -8.379 6.62E-06 2
2-Mpentane 230 497.5 101.3 72.46 -5929 0 -8.765 7.62E-06 2
3-Mpentane 235 504.4 101.3 70.35 -5909 0 -8.419 7.06E-06 2
22-Mbutane 225 488.8 101.3 56.69 -5087 0 -6.384 5.41E-06 2
23-Mbutane 235 500 101.3 67.02 -5625 0 -7.959 6.96E-06 2
n-Heptane 230 540.2 101.3 78.33 -6947 0 -9.449 6.48E-06 2
2-Mhexane 230 530.4 101.3 75.79 -6688 0 -9.1 6.44E-06 2
3-Mhexane 235 535.3 101.3 74.79 -6650 0 -8.95 6.30E-06 2
22-Mpentane 225 520.5 101.3 70.43 -6198 0 -8.363 6.29E-06 2
23-Mpentane 230 537.3 101.3 70.99 -6430 0 -8.391 5.88E-06 2
24-Mpentane 225 519.8 101.3 71.35 -6255 0 -8.497 6.39E-06 2
33-Mpentane 225 536.4 101.3 77.56 -6450 0 -9.517 7.89E-06 2
3-Epentane 265 540.6 101.3 78.75 -6816 0 -9.568 6.93E-06 2
223-Mbutane 250 531.2 101.3 69.23 -6100 0 -8.213 6.30E-06 2
Benzene 213 552 101.3 169.7 -1.03E+04 0 -23.59 2.09E-05 2
Toluene 178.2 591.8 101.3 76.45 -6995 0 -9.164 6.23E-06 2
Cyclopentane 288 511.6 101.3 51.84 -4915 0 -5.623 4.80E-06 2
Mcyclopentan 288 532.7 101.3 71.34 -6030 0 -8.572 7.17E-06 2
Cyclohexane 293 553.2 101.3 70.98 -6187 0 -8.465 6.45E-06 2
Cyclopentane 376.6 569.5 101.3 98.91 -7885 0 -12.58 8.90E-06 2
Mcyclohexane 298 572.1 101.3 72.24 -6555 0 -8.597 5.97E-06 2
H2O 275 647.3 101.3 65.93 -7228 0 -7.177 4.03E-06 2
CCl4 250 556.4 101.3 74.22 -6240 0 -8.987 7.19E-06 2
 Gibbs Free Energy G = a + b*T + c*T^2 + d*T^3 + e*T^4

a b c d e

Hydrogen 0 0 0 0 0
Methane -7.72E+04 87.74 8.60E-03 0 0
Ethane -8.58E+04 168.6 2.69E-02 0 0
Propane -1.06E+05 264.8 3.25E-02 0 0
n-Butane -1.28E+05 360.5 3.83E-02 0 0
i-Butane -1.37E+05 376.4 3.75E-02 0 0
n-Pentane -1.49E+05 457.5 4.44E-02 0 0
i-Pentane -1.57E+05 464 4.34E-02 0 0
22-Mpropane -1.69E+05 502.8 3.96E-02 0 0
n-Hexane -1.71E+05 554.2 5.03E-02 0 0
2-Mpentane -1.78E+05 563 4.83E-02 0 0
3-Mpentane -1.75E+05 562.7 5.04E-02 0 0
22-Mbutane -1.89E+05 586.5 4.76E-02 0 0
23-Mbutane -1.81E+05 577.8 4.97E-02 0 0
n-Heptane -1.92E+05 650.5 5.64E-02 0 0
2-Mhexane -1.99E+05 658.4 5.65E-02 0 0
3-Mhexane -1.96E+05 654.3 5.65E-02 0 0
22-Mpentane -2.10E+05 685.6 5.64E-02 0 0
23-Mpentane -2.03E+05 664.6 5.63E-02 0 0
24-Mpentane -2.06E+05 681.9 5.63E-02 0 0
33-Mpentane -2.05E+05 678.9 5.63E-02 0 0
3-Epentane -1.93E+05 666.9 5.65E-02 0 0
223-Mbutane -2.09E+05 698.1 5.26E-02 0 0
Benzene 8.15E+04 152.8 2.65E-02 0 0
Toluene 4.78E+04 238.3 3.19E-02 0 0
Cyclopentane -8.05E+04 384.5 4.52E-02 0 0
Cyclopentane -1.10E+05 474 4.91E-02 0 0
Cyclohexane -1.28E+05 520.3 4.47E-02 0 0
Ecyclopentane -1.31E+05 571.4 5.48E-02 0 0
Mcyclohexane -1.60E+05 612.5 4.63E-02 0 0
H2O -2.41E+05 43.41 4.96E-03 0 0
CCl4 -1.01E+05 145.6 -8.68E-03 0 0
 Enthalpy H = a + b*T + c*T^2 + d*T^3 + e*T^4

a b c d e

Hydrogen -49.68 13.84 3.00E-04 3.46E-07 -9.71E-11

Methane -12.98 2.365 -2.13E-03 5.66E-06 -3.73E-09
Ethane -1.768 1.143 -3.24E-04 4.24E-06 -3.39E-09
Propane 39.49 0.395 2.11E-03 3.97E-07 -6.67E-10
n-Butane 67.72 8.54E-03 3.28E-03 -1.11E-06 1.77E-10
i-Butane 30.9 0.1533 2.64E-03 7.27E-08 -7.28E-10
n-Pentane 63.2 -1.17E-02 3.32E-03 -1.17E-06 2.00E-10
i-Pentane 64.25 -0.1318 3.54E-03 -1.33E-06 2.51E-10
22-Mpropane 0 -2.20E-02 3.29E-03 -8.71E-07 -9.07E-11
n-Hexane 74.51 -9.67E-02 3.48E-03 -1.32E-06 2.52E-10
2-Mpentane 111.5 -0.6057 4.92E-03 -3.02E-06 1.07E-09
3-Mpentane 83.82 -0.1695 3.68E-03 -1.56E-06 3.54E-10
22-Mbutane 0 -0.193 3.65E-03 -2.42E-06 6.44E-10
23-Mbutane 0 -0.1695 3.57E-03 -2.35E-06 6.41E-10
n-Heptane 71.41 -9.69E-02 3.47E-03 -1.33E-06 2.56E-10
2-Mhexane 47.74 -0.125 3.60E-03 -1.28E-06 9.86E-11
3-Mhexane 1.96E-08 -5.61E-02 3.38E-03 -1.21E-06 1.85E-10
22-Mpentane 77.69 0.2155 2.82E-03 -6.68E-07 0
23-Mpentane 80.01 0.158 2.83E-03 -6.76E-07 0
24-Mpentane 75.92 0.2227 2.82E-03 -6.68E-07 0
33-Mpentane 82.69 0.1556 2.83E-03 -6.75E-07 0
3-Epentane 78.61 0.1546 2.83E-03 -6.77E-07 0
223-Mbutane 86.02 0.1548 2.83E-03 -6.74E-07 0
Benzene 84.47 -0.5133 3.25E-03 -1.54E-06 3.65E-10
Toluene 74.16 -0.4231 3.18E-03 -1.44E-06 3.27E-10
Cyclopentane 1.56E-08 -0.7645 3.87E-03 -1.44E-06 2.31E-10
Mcyclopentan 127.2 -0.6841 4.01E-03 -1.68E-06 3.58E-10
Cyclohexane 4.56E-09 -0.6481 3.63E-03 -9.99E-07 3.92E-11
Ecyclopentane 64.92 -0.677 4.22E-03 -2.12E-06 7.00E-10
Mcyclohexane 107.6 -0.7046 4.10E-03 -1.53E-06 1.83E-10
H2O -5.73 1.915 -3.96E-04 8.76E-07 -4.95E-10
0 0.2649 6.67E-04 -4.92E-07 1.44E-10
 Heat Capacity (Gas) CpG
CpG = a + b*T + c*T^2 + d*T^3

a b c d
Hydrogen 27.143 9.27E-03 -1.38E-05 7.65E-09
Methane 19.251 5.21E-02 1.20E-05 -1.13E-08
Ethane 5.409 1.78E-01 -6.94E-05 8.71E-09
Propane -4.224 3.06E-01 -1.59E-04 3.21E-08
n-Butane 9.487 3.31E-01 -1.11E-04 -2.82E-09
n-Pentane -3.626 4.87E-01 -2.58E-04 5.30E-08
n-Hexane -4.413 5.82E-01 -3.119E-04 6.49E-08
n-Heptane -5.146 6.76E-01 -3.65E-04 7.66E-08
i-Butane -1.39 3.85E-01 -1.85E-04 2.90E-08
i-Pentane -9.525 5.07E-01 -2.73E-04 5.72E-08
2-Mpentane -10.57 6.18E-01 -3.57E-04 8.08E-08
3-Mpentane -2.386 5.69E-01 -2.87E-04 5.03E-08
22-Mbutane -16.634 6.29E-01 -3.48E-04 6.85E-08
23-Mbutane -14.608 6.15E-01 -3.38E-04 6.82E-08
2-Mhexane -39.389 8.64E-01 -6.29E-04 1.84E-07
3-Mhexane -7.046 6.84E-01 -3.73E-04 7.83E-08
22-Mpentane -50.099 8.96E-01 -6.36E-04 1.74E-07
23-Mpentane -7.046 7.05E-02 -3.73E-04 7.83E-08
24-Mpentane -7.046 6.84E-01 -3.73E-04 7.83E-08
33-Mpentane -7.046 6.84E-01 -3.73E-04 7.83E-08
3-Epentane -7.046 6.84E-01 -3.73E-04 7.83E-08
Benzene -33.917 4.74E-01 -3.02E-04 7.13E-08
Toluene -24.355 5.12E-01 -2.77E-04 4.91E-08
Cyclopentane -53.625 5.43E-01 -3.03E-04 6.49E-08
Mcyclopentane -50.108 6.38E-01 -3.64E-04 8.01E-08
Cyclohexane -54.541 6.11E-01 -2.52E-04 1.32E-08
Ecyclopentane -61.919 7.84E-01 -4.44E-04 9.37E-08
Mcyclohexane -55.312 7.51E-01 -4.40E-04 1.00E-07
223-Mbutane -22.944 7.52E-01 -4.42E-04 1.00E-07
 Heat Capacity (Liquid) CpL
CpL = a + b*T + c*T^2 + d*T^3 +e*T^4

a b c d e

Hydrogen 15.84 -0.8189 4.87E-02 0 0

Methane
370.4 -11.3 0.1483 -8.55E-04 1.86E-06
Ethane
143.4 -2.118 2.15E-02 -9.35E-05 1.52E-07
Propane
124.03 -1.0717 1.01E-02 -3.84E-05 5.57E-08

n-Butane
319.19 -3.5845 2.26E-02 -6.07E-05 6.28E-08

n-Pentane
164.2199 -0.3209 1.11E-03

n-Hexane
198.2 -0.3866 1.26E-03
n-Heptane
218.5 -0.2968 1.06E-03
i-Butane
172.37 -1.7839 1.48E-02 -4.79E-05 5.81E-08

i-Pentane
108.3 0.146 -2.92E-04 1.51E-06

2-Mpentane
142.22 -4.78E-02 7.39E-04

3-Mpentane
140.49 -3.48E-02 6.81E-04

22-Mbutane
125.45 3.54E-02 5.96E-04
23-Mbutane
129.45 1.85E-02 6.08E-04

2-Mhexane
174.01 -0.10578 9.05E-04

3-Mhexane
157.94 -4.40E-03 7.10E-04

22-Mpentane
133.57 0.1093999 6.19E-04

23-Mpentane
 146.42 5.92E-02 6.04E-04
24-Mpentane
133.5 0.1278 5.92E-04
33-Mpentane
156.03 -5.28E-02 8.34E-04
3-Epentane
148.02 6.39E-02 5.91E-04 -2.72E-17 3.61E-20

Benzene
129.44 -0.1695 6.48E-04
Toluene
140.1399 -0.1523 6.95E-04 3.98E-20 -3.47E-23
Cyclopentane
122.53 -0.4038 1.73E-03 -1.10E-06
Mcyclopentane
155.92 -0.4899999 2.14E-03 -1.56E-06

Cyclohexane
-220.6 3.1183 -9.42E-03 1.07E-05 9.34E-22
Ecyclopentane
178.52 -0.51835 2.33E-03 -1.68E-06 1.17E-22

Mcyclohexane
131.34 -6.31E-02 8.13E-04

223-Mbutane
88.446 0.40272 5.62E-05
H2O
276.37 -2.0901 8.13E-03 -1.41E-05 9.37E-09
 APPENDIX C
iC4/nC4
Temerature Temerature
a b c G nC4 a b c G iC4 ∆G ln K K X X%
C K
100 373 -1.28E+05 3.60E+02 3.83E-02 1.14E+04 -1.37E+05 3.76E+02 3.75E-02 8.82E+03 -2.59E+03 0.835144 2.305145 0.697441 69.74414
110 383 -1.28E+05 3.60E+02 3.83E-02 1.53E+04 -1.37E+05 3.76E+02 3.75E-02 1.29E+04 -2.44E+03 0.765084 2.149176 0.682457 68.24566
120 393 -1.28E+05 3.60E+02 3.83E-02 1.92E+04 -1.37E+05 3.76E+02 3.75E-02 1.69E+04 -2.28E+03 0.698637 2.01101 0.667886 66.78855
130 403 -1.28E+05 3.60E+02 3.83E-02 2.31E+04 -1.37E+05 3.76E+02 3.75E-02 2.10E+04 -2.13E+03 0.635533 1.888027 0.653743 65.37429
140 413 -1.28E+05 3.60E+02 3.83E-02 2.70E+04 -1.37E+05 3.76E+02 3.75E-02 2.51E+04 -1.98E+03 0.575528 1.77807 0.640038 64.00378
162

150 423 -1.28E+05 3.60E+02 3.83E-02 3.10E+04 -1.37E+05 3.76E+02 3.75E-02 2.91E+04 -1.82E+03 0.518404 1.679346 0.626775 62.67745
160 433 -1.28E+05 3.60E+02 3.83E-02 3.49E+04 -1.37E+05 3.76E+02 3.75E-02 3.32E+04 -1.67E+03 0.463961 1.590361 0.613953 61.39534
170 443 -1.28E+05 3.60E+02 3.83E-02 3.88E+04 -1.37E+05 3.76E+02 3.75E-02 3.73E+04 -1.52E+03 0.412017 1.50986 0.601571 60.15713
180 453 -1.28E+05 3.60E+02 3.83E-02 4.28E+04 -1.37E+05 3.76E+02 3.75E-02 4.14E+04 -1.36E+03 0.362406 1.436782 0.589623 58.96228
190 463 -1.28E+05 3.60E+02 3.83E-02 4.67E+04 -1.37E+05 3.76E+02 3.75E-02 4.55E+04 -1.21E+03 0.314978 1.370229 0.5781 57.80999
200 473 -1.28E+05 3.60E+02 3.83E-02 5.07E+04 -1.37E+05 3.76E+02 3.75E-02 4.96E+04 -1.06E+03 0.269594 1.309433 0.566993 56.69932
 iC5/nC5
Temperature
Temperature a b c G nC5 a b c G iC5 ∆G ln K K X X%
K
C
100 373 -1.49E+05 4.57E+02 4.44E-02 2.77E+04 -1.57E+05 4.64E+02 4.34E-02 2.17E+04 -6.01E+03 1.938594 6.948976 0.874198 87.41976
110 383 -1.49E+05 4.57E+02 4.44E-02 3.26E+04 -1.57E+05 4.64E+02 4.34E-02 2.66E+04 -5.95E+03 1.869926 6.487819 0.86645 86.64498
120 393 -1.49E+05 4.57E+02 4.44E-02 3.75E+04 -1.57E+05 4.64E+02 4.34E-02 3.16E+04 -5.90E+03 1.804815 6.078845 0.858734 85.8734
130 403 -1.49E+05 4.57E+02 4.44E-02 4.24E+04 -1.57E+05 4.64E+02 4.34E-02 3.66E+04 -5.84E+03 1.742994 5.714428 0.851067 85.1067
140 413 -1.49E+05 4.57E+02 4.44E-02 4.74E+04 -1.57E+05 4.64E+02 4.34E-02 4.16E+04 -5.78E+03 1.684226 5.38828 0.843463 84.34633
150 423 -1.49E+05 4.57E+02 4.44E-02 5.23E+04 -1.57E+05 4.64E+02 4.34E-02 4.66E+04 -5.73E+03 1.628294 5.095175 0.835936 83.59358
160 433 -1.49E+05 4.57E+02 4.44E-02 5.73E+04 -1.57E+05 4.64E+02 4.34E-02 5.16E+04 -5.67E+03 1.575001 4.830747 0.828495 82.84954
170 443 -1.49E+05 4.57E+02 4.44E-02 6.22E+04 -1.57E+05 4.64E+02 4.34E-02 5.66E+04 -5.61E+03 1.524169 4.591326 0.821152 82.11515
180 453 -1.49E+05 4.57E+02 4.44E-02 6.72E+04 -1.57E+05 4.64E+02 4.34E-02 6.17E+04 -5.56E+03 1.475634 4.373809 0.813912 81.39123
190 463 -1.49E+05 4.57E+02 4.44E-02 7.22E+04 -1.57E+05 4.64E+02 4.34E-02 6.67E+04 -5.50E+03 1.429249 4.17556 0.806784 80.67842
200 473 -1.49E+05 4.57E+02 4.44E-02 7.72E+04 -1.57E+05 4.64E+02 4.34E-02 7.17E+04 -5.45E+03 1.384875 3.994328 0.799773 79.97728
 2MP/nC6
Temperature
Temperature a b c G nC6 a b c G 2MP ∆G ln K K X X%
C
K
100 373 -1.70E+05 5.54E+02 5.30E-02 4.36E+04 -1.78E+05 5.63E+02 4.83E-02 3.91E+04 -4.57E+03 1.473963 4.366507 0.813659 81.36591
110 383 -1.70E+05 5.54E+02 5.30E-02 4.96E+04 -1.78E+05 5.63E+02 4.83E-02 4.51E+04 -4.52E+03 1.418852 4.132373 0.805158 80.51583
120 393 -1.70E+05 5.54E+02 5.30E-02 5.55E+04 -1.78E+05 5.63E+02 4.83E-02 5.11E+04 -4.47E+03 1.366833 3.922909 0.796868 79.68681
130 403 -1.70E+05 5.54E+02 5.30E-02 6.15E+04 -1.78E+05 5.63E+02 4.83E-02 5.71E+04 -4.42E+03 1.317678 3.73474 0.788795 78.87952
140 413 -1.70E+05 5.54E+02 5.30E-02 6.75E+04 -1.78E+05 5.63E+02 4.83E-02 6.31E+04 -4.37E+03 1.271178 3.565051 0.780944 78.09444
150 423 -1.70E+05 5.54E+02 5.30E-02 7.35E+04 -1.78E+05 5.63E+02 4.83E-02 6.91E+04 -4.32E+03 1.227145 3.411476 0.773319 77.33185
160 433 -1.70E+05 5.54E+02 5.30E-02 7.94E+04 -1.78E+05 5.63E+02 4.83E-02 7.52E+04 -4.27E+03 1.185408 3.272021 0.765919 76.59188
170 443 -1.70E+05 5.54E+02 5.30E-02 8.55E+04 -1.78E+05 5.63E+02 4.83E-02 8.12E+04 -4.22E+03 1.145811 3.144991 0.758745 75.8745
180 453 -1.70E+05 5.54E+02 5.30E-02 9.15E+04 -1.78E+05 5.63E+02 4.83E-02 8.73E+04 -4.17E+03 1.108213 3.028941 0.751796 75.17958
190 463 -1.70E+05 5.54E+02 5.30E-02 9.75E+04 -1.78E+05 5.63E+02 4.83E-02 9.34E+04 -4.13E+03 1.072484 2.922631 0.745069 74.5069
200 473 -1.70E+05 5.54E+02 5.30E-02 1.04E+05 -1.78E+05 5.63E+02 4.83E-02 9.95E+04 -4.08E+03 1.038506 2.824993 0.738562 73.85616

3MP/nC6
Temperature
Temperature a b c G nC6 a b c G 3MP ∆G ln K K X X%
C
K
100 373 -1.70E+05 5.54E+02 5.30E-02 4.36E+04 -1.75E+05 5.63E+02 4.83E-02 4.18E+04 -1.87E+03 0.603146 1.827861 0.646376 64.63758
110 383 -1.70E+05 5.54E+02 5.30E-02 4.96E+04 -1.75E+05 5.63E+02 4.83E-02 4.78E+04 -1.82E+03 0.571776 1.771411 0.639173 63.91729
120 393 -1.70E+05 5.54E+02 5.30E-02 5.55E+04 -1.75E+05 5.63E+02 4.83E-02 5.38E+04 -1.77E+03 0.542291 1.719943 0.632345 63.23453
130 403 -1.70E+05 5.54E+02 5.30E-02 6.15E+04 -1.75E+05 5.63E+02 4.83E-02 5.98E+04 -1.72E+03 0.514551 1.672888 0.625873 62.58728
140 413 -1.70E+05 5.54E+02 5.30E-02 6.75E+04 -1.75E+05 5.63E+02 4.83E-02 6.58E+04 -1.68E+03 0.488429 1.629755 0.619736 61.97364
150 423 -1.70E+05 5.54E+02 5.30E-02 7.35E+04 -1.75E+05 5.63E+02 4.83E-02 7.18E+04 -1.63E+03 0.463811 1.590122 0.613918 61.39178
160 433 -1.70E+05 5.54E+02 5.30E-02 7.94E+04 -1.75E+05 5.63E+02 4.83E-02 7.79E+04 -1.59E+03 0.440591 1.553626 0.6084 60.84
170 443 -1.70E+05 5.54E+02 5.30E-02 8.55E+04 -1.75E+05 5.63E+02 4.83E-02 8.39E+04 -1.54E+03 0.418676 1.519949 0.603167 60.31665
180 453 -1.70E+05 5.54E+02 5.30E-02 9.15E+04 -1.75E+05 5.63E+02 4.83E-02 9.00E+04 -1.50E+03 0.39798 1.488814 0.598202 59.82021
190 463 -1.70E+05 5.54E+02 5.30E-02 9.75E+04 -1.75E+05 5.63E+02 4.83E-02 9.60E+04 -1.46E+03 0.378422 1.459979 0.593492 59.34924
200 473 -1.70E+05 5.54E+02 5.30E-02 1.04E+05 -1.75E+05 5.63E+02 4.83E-02 1.02E+05 -1.42E+03 0.359931 1.43323 0.589024 58.90237
 22DMB/nC6
Temperature
Temperature a b c G nC6 a b c G 22DMB ∆G ln K K X X%
C
K
100 373 -1.70E+05 5.54E+02 5.30E-02 4.36E+04 -1.89E+05 5.86E+02 4.76E-02 3.62E+04 -7.47E+03 2.407693 11.10831 0.917412 91.74121
110 383 -1.70E+05 5.54E+02 5.30E-02 4.96E+04 -1.89E+05 5.86E+02 4.76E-02 4.24E+04 -7.18E+03 2.256172 9.546472 0.905182 90.51816
120 393 -1.70E+05 5.54E+02 5.30E-02 5.55E+04 -1.89E+05 5.86E+02 4.76E-02 4.86E+04 -6.90E+03 2.112692 8.270474 0.892131 89.21307
130 403 -1.70E+05 5.54E+02 5.30E-02 6.15E+04 -1.89E+05 5.86E+02 4.76E-02 5.49E+04 -6.62E+03 1.976655 7.218559 0.878324 87.83242
140 413 -1.70E+05 5.54E+02 5.30E-02 6.75E+04 -1.89E+05 5.86E+02 4.76E-02 6.11E+04 -6.34E+03 1.847522 6.344076 0.863836 86.38358
150 423 -1.70E+05 5.54E+02 5.30E-02 7.35E+04 -1.89E+05 5.86E+02 4.76E-02 6.74E+04 -6.07E+03 1.724801 5.611403 0.848746 84.87462
160 433 -1.70E+05 5.54E+02 5.30E-02 7.94E+04 -1.89E+05 5.86E+02 4.76E-02 7.37E+04 -5.79E+03 1.608049 4.993059 0.83314 83.31403
170 443 -1.70E+05 5.54E+02 5.30E-02 8.55E+04 -1.89E+05 5.86E+02 4.76E-02 7.99E+04 -5.51E+03 1.496861 4.467645 0.817106 81.71059
180 453 -1.70E+05 5.54E+02 5.30E-02 9.15E+04 -1.89E+05 5.86E+02 4.76E-02 8.62E+04 -5.24E+03 1.39087 4.018345 0.800731 80.07311
190 463 -1.70E+05 5.54E+02 5.30E-02 9.75E+04 -1.89E+05 5.86E+02 4.76E-02 9.25E+04 -4.96E+03 1.289738 3.631835 0.784103 78.41028
200 473 -1.70E+05 5.54E+02 5.30E-02 1.04E+05 -1.89E+05 5.86E+02 4.76E-02 9.88E+04 -4.69E+03 1.193157 3.297476 0.767305 76.73053

23DMB/nC6
Temperature
Temperature a b c G nC6 a b c G 23DMB ∆G ln K K X X%
C
K
100 373 -1.70E+05 5.54E+02 5.30E-02 4.36E+04 -1.81E+05 5.78E+02 4.97E-02 4.11E+04 -2.48E+03 0.801183 2.228175 0.690227 69.02275
110 383 -1.70E+05 5.54E+02 5.30E-02 4.96E+04 -1.81E+05 5.78E+02 4.97E-02 4.73E+04 -2.27E+03 0.713815 2.041766 0.671244 67.12436
120 393 -1.70E+05 5.54E+02 5.30E-02 5.55E+04 -1.81E+05 5.78E+02 4.97E-02 5.35E+04 -2.06E+03 0.631096 1.87967 0.652738 65.2738
130 403 -1.70E+05 5.54E+02 5.30E-02 6.15E+04 -1.81E+05 5.78E+02 4.97E-02 5.96E+04 -1.85E+03 0.55268 1.737904 0.634757 63.47571
140 413 -1.70E+05 5.54E+02 5.30E-02 6.75E+04 -1.81E+05 5.78E+02 4.97E-02 6.58E+04 -1.64E+03 0.478253 1.613254 0.617335 61.73354
150 423 -1.70E+05 5.54E+02 5.30E-02 7.35E+04 -1.81E+05 5.78E+02 4.97E-02 7.20E+04 -1.43E+03 0.407534 1.503107 0.600496 60.04965
160 433 -1.70E+05 5.54E+02 5.30E-02 7.94E+04 -1.81E+05 5.78E+02 4.97E-02 7.82E+04 -1.23E+03 0.340265 1.40532 0.584255 58.42549
170 443 -1.70E+05 5.54E+02 5.30E-02 8.55E+04 -1.81E+05 5.78E+02 4.97E-02 8.44E+04 -1.02E+03 0.276213 1.318128 0.568617 56.86175
180 453 -1.70E+05 5.54E+02 5.30E-02 9.15E+04 -1.81E+05 5.78E+02 4.97E-02 9.07E+04 -8.10E+02 0.215164 1.240065 0.553584 55.35844
190 463 -1.70E+05 5.54E+02 5.30E-02 9.75E+04 -1.81E+05 5.78E+02 4.97E-02 9.69E+04 -6.04E+02 0.156924 1.169907 0.539151 53.91507
200 473 -1.70E+05 5.54E+02 5.30E-02 1.04E+05 -1.81E+05 5.78E+02 4.97E-02 1.03E+05 -3.98E+02 0.101315 1.106625 0.525307 52.53071
 2MH/nC7
Temperatu Temperature
a b c G nC7 a b c G 2MH ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -1.99E+05 6.58E+02 5.65E-02 5.48E+04 -4.19E+03 1.350422 3.859053 0.794199 79.41986
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -1.99E+05 6.58E+02 5.65E-02 6.18E+04 -4.11E+03 1.290441 3.634389 0.784222 78.42218
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -1.99E+05 6.58E+02 5.65E-02 6.88E+04 -4.03E+03 1.233511 3.433263 0.774433 77.44325
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -1.99E+05 6.58E+02 5.65E-02 7.59E+04 -3.95E+03 1.179405 3.252437 0.764841 76.48407
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -1.99E+05 6.58E+02 5.65E-02 8.29E+04 -3.87E+03 1.127916 3.089213 0.755454 75.54542
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -1.99E+05 6.58E+02 5.65E-02 9.00E+04 -3.79E+03 1.078861 2.941327 0.746278 74.62783
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -1.99E+05 6.58E+02 5.65E-02 9.70E+04 -3.72E+03 1.032069 2.806869 0.737317 73.73169
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -1.99E+05 6.58E+02 5.65E-02 1.04E+05 -3.64E+03 0.987389 2.684216 0.728572 72.85719
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -1.99E+05 6.58E+02 5.65E-02 1.11E+05 -3.56E+03 0.944679 2.571988 0.720044 72.00439
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -1.99E+05 6.58E+02 5.65E-02 1.18E+05 -3.48E+03 0.903813 2.469 0.711732 71.17325
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -1.99E+05 6.58E+02 5.65E-02 1.25E+05 -3.40E+03 0.864673 2.37423 0.703636 70.36361

3MH/nC7
Temperatu Temperature
a b c G nC7 a b c G 3MH ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -1.96E+05 6.54E+02 5.65E-02 5.59E+04 -3.08E+03 0.993105 2.699603 0.729701 72.97007
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -1.96E+05 6.54E+02 5.65E-02 6.29E+04 -3.04E+03 0.955376 2.599647 0.722195 72.2195
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -1.96E+05 6.54E+02 5.65E-02 6.98E+04 -3.00E+03 0.919566 2.508202 0.714954 71.49537
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -1.96E+05 6.54E+02 5.65E-02 7.68E+04 -2.97E+03 0.885533 2.424276 0.707967 70.79675
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -1.96E+05 6.54E+02 5.65E-02 8.38E+04 -2.93E+03 0.853148 2.347023 0.701227 70.1227
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -1.96E+05 6.54E+02 5.65E-02 9.09E+04 -2.89E+03 0.822293 2.275712 0.694723 69.47228
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -1.96E+05 6.54E+02 5.65E-02 9.79E+04 -2.85E+03 0.792863 2.209713 0.688446 68.84457
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -1.96E+05 6.54E+02 5.65E-02 1.05E+05 -2.82E+03 0.764761 2.14848 0.682386 68.23864
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -1.96E+05 6.54E+02 5.65E-02 1.12E+05 -2.78E+03 0.737899 2.091536 0.676536 67.65362
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -1.96E+05 6.54E+02 5.65E-02 1.19E+05 -2.74E+03 0.712197 2.038464 0.670886 67.08864
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -1.96E+05 6.54E+02 5.65E-02 1.26E+05 -2.70E+03 0.687581 1.988899 0.665429 66.54286
 22DMP/nC7
Temperatu Temperature
a b c G nC7 a b c G 22DMP ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -2.10E+05 6.86E+02 5.64E-02 5.37E+04 -5.29E+03 1.704711 5.499794 0.846149 84.6149
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -2.10E+05 6.86E+02 5.64E-02 6.10E+04 -4.94E+03 1.550164 4.712242 0.824937 82.49374
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -2.10E+05 6.86E+02 5.64E-02 6.83E+04 -4.59E+03 1.403488 4.069368 0.802737 80.27368
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -2.10E+05 6.86E+02 5.64E-02 7.56E+04 -4.24E+03 1.264096 3.539892 0.77973 77.97305
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -2.10E+05 6.86E+02 5.64E-02 8.29E+04 -3.89E+03 1.13146 3.100181 0.756108 75.61083
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -2.10E+05 6.86E+02 5.64E-02 9.02E+04 -3.53E+03 1.005101 2.732183 0.73206 73.20603
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -2.10E+05 6.86E+02 5.64E-02 9.76E+04 -3.18E+03 0.884583 2.421975 0.707771 70.77711
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -2.10E+05 6.86E+02 5.64E-02 1.05E+05 -2.83E+03 0.769511 2.158711 0.683415 68.34152
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -2.10E+05 6.86E+02 5.64E-02 1.12E+05 -2.48E+03 0.659525 1.933873 0.659154 65.91536
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -2.10E+05 6.86E+02 5.64E-02 1.20E+05 -2.13E+03 0.554294 1.740712 0.635131 63.51313
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -2.10E+05 6.86E+02 5.64E-02 1.27E+05 -1.78E+03 0.453517 1.573838 0.611475 61.14752

23DMP/nC7
Temperatu Temperature
a b c G nC7 a b c G 23DMP ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -2.03E+05 6.65E+02 5.63E-02 5.27E+04 -6.28E+03 2.023518 7.564889 0.883244 88.32443
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -2.03E+05 6.65E+02 5.63E-02 5.98E+04 -6.14E+03 1.926974 6.868691 0.872914 87.29141
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -2.03E+05 6.65E+02 5.63E-02 6.69E+04 -6.00E+03 1.835352 6.267342 0.862398 86.23981
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -2.03E+05 6.65E+02 5.63E-02 7.39E+04 -5.86E+03 1.748287 5.744756 0.851737 85.17367
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -2.03E+05 6.65E+02 5.63E-02 8.11E+04 -5.72E+03 1.665448 5.288042 0.840968 84.0968
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -2.03E+05 6.65E+02 5.63E-02 8.82E+04 -5.58E+03 1.586534 4.886784 0.830128 83.0128
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -2.03E+05 6.65E+02 5.63E-02 9.53E+04 -5.44E+03 1.511274 4.532504 0.81925 81.925
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -2.03E+05 6.65E+02 5.63E-02 1.02E+05 -5.30E+03 1.439421 4.218252 0.808365 80.8365
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -2.03E+05 6.65E+02 5.63E-02 1.10E+05 -5.16E+03 1.370748 3.938296 0.797501 79.7501
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -2.03E+05 6.65E+02 5.63E-02 1.17E+05 -5.02E+03 1.30505 3.687873 0.786684 78.66837
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -2.03E+05 6.65E+02 5.63E-02 1.24E+05 -4.88E+03 1.242138 3.463009 0.775936 77.59359
 24DMP/nC7
Temperatu Temperature
a b c G nC7 a b c G 24DMP ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -2.06E+05 6.82E+02 5.63E-02 5.64E+04 -2.54E+03 0.820507 2.271651 0.694344 69.43439
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -2.06E+05 6.82E+02 5.63E-02 6.37E+04 -2.23E+03 0.700839 2.015443 0.668374 66.83738
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -2.06E+05 6.82E+02 5.63E-02 7.09E+04 -1.92E+03 0.587269 1.799068 0.642738 64.27382
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -2.06E+05 6.82E+02 5.63E-02 7.82E+04 -1.61E+03 0.479341 1.615009 0.617592 61.75922
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -2.06E+05 6.82E+02 5.63E-02 8.55E+04 -1.29E+03 0.376646 1.457388 0.593064 59.30639
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -2.06E+05 6.82E+02 5.63E-02 9.28E+04 -9.81E+02 0.278813 1.321561 0.569255 56.92553
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -2.06E+05 6.82E+02 5.63E-02 1.00E+05 -6.68E+02 0.185506 1.203827 0.546244 54.62438
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -2.06E+05 6.82E+02 5.63E-02 1.07E+05 -3.55E+02 0.096416 1.101218 0.524085 52.40855
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -2.06E+05 6.82E+02 5.63E-02 1.15E+05 -4.24E+01 0.011267 1.01133 0.502817 50.28166
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -2.06E+05 6.82E+02 5.63E-02 1.22E+05 2.70E+02 -0.0702 0.932208 0.482457 48.24574
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -2.06E+05 6.82E+02 5.63E-02 1.29E+05 5.83E+02 -0.14821 0.862246 0.463014 46.3014

33DMP/nC7
Temperatu Temperature
a b c G nC7 a b c G 33DMP ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -2.05E+05 6.79E+02 5.63E-02 5.57E+04 -3.25E+03 1.048635 2.853753 0.740513 74.05127
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -2.05E+05 6.79E+02 5.63E-02 6.29E+04 -2.97E+03 0.932509 2.540876 0.717584 71.7584
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -2.05E+05 6.79E+02 5.63E-02 7.02E+04 -2.69E+03 0.8223 2.275728 0.694724 69.47243
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -2.05E+05 6.79E+02 5.63E-02 7.74E+04 -2.40E+03 0.717567 2.049441 0.672071 67.20711
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -2.05E+05 6.79E+02 5.63E-02 8.47E+04 -2.12E+03 0.617913 1.855053 0.649744 64.97438
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -2.05E+05 6.79E+02 5.63E-02 9.19E+04 -1.84E+03 0.522978 1.687044 0.627844 62.78438
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -2.05E+05 6.79E+02 5.63E-02 9.92E+04 -1.56E+03 0.432434 1.541003 0.606455 60.64546
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -2.05E+05 6.79E+02 5.63E-02 1.06E+05 -1.27E+03 0.345984 1.413379 0.585643 58.56433
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -2.05E+05 6.79E+02 5.63E-02 1.14E+05 -9.92E+02 0.263357 1.301291 0.565461 56.54612
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -2.05E+05 6.79E+02 5.63E-02 1.21E+05 -7.09E+02 0.184305 1.202382 0.545946 54.59462
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -2.05E+05 6.79E+02 5.63E-02 1.28E+05 -4.27E+02 0.108602 1.114718 0.527124 52.71238
 2EP/nC7
Temperatu Temperature
a b c G nC7 a b c G 2EP ∆G ln K K X X%
re K
100 373 -1.92E+05 6.51E+02 5.64E-02 5.90E+04 -1.93E+05 6.67E+02 5.64E-02 6.32E+04 4.25E+03 -1.37008 0.254086 0.202606 20.26065
110 383 -1.92E+05 6.51E+02 5.64E-02 6.59E+04 -1.93E+05 6.67E+02 5.64E-02 7.03E+04 4.41E+03 -1.38566 0.250157 0.200101 20.01007
120 393 -1.92E+05 6.51E+02 5.64E-02 7.29E+04 -1.93E+05 6.67E+02 5.64E-02 7.74E+04 4.58E+03 -1.40045 0.246485 0.197744 19.7744
130 403 -1.92E+05 6.51E+02 5.64E-02 7.98E+04 -1.93E+05 6.67E+02 5.64E-02 8.45E+04 4.74E+03 -1.41451 0.243045 0.195524 19.55236
140 413 -1.92E+05 6.51E+02 5.64E-02 8.68E+04 -1.93E+05 6.67E+02 5.64E-02 9.17E+04 4.90E+03 -1.42789 0.239815 0.193428 19.34282
150 423 -1.92E+05 6.51E+02 5.64E-02 9.37E+04 -1.93E+05 6.67E+02 5.64E-02 9.88E+04 5.07E+03 -1.44063 0.236779 0.191448 19.14478
160 433 -1.92E+05 6.51E+02 5.64E-02 1.01E+05 -1.93E+05 6.67E+02 5.64E-02 1.06E+05 5.23E+03 -1.45279 0.233918 0.189573 18.95733
170 443 -1.92E+05 6.51E+02 5.64E-02 1.08E+05 -1.93E+05 6.67E+02 5.64E-02 1.13E+05 5.39E+03 -1.46439 0.231219 0.187796 18.77965
180 453 -1.92E+05 6.51E+02 5.64E-02 1.15E+05 -1.93E+05 6.67E+02 5.64E-02 1.20E+05 5.56E+03 -1.47549 0.228667 0.18611 18.61101
190 463 -1.92E+05 6.51E+02 5.64E-02 1.22E+05 -1.93E+05 6.67E+02 5.64E-02 1.27E+05 5.72E+03 -1.4861 0.226253 0.184507 18.45074
200 473 -1.92E+05 6.51E+02 5.64E-02 1.29E+05 -1.93E+05 6.67E+02 5.64E-02 1.35E+05 5.88E+03 -1.49627 0.223964 0.182983 18.29825
Figure 3.1 C5 paraffin equilibrium plot

Equilibrium Curve
Iso-pentane equilibrium curve

2-2Dimethyl butane Equilibrium curve

APPENDIX D

Typical Baffles clearances and Tolerances

Shell Bundle Clearance

Tube side heat transfer Factor
Tube side friction factor
Shell side heat transfer factor, for segmental baffles
Shell side friction Factor, for segmental baffles
Temperature Correction factor: Two shell passes, four or multiple of four tube passes

Temperature Correction factor: One shell passes, two or even tube passes
Typical Overall Coefficients
Designing Algorithm for Heat Exchanger
Discharge Coefficient sieve plate
Pump selection guide
Pipe Friction verse Reynolds number and relative roughness
Compressor operating range