Synopsis


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(a) CHC
1 c 2 c 3 a 4 d 5 c 6 a 7 d 8 c 9 b 10 b

11 b 12 c 13 c 14 a 15 a 16 b 17 a 18 b 19 c 20 d

21 c 22 d 23 c 24 c 25 b 26 c 27 c 28 a 29 c 30 c

31 a 32 a 33 d 34 d 35 b 36 a 37 d 38 d 39 b 40 c

41 a 42 d 43 c 44 b 45 d 46 d 47 c 48 a 49 d 50 d

51 b 52 a 53 c 54 d 55 d 56 c 57 b 58 b 59 a 60 d

61 b 62 b 63 c 64 b 65 d 66 d 67 b 68 a 69 d 70 a

71 d 72 b 73 d

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1 b 2 d 3 a 4 d 5 c 6 b 7 a 8 a 9 d 10 c

11 a 12 b 13 c 14 c 15 c 16 b 17 a 18 c 19 b 20 b

21 d 22 b 23 c 24 a 25 c 26 a 27 d 28 d 29 d 30 c

31 a 32 b 33 b 34 c 35 a 36 c 37 d 38 d 39 d 40 a

41 a 42 b 43 c 44 b 45 c 46 c 47 b 48 c 49 d 50 b

51 c 52 b 53 b 54 c 55 a 56 d 57 d 58 b 59 d 60 c

61 b 62 c 63 b 64 d 65 c 66 c 67 a 68 b 69 b 70 b

71 d 72 a 73 c 74 b 75 b 76 b 77 c 78 a 79 d 80 c

81 c 82 d 83 b 84 a 85 b 86 c 87 a 88 b 89 c 90 a

91 a 92 c 93 d 94 b 95 d 96 d 97 c 98 d 99 d 100 c

101b 102 c 103 c 104 a 105 d 106 a 107 d 108 d 109 d 110d

111c 112 b 113 c 114 c 115 c 116 d 117 c 118 a 119 a 120b

121c 122 b 123 b 124 c 125 a 126 c 127 d 128 b 129 b 130d

131c 132 d 133 b 134 d 135 b 136 b 137 d 138 a 139 c 140c

141d 142 d 144 b 144 c 145 a 146 b 147 b 148 a 149 c 150c

151a 152 a 153 d 154 d

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EVALUATION PAPER ­ HALOGEN DERIVATIVES OF ALKANES AND ARENES

Time : 30 Min. Marks : 25

The following reaction is known as

Kharasch effect Darzen’s procedure

Williamson’s synthesis Hunsdiecker synthesis reaction

Isopropyl chloride Isobutyl chloride

n-propyl chloride n-butyl chloride

propan-2-ol propan-1-ol propyne propene

An alkyl bromide (X) reacts with Na to form 4,5-diethyloctane. Compound X is

3-bromobut-1-ene 1-bromobut-2-ene
a mixture of both (a) and (b) 2-bromobut-2-ene

Which of the following halogen-exchange reactions is possible ?


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Identify Z, in the following series.

C2H5I X Y Z
CH3CH2CN NCCH2 – CH2CN
BrCH2 – CH2CN BrCH = CHCN

isobutylene
sodium t-butoxide t-butyl methyl ether
Ethyl chloride on heating with silver cyanide forms a compound X (major).
The functional isomer of X is
C2 H5 CN
H3C – NH – CH3 C2 H5NH 2

Which of the following is the correct formula of dichlorodiphenyl trichloroethane ?

(C6H5) 2CHCl (C6H5)3CCl

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CuF/HF Cu/HF
Which is not the Wurtz-Fittig reaction ?

None of the above

Azo coupling reaction

Friedal-Crafts reaction Riemer-tiemann reaction

List – I List – II
A) C2H2Cl 1) Williamson synthesis
B) Mg + dry ether 2) Wurtz reaction
C) C2H5Cl + C2H5ONa 3) Anaesthetic
D) Na + dry ether 4) Antiseptic
5) Grignard reagent
The correct match is
A B C D

5 3 1 2
3 4 1 2
3 5 1 4

Which of the following alkyl halides would be most likely to give a rearranged product
under SN1 condition ?
Chlorobenzene on heating with aqueous NH3 under pressure in the presence of

Nitrobenzene
- Chloroaminobenzene

Out of

All except II, IV

All except I, III All except IV

Chlorobenzene reacts with Mg in dry ether to give a compound (A) which further

benzene
ethyl benzene phenyl ether

p-bromotoluene
o-and p-bromotoluene m-bromotoluene

C2H5Br when treated with metallic sodium gives ethane

C2H5Br when treated with sodium ethoxide forms diethyl ether
Both a and b

6 3 4

In the following sequence of reactions

CH3 – OH A B

CH3 – O – C2H5 C2H5OH CH3 – OH

 C4H9Br + HCN C3H7OH + KCN C4H9OH + KCN

Chlorobenzene when heated with .... in the presence of conc.H2SO4 gives D.D.T. The

Ethanal Chloroform Chloral

1 b 2 a 3 a 4 d 5 c 6 d 7 b 8 b 9 bd 10 a

11 d 12 a 13 a 14 a 15 a 16 c 17 c 18 b 19 b 20 c

21 d 22 d 23 d 24 a 25 d

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