1.

(a) H tan  4H  4H 
Sol. Here, mass of the box (;gkW] cDlsa dk nzO;eku),  or tan   or   tan 1  
m = 2.3kg
R 4 R  R 
6. (a)
Mass of one gold piece (,d lksusa ds VqdMs dk nzO;eku) , Sol. The free body diagram of 3 kg block is shown
m1  20.15g  0.02015kg In the fig (a)
Mass of other gold piece (vU; lksusa ds VqdMas dk nzO;eku) , (3 fdxzk xqVds dh eqDr fi.M dh vk—fr fp= (a)es n”kkZbZ xbZ gS)
m 2  20.17g  0.02017kg
Total mass (dqy nzO;eku)  m  m1  m 2
 2.3kg  0.02015kg  0.02017kg
 2.34032kg
As the result is correct only upto one place of decimal,
The equation of motion of 3 kg block is
therefore on rounding off, we get
(3 fdxzk ds xqVdsa dh xfr dk lehdj.k)
(,slk ifj.kke n”keyo ds dsoy ,d LFkku rd lgh gSa] blfy, iw.kkZdu
djusa ij) T2  3g  3a
Total mass (dqy nzO;eku)  2.3 kg T2  3(a  g
2. (a)  3(2  10)  36N ….. (i)
Sol. Difference in masses (nzO;ekukasa esa vUrj) The free body diagram of 5 kg is shown as in the fig (b)
= m2  m1  20.17g  20.15g (5 fdxzk ds eqDr fi.M dh vk—fr fp= es n”kkZbZ xbZ gS)
0.02g (correct upto two places of decimal)
( 0.02g n”keyo ds nksa LFkkuksa rd lgh gSaA)
3. (c)
Sol. Here (;gk¡) , u = 0 v 2  2as It is a parabola of the The free body diagram of 5 kg block is
type y 2  4ax (5 fdxzk xqVds dk xfr dk lehdj.k)
Hence, option (c) represent the correct graph T1  T2  5g  5a
(;g y 2  4ax izdkj dk ,d ijoy; gSaAvr% fodYi (c) lgh xzkQ T1  5(a  g)  T2
iznf”kZr djrk gSAa )  5(2  10) 36
4. (d)  96N
u2 7. (d)
Sol. Stopping distance (:dusa okyh nwjh), d 2  
2a
Where u is the initial speed of the car. (tgk¡ u dkj dh work enegy mgh wh
Sol. Power    
izkjfEHkd pky gSaA) time time t t
As the stopping distance is proportional to square of the (w = weight)
initial velocity. Doubling the initial velocity increases the dk; Z ÅtkZ
( ' kfDr   )
stopping distance by a factor of 4. (D;ksfd :dusa okyh nwjh le; le;
vkjfEHkd osx ds oxZ ds O;qRØekuqikrh gksrh gSaA vkjfEHkd osx dks nqxquk P W t 4 11 11
djusa ij :dusa dh nwjh 4 ds dkjd ds }kjk c<+ tkrh gSaA)  1  1 2    (h is same in both cases)
P2 W2 t 1 3 12 9
(h nksuksa izdj.kksa esa leku gSA)
5. (c)
Sol.
8. (a)
Sol.

u 2 sin2 
Maximum height (vf/kdre Å¡pkbZ), H  ….(i)
2g
Horizontal range ({kSfrt ijkl), Let AB be ladder (ekuk AB lh<h gSA)
u 2 sin 2 2u 2 sin  cos  AB = 3m
R  ..(ii) Its foot A is a distance 1m from the wall.
g g (bldk ikn nhokj 1 lsa eh nwjh ij gSaA)
Divide (i) by (ii), we get ((i) dksa (ii) lsa Hkkx nsus ij])  AC = 1m
 And BC  (AB) 2  (AC) 2  (3) 2  (1) 2  2 2m
The various force acting on the ladder are
(fofHkUu cy lh<+h ij dk;Zjr gSa&)
(i) Weight W acting at its center of gravity G.
(Hkkj W blds xq:Ro dsUnz G ij dk;Zjr gSa)
(ii) Reactions force R 1 of the wall acting
Draw a perpendicular AD to the side BC.
Perpendicular to the wall ( the wall is frictionless). (Hkqtk BC ij ,d yEc AD [khfp,aA)
(nhokj dk izfrfØ;k cy R 1 nhokj lsa yEcor~ dk;Zjr gSa) ( nhokj
3
?k’kZ.kjfgr gSa)  AD  AB sin 60  l
(iii) Reactions force R 2 of the floor. This force can be
2
2
resolved into two components, the normal reactions N Distance AO of the centroid O from A is AD .
and the force of frictions f. 3
For translator equilibrium in the horizontal directions, 2
(A lsa dsUnzd O dh nwjh AO, AD . gSa )
(Q”kZ dk izfrfØ;k cy R 2 bl cy dks nks ?kVdksa esa ck¡Vk tk ldrk 3
gSa] vFkkZr~ lkekU; izfrfØ;k N ,oa ?k’kZ.k cy f. {kSfrt fn”kk esa 2 3  1
LFkkukUrjh; larqyu ds fy,)  AO   l 
3  2  3
f  R1  0 or f  R1 …..(i)
1
For translator equilibrium in the vertical directions, By Symmetry (lefefr }kjk) , AO = BO = CO 
(Å/okZ/kj fn”kk esa LFkkukUrjh; larqyu ds fy,]) 3
N – W = 20g = 20 × 10 = 200 N ….. (ii) Force on mass 2m at O due to mass m at A is
For rotational equilibrium, taking moment of the forces (A ij nzO;eku m ds dkj.k O ij nzO;eku 2m ij cy gSa&)
about A, we get
Gm(2m) 6Gm2
(?kw.kZu larqyu ds fy,] ds ifjr% cyksa dk vk?kw.kZ ysusa ij) FOA   2 along OA
(l / 3 ) 2
  1 l
R 1 2 2  W   0 Force on mass 2m at O due to mass m at B is
2 (B ij nzO;eku m ds dkj.k O ij nzO;eku 2m ij cy gSa&)
W 200
R1    25 2 N ….. (iii) Gm(2m) 6Gm2
4 2 4 2 FOB   2 along OB
(l / 3 ) 2 l
From (ii), f  R1  25 2N Force on mass 2m at O due to mass m at C is
R 2  N  f  (200N)  (25 2 N)  203N
2 2 2 2 (C ij nzO;eku m ds dkj.k O ij nzO;eku 2m ij cy gSa)
Gm(2m) 6Gm2
9. (d) FOC   2 along OC
Sol. (l / 3) 2 l
Draw a line PQ parallel to BC passing through O. Then
BOP  30  COQ
(O lsa tkusa okyh BC ds lekukUrj ,d js[kk PQ [khapusa ij] rc
BOP  30  COQ )
Moment of inertia of the solid sphere of mass M and Resolving F OB and FOC into two components.
radius R about any diameter is
(fdlh O;kl ds ifjr% nzO;eku M ,oa f=T;k R ds Bksl xksy
a s dk tM+Ro ( F OB ,oa FOC dks nks ?kVdksa es ysusa ij])
vk?kw.kZ gSaA) Resolving acting along OP and OQ are equal in
2 magnitude and opposite in directions. So, they will
I diamete  MR 2 cancel out while the components acting along OD will
5 add up.
According to theorem of parallel axes (OP ,oa OQ ds vuqfn”k dk;Zjr ?kVdksa ds ifjek.k leku gksrs gSa rFkk
(lekukUrj v{k ize; sa ds vuqlkj) fn”kk foijhr gksrh gSa] blfy, ;sa fujLr gksxas tcfd OD ds vuqfn”k
I tan gent  I diameter  MR 2 , I Li' kZT; k  I O; kl  MR 2 dk;Zjr ?kVd tqMsxasA)
2 7  The resultant force on te mass 2m at O is
 MR 2  MR 2  MR 2 (O ij nzO;eku 2m ij ifj.kkeh cy gSaA)
5 5 FR  FOA  (FOR sin 30  FOC sin 30)
6Gm 2  6Gm 2 1 6Gm 2 1 
10. (a)    2   2    0
Sol.
l2  l 2 l 2
11. (c)
 Sol. The gravitations force is independent of the Water (ty) 4186 J kg 1K 1
intervening medium. In other words, the force between
two mass remains the same whether they are in air, Ice (cQZ) 2060 J kg 1K 1
vacuum, water or separated by a brick wall. Aluminium (,syqfefu;e) 900 J kg 1K 1
(xq:Roh; cy e/;orhZ (intervening) ek?;e lsa Lora= gksrk gSaA vU; Mercury (ikjk) 140 J kg 1K 1
“kCnksa es]a nksa nzO;ekuks ds e/; cy leku jgrk gSa] pkgsa os gok] fuokZr]
ty vFkok bZV dh nhokj ds }kjk i`Fkd gksaA) Water has the highest specific heat capacity.
Hence, (a) is an incorrect statement. (ty dh fof”k’V Å’ek /kkfjrk vf/kdre gksrh gSaA)
(vr% (a) xyr dFku gSaA) 16. (c)
The gravitational force is a conservative force. Sol. Molar specific heat of mixture at constant volume is
(xq:Roh; cy laj{kh cy gksrk gSaA) (fu;r vk;ru ij feJ.k dh eksyj fof”k’V Å’ek)
Hence, (b) is an incorrect statement. n1CV1  n2CV2
(CV ) mixture 
(vr% (b) dFku xyr gSA) n1  n2
The gravitational force obeys newton’s third law of
motion. Thus, it form action – reactions pair. 5R 3R
2  8
(xq:Rokd’kZ.k cy U;wVu ds rhljsa fu;e dk ikyu djrk gSA vr% ;g  2 2  1.7 R
fØ;k^&izfrfØ;k ;qXe dk fuekZ.k djrk gSaA) 28
Hence, (c) is a correct statement. 17. (b)
(vr% dFku (c) lgh gSa) Sol. Total work done by the gas from D to E to F is equal
The gravitational force is a central force. Hence, (d) is an to the area of DEF .
incorrect statement. (D ls E ls F rd xSl }kjk fd;k x;k dqy dk;Z DEF . ds {ks=Qy
(xq:Roh; cy ,d dsUnzh; cy gSaA vr% (d) ,d xyr dFku gSaA) ds cjkcj gksrk gSA)
12. (d) 1
Sol. From the given graph for a stress of 150  1016 N m 2  the area of DEF  DF  EF
2
the strain in 0.002. Here, DF change in pressure
( 150  1016 N m 2 izfrcy ds fy, fn;s x;s xzkQ ls fod`fr 0.002 (;gk¡ DF nkc esa ifjorZu)
gSA)  600  200  400 Nm 1
 Young ' s mod ulus Y 
Stress Also, EF = change in volume (vk;ru esa ifjroZu)
Strain  7m3  3m3  4m3
izfrcy
; x a izR; kLFkrk xq.kkad Y  1
fod`fr Area of DEF   400  4  800 J
2
150  10 6 Thus, the total work done by the gas form D to E to F is
Y N m  2  7.5  10 10 N m  2
0.002 800 J.
13. (a) (bl izdkj D ls E vkSj E ls F rd xSl }kjk fd;k x;k dqy dk;Z
Sol. The shape of the aero plane wings is such that when 800 J gSA)
it moves forward the air molecules at the top of the wings 18. (a)
have a greater velocity (relative to the wings) compared 1 2 1 mN 2
to the air molecules at the bottom there force in Sol. Using, P  v rms  v rms
3 3 V
accordance with Bernoulli’s principle the pressure at the
top of the wings is less than that at the bottom. This  P  mv 2 rms
results in a dynamic lift of the wings which balances the As m is halved v rms is doubled P0 becomes twice  2P0
weight of the plane.
(pw¡fd m vk/kk gSa rFkk v rms nqxuq k gSa] vr% P0 nqxuq k gksxk vFkkZr~ 2 P0
(ok;q;ku ds ia[kks dh vkd`fr ,slh gksrh gS fd tc ;s vkxs dh vksj xfr
djrk gSA rks ia[kks ds “kh’kZ ij ok;q ds v.kqvks dk osx (ia[kks ds lkis{k) )
ia[kks ds uhps dh vksj ds ok;q ds v.kqvks dh rqyuk esa vf/kd gksrk gsA 19. (d)
blfy, cuwy Z h ds fl)karuqlkj ia[kks ds “kh’kZ ij nkc ia[kks ds uhps ds Sol. Since there is no loss of energy in the process,
nkc ls de gksrk gSA ;g ia[kks ds xfrd mRFkkid esa ifj.kfer gksrk gS therefore, sum of kinetic energy of gases A and B =
tks ok;q;ku ds Hkkj dks larfq yr djrh gSA) Kinetic energy of mixture.
14. (c) (pw¡fd bl izØe esa ÅtkZ dh gkfu ugha gksrh gSa] blfy, xSl A ,oa B
Sol. The volume of water a man drinks, will be equal to dh xfrt ÅtkZ dk ;ksx = feJ.k dh xfrt ÅtkZ])
additional volume of water displaced by the boat, due to Temperature of the mixture (feJ.k dk rki),
which the level of water will remain same.  T   2T2
(ty dk og vk;ru ftls O;fDr ihrk gS uko }kjk gVk, x;sty ds T 1 1
vfrfjDr vk;ru ds cjkcj gksrk gS ftlds dkj.k ty dk Lrj leku 1   2
cuk jgrk gSA) 2(27  273)  3(37  273)

15. (a) 23
Sol. Substances - Specific heat capacity
(inkFkZ) (fof”k’V Å’ek /kkfjrk)
 600  930 1530
 
5 5
 360K  360  273  33C
20. (a)
Sol. In equilibrium (lkE; ea)s , kx = mg
mg 20  9.8
x  
k 4000
 0.049 m  4.9 cm
21. (a)  AC  BD  10 2  10 2  10 2 cm
Sol. Here, m  1kg , k  100 N m 1 10 2 10
A  10 cm  0.1 m OA  OB  OC  OD   cm
2 2
The block executes SHM, its angular frequency is given
by Forces of repulsion on 1C charge at O due to 3C
charge, at A and C are equal and opposite. So they cancel
(xqVdk ljy vkorZ xfr djrk gS bldh dks.kh; vko`fr bl izdkj gS)
each other. Similarly, forces of attraction of 1C charge
k 100 N m 1 1
   10 rad s at O due to  4 C charges at B and D are also equal and
m 1 kg
opposite. So they also cancel each other.
Velocity of the block (xqVds dk osx ) at x = 5 cm Hence the net force on the charge of 1C at O is zero.
( 0.05m ) is
( 3 C vkos”k ds dkj.k O ij vkos”k 1C dk izfrd’kZ.k cy] A ,oa
v   A  x  10 (0.1)  (0.05)
2 2 2 2
C ij cjkcj ,oa foijhr gksrs gSA blfy, os ,d & nwljs dks u’V djrs
gsa blh izdkj  4 C vkos”k ds dkj.k O ij 1C vkos”k dk
 10 7.5  103 m s 1
vkd’kZ.k cy] B ,oa D ij Hkh cjkcj ,oa foijhr gksrs gSA blfy, ;s
Kinetic energy of the block,
(xqVds dh xfrt ÅtkZ) Hkh ,d & nwljs dks u’V djrs gSA vr% O ij 1C vkos”k ij dqy
1 1 cy “kwU; gksrk gSA)
K  mv 2   1  0.75  0.375J 25. (b)
2 2
Potential energy of the block, Sol. F  qE  5  10 6  2  105 1 N
(xqVds dh fLFkfrt ÅtkZ) Since, the particle is thrown against the field (pw¡fd] d.k dks
1 1 {ks= ds fo:) Qsd a k x;k gS)
U kx 2   100  (0.05) 2  0.125J 1
2 2 a   F / m   3
 103 m s  2
22. (b) 10
As (pw¡fd) v  u  2as
2 2
Sol. Here,
  3.2 MHz  3.2  106 Hz  3.2  106 s 1 0 2  (20) 2  2  (103 )  s
v  1.6km s 1  1.6  103 ms 1 or (;k) s = 0.2 m
26. (c)
v 1.6  103 ms 1 oA
Wavelength (rjaxnS/;Z),   
 3.2  106 s 1 Sol. As capacitance (pw¡fd /kkfjrk) C o 
d
0.5  103 m  0.5mm  After inserting copper plate
23. (c)
Sol. Here (;gk¡), Length (yEckbZ), L=10m (rkez IysV izo”s k djus ds i”pkr~)
3
Mass (nzO;eku), M  5g  5  10 kg
oA
Tension (ruko), T  80N C
Mass per unit length of the wire is db
(rkj dk izfr ,dkad yackbZ nzO;eku gSa]) 27. (c)
M 5  103 kg
   5  104 kg m 1 Sol. From the figure, C1, C 2, C3 are connected in series.
L 10m (fp= ls] C1, C 2, C3 dks Js.khØe esa tksM+k tkrk gSA)
Speed of the transverse wave on the wire is
(fdlh rki ij vuqizLFk dh pky gSAa )
1 1 1 1
T 80N     …(i)
v   4  102 ms 1  400ms 1 C s C1 C 2 C 3
 5  104 kg m 1
24. (d) 1 1 1 3
    F
Sol. From figure, length of diagonal of the square 20 20 20 20
(fp= ls] oxZ ds fod.kZ dh yEckbZ)
 20
or C s  F
3

30. (c)
Sol. Given (fn;k gS) I1  2A, I 2  5A, r  2m
 0 2 I1 I 2 2 25
f   107   1 106 Nm 1
4 r 2
31. (a)
Now C S is in parallel with C 4 Sol. The torque acting on the coil
  m  B  mB sin  Here the circular coil is placed
(vc C S C 4 ds lkFk lekukUrj Øe esa gSA)
normal to the direction of magnetic field then the angle
equivalent capacitance, (rqY; /kkfjrk), between the direction of magnetic moment ( m) and

20 80 magnetic field (B) is zero, then

C eq  C s  C 4   20   26.67F
3 3   mB sin   mB sin 0  0   0

28. (d) (dq.Myh ij dk;Zjr cy vk?kw.kZ   m  B  mB sin 

Sol. Resistance of heater coil, (ghVj dh dq.Myh dk izfrjks/k) ;gk¡] o`rh; dq.Myh pqEcdh; {ks= dh fn”kk ds vfHkyEcor fLFkrgS vr%
V 2
200  200 pqEcdh; vk?kw.kZ ( m ,oa pqEcdh; {ks= ( B) dh fn”kk ds e/; dks.k
R'    400
P 100 “kwU; gksxk blfy,
  mB sin   mB sin 0  0   0 )
Resistance of either half part  200 .
32. (b)
Equivalent resistance when both parts are connected in Sol. The liquid rises up in the part of the tube which is
parallel. (;k vk/ks Hkkx dk izfrjks/k  200 tc nksuksa Hkkxksa dks between the poles.
(nzo uyh ds ml Hkkx esa Åij p<+rk gSA tks /kzqoksa ds e/; gksrk gSA)
lekukUrj Øe esa tksM+k tkrk gS]rksa rqY; izfrjks/k),
33. (b)
200  200
R'   100. Sol. The polarity of emf will be opposite in the two cases
200  200 while the magnet enters the coil and while the magnetic
leaves the coil. Only in option (b) polarity is changing.
Energy liberated per second when combination is (fo- ok- cy dh /kqzork nks izdj.kksa esa foijhr gksxh tc pqEcd daMq yh
connected to a source of 200 V, (tc la;kstu 200 V ds L=ksr esa izos”k djrk gS rFkk tc pqEcd dks dqaMyh ls fudkyk tkrk gSA dsoy
ls tqM+ tkrk gS rks izfr lsd.M eqDr dh xbZ ÅtkZ), fodYi (b) esa /kqoz rk ifjofrZr gks jgh gSA)
34. (d)
V 2 200  200 Sol. When a circular coil expands radially in a region of
   400J. magnetic field, induced emf developed is
R' 100
  Blv  B  rate of change area
29. (d) Here, magnetic field B is in a plane perpendicular to the
Sol. Wire of length 2  0.1m of 12 m is bent to a 1 plane of the circular coil.
circle. As   0 , magnetic field must be in the plane of circular
coil so that its component perpendicular to the plane of
Resistance of each part  12    0.1
the coil, whose magnitude is decreasing suitably so that
 1.2 magnetic flux linked with the coil stays constant then
d
Total resistance  0.6.  0
dt
So both options (b) and (c) are correct.
( 2  0.1 m yEckbZ ,oa 12  m 1 ds rkj dks ,d o`Ÿk esa eksM+k (tc o`rh; daM q yh pqEcdh; {ks= ds {ks= esa f=T;h; :Ik ls izlkfjr gksrh
tkrk gSA izR;sd Hkkx dk izfrjks/k  12    0.1 gS rks izsfjr fo- ok cy mRiUu gksrk gSA
  Blv  B  {ks=Qy ifjorZu dh nj )
 1.2 ;gk¡ pqEcdh; {ks= B o`rh; dqaMyh ds ry ds yEcor ry esa gksrk gSA
pw¡fd   0 pqEacdh; {ks= esa B o`rh; daqMyh ds ry esa gksuk pkfg,
dqy izfrjks/k  0.6. ) rkfd bldk ?kVd dqaMyh ry ds yEcor gks ftldk ifjek.k mi;qDr
:Ik ls ?kVrk jgrk gSA ftlls dqaMyh ls tqM+k pqEcdh; ¶yDl fu;r
jgrk gS rks
 d Hence, change in focal length of the lens, (vr%] ysl
a dh
 0 Qksdl nwjh esa ifjorZu),
dt
blfy, nksuks fodYi (b) ,oa (c) lgh gSA)
f w  fa
35. (d)
 0.78  02  058m
Sol. Here, (;gk¡), C  100F  100  10 6 F  10 4 F,
R = 40  , 38. (d)
Vrms  100 V,   60Hz Sol. The far point of 6.0 m tell us that the focal length of
the lens is
 V0  2Vrms  100 2V
(nwj fcUnq 6.0 m gS rks ysl
a dh Qksdl nwjh)
In series RC circuit, (Js.kh RC ifjiFk esa),
f  6.0m,u  18m and h  2m
1
Z  R 2  X C2  R 2  1 1 1
Using,      
1 1 1 1

1
 C2
2
f v u v f u 6.0 18.0
1
 [  2]  v  4.5m
1
R2  2 2 2
4  C  The image size, (izfrfcEc dk vkdkj), h’ = h
Maximum current in the circuit, (ifjiFk esa vf/kdre /kkjk),
 v   4.5 
V
I0  0 
V0  u   2    18.0   0.50m
   
Z 1
R2 
4  2 C 2 2 39. (c)
100 2 Sol. Given (fn;k gS) :   5  107 m , D 1 m, d 1mm
 Distance of nth bright fringes from the centre
1
(40) 2  nD
4  (3.14)  (60) 2  (104 ) 2
2
(dsUnz ls n oha nhIr fQzUt dh nwjh) 
d
36. (c)
Where (tgk¡) n = 1,2,3……
Sol. Gamma rays (xkek fdj.ks)a
37. (c) So the distance of 5th bright fringes
 1 1  5D
1
 (a  g )   (blfy, 5oha nhIr fQzUt dh nwjh) 
Sol. Using  d
fa  R1 R 2 
Distance of nth dark fringe from the centre
Here, fa  0.2m, a g  1.50
 1  D
(dsUnz ls n ohsa vnhIr fQzUt dh nwjh)   n  
1  1 1   1 1   2 d
  (1.50  1)     0.50    Where (tgk¡) n= 1,2,3……
0.2  R1 R 2   R1 R 2 
 1  D 5 D
3rd dark fringe (vnhIr fQzUt)   3   
1 1  2 d 2 d
   10
R1 R 2 Distance between them (muds chp dh nwjh)
 5  D 5 D
Consider f w be the focal length of the lens, when 5   
 2 d 2 d
w
g
immersed in water if be refractive index of glass 5  1  5  107
w.r.t. water, then  3
12.5  10 4 m 1.25 mm
2  1  10
40. (d)
(ekuk f w ysl a dh Qksdl nwjh gS] tc ml sty esa Mqcks;k tkrk gSA
Sol. Let I 0 be the intensity of unpolarized light, then
rc ;fn dk¡p dk ty ds lkis{k viorZukad w g gS] rks)
intensity of light from first transparent thin plate of a
Polaroid is
a
 1.50 (ekuk I 0 v/kzqfor izdk”k dh rhozrk gS rks iksysjkWbM dh izFke ikjn”khZ
g  a   1.128
w g

 w 1.33 iryh IysV ls izdk”k dh rhozrk)

I0
 1 1  I
Now,
1
  w

g  1     (1.128  1)  10  1.28 2
fw  R1 R 2  Now, this light will pass through the second similar plate
whose axis is inclined at an angle of 30º to that of first
1
fw   0.78 plate.
1.28
 According to Malus law, the intensity of emerging light Chemistry
is
(vc ;g izdk”k nwljh le:i IysV ls xqtjsxkk ftldk v{k igyh IysV 1. (b)
ds lkFk 30 dks.k ij >qd tkrk gSA Sol. H 2  Cl 2  2HCl
2g 71g 73 g
esyl fu;e ds vuqlkj fuxZr izdk”k dh rhozrk)
2 2g of H 2 reacts with 71 g of Cl 2
I  3  3 I ' 3
I'  I cos2 30º  0    I0   ( H 2 ds 2g Cl 2 fØ;k djax s s)
2  2  8 I0 8 71
100 g of H 2 will react with  100  3550 g of
41. (d) 2
Sol. Here (;gk¡) 0  2.14eV 71
( H 2 ds 100 g fØ;k djsx a s 2  100  3550g Cl2 ls)
Work function (dk;Z&Qyu) 0  h0
Cl 2 Hence, Cl 2 is the limiting reagent.
Where  0 is the threshold frequency
(vr% Cl 2 lhekar vfHkdeZd gSaA)
(tgk¡  0 nsgyh vko`fÙk gS)
71 g of Cl 2 produces 73 g of HCl.
19
 2.14  1.6  10 ( Cl 2 ds 71 g HCl ds 73 g mRiUu djrs gSa)
0  0   5.16  1014 Hz
h 6.63  10 34
73
42. (c) 100 g of Cl 2 will produce  100  102.8 g of HCl
st
71
Sol. 1 transition is showing absorption of a photon. 73
From rest of three transition III is having maximum ( Cl 2 ds 100 g mRiUu djsx a s  100  102.8g HCl )
71
energy from level n = 2 to n = 1
2. (c)
 1 1  Sol. If n  3 then l  0 to n  1 & m  l to  l
E   2  2 
 n1 n 2  (;fn n  3 rc l  0 ls n  1 vkSj m  1 ls 1 )
3. (c)
(izFke laØe.k QksVkWu ds vo”kks’k.k dks n”kkZ jgk gSA rhuksa laØe.kks esa
ls r`rh; Lrj n =2 ls n =1 ls ÅtkZ vf/kdre gS n 1  n 2  4
Sol.  so n1 = 3 and n2 = 1.
 1 1  n 1  n 2  2
E   2  2  )
 n1 n2 
 1 1 
v  R 3  2  2   8R.
2
43. (a)
Sol. During nuclear fusion, two or more light nuclei  1 3 
combine from a heavier nucleus. As 6 C is radioactive, 4. (b)
14

so (a) is not possible Sol. For isoelectronic species, ionic radii decrease with
(ukfHkdh; lay;u ds nkSjku ] nks ;k nks ls vf/kd gYds ukfHkd ,d increase in nuclear charge (i.e., no. of protons). Thus, the
14 cation with greater +ve charge will have a smaller radius
Hkkjh ukfHkd es la;ksftr gks tkrs gS pw¡fd 6 C jsfM;ks& lfØ; gS] and the anion with greater – ve charge will have a larger
blfy, (a ) laHko ugha gS) radius. Thus, the correct order of increasing ionic radii is
44. (c) (lebysDVªkWfud Lih”kht ds fy, vk;fud f=T;k,¡ ukfHkdh; vkos”k]
 I  (vFkkZr~ QksVkWu dh la[;k) esa o`f) ds lkFk ?kVrh gSA bl izdkj vf/kd
Sol. Current gain (/kkjk ykHk),    C  /kuk;u okys /kukos”k dh f=T;k NksVh gksxh rFkk vf/kd _.kkos”k okys

 B VCE
I _.kk;u dh f=T;k cM+h gksxhA bl izdkj vk;fud f=T;kvksa dk c<+rk
gqvk lgh Øe gS%)
R
And voltage gain (rFkk oksYVrk ykHk), AV   out Mg 2  Na   F  O2
Rin
5. (a)
200  5  10 3
Sol. Ais Ne(10) :1s 2 2s 2 2p6
Here, A  V 1000
1000 Bis O(8) :1s 2 2s 2 2p 4
45. (b)
V 2 Cis Na(11) :1s 2 2s 2 2p6 3s1
Sol. Using , I C  CE  103 1mA
RC 2  103 Dis F(9) :1s 2 2s 2 2p5
I Noble gases (A) have completely filled orbitals hence,
  C they have no tendency to gain electrons. Element C
IB
prefers to lose electron (3s1 ) to attain stable noble gas
I C 103
IB   A  20 A configuration.
 50
Element D has only 1 electron less than stable noble gas
configuration. Thus, it has greater tendency to gain
electron than element B which has 2 electrons less than
 noble gas configuration. Thus, the correct order of H 42600J mol1
increasing tendency to gain electron is: A < C < B < D.  S    114.2 J K 1mol1
(vkn”kZ xSl (A) esa iw.kZ Hkjs gq, d{kd gksrs gSa vr%- muesa bysDVªkWuksa dks T 373K
izkIr djus dh dksbZ Hkh izo`fŸk ugh gksrh gSA rRo C LFkk;h vkn”kZ xSl 11. (d)
Sol. As concentration of solution decreases, degree of
foU;kl dks izkIr djus ds fy, bysDVªkWu (3s1 ) dks [kksus ds fy, dissociation of weak electrolyte increases.
izkFkfedrk nsrk gSA rRo D esa LFkk;h vkn”kZ xsl foU;kl ls ,dek= 1 (foy;u dh lkUnzrk ?kVus ij nqcZy fo|qr vi?kV~; ds fo;kstu dh
bysDVªkWu de gSa vr%] blesa ml rRo B dh rqyuk esa bysDVªkWu dks izkIr ek=k c<+sxhA)
djus dh izo`fŸk vf/kd gksrh gS ftlesa vkn”kZ xSl foU;kl ls 2 bysDVªkWu 12. (b)
de gksrs gSa bl izdkj] bysDVªkWu dksj izkIr djus dh izo`fŸk dk c<+rk Sol. Ca 3 N 2  6H 2 O  3Ca (OH) 2  2 NH 3
gqvk lgh Øe gS% A < C < B < D) 13. (a)
Sol. The blue colour of the solution is due to the
6. (b)
ammoniated electron which abwsorbs energy in the
Sol. Atomic radius increases on moving top to bottom in
visible region of light and thus imparts blue colour to the
a group due to increasing number of shells. However, it
solution.
decreasing on moving left to right in a period due to
(foy;u dk uhyk jax veksfu;kd`r bysDVªkWu ds dkj.k gksrk gSA tks
increasing Zeff and addition of electrons to the same shell.
izdk”k ds n`”; {ks= esa ÅtkZ dks vo”kksf’kr djrk gSA rFkk bl izdkj
Nb (4d)  Ta (5d) (due to poor shielding of nuclear foy;u dks uhyk jax iznku djrk gSA)
charge by 4f electrons).
For isoelectronic species, ionic radius M  ( x  y) NH  [M( NH ) ]  [e( NH ) ]
3 3 x 3 y
1
 .So correct order is Y3+ < Sr2+ < Rb+.
nuclear ch arg e 14. (b)
(ijekf.od f=kT;k oxZ esa Åij ls uhps tkus ij dks'kksa dh la[;k c<+us Sol. Calcium imparts brick red colour to the flame and
ds dkj.k c<+rh gSA tcfd ;g vkorZ esa ck¡;s ls nk¡;s tkus ij] çHkkoh calcium nitrate evolves O 2 nad a brown gas, NO 2 upon
ukfHkdh; vkos'k ds c<+us rFkk bysDVªkWuksa ds leku ckáre dks'k esa tqM+us heating.
ds dkj.k] ?kVrh gSA (dSfYl;e bZV ds leku yky jax Tokyk dks nsrk gS rFkk dSfYl;e
Nb (4d)  Ta (5d) (4f bysDVªkWuksa }kjk ukfHkdh; vkos'k ds nqcZy
ukbVªsV O 2 rFkk Hkwjh xSl NO 2 dks xeZ djus ij eqDr)
ifjj{k.k ds dkj.k)
lebysDVªkWuh Lih'kht ds fy,] vk;fud f=kT;k 
1 2Ca ( NO 3 ) 2  2CaO  O 2  4 NO 2 
 A blfy, lgh Øe Y3+ < Sr2+ < Rb+ gSA) ( Brown gas )
ukfHkdh; vkos' k
7. (d) 15. (a)
Sol. Due to electro negativity difference. The stability
Sol. BrF5 and XeOF4 have sp 3 d 2 hybridisation hence of interhalogen compounds follows following
their shape is square pyramidal. order : IF3  BrF3  ClF3
( BrF5 ,oa XeOF4 esa sp 3 d 2 ladj.k gksrs gS vr% mudh vkd`fr
(_.kfo|qrrk ds vUrj ds dkj.k] vUr% gSykstu ;kSfxd LFkkf;Ro dk
oxZ fijkfeMh; gksrh gSA) fuEu Øe iznf’kZr djrs gSa IF3  BrF3  ClF3 )

8. (b)
Sol. Volume decreases when pressure is increased at
constant temperature when temperature is decreased at
constant pressure, the volume decreases.
(fu;r rki ij tc nkc dks c<+k;k tkrk gS rks vk;ru de gksrk gSA
tc fu;r nkc ij rki de gksrk gS] rks vk;ru de gksrk gSA)
9. (d)
Sol. When work is done by the system,
(tc fdlh fudk; }kjk dk;Z fd;k tkrk gS] rc) U  q  W.
10. (d)
Sol. G  H  TS
At equilibrium, (lkE; es)a , G  0, H  TS
16. (a)
Sol. The thermal stability of the hydrides f nitrogen
family or group 15 elements decrease on moving
downwards in the group. Therefore NH 3 is the most
stable and BiH 3 is the least stable. The stability of the
hydrides of group 15 elements decreases in the order
NH 3.  PH 3  AsH 3  SbH 3.  BiH 3
(lewg 15 ds rRoksa ;k ukbVªkstu ifjokj ds gkbMªksbMksa dk rkih;
LFkkf;Ro] lewg esa uhps tkus ij ?kVrk gSA blfy;s] NH 3 vf/kdre
LFkk;h gSA rFkk BiH 3 lcls de LFkk;h gSA lewg 15 ds rRoksa ds
gkbMªkbMksa ds LFkkf;Ro ?kVrs Øe esa gS%
NH 3.  PH 3  AsH 3  SbH 3.  BiH 3 )
17. (d)
Sol. All other oxides of nitrogen except N 2 O and NO are
acidic in nature.
 ( N 2 O vkSj NO dks NksM+dj ukbVªkstu ds lHkh vkWDlkbM vEyh;  1  1
izÑfr ds gksrs gSa) i  1  1    1  1    0.2
 n  5
18. (d)
26. (c)
Sol. It is stabilized both by +I effect and hyper –
conjugation. Sol. Tf  i  K f  m
(bls +I izHkko ,oa vfrla;qXeu nksuksa }kjk LFkk;h fd;k tkrk gSA) 0.0054  i  1.8  0.001  i  3
Since it give 3 particles on dissociation the correct
19. (c) formula of the molecules is [Pt( NH 3 ) 4 Cl 2 ]Cl 2 .
Sol. Cl 2 is added to benzene ring in presence of sunlight
(pw¡fd ;g fo;kstu ij 3 d.k iznku djrk gS blfy, v.kq dk lgh lw=
to give benzene hexachloride.
[Pt( NH 3 ) 4 Cl 2 ]Cl 2 gSA
( Cl 2 dks lw;Z ds izdk”k dh mifLFkfr esa csathu oy; esa feyk;k tkrk
27. (b)
gS rks csathu gsDlkDyksjkbM izkIr gksrk gSA)
0.591
Sol. E  Eº  log Q
n
Eº  0 for all concentration cells
( Eº  0 lHkh lkUnz.k ds lsyks ds fy,)
0.0591  0.01 
0 log    0.0413 V
1  0.05 
20. (c) 28. (c)
Sol. Suppose (ekuk fd) At

We know (ge tkurs gS) (A0 – At) = kt for zeroth order

('kwU; dksfV ds fy,)

(0.50 – At) = 0.025 × t

0.50 – At = 0.025 × 15
Sol.
21. (c) At = 0.125 M
Sol. Carbon dioxide, methane, water vapour, nitrous
oxide, CFCs and ozone are greenhouse gases. 29. (a)
(dkcZu MkbvkWDlkbM] esFa ksu] tyck’I] ukbVªl] vkWDlkbM CFCs ,oa 256 256
vkstksu xzhugkml xSlasA) Sol.   4.
22. (a)
26 64
30. (d)
Sol. The amount of BOD in water is the measure of the
Sol. Addition of protective colloid is a method of
amount of organic matter in water in terms of how much
preventions of coagulations.
oxygen is required to break it down biologically.
(j{kh dksykWbM dk ;ksx Ldanu dksa jksdusa dh ,d fof/k gksrh gSaA)
(ty esa BOD dh ek=k bl :i esa ty esa dkcZfud inkFkZ dh ek=k
dk iSekuk gS ftruh vkWDlhtuu mls tSfod :i rksM+us ds fy, vko”;d 31. (b)
Sol. Gold sol is a lyophobic colloid.
gksrh gSA)
23. (c) (Lo.kZ lkWy ,d nzo&fojks/kh dksykWbM gSaA)
Sol. In orthorhombic crystal system,   b  c but axial
angles ,  and  are equal and 90. 32. (a)
(fo’keyEck{k fØLVy ra= es]a   b  c fdUrq v{kh; dks.k ,  ,oa Sol. Collectors like pine oil, xanthates, etc enhance non-
wettability of the mineral particles
 cjkcj rFkk 90. ds gksrsa gSaA)
(laxkz gd tSls phM+ ds rsy tSUFkSVl vkfn [kfut yo.kks ds xhyk u
24. (d) gksus ds xq.k/keZ dks c<+k nsrs gSA)
1
Sol. No. of atoms of (ijek.kqvksa dh la[;k) P  8  1
2
No. of atoms of (ijek.kqvksa dh la[;k) Q = 1 × 1 = 1 33. (a)
The formula of the compound is PQ. Sol.
(;kSfxd dk lw= PQ gSaA)
Coordination no. of P and Q
(P ,oa Q dh leUo;u la[;k) = 8 : 8
25. (c)
34. (c)
Sol. 5A  A 5
Sol. In Wacker process the oxidation of ethyne to ethanol
is catalysed by PdCl 2
 (csdj fof/k es ,Fkhu ls ,Fksuy ds vkWDlhdj.k dks PdCl 2 }kjk
mRizsfjr fd;k tkrk gSA)
35. (c)
Sol. In set Cu 2  , Fe 2  , Co 2  , all the ions have unpaired d
electrons. Hence, they are all coloured ions.
( Cu 2  , Fe 2  , Co 2  lewg ds lHkh vk;uksa es v;qfXer d-bysDVªkWu gS]
blfy;s lHkh vk;u jaxhu gksrs gSA)
41. (a)
Cu 2   [Ar]3d 9 4s 0 Sol.
Fe 2   [Ar]3d 6 4s 0 CH 3CH 2 CH(OH)CH 3 Conc
  CH 3CH  CHCH 3
2 H 2SO4
Co  [Ar]3d 4s 7 0 (X) (Y)

36. (b)
Sol. [Co( NH 3 ) 5 CO 3 ]Cl
Pentaamminecarbonatocobalt(III) chloride
(isUVk,sehudkcksuZ Vs ksdksckYV (III) DyksjkbM) 42. (b)
37. (c) Sol.
Sol. Linkage isomer of [Co( NH 3 ) 5 NO 2 ]Cl 2 will be
[Co( NH 3 ) 5 ONO]Cl 2
The name of the linkage isomer of
[Co( NH 3 ) 5 NO 2 ]Cl 2 is pentaaminenitritocobalt (III)
chloride.
( [Co( NH 3 ) 5 NO 2 ]Cl 2 dk vkcU/ku leko;oh
[Co( NH 3 ) 5 ONO]Cl 2 gksxkA 43. (d)
[Co( NH 3 ) 5 NO 2 ]Cl 2 dsa vkcU/ku leko;oh dk uke isUVk,sEehu Sol. Self explanatory. (Lor% le>us ;ksX;)
ukbVªkbVksdksckYV (III) DyksjkbM gSaA) 44. (c)
38. (c)
Sol. The CFSE of the ligands is in the order : Sol. Only  CH 3 group is electron donating group hence
(fyxs.M ds CFSE bl Øe esa gSa) it increases the electron density on nitrogen making it

H 2O  NH3  CN most basic.
Hence, excitation energies are in the order : (dsoy  CH 3 lewg bysDVªkWu nkrk lewg gksrkgS vr% ;g ukbVªkstu
(vr% mÙksftr ÅtkZ,¡ bl Øe esa gSa%) ij blds bysDVªkWu ?kuRo dks c<+kdj bl lokZf/kd {kkjh; cukrk gSA)
3
[Co(H O) ]  [Co( NH ) ]  [Co(CN) ] 3 3 45. (b)
2 6 3 6 6
hc 1 Sol.
For the relation (ds lEcU/k) E  E
 
The order of absorption of wavelength of light in the
visible region is :
(n`”; {ks= esa izdk”k dh rjaxnS/;Z ds vo”kks’k.k dk Øe gSa%)
[Co(H 2O)6 ]3  [Co( NH3 )6 ]3  [Co(CN)6 ]3
39. (d)
Sol. Biology
1. (d)
2. (a)
3. (c)
4. (d)
40. (a) 5. (c)
Sol. 6. (d)
7. (b)
8. (c)
9. (d)
10. (a)
11. (d)
12. (c)
13. (c)
14. (a) 73. (a)
15. (a) 74. (b)
16. (c) 75. (a)
17. (b)
76. (b)
18. (b)
77. (d)
19. (d)
20. (b) 78. (d)
21. (b) 79. (c)
22. (d) 80. (b)
23. (d) 81. (c)
24. (d) 82. (a)
25. (c) 83. (a)
26. (a)
84. (c)
27. (a)
28. (b) 85. (c)
29. (b) 86. (c)
30. (d) 87. (d)
31. (b) 88. (b)
32. (b) 89. (d)
33. (d) 90. (c)
34. (d)
35. (b)
36. (c)
37. (a)
38. (a)
39. (b)
40. (c)
41. (a)
42. (a)
43. (b)
44. (c)
45. (b)
46. (a)
47. (b)
48. (a)
49. (d)
50. (b)
50. (d)
52. (c)
53. (d)
54. (d)
55. (d)
56. (b)
57. (d)
61. (b)
59. (d)
60. (b)
61. (b)
62. (d)
63. (d)
64. (b)
65. (a)
66. (a)
67. (b)
68. (a)
69. (a)
70. (c)
71. (a)
72. (b)