Parallel Reactions-Competitive Reactions

[A]
k1 [B]
[B] [A]
A -> B - d[A]
dt = k1 [A] + k2[A]
k2 [C]
-> C [C]
k = k1 + k2

t ->

- d[A]
dt = k [A] [A] = [A]o e-kt = [A]o e-(k1 +k 2 ) t

d[B] -(k +k ) t
dt = k1 [A] = k1 [A]o e 1 2
d[C] -(k +k ) t
dt = k2 [A] = k2 [A]o e 1 2

k [A]o -(k +k ) t
[B] = - 1
(k1 + k2) e 1 2 + c

k [A]o k [A]
0=- 1 c = (k1 + ko)
(k1 + k2) + c 1 2

k1 [A]o -(k +k ) t
(k1 + k2) ( 1 - e 1 2 )
[B] =

k2 [A]o -(k +k ) t
(k1 + k2) ( 1 - e 1 2 )
[C] =

[B] k1
[C] = k2

Opposed Reactions
kf
->
A + B <- C + D - d[A]
dt = kf [A] [B] - kr [C] [D]
kr

- d[A]
dt = kf [A] [B] - kr [C] [D] = 0

kf  [C] [D] 
kr =  [A] [B] eq