C-101

6000 kg/h 6000 kg/h

Ethylene = 1 Ethylene = 1

T = 25oC P = 1 atm T = 100oC P = 30 atm

Molar flowrate Ethylene = 59.41 mol/s

References state: Ethylene (g, 25 oC, 1 atm)

Substances ńin ( mol/s) Ĥin (kJ/mol) ńout ( mol/s) Ĥout (kJ/mol)

Ethylene 59.41 0 59.41 Ĥ1

Ĥ1
o
Ethylene (g, 25 C, 1 atm) Ethylene (g, 100 oC, 30 atm)

Ĥa
Ĥb
Ethylene (g, 100 oC, 1 atm)

100
Ĥa = ∫25 𝐶𝐶 𝐶𝐶

11.47×10−5 (1002 −252 ) (−6.891×10−8 )(1003 −253 )

Ĥa = 40.75 × 10−3 (100 − 25) + +
2 3

17.66×10−12 (1004 −254 )

+ 4

Ĥa = 3.57 kJ/mol
Ĥb = 1/ρ (P2 – P1)

1𝐶3 28.05 𝐶𝐶 1 𝐶𝐶𝐶𝐶 𝐶𝐶𝐶 .𝐶 8.314 𝐶 1𝐶𝐶 1000𝐶

Ĥb = 1.18 𝐶𝐶 × (30 − 1)𝐶𝐶𝐶 × × 1000 𝐶𝐶𝐶 × 0.08206 𝐶 . + + 1000𝐶 +
𝐶𝐶𝐶𝐶 𝐶𝐶𝐶 𝐶𝐶𝐶 .𝐶 1𝐶3

Ĥb = 69.84 kJ/mol

Ĥ1 = Ĥa + Ĥb = 3.57 kJ/mol + 69.84 kJ/mol = 73.41 kJ/mol

C-103

5000 kg/h 5000 kg/h

Nitrogen gas = 1 Nitrogen = 1

T = 25oC P = 1 atm T = 25oC P = 10 atm

Molar flowrate Nitrogen = 49.57 mol/s

References state: Nitrogen (g, 25 oC, 1 atm)

Substances ńin ( mol/s) Ĥin (kJ/mol) ńout ( mol/s) Ĥout (kJ/mol)

Ethylene 49.57 0 49.57 Ĥ1

Ĥ1
o
Ethylene (g, 25 C, 1 atm) Ethylene (g, 25 oC, 10 atm)

Ĥ1 = 1/ρ (P2 – P1)

1𝐶3 28.02 𝐶𝐶 1 𝐶𝐶𝐶𝐶 𝐶𝐶𝐶 .𝐶 8.314 𝐶 1𝐶𝐶 1000𝐶

Ĥ1 = 1.2504 𝐶𝐶 × (10 − 1)𝐶𝐶𝐶 × × 1000 𝐶𝐶𝐶 × 0.08206 𝐶 . + + 1000𝐶 +
𝐶𝐶𝐶𝐶 𝐶𝐶𝐶 𝐶𝐶𝐶 .𝐶 1𝐶3

Ĥ1 = 20.43 kJ/mol