Professional Documents
Culture Documents
Diversified Enterprises: Safety Data Sheet
Diversified Enterprises: Safety Data Sheet
Diversified Enterprises: Safety Data Sheet
Product identifiers
Product name: ACCU OYruf tfst'MMarker Pens
2. HAZARDS IDENTIFICATION
Classification:
2-ethoxyethanol and MethylViolet 28 are considered hazardous by the 20'12 OSHA Standard (29 CFR 1910.1200).
Label elements:
Signalword: Danger
Hazard statements:
HZ22:Flammable liquid and vapor
H302: Harmful if swallowed
H313: Causes eye iritation
H332:Harmtulif inhaled
H351 Suspected of causing cancer
H360 May damage fertility of the unborn child
H373 May cause damage to organs through prolonged or repeated exposure if swallowed
Page 1 of 6
Prccautionary statements - Response:
lf in eyes: Rise with water br several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. lf irritation persists get
medical attention.
lf on skin: Remove all contaminated clothing immediately. Rinse skin with water. lf skin initation o@urs, get medical attention.
lf swallowed: Call a poison center or physician if you feel unwell.
3. COMPOSITION/INFORMATION ON INGREDIENTS
* 2ethoxyethanol is also known as ethylene glycol monoetryl ether, cellosolve solvent, ethylcellosolve, and glycol
ether EE
* Formamide is also known as methanamide.
General Advice: Poison information centers in each State capital city can provide additional assistance for scheduled poisons (13 1126).
Skin e,ontact:: Remove contaminated clothing. Wash exposed area with soap and water. Rinse thoroughly. lf irritation persists or if
contact has been prolonged, seek medicalattention. Launder clohing before re-use.
Eye contact: Gently rinse eyes for 15 minutes. Consult a physician. Move individual into fresh air.
lnhalation: Move individual into fresh air. lf breathing is difficult, oxygen may be given by qualified personnel. Seek immediate medical
attention.
Most important symptoms and efbcts, both acute and delayed: lrritating to eyes. May cause slight skin irritation. Central nervous
system effecb. lngestion may cause gastrointestinal irritiation, nausea, vomiting, and dianhea. May affect the liver. May affect the kidneys.
May affect the blood. May affect the bone marrow. May affect respiration. May affect fertility or cause teratogenic effects.
lndication of any immediate medica! attention and special treatment needed: No data available.
Page 2 of 6
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: Carbon dioxide, alcohol-resistant foam, dry chemical, or water spray.
Special ha,ards arising from the substance: 2-ethoxyethanol is flammable. lt may be ignited by heat, sparks, or flames. Most vapors
are heavier han air. They will spread along the ground and collect in low or confined areas.
Advice for firefighters: Wear self-contained brathing apparatus for firefghting il necessary.
Personal precautions: Use personal protective equipment. Ensure adequate ventilation. Avoid breating vapors.
Environmental precautions: Prevent futher leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials ior cleaning up: Soak up with inert absorptive material and put into a suitable chemical waste disposal
container.
Precautions for sah handling: Avoid contact with skin and eyes. Avoid inhalation of vapor.
Conditions for safe storage: Keep bofles securely closed in a dry, well-ventilated place when not in use. Avoid strong oxidizing agents.
2+ffioryehanol:
OSHA Table Z-1 - 2W ppm TWA
ACGIH TLV- 5 ppmTWA
Formamide:
OSHA Table Z-1 -20 ppm TWA
ACGIH TLV - 10 ppm TWA
Appropriate engineering conEols: Ensure adequate ventilation. Handle in accordance witkr good industrial hygiene and safety practice.
Page 3 of 6
10. STABIL]rY AND REACTIVITY
1 1. TOXICOLOGICAL INFORMATION
The most likely route of entry is by dermal absor$ion. Routes of entry include eye and skin contact, ingestion, and inhalation. Specific
health effects are broken out by the two primary ingredients.
2cthoryethano!:
Carcinogenic effects: Not considered carcinogenic. Not listed by ACGIH, IARC, NTP, or OSHA HCS.
Mutagenc effects: May affect genetic material based on animal test data.
Reproductive effects: May cause adverse reproductive effects. May impair fertility.
Teratogenic effects: May cause birth defects.
Specific target organ toxicity, single exposure: No information available.
Specific target organ toxicity, repeated exposure: May cause damage to central nervous system, blood, kidneys, liver, bone marrow.
Aspiration hazard: No data available.
Formamide:
Carcinogenic effects: Not identi{ied as probable, possible, or confirmed human carcinogen by IARC, ACGIH, NTP, or OSHA.
Mutagenic effects: Mouse, male and female by micronucleus test - negative.
Reproductive effects: Presumed human reproductive toxicant.
Teratogenic effects: May cause birth defects.
Speciflc target organ toxicity, single exposure: No information available.
Specific target organ toxicity, repeated exposure: Oral - may cause damage to blood or organs through prolonged or repeated exposure.
Aspiration hazard: No data available.
1 2. ECOLOGICAL INFORMATION
2ethoryethanol:
Formamide:
Page 4 of 6
13. DISPOSAL CONSIDERANONS
Waste must be disposed of in accordance with federal, state, and local environmental control regulations.
Spent material samples must be handled with care. Disposal of these contiaminated materials also presents exposure hazards, and
should not be handled wihout gloves or in areas with poor ventilation.
DOT
UN No.:UN 1171
Proper shipping name: Etlrylene glycol monoethyl ether
Hazard class:3
Packing group: lll
ERG No.:127
Symbol:R4
IMO/IMDG
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class:3
Packing group: lll
EMS: F-E
IATA
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class:3
Packing group: lll
ERG Code:31
1 5. REGULATORY INFORMATION
lnventories:
Page 5 of 6
CERCTA/SARA Reportable quantity, 2-etoryethanol = 1,669
'0.
Canada WHMIS hazad class: 2-ethoxyethanol - 83, D1B, D2A,DzB. Classified according to the hazard criteria of the CPR
EU classification:2-ethoxyethanol - R10, R60, R61,R2022,S53, Sr+5, Xn. Classified in accordwith Annex Vlto Directive lTlS/;glEEC
License is granted to make unlimited paper copies for internal use only.
The above information is believed to be conect, but does not claim to be all-inclusive and is to be used only as a guide. This information
should not be taken as a wananty for which Diversif,ed Enterprises assumes legal responsibility. lt is provided solely for consideration,
investigation, and verification. The information contained in this document is based on our cunent understanding of available data and is
applicable to the product with regard to appropriate safety precautions. lt is the use/s responsibility to develop proper methods based on
the actual conditions of use.
Page 6 of 6