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    Unit 1: Introduction: Organic Inorganic

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    Ellah Gutierrez
    This document provides an introduction to inorganic chemistry. It discusses how inorganic chemistry involves the study of elements other than carbon in the periodic table, including metals. Key points include that metal-metal and metal-carbon bonds can form multiple bonds using d orbitals, and that hydrogen and methyl groups can serve as bridges in metal clusters. Coordination compounds can have coordination numbers higher than four, which is the typical coordination number for carbon. Carbon can be the center of metal clusters and aromatic rings can form bonds with metals.

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    Unit 1: Introduction: Organic Inorganic

    Uploaded by

    Ellah Gutierrez
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    This document provides an introduction to inorganic chemistry. It discusses how inorganic chemistry involves the study of elements other than carbon in the periodic table, including metals. Key points include that metal-metal and metal-carbon bonds can form multiple bonds using d orbitals, and that hydrogen and methyl groups can serve as bridges in metal clusters. Coordination compounds can have coordination numbers higher than four, which is the typical coordination number for carbon. Carbon can be the center of metal clusters and aromatic rings can form bonds with metals.

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    This document provides an introduction to inorganic chemistry. It discusses how inorganic chemistry involves the study of elements other than carbon in the periodic table, including metals. Key points include that metal-metal and metal-carbon bonds can form multiple bonds using d orbitals, and that hydrogen and methyl groups can serve as bridges in metal clusters. Coordination compounds can have coordination numbers higher than four, which is the typical coordination number for carbon. Carbon can be the center of metal clusters and aromatic rings can form bonds with metals.

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    69 views1 page

    Unit 1: Introduction: Organic Inorganic

    Uploaded by

    Ellah Gutierrez
    This document provides an introduction to inorganic chemistry. It discusses how inorganic chemistry involves the study of elements other than carbon in the periodic table, including metals. Key points include that metal-metal and metal-carbon bonds can form multiple bonds using d orbitals, and that hydrogen and methyl groups can serve as bridges in metal clusters. Coordination compounds can have coordination numbers higher than four, which is the typical coordination number for carbon. Carbon can be the center of metal clusters and aromatic rings can form bonds with metals.

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    INORGANIC CHEMISTRY

    UNIT 1: INTRODUCTION

    organic inorganic
    • about the rest of the elements in the periodic table (including
    • compounds of C
    C)
    • metal-metal and metal-C bonds can form quadruple bonds (,
    from d orbitals), even quintuple bonds
    CO CO
    CO CO
    OC Mn CH3 I Cr C CH3
    • C is capable of single, double and OC OC
    triple bonds CO CO
    3-
    Cl Cl
    Cl Cl
    Re Re
    Cl Cl
    Cl Cl
    • H and CH3 serve as bridges in metal clusters
    Li CH3
    • H is terminal - CH3 Li
    • CH3 is terminal CO CO
    CO CO
    CH3
    OC Cr H Cr CO
    Li Li
    OC OC
    CO CO CH3

    • coordination number of C is 4 • coordination compounds can have 5, 6 and higher


    coordination numbers

    • C with coordination number of 4


    • can be tetrahedral or square planar
    is tetrahedral

    • C can be a center of a metal cluster


    Fe(C O3)
    • C only has 4 bonds
    (C O3)F e Fe(C O3)
    C
    (C O3)F e Fe(C O3)

    • aromatic ring forms a bond with metals

    Ni
    • aromatic ring undergoes NAS

    Cr Ni

    1|CHEM 104

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