Document PDF 33

RET–16
FIITJEE RET – 16
(2018 – 2020)(1ST YEAR_CHAMPION–20’S)
IIT-2015 (P2)
DATE: 10.12.2018
Time: 3 hours Maximum Marks: 180
INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 60 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
3. Fill in the boxes provided for Name and Enrolment No.
4. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
5. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format:
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part
consists of three sections.
8. Section I contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE is correct.
9. Section II contains 3 paragraphs. Each describing theory, experiment, data etc., Six questions related to
three paragraphs with two questions on each paragraph. Each question to a particular passage should
have ONLY ONE correct answer among the four given choices (A), (B), (C) and (D).
10. Section III contains 4 Multiple choice questions. Each question has two lists (List–1: P, Q, R and S; List–
2: 1, 2, 3 and 4). The options for the correct match are provided as (A), (B), (C) and (D) out of which ONLY
ONE is correct.
D. Marking Scheme
11. For each question in Section 1, 2 and 3 you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one
(–1) mark will be awarded.
Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.
NAME:
ENROLLMENT NO.:
FIITJEE (Hyderabad Classes) Limited., 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad–500 063. Phone: 040-66777000-03 Fax: 040-66777004
RET–16
PAPER – II
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
The section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. A metallic cylinder of radius r and height h is totally submerged

in a liquid contained in a beaker as shown in the figure. If force
F is pulling the string with a constant velocity v, the graph
showing the variation of force F against displacement of
cylinder is best represented by.
(A) (B) (C) (D)
2. A non – homogeneous small sphere having average

density same as that of the liquid. It is released from
rest, in the position as shown in figure. C being its
centre of mass O being the centre of sphere.
(A) C moves left (B) O moves down
(C) O moves up (D) None of these
3. A U – tube of base length filled with same volume

of two liquids of densities  and 2 is moving with
an acceleration ‘a’ on the horizontal plane. If the
height difference between the two surfaces (open to
atmosphere) becomes zero, then the height h is
given by
3a a
(A) (B)
2g 2g
a
(C) (D) None of these
g
Space for rough work
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4. The area of cross section of the two vertical arms of

a hydraulic press are 1 cm2 and 10 cm2
respectively. A force of 10 N applied, as shown in
the figure, to a tight fitting light piston in the thinner
arm balances a force F applied to the corresponding
piston in the thicker arm. Assuming that the levels of
water in both the arms are the same, we conclude.
(A) F = 100 N
(B) F = 25 N
(C) F= 50 N
(D) F, as applied, cannot keep piston in equilibrium
5. A sealed tank containing a liquid of density p moves with horizontal

acceleration a as shown in the figure. The difference in pressure between
two points A and B will be
(A) hg (B) lg (C) hg  la (D) hg + la
6. When two equal volumes of two substances are mixed together, the specific gravity of the mixture is 4. But
when equal weights of the same substances are mixed together, the specific gravity is 3. The specific
gravity of the two substances are
(A) 6, 2 (B) 5, 3 (C) 7, 1 (D) 7, 8
7. In the adjoining figure, the cross sectional area of the smaller tube is ‘a’ and
the larger tube is ‘2a’, A block of mass m is kept in the smaller tube having
the same base area ‘a’, as that of the tube. The difference in between water
levels of the two tubes are
P0 m P0 m m m
(A)  (B)  (C) (D)
g a g 2a a 2a
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8. A hemispherical portion of radius R is removed from the bottom of a cylinder of radius R.

The volume of the remaining cylinder is V and its mass is M. It is suspended by a string in a
liquid of density  where it stays vertical. The upper surface of the cylinder is at a depth h
below the liquid surface. The force on the bottom of the cylinder by the liquid is
(A) Mg (B) Mg  Vg (C) Mg  R2hg 

(D) g V+R2h 
9. If a sample of metal weighs 210 gin air, 180 gin water and 120 g in a liquid then RD of metal and liquid are
respectively.
(A) 3,7 (B) 7,3 (C) 4,6 (D) 6,4
10. A cylindrical vessel filled with water is released on an inclined surface

of angle  as shown in figure. The friction coefficient of surface with
vessel is  (< tan ). Then the constant angle made by the surface of
water with the incline will be
(A) cot 1  (B)   tan1 
(C)   tan1  (D) tan1 
SECTION – II: Paragraph Type

This section contains 3 paragraphs each describing theory, experiment, data etc., Six questions relate to three
paragraphs with two question on each paragraph. Each question of a paragraph has only one correct answer
among the four choices (A), (B), (C) and (D).
Paragraph For Questions 11 & 12

An open rectangular tank of dimensions 6m x 5m x 4m contains
water upto a height of 2 m. The vessel is accelerated horizontally
with an acceleration of a m / s2 as shown. Take
water  103 kg/ m3 , g 10 m/ s2 , atmospheric pressure
 10 N/ m .
5 2
Based on above information answer the following questions.
11. Determine the maximum value of a so that no water comes out from tank.
2g g
(A) g (B) (C) (D) 2g
3 3
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12. If instead of open top, the vessel is closed, then absolute pressure at point A would be:
20
[ take a  m / s2 and initially height of water in tank is 2 m]
3
(A) 1.33  105 N/ m2 (B) 1.0  105 N/ m2
(C) 3.33  104 N/ m2 (D) None of these

A small spherical ball of radius r is released from its completely
submerged position (as shown in the figure) in a liquid whose
density varies with height h (measured from the bottom) as
L  0 4   3h / h0  . The density of the ball is (5/2) 0 . The
height of the vessel is h0  12 / 2 . Consider r  h0 and g = 10
2
m/s
13. Where will the ball come in the equilibrium ?

(A) At a depth h0 / 2 from top
(B) At the bottom of the vessel
(C) At a depth 3h0 / 4 from top
(D) The ball will never be at equilibrium
14. The ball will reach at the bottom of the vessel

(A) in 1 s
(B) in 2 s
(C) in 0.5 s
(D) The ball will not reach at the bottom of the vessel
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A rod of length 6m has a mass 12 kg. It is hinged at one end A at
a distance of 3 m below the water surface. The specific gravity of
the material of rod is 0.5
15. What weight must be attached to the other end B so that 5 m of the rod is immersed in water ?
17 7 7
(A) 7 kgf (B) kgf (C) kgf (D) kgf
3 5 2
16. Find the magnitude and direction of the force exerted by the hinge on the rod
(A) 17/3 kgf in the downward direction (B) 8 kgf in the downward direction
(C) 4kgf in the downward direction (D) 5kgf in the downward direction
SECTION – III: (Matching List Type)
This section contains 4 questions, each having two matching lists. Choices for the correct combination of
elements from List–I and List–II are given as option (A), (B), (C) and (D) out of which ONLY ONE is correct.
17. A spherical body of radius R consists of fluid of constant density and is in equilibrium under its own
gravity. If P (r)is the pressure at r (r < R), then the correct option(s) is
List – I List – II
P r  0 
63
(P)  2R  (1)
Pr 
3 
80

 3R 
Pr 
 4 
(Q) (2) 0
 2R 
Pr 
 3 
 3R 
Pr 
 5  16
(R) (3)
 2R  21
Pr 
 5 
P r  R / 2 
9
(S)  R (4)
Pr   5
 3
27
(5)
32
P Q R S
(A) 5 3 1 2
(B) 2 1 5 3
(C) 4 1 3 5
(D) 3 1 4 2
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18. The spring balance A reads 2 kg with a block m suspended from it. A
balance B reads 5 kg when a beaker with liquid is put on the pan of the
balance. The two balances are now so arranged that the hanging mass is
inside the liquid in the beaker as shown in the figure. In this situation.
(P) The reading of spring balance A (1) Less than 2 kg
(Q) The reading of spring balance B (2) Less than 5 kg
If the set up is placed in lift moving downwards with
(R) an acceleration, then the spring balance A’s reading (3) More than 2 kg
will be
If Set up is placed in a lift moving upwards with an
(S) acceleration, then the spring balance B’s reading will (4) More than 5 kg
be
(5) Remains Same
P Q R S
(A) 1 4 3 2
(B) 1 4 1 4
(C) 3 2 5 2
(D) 1 4 1 5
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19. A U – tube is held in a vertical plan such that its two limbs are vertical with
middle portion horizontal as shown in the figure. Three liquids A, B and C
are poured into it and in steady state their interface are as shown in the
figure. Which of the following options is correct
(P) Pressure at T (1) Less than that of liquid C
(Q) Density of liquid A (2) Greater than that of liquid C
(R) Density of liquid B (3) More than that at S
(S) Pressure at R (4) Less than that at R
(5) Equal to that at S
P Q R S
(A) 5 2 2 4
(B) 3 1 1 5
(C) 4 1 2 5
(D) 3 2 1 5
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20. If the container filled with liquid gets accelerated horizontally or vertically, pressure in liquid gets changed.
 
In liquid a y for calculation of pressure, effective g is used. A closed box with horizontal base 6 m by 6 m
2
and a height 2 m is half filled with liquid. It is given a constant horizontal acceleration 5 m /s and vertical
2
downward acceleration 5 m /s
(take atmospheric pressure = 105 N/ m2 , density of water = 1000 kg/ m3 ,g  10m/ s2 )
Length of exposed portion of top of box (in m) is equal to
(P) (1) 5
The maximum value of water pressure in the box (in 105 Pa )is
(Q) equal to (2) 2
Water pressure at the bottom of centre of the box (in 105 Pa ) is

(R) equal to (3) 1.1
2
What is the magnitude of vertical acceleration of box(m/s ) for
2
given horizontal acceleration (5 m /s ) , so that no part of the
(S) (4) 1.4
bottom of the box is exposed
(5) 2.5
P Q R S
(A) 1 4 3 2
(B) 3 5 2 1
(C) 2 4 5 1
(D) 2 3 4 1
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PART II: CHEMISTRY

21. The order of decreasing stability of the following cations is :

  
CH3 CHCH3 ,CH3 CHOCH3 ,CH3 CHCOCH3
(A) III > II > I (B) I > II > III (C) II > I > III (D) I > III > II
22. The group which exhibits – I effect as well as + M effect is

(A) >C=O (B) –CN (C) –NO2 (D) –F
23. The most stable carbanion among the following is

CH 2 CH 2
CH 2 CH3 CH 2
(A) (B) (C) (D)
OCH 3 NO 2
24. Maximum – I effect is exerted by the group


(A)  N H3 (B) C6H5 (C) –NO2 (D) –OCH3
25. Which of the following is weakly acidic ?

(A) CH3CHFCOOH (B) FCH2CH2COOH
(C) BrCH2CH2COOH (D) CH3CHBrCOOH
26. Identify the correct order of stability
CH 2 CH 2 CH 2
CH 2
NO 2
:
NO 2
NO 2
(P) (Q) (S)
(R)
(A) Q > R > P > S (B) S > R > Q > P (C) S > R > P > Q (D) R > P > Q > S
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27. Arrange the following in increasing order of stability.
(I) (II) (III)

(A) I < II < III (B) II < I < III (C) I < III < II (D) II < III < I
28. In the following there are three carbon– O Their lengths are
oxygen bonds denoted by x, y and z : x y z in the order
H3C C O CH3
(A) x = y = z (B) x < y < z (C) x < y = z (D) y < x < z
29. Identify the major contributor in following canonical structures.

H3C CH C N H3C CH C N
(a)
I II
(b) H3C CH CH CH NO 2 H3C CH CH CH NO 2

I II
NH2 NH2
(c) H3C CH2 C NH2 H3C CH2 C NH 2
I II
(A) a – II, b – II, c – I (B) a – I, b – II, c – II
(C) a – II, b – II, c – II (D) a – I, b – I, c – II
30. Which of the following resonating structures is the major contributor to the resonance hybrid?
 
(I) CH3 – CH2 – CH  OCH3 (II) CH3 – CH2 – CH = O CH3
 
(A) I (B) II
(C) Both have equal contributions (D) They are not resonating structures
RET–16

In a substance that are resonance hybrids, the measured length of given bond usually differs from that predicted
from any one of the contributing structures. Chloroethylene is found by measurement to have a C—Cl distance of 1
0 0
.69 A . This is shorter than C—Cl bond in such compounds a methyl chloride (I.77 A ), an indication that in
chloroethylene the C—Cl bond has some double bond character.
31. Which of the following molecules has the shortest carbon–carbon single bond length ?
(A) CH2 = CH–CCH (B) CH2=CH–CN
(C) CH2=CH–CH=O (D) CH2=CH–CH=CH2
32. Arrange following in increasing order of C–N bond length :
(A) Q < P < R < S (B) P < R < S < Q (C) R < S < Q < P (D) S < R < Q < P
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It has been observed that in cases of certain compounds or ions, no single electronic structure can explain all the
properties of compounds or ions. Hence, more than one electronic structures are required for explaining the
properties of compounds or ions. This phenomenon is known as Resonance and the various electronic structures
are known as resonating structures. Resonance has an important role in deciding the stability of ions or molecules
and acid – base character of species.
33. Which among the following structures is most stable?

O O
(A) (B)
H3C CH CH C CH3 H3C CH CH C CH3
O O
(C) (D)
H3C CH CH C CH3 H3C CH CH C CH3
34. Consider the following two carbocations:

+ +
(i) (C6H5)2 CH (ii) C6H5 CH2
Which of the following statements is correct?
(A) (i) is less stable than (ii) (B) (ii) is less stable than (i)
(C) (i) and (ii) are equally stable (D) the stabilities of A and B cannot be predicted

–
Generally e & lone pair of electron enter into delocalization. But in hyperconjugation it is electrons which
participates in delocalization / which changes to unsaturation. This hyperconjugation is observed in alkenes,
carbocations & carbon radicals.
35. Which of the following is more stable ?

(A) CH2 = CH2 (B) CH3–CH=CH2
H3C
(C) (D)
H3C
36. Which is most stable alkene.

(A) 3, 3 dimethyl but–1–ene (B) 2, 3dimethyl but–2–ene
(C) 2–methyl but–2–ene (D) but–2ene
RET–16

37.
Column – I Column – II
(compounds) (Characteristics)
(P) (1) Mesomeric effect / resonance
(Q) Ph–CH=CH–CH3 (2) Inductive effect
(R) (3) Polar
(S) (4) Nonpolar
Code :
P Q R S
(A) 2 3 1 4
(B) 1, 2, 3 1, 2, 3 1, 2, 3 1, 4
(C) 1, 2, 3 1, 2 1, 2, 3 3, 4
(D) 1, 3 2, 3 1, 2 1, 4
38.
(intermediate) (stabilized by)

Resonance
(P) H3C  CH CH3 (1)
(Q) Ph CH CH3 (2) Inductive effect
Hyperconjugation
(R) Ph CH CH3
(3)

(S) H2C = CH  CH  CH3 (4) Electrometric effect
Code :
P Q R S
(A) 2,3 1, 2,3 1 1, 3
(B) 1, 2 2, 3 3, 2 4
(C) 1, 3 1, 3 1, 2 1
(D) 1, 2 1, 3 1 1, 2, 3
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39.
 Resonance
(P) H3 C  CH2 (1)
 Hyperconjugation
(Q) H3 C  CH2 (2)
 +I effect
Cl  C  Cl
(R) | (3)
C
 I effect
(S) CH2  CH  CH 
 C NO2  CH3 2 (4)
Code :
P Q R S
(A) 1, 3 1, 3 2, 4 2, 4
(B) 1, 2 1, 2 3, 4 3, 4
(C) 1, 4 1, 4 2, 3 2, 3
(D) 2, 3 2 1, 4 1, 3, 4
40.
(Stability) (Reason)
CH3 Inductive effect only
(P) Ph C > CH 3 (1)
CH3
CH3 Resonance effect only
(Q) CH 3 C < CH3 (2)
CH3
CH3 Hyper conjugation, resonance and Inductive
< CH3CH 2 effect
(R) CH 3 C (3)
CH3
CH3 Hyper conjugation and Inductive effect
(S) PH CH2 > Ph CH2 CH2 C CH2 (4)

CH3
Code :
P Q R S
(A) 2 4 1 3
(B) 1 4 3 2
(C) 3 1 4 2
(D) 4 2 3 1
RET–16
PART III: MATHEMATICS

  x 2  sin  x 
 for  x   0
41. If f(x) =   x where [x] denotes the greatest integer less than or equal to x, then

 0 for  x   0
lim f(x) equals
x 0
(A) 1 (B) 0 (C) –1 (D) does not exist
1  cos3 x
42. lim is equal to
x 0 x sin x cos x
2 3 3 3
(A) (B) (C) (D)
5 5 2 4
n
1
43. If [x] denotes the greatest integer less than or equal to x, then lim
n  n2
 kx 
k 1
equals
x x
(A) (B) (C) x (D) 0
2 3
x  x 2      xn  n
44. The value of lim is
x 1 x 1
n 1 n  n  1 n  n  1
(A) n (B) (C) (D)
2 2 2
 1 2 n 
45. lim       is equal to
 1 n 1 n 1  n2 
n  2 2
1 1
(A) 0 (B)  (C) (D) none of these
2 2
RET–16
46. If {x} and [x] are the fractional part function and greatest integer functions of x respectively, then
e   x  1
x
lim is equal to
x a
x
2
1
(A) 0 (B) (C) e – 2 (D) does not exist
2
 1000 
  x  k
m

47. lim  k 1  is (m > 101)
x   x m  101000 
 
 
2 3
(A) 10 (B) 10 (C) 10 (D) none of these
1  2  3  4  5  6      2n 
48. lim is equal to
n 
 
n2  1   4n2  1 
1 1
(A) –1 (B) 1 (C)  (D)
3 3
1  cos x cos2x cos3x

49. lim is equal to
x 0 sin2 2x
7 7 7 7
(A) (B) (C) (D)
2 3 4 5
2
50. The value of lim [x + x + sin x] is
x 0
(where [.] denotes greatest integer function)
(A) does not exist (B) is equal to zero (C) –1 (D) none of these
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x  ai
Ai = , i = 1, 2, ...... n, and a1 < a2 < a3 < ...... < an.
x  ai
51. If 1  m  n, m  N, then the value of L = lim  A1A 2    An  is
x am
n–m+1 n–m
(A) always 1 (B) always –1 (C) (–1) (D) (–1)
52. If 1  m  n, m  N, then the value R = lim  A1A 2    A n  is

x am
m+1 n–m
(A) always 1 (B) always –1 (C) (–1) (D) (–1)
A sequence is a function whose domain is the set of natural number. A sequence s 1, s2, ....... of real numbers is
said to have a limit  if lim sn = . If  < , then < sn > is said to convergent. The following are well known
n 
1
(i) lim p = 0 (p > 0)
n  n
(ii) lim xn = 0 (|x| < 1)

n 
s1  s2      sn
(iv) If lim sn = , then lim =
n  n  n
53. Which of the following sequences do not converge to zero

1 1 1 1  1
(A) 1   2      n1  (B)
n 3 3 3  n!
n
 1
(C)  1   (D) n 1 n
 n
54. Let f(x) = –1 + |x – 1|, g(x) = 2 – |x + 1|, then

 1  1  1  1
(A) lim fog    0 (B) lim fog    1 (C) lim gof    0 (D) lim gof    1
n 
n n 
n n
n n 
n
RET–16
sin x  aex  be x  c ln 1  x 

If lim f(x) = finite where f(x) = and a, b, c are real numbers
x 0 x3
55. The value of b is
1 1
(A)  (B) (C) 0 (D) 1
2 2
56. The value of lim f(x) is

x 0
1 1
(A) –2 (B) –1 (C)  (D) 
2 3

57. lim f(x) , where f(x) is as in column I is

x 0
tan e  x 2  tan  e2  x 2
2
2
(P) f(x) = (1)
sin2 x 8
5 2  5
 2  tan x  tan x    2 
(Q) f(x) =     (2) 15
tan x
(where [x] denotes greatest integer function)
(R)
3
1  x 2  4 1  2x (3) 0
f(x) =
x  x2
2  1  cos x 1
(S) f(x) = (4)
sin2 x 2
Code: P Q R S
(A) 2 3 4 1
(B) 3 1 2 4
(C) 2 3 1 4
(D) 2 1 4 3
RET–16
a0 xm  a1xm1      ak xmk
58. Let (x) =
b0 xn  b1xn1      b xn
Where a0  0, b0  0, then lim (x) is equal
x 0
(P) m>n (1) 
(Q) m=n (2) –
a0 a0
(R) m < n and n – m is even, >0 (3)
b0 b0
a0
(S) m < n and n – m is even, 0 (4) 0
b0
Code: P Q R S
(A) 1 2 4 3
(B) 4 3 2 1
(C) 4 3 1 2
(D) 2 1 4 3
59. lim f(x) where f is given as in Column I

x 0
sin3x 4
(P) f(x) = (1)
log 1  5x  5
esin3x  1 3
(Q) f(x) = (2)
log 1  tan2x  5
log  2  cos 2x  3
f(x) =
 
(R) (3)
log 1  sin2 3x 2
log 1  sin 4x  2
(S) f(x) = (4)
e sin5x
1 9
Code: P Q R S
(A) 3 2 4 1
(B) 4 2 4 1
(C) 2 3 4 1
(D) 4 1 2 3
RET–16
60. The set of all points where limit of f(x) exists, where f is given by
(P) [x] + x   x (1) 
R ~  n,n  N 
(Q) [x] + [–x] (2) (0, )
(R) cos log x (3) R~I
2 2
(S) x + [x ] (4) R
Code: P Q R S
(A) 3 2 4 3
(B) 4 3 2 1
(C) 4 1 3 2
(D) 4 1 2 3
RET–16
FIITJEE RET – 17
(2018 – 2020)(1ST YEAR_CHAMPION–20’S)
IIT-2014 (P2)
DATE: 10.12.2018
ANSWERS
PHYSICS
1. A 2. C 3. A 4. C
5. D 6. A 7. C 8. D
9. B 10. D 11. B 12. A
13. A 14. BONUS 15. BONUS 16. A
17. C 18. B 19. C 20. BONUS
CHEMISTRY
21. C 22. D 23. D 24. A
25. C 26. B 27. C 28. B
29. C 30. B 31. B 32. B
33. A 34. B 35. C 36. B
37. B 38. A 39. D 40. C
MATHEMATICS
41. D 42. C 43. A 44. C
45. B 46. D 47. C 48. C
49. C 50. A 51. C 52. D
53. C 54. B 55. B 56. D
57. A 58. C 59. C 60. B

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RET–16

Don’t write / mark your answers in this question booklet.

1. A metallic cylinder of radius r and height h is totally submerged

(A) (B) (C) (D)

2. A non – homogeneous small sphere having average

3. A U – tube of base length filled with same volume

Space for rough work

4. The area of cross section of the two vertical arms of

5. A sealed tank containing a liquid of density p moves with horizontal

Space for rough work

8. A hemispherical portion of radius R is removed from the bottom of a cylinder of radius R.

(A) Mg (B) Mg  Vg (C) Mg  R2hg 

10. A cylindrical vessel filled with water is released on an inclined surface

SECTION – II: Paragraph Type

Paragraph For Questions 11 & 12

Based on above information answer the following questions.

Space for rough work

Paragraph For Questions 13 & 14

13. Where will the ball come in the equilibrium ?

14. The ball will reach at the bottom of the vessel

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Paragraph For Questions 15 & 16

Space for rough work

Space for rough work

Space for rough work

Water pressure at the bottom of centre of the box (in 105 Pa ) is

Space for rough work

PART II: CHEMISTRY

21. The order of decreasing stability of the following cations is :

22. The group which exhibits – I effect as well as + M effect is

23. The most stable carbanion among the following is

(A) (B) (C) (D)

24. Maximum – I effect is exerted by the group

25. Which of the following is weakly acidic ?

26. Identify the correct order of stability

Space for rough work

(I) (II) (III)

29. Identify the major contributor in following canonical structures.

(b) H3C CH CH CH NO 2 H3C CH CH CH NO 2

Space for rough work

SECTION – II: Paragraph Type

Paragraph For Questions 31 & 32

32. Arrange following in increasing order of C–N bond length :

Space for rough work

33. Which among the following structures is most stable?

34. Consider the following two carbocations:

Paragraph For Questions 35 & 36

35. Which of the following is more stable ?

36. Which is most stable alkene.

Space for rough work

SECTION – III: (Matching List Type)

(P) (1) Mesomeric effect / resonance

(Q) Ph–CH=CH–CH3 (2) Inductive effect

(R) (3) Polar

(S) (4) Nonpolar

Space for rough work

(S) PH CH2 > Ph CH2 CH2 C CH2 (4)

Space for rough work

PART III: MATHEMATICS

Space for rough work

1  cos x cos2x cos3x

Space for rough work

SECTION – II: Paragraph Type