01.

Introduction

Analytical Chemistry

Fakultas Ilmu dan Teknologi Kebumian

Universitas Halu Oleo
Aturan Perkuliahan
 Tidak boleh memakai sendal
 Pakaian bebas rapi (tidak memakai kaos oblong)
 Persentase kehadiran minimal 80% (syarat mengikuti UTS dan
UAS)
 Hp harus dimatikan atau dalam mode silent selama
perkuliahan
 Toleransi keterlambatan 15 menit.
 Syarat lulus “KIMIA DASAR’’
Penilaian
• Rumus nilai akhir (NA)
NA = [(20% x NT) +(30% x UTS) + (50% x UAS)]/100%.

A : ≥ 81
B : 61 – 80
C : 41 – 60
D : 21 – 40
E : ≤ 20
Course Outline
1. Introduction
 What is Analytical Chemistry?
 The Analytical Perspective
 Common Analytical Problems
2. Basic Tools on Analytical Chemistry
 Numbers in Analytical Chemistry
 Units for Expressing Concentration
 Stoichiometric Calculations
 Basic Equipment and Instrumentation
 Preparing Solutions
3. The Language of Analytical Chemistry
 Analysis, Determination, and Measurement
 Technique, Methods, Procedures, and Protocols
Course Outline (cont.)
 Classifying Analytical Techniques
 Selecting an Analytical Method
 Developing the Procedure
4. Evaluating Analytical Data
 Characterizing Measurements and Results
 Characterizing Experimental Errors
 Propagation of Uncertainty
 The Distribution of Measurements and Results
 Statistical Analysis of Data
 Statistical Methods for Normal Distributions
5. Calibrations, Standarizations, and Blank Corrections
 Calibrating Signals
 Standardizing Methods
Course Outline (cont.)
 Linear Regression and Calibration Curves
 Blank Corrections

Mid Exam (UTS)

6. Equilibrium Chemistry
 Reversible Reactions and Chemical Equilibria
 Thermodynamics and Equilibrium Chemistry
 Manipulating Equilibrium Constants
 Equilibrium Constants for Chemical Reactions
 Le Chatelier’s Principle
 Ladder Diagrams
 Solving Equilibrium Problems
 Buffer Solutions
 Activity Effects
 Two Final Thoughts About Equilibrium Chemistry
Course Outline (cont.)
7. Obtaining and Preparing Samples for Analysis
 The Importance of Sampling
 Designing a Sampling Plan
 Implementing the Sampling Plan
 Separating the Analyte from Interferents
 General Theory of Separation Efficiency
 Classifying Separation Techniques
 Liquid-Liquid Extractions
 Separation versus Preconcentration
8. Gravimetric Methods of Analysis
 Overview of Gravimetry
 Precipitation Gravimetry
 Volatilization Gravimetry
Course Outline (cont.)
 Particulate Gravimetry
9. Titrimetric Methods of Analysis
 Overview of Titrimetry
 Titration Based on Acid-Base Reaction
 Titration Based on Complexation Reactions
 Titrations Based on Redox Reactions
 Precipitation Titrations
10. Spectroscopic Methods of Analysis
 Overview of Spectroscopy
 Basic Components of Spectroscopic Instrumentation
 Spectroscopy Based on Absorption
 Ultraviolet-Visible and Infrared Spectrophotometry
 Atomic Absorption Spectroscopy

Final Exam (UAS)

Referensi
1. Harvey, D., Modern Analytical Chemistry, Mc Graw Hill, 2000.
Whats is Analytical Chemistry?
 Analytical chemistry is often described as the area of
chemistry responsible for caharacterizing the composition of
matter, both qualitatively (what is present) and
quantitatively (how much is present).
Application of Analytical Chemistry
The Analytical Perspective
 Although there are probably as many descriptions of the
analytical approach as there are analytical chemists, it is
convenient for our purposes to treat as a five-step process:
1. Identify and define the problem
2. Design the experimental procedure
3. Conduct an experimental, and gather data
4. Analyze the experimental data
5. Propose a solution to the problem
Common Analytical Problems
 Many problems on which analytical chemist work ultimately
involve either a qualitative or quantitative measurement.
 Other problems may involve characterizing a sample’s
chemical or physical properties.
 Finally, many analytical chemists engage in fundamental
studies of analytical methods.
Common Analytical Problems (cont.)
a. Qualitative analysis :
An analysis in which we determine the identify of the
constituent species in a sample.
b. Quantitative analysis :
An analysis in which we determine how much of a constituent
species is present in a sample.
c. Characterization analysis :
An analysis in which we evaluate a sample’s chemical or
physical properties.
d. Fundamental analysis :
An analysis whose purpose is to improve an analytical
method’s capabilities.
Tugas 1
• Tuliskan masing-masing 2 contoh kasus
pengaplikasian kimia analitik baik analisis
secara kualitatif maupun kuantitatif di
pertambangan/geologi (masing-masing
mahasiswa tdk boleh sama dan ditulis tangan
pada selembar kertas) dikumpul
pertemuan minggu depan.
Thank you for your attention!