Fiitjee Aits 16

1 AITS-CRT-III-PCM (Sol)-JEE(Main)/17
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ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST – III
Integrated School Program & 4423 Students from All Programs have qualified in JEE Advanced, 2016
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. D B A
2. B D C
3. B B A
4. C B A
5. D D A
6. C C D
7. C C D
8. B B C
9. B C C
10. A D C
11. D D A
12. D C A
13. D B B
14. A D C
15. B D C
16. D A D
17. B C C
18. B D D
19. C D A
20. A C B
21. B C A
22. A D B
23. B C C
24. A C A
25. B A C
26. B B C
27. A C A
28. B B C
29. C A B
30. C A B
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AITS-CRT-III-PCM (Sol)-JEE(Main)/17 2
Physics PART – I
SECTION – A
3
1. tan  
4
2a 3
sin  
v0 2a
3 v0 
a
2 4
2. From the frame of cabin a cos 600 u0

 a0 cos600  gcos600
 a0  10 m / s2
0
30
0
30
0
60
a0
gcos 600
g
3. When ‘v’ is maximum
gsin   kxgcos 
tan  3
x 
k 2
vdv
Also,  gsin   kxgcos   
dx
v2 kx 2
  gx sin   gcos  ........... i
2 2
3
putting x  , we get v max  3m / s
2
3
putting v  in equation  i
2
we get x1 & x 2  x 2  x1 
3 3
 m
2
2
4. i rms  R T  H
5. when sleeping starts for the first time

1 2 sin mgcos 
cos  
2
 mg sin 

4  mg
Just before sliding, f = mgsin
mg
Just after sliding, f = sin2
2
V
6. % error =  100  6.25%
V
7. ndt  m  v ' v 0 
Ncos   N'  dt  mv v'
B
N'  Nsin 
2 N'
N'Rdt  mR2  v0
5
N A
5v 0
for   370 , we get v 
7

4
putting v  R, we get tan   N'
7 N
4
 for   tan1   , friction will be static
7
& pure rolling will occur.
8. if K  0 , workdone by external force = U

 G G
9. Fnet  m R
R
G
R
G
R
G
R
P
10. 
v2
2
  1
F
P  2
  2 . 1  
v  f
putting these value we get
  1.3 mg / cm3
dv v v0
11.    1 at v  v 0 , T  T0 ............. i 
dT T    1  dv 
T0  
 dT 
R
and Cv 
 1
3R R
 ......  ii 
2  1
putting the value of   1
dv 3v 0
we get 
dT 2T0
12. IC  100  0.04 mA  4 mA

VC  20  12  8V
8
 RC   2000
4  10 3
13. Heat ui  uf +5Q -Q +5Q +5Q +5Q

2 +Q
1 Q
 0
2  0 A 
 d 
 
1
14. W mv 2
2
1 4 
  r 3   v 2
2 3 
V terminal  r2 
 W  r7
1
15. mv 20  h  2f0   hf0
2
1
mv 2  h  4f0   hf0
2
16. Let v x  v y  v z  v 0
V  2v 
 V0   P  nm  
3  3
V 2 KAd
17. 
R 
a
18.   tan1  
g 
KA  4  0  3KA  0   2  
19. 
Lx x
3L
x
5
h 1
20. e  ,E e  me v e2
me v e 2
h2
 Ee 
2 2eme
 100nv e 
h
hc hc 2 
 Ep    
 p n e n e
Ee 1
 
Ep 100
21.  i  stress A   stress B

TA TB
  & TA x1  TB    x1 
a A aB
2
 x1 
3
 ii  strain A   strain B
YA YB
  & TA x 2  TB    x 2 
 TA   TB 
   
 a A   aB 
6
 x2 
7
Hence x1 : x 2  7 : 9
 a  Area of cross  sec tion 
 
 T  Tension in the wire 
 Y  Youngs Modulus 
 
R
qin
22. 10q   4 r 2 dr0 r  E.ds  
0 0
10q 1
 0   E r   0 r 2
R 4 4 0
For ' 2q'
10q r12 1  2q  4q
 2q  ..........  i 
R 4 4 0 4 0  r1  r2 2
For ' 4q'
10q r22 1  2q 4q 
4  4q  ..........  i 
R 4 0 4 0  r1  r2 2
from  i  &  ii
R
r2  1
 5 2 1  2
 A  Dm 
sin  
23.   2 , D  A
m
A
sin  
2
A 1
 cos 
2 2
 A  900
24. For material with negative refractive index, ray bends or refracts differently as compared to
materials with positive refractive index.
25. Use lens formula
26. i2rdt  nCp dT

nCp dT
i2  T  T0  t  t 2  t 3
r dt
2 7R dT
i
r 2

  2t  3 t 2  dt
   2 t  3t 2
7R
i 3
r
27. A  N0 e t

A0  A
%decrease   100
A0
1
  20 days


28.  R
6 A
T 1 2 O
t  
6 6  2
R
 3

3t
Bs
29. P
x
e
30.    E black body for a particular wavelength.
 a body
Chemistry PART – II
SECTION – A
1. because they must have same constitution and configuration at all other carbon atoms from C – 3
to C – 6 but different constitution at C – 1 & C – 2.
2. CH3 H Br
H2 H3C
Br
H3C CCH 3 C C H3C C C CH3
Lindlars catalyst H
H Br H
racemic
3. At cathode  S2   2e   S
At anode  Sn2   Sn4   2e
Total S lost from solution is 2  0.119 g of Sn2 
At cathode = so mass of reaming SnCl2  18.621 g
MSnCl2
& mass of SnCl4   mSn  0.26 g
MSn
m  SnCl2  18.621
now   71.62
m  SnCl4  0.260
–
4. I & -M effect increases the nucleophilic reactivity
5. Buta  1,3  diene  styrene  Buna  s
6. It is curve of 2s so  n     2  0  2
n
 1 20
7. N  N0   & no. of t 1  2
2
  2 10
N 1
So, 
N0 4
1 3
Now, no. of decayed moles = 1  
4 4
3 9
Total amt. of He = 3   mole
4 4
9
Vol. at STP = 22.4   50.4 lit
4
8. K sp  AgCl   1.6  10 10   Ag  Cl  ....... i 
K sp  CuCl  1 106  1s '  1s ' 
1
10 6   S2 S12  104
100
S '  10 2  Cl 
 1 102
 103
now put S ' in eq i 

1.6  10 10   Ag  103   1.6  10 7
so x  7 so 10  x  7
9. Cubic, orthorhombic, Rhombohedral, Tetrahedral, hexagonal.
th
 1
10. Octalhedral void present at the centre of cube and tetrahedral void is present at   of the
4
distance along each body diagonal.
11. KI  AgNO3  KNO3  AgI 

Total moles of solute ions after reaction,
 0.1  0.2   I  0.6 moles
0.6
solute 
4
0.6
Tf  K f   0.279 K
4
12. E5  E1  96
1 1
E1  Z2  2  2   96
 n2 n1 
so E1  100J
13. O O O
NaOI SOCl2 Ph - NH2
(B) X C CH3 X C OH X C Cl
O O
(HNO3H + H2SO4)
X C NH Ph X C NH NO2
14. D
15. H
- +
O3 O Conc NaOH COO Na
Zn + H2O O CH2 OH
H
16. In basic solution Cr (III) converted Cr (VI) & it poses yellow chromate ion
17. Microcosmic salt is a white crystalline salt Na(NH4)HPO4 obtained by mixing solution of sodium
phosphate & ammonium phosphate.
18. All rxns are involved in solvey process
19.
H+
H  9  P

OH
OH H+
&   10  Q

so P  Q  19
20. 

for equilibrium  2NO2 
 N2 O4
P 'N2 O4
6.8  k P   6.8 P 'N2 O 4  1.7 atm
P 'NO2 
for IInd equilibriua


NO  NO 2 
 N2 O3
at t  0P 2P 0
at eq. P  x 2P  x  3.4 x
since NO & NO2 is in 1: 2 ratio
at eq. P  x  0.5 x
P 'NO is same for both equilibria
now total P  P  x  0.5  x  1.7  5.05
x  1.80 atm
P 'NO  1.05 atm
21. due to max. force of attraction
22. Av.Cv1m  2R
For adiabatic process dv = dw
dr R  dv 
  
r Cv 'm  v 
1Cvm1 dT  2Cvm2 dT
dv
   1RT  2RT 
v
T2 1 v 
n   n  2 
T1 2  v1 
1
 1 2
T2  320   
4
 160k
 
U  1Cv1m1  2 Cv2m2 T  960 R
23. Fe has one unpaired e-

.
24. CH3
C
Br
25. A (Fact based)
26. 2Cu2S  3O2  2Cu2O  2SO 2  does not occur in Bessemer’s converter
27. X can’t be Zn
28. Slowest step is R.d.s step
29. A is Na2CrO4 & B is H2SO4
30. Because Cr2O3 can’t be reduced by C due to requirement of high energy.
Mathematics PART – III
SECTION – A
1. A
The number of gaps when 10 persons seat is 11.
Let x1, x2, x3, …., x11 be the number of vacants in the gaps
x1  x 2  ....  x11  30
x1 & x11  0 other xi  2 i  2, 11
22
Number of integral solution is C10
2. C
2
Let the GP be a, ar, ar , …
S 2n 

a 1  r 2n ; S 

a 1  rn ; S 

a 1  r 3n 
n 3n
1 r 1 r 1 r
Clearly, Sn , S2n  Sn , S3n  S2n in GP
Let Sn  A, S2n  Sn  AR, S3n  S2n  AR2
Then, AR + A, 2AR, AR2 + AR in HP as
1 1 1 2
  
A  R  1 AR  R  1 AR 2AR
3. A
 2  3  4 22  3  2
We have  K
2 1
Clearly,  2  3  4  2K  0 has roots  & - 2
 2    4  2K 
   2  K
2   1
 
2K 2
4. A
 qr n! 
  1 sin2q .cos2r   , n  p  q  r, x,p,q,r  N is the expansion of
 p!q!r! 
n
1  sin 2
  cos 2   0
Hence no solution.
5. A
Contrapositive of p   q  q   p
Inverse of p   q  q   p
Now, inverse of p   q   p  q
Contrapositive of  p  q   q  p
6. D
1
0 x
 1 and 0  ln x  1
2 1
 2x  1  1  0  x  e
 x 1
 x  1,e 
7. D

 x 2  2x  2  0 x  
2
mx  3x  4
 5
x 2  2x  2
  m  5  x 2  7x  6  0 x  R
71
m5  0 & D  0  m 
24
8. C
n n
 1  2n n     2ln2 
 ln2
  n!  ln2     n!   n!
n 1 
  n1 n 1
 eln 2  1  e2ln 2  1  4
9. C
Point of concurrency (a + m, - 2)
2  m  a  m   m2  am  2  0
a2  8  a  2 2
10. C
4 4
1 1
I dx  I  
0
1  nf  x  0
1  nf  4  x
4
 1 1 
II     dx
01  nf  x  1  nf  4  x  
4 2  n  f  x   f  4  x 
 2
dx
0 1 n f  x  f  4  x   n  f  x   f  4  x 
4
  dx  4
0
I  2
11. A
Let A be (, ) & B(, –)
P(h, k) be midpoint
2h =  + , 2k =  – 
 = h + k;  = (h – k)
    2      2  d2
 4k 2  4h2  d2
Which is a circle
12. A
an
Given an 1  1 
n
 1  1   1 
 lim 1   1   ...  1  
n  a1  a2   an 
a  1  an 
 lim n1  lim  
n  n  1 ! n  n! 
1 1 a 
 lim    n 1 
n  n!  n  1 !  n  1 ! 
 
as a1  1
1 1 1
Unit value = lim   ...   e
n n!  n  1 ! n
13. B
 1  sin x t  1
f  x   lim  
t   1  sin x t  1
   
1, 2n  x  2n  1

 1, 2n  1  x  2n  2
0, x  0,1,2,...............

14. C
px3  qx2  r  0 , , 
      0
         
             C1  C1  C2  C3   0
         
15. C
0 1 2
A 0 0 3
0 3 1
2 3
Find A , A to verify
16. D
  
a  b  kc ... I
  
b  c  a .... II
I  II
   
a  c  kc  a
 
 1    a  1  k  c  0
   k  1
  
i.e a  b  c  0
17. C
The points A, B and C are (3p, 0, 0); (0, 3q, 0) and (0, 0, 3r) respectively.
18. D
Agreement happens when both speak either the truth or both tell a lie
E1 = A and B both speak truth
E2 = A and B both tell a lie
E = A and B agree in a certain statement
E  xy
P 1  
 E  1  x  y  2xy
19. A
1
P  X  x   K  x  1 ,K is proportionality cons tan t
5x
16
k
25
Only (B) is true
20. B
15
1
dx  
 1 x2  x  dx
 15
1 x2
1 x 1 x  x
2 2
15
1
15 
 1 x  x  c
2
21. A
1
dx
I 
0
1 x 2
In (0, 1)
1
dx
I  I  ln2
0
1 x
1
1 
And I   1  x2 dx  I  4
0
22. B
1  x , x  1
f  x  
 0, x 1
f  x  is even function
g  x   f  x  1  f  x  1
g   x   f   x  1  f   x  1
 f  x  1  f  x  1
 g(x) is also even only.
23. C
 x2 
y    2  ; y  x  1 or x  0
 64 
x
y  sin1   = 0 for |x| < 4
4
B
C y=2
y=x-1
A
x=0
1 9
 area  33 
2 2
9 1
Area above x-axis =   1 1
2 2
=4
24. A
dy
2y sin x  y 2 cos x  sin 2 x
dx


d y 2 sin x   sin2x
dx
cos 2 x
 y 2 sin x   c
2

At x 
2
1 1
1 c  c 
2 2
1  cos 2x
y 2 sin x 
x
 y 2  sin x
25. C
df  tan x  f   tan x  sec 2 x

dg  sec x  g  sec x  sec x.tan x
At tan x  1 & secx  2

x  2n  , nN
4
df  tan x  2 2 1
  
dg  tan x  4  2 2
26. C
z 1 ei
Let   
ei z 1
If z = x + iy

 x  1  iy  cos   isin 
cos   isin   x  1  iy
Im() = 0
sin   x  1  y cos 
  sin   x  1  y cos   0
 x  12  y 2
 x 1   y 
 sin   x  1  2
  cos   y 
2
0
 2  2
  x  1   y    x  1  y 
2 2
  x  1  x  1  y  1  0 and y  x  1  y  1  0
2 2
   
 locus is circle with unity radius
27. A
tan .tan 2  tan2.tan 4  tan 4.tan 
sin .sin2 cos 4  sin 2.sin 4.cos   sin 4.sin .cos 2

cos .cos 2.cos 4
cos .cos 2.cos 4  cos    2  4  8 sin 
  1  7
cos .cos 2.cos 4 sin8
28. C
2
1 2 a  x  6 a
3
 
x  12x  39  sin   
x 3
 1  sin  
x
a  x6
  2n  & 0 x6
x 2 3
 a  3  1  4n  , n  z
29. B
2
Let the parabola be y = Ax + Bx + C
(1, 1) satisfies  A + B + C = 1 …. (1)
dy
 1  2A  B  1 ....(2)
dx x 1
f 0   C & f 0   B
 2f  0   f   0   1
30. B
10 10
  xi  4   10    xi  5   0
i1 i1
10 10
2 2
  xi  4   100    xi  5   90
i1 i 1
Also,
1
  90  3
10
 right triangle but scalene.

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1 AITS-CRT-III-PCM (Sol)-JEE(Main)/17

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

2. From the frame of cabin a cos 600 u0

5. when sleeping starts for the first time

8. if K  0 , workdone by external force = U

12. IC  100  0.04 mA  4 mA

13. Heat ui  uf +5Q -Q +5Q +5Q +5Q

21.  i  stress A   stress B

25. Use lens formula

26. i2rdt  nCp dT

27. A  N0 e t

now put S ' in eq i 

9. Cubic, orthorhombic, Rhombohedral, Tetrahedral, hexagonal.

11. KI  AgNO3  KNO3  AgI 

18. All rxns are involved in solvey process

21. due to max. force of attraction

23. Fe has one unpaired e-

25. A (Fact based)

28. Slowest step is R.d.s step

29. A is Na2CrO4 & B is H2SO4

30. Because Cr2O3 can’t be reduced by C due to requirement of high energy.

Mathematics PART – III

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