2007 CH: Chemical Engineering Duration : Three Hours Maximum Marks :150 10. Read the following instructions carefully. This question paper contains 85 objective type questions. Q.1 to Q.20 carry one mark each and Q.21 to Q.85 carry two marks each. Attempt all the questions. Questions must be answered on Objective Response Sheet (ORS) by darkening the appropriate bubble (marked A, B, C, D) using HB peneil against the question number on the left hand side of the ORS. Each question has only one correct answer. In case you wish to change an answer, erase the old answer completely. Wrong answers will carry NEGATIVE marks. In Q.1 to Q.20, 0.25 mark will be deducted for each wrong answer, In Q.21 to Q.76, Q.78, Q.80, Q.82 and in Q.84, 0.5 mark will be deducted for each wrong answer. However, there is no negative marking in Q77, Q79, Q.81, Q.83 and in Q.85. More than one answer bubbled against a question will be taken as an incorrect response. Unattempted questions will not carry any marks. Write your registration number, your name and name of the examination centre at the specified locations on the right half of the ORS. Using HB pencil, darken the appropriate bubble under each digit of your registration number and the letters corresponding to your paper code. Calculator is allowed in the examination hall, Charts, graph sheets or tables are NOT allowed in the examination hall. Rough work can be done on the question paper itself. Additionally blank pages are given at the end of the question paper for rough work. This question paper contai 36 printed pages including pages for rough work. Please check all pages and report, if there is any discrepancy. 8/121 Food/0s-CH-1A CH- 1/36Q2 Q. 1-Q. 20 carry one mark each. (i +3) (+1) (A)i (B) -2 (C) -i+2 (D) i+1 Given i= 1, the ratio is given by The value of “a” for which the following set of equations y+2z=0 Qr+ytz =0 a@+2y =0 have non-trivial solution, is (ayo (B)8 (©)-2 (D3 The initial condition for which the following equation + 2) x+y; yb%)=y» has infinitely many solutions, is (A) x=0)=5 — (B) y(x=0)=1 (©) Ax=2)=1 — @) »(x=-2)=0 Given that the Laplace transform ofthe function below over a single period 0 <1 <2 is +t ~e*), the Laplace transform of the periodic function over 0<1 Ta and Ta (©) Tr> Tas > Ts (©) Ts > Taa>Ta The state of an ideal gas is changed from (T;, P1) to (Ts, P2) in a constant volume process. To calculate the change in enthalpy, Ah, ALL of the following properties/variables are required, (A) Cy, Pi, Po (B)C,, 71, T2 (Cp, Ti, T2, Pi, P2 (D)Cy, Pi, P2,T1,T2 The change in entropy of the system, AS,, undergoing a cyclic irreversible process is (A) greater than 0 (B) equal to zero (C) less than zero (D) equal to the ASyuroundings Parameters ‘a’ and ‘b’ in the van der Waals and other cubic equations of state represent (A) a — molecular weight b-- molecular polarity (B) a ~ molecular size b— molecular attraction (©) a ~ molecular size b-- molecular speed © molecular attraction - molecular size If m, m,, mi, mf are molar, partial molar, residual and excess properties respectively for a pure species "i", the mixture property M of a binary non-ideal mixture of components 1 and 2, is given by (A) xm +x,m, (B) xm" + x, (©) xm + xm, (D) xym? + xmy CH- 3/36