NAMA: Muhammad Ade Rakha

NIM: 1811013044
KELAS A
Tata nama Alcohols and Ethers
Why do the compounds hexane, hexanol, and hexene have such similar names?
 Heksana, heksanol, dan heksena memiliki jumlah atom C yang sama yaitu 6 gugus
atom C walaupun memiliki ikatan dan gugus lain yang berbeda beda

1. Write condensed formulas and provide IUPAC names for the following compounds:
(a) ethyl alcohol (in beverages)
 CH3-CH2-OH (1-etanol)
(b) methyl alcohol (used as a solvent, for example, in shellac)
 CH3-OH (1-metanol)
(c) ethylene glycol (antifreeze)
 CH2-OH (1,2-etanadiol)
|
CH2-OH
(d) isopropyl alcohol (used in rubbing alcohol)
 CH3-CH-CH3 (2-propanol)
|
OH
(e) glycerine
 CH2-OH (1,2,3-propanatriol)
|
CH-OH
|
CH2-OH
2. Give the complete IUPAC name for each of the following compounds:

(a) 2-butanol

(b) 3,3-dimetil-2-iodo-2-pentanol

(c) 3-chloro-3-etil-2-heksanol

(d) 4-metoksi-1-butanol
(e) 2-propanol / isopropanol

(f) 2-bromo-4-kloro-3-pentanol

(g) 4-bromo-1-pentanol

(h) 3,4-heksanadiol

(i) 1-siklopentanol

(j) 2-etil-1-sikloheksanol

(k) 2-etil-5-metil-1-sikloheksanol

3. Give the complete IUPAC name and the common name for each of the following
compounds:

(a) 1-etoksi butana / trivial: etil-butil-eter

(b) 1-etoksi propana / trivial: etil-propil-eter

(c) metoksi propana / trivial: metil-propil-eter

4. Draw the condensed formulas for each of the following compounds:

(a) dipropyl ether
 CH3-CH2-CH2-O-CH2-CH2-CH3
(b) 2,2-dimethyl-3-hexanol
CH3
|
 CH3 – C – CH – CH2 – CH2 - CH3
| |
CH3 OH
(c) 2-ethoxybutane
 CH3-CH2-O-CH-CH2-CH3
|
CH3

5. MTBE, Methyl tert-butyl ether, CH3OC(CH3)3, is used as an oxygen source in oxygenated

gasolines. MTBE is manufactured by reacting 2-methylpropene with methanol.
(a) Using Lewis structures, write the chemical equation representing the reaction.
CH3
.. |
CH3-C=CH2 + CH3-OH  CH3-O-C-CH3
| .. |
CH3 CH3
(b) What volume of methanol, density 0.7915 g/mL, is required to produce exactly 1000 kg of
MTBE, assuming a 100% yield?
4,593 × 102 L

6. Write two complete balanced equations for each of the following reactions, one using
condensed formulas and one using Lewis structures.
(a) propanol is converted to dipropyl ether
 CH3-CH2-CH2-OH + CH2=CH-CH3  CH3-CH2-CH2-O-CH2-CH2-CH3
.. ..
 CH3-CH2-CH2-OH + CH2=CH-CH3  CH3-CH2-CH2-O-CH2-CH2-CH3
.. ..
(b) propene is treated with water in dilute acid.
 CH2=CH-CH3 + H2O  CH3-CH-CH3
|
OH
..
 CH2=CH-CH3 + H-O-H  CH3-CH-CH3
.. |
OH

7. Write two complete balanced equations for each of the following reactions, one using
condensed formulas and one using Lewis structures.
(a) 2-butene is treated with water in dilute acid
CH3-CH=CH-CH3 + H2O  CH3-CH2-CH-CH3
|
OH

(b) ethanol is dehydrated to yield ethane

CH3-CH2-OH  CH2=CH2 + H2O