Isoterma

Adsorção Dessorção
Pressão relativa (P/P0) Volume adsorvido (cm .g )
3 -1 Pressão relativa (P/P0)
6.92E-02 63.3586 9.87E-01
9.57E-02 67.5079 9.21E-01
1.98E-01 80.0587 8.29E-01
2.99E-01 91.6749 7.34E-01
3.46E-01 97.3702 5.87E-01
5.11E-01 122.9142 4.93E-01
6.69E-01 167.0583 4.43E-01
7.46E-01 204.9871 2.90E-01
8.31E-01 257.5213 1.85E-01
9.11E-01 279.2374 1.51E-01
9.87E-01 291.1107 9.54E-02

300
Adsorção
Dessorção
250
Volume adsorvido (cm.g )
-1
3

200

150

100
2 -1
Área superficial específica = 282 m .g
50
0.0 0.2 0.4 0.6 0.8 1.0
Pressão relativa (P/P0)
 Dessorção Modelo BJH
Volume adsorvido (cm3.g-1) Raio do poro (Å) Volume acumulado (cm3.g-1)
291.1107 18.8 0.02
280.7077 22.5 0.09
275.5775 32.5 0.33
249.5022 50.9 0.39
155.7721 96.3 0.40
124.9395 436.0 0.41
112.959
90.4085
78.2373
74.1077
66.7145 0.016
0.4

-1
Volume acumulado (cm.g )
-1

-1
0.012
3

0.3

3
Modelo BJH

0.008
0.2

0.004
0.1

0.000
0.0
0 100 200 300 400
Raio do poro (Å)
2 -1
282 m .g

1.0
 Distribuição de tamanho de poros
BJH Modelo NLDFT
Volume diferencial (cm .Å .g ) 3 -1 -1
Raio do poro (Å) Volume acumulado (cm3.g-1)
0.011 11.3 0.00E+00
0.013 11.7 0.00E+00
0.016 12.1 0.00E+00
0.003 12.5 0.00E+00
0.000 12.9 0.00E+00
0.000 13.5 0.00E+00
14.1 0.00E+00
14.7 0.00E+00
15.3 4.18E-05
15.9 1.51E-03
0.016 16.5 2.71E-03
17.1 4.00E-03
Volume diferencial (cm.Å .g )
-1

17.7 5.54E-03
-1

0.012 18.3 9.02E-03

18.9 1.40E-02
3

H
19.7 1.97E-02
20.5 2.56E-02
0.008
21.3 3.02E-02
22.1 3.36E-02
22.9 3.63E-02
0.004
23.6 3.89E-02
24.4 4.38E-02
25.4 5.46E-02
0.000 26.4 6.51E-02
300 400 27.4 7.84E-02
28.4 9.40E-02
Å)
29.4 1.07E-01
30.4 1.19E-01
31.6 1.32E-01
32.8 1.52E-01
34.0 1.77E-01
35.2 2.05E-01
36.6 2.30E-01
37.9 2.49E-01
39.3 2.66E-01
40.7 2.87E-01
42.3 3.06E-01
43.9 3.23E-01
45.5 3.39E-01
47.1 3.53E-01
48.9 3.66E-01
50.7 3.72E-01
 52.4 3.77E-01
54.4 3.83E-01
56.4 3.88E-01
58.4 3.93E-01
60.6 3.98E-01
62.8 4.02E-01
65.0 4.07E-01
67.3 4.10E-01
69.7 4.14E-01
72.3 4.17E-01
74.9 4.18E-01
77.7 4.18E-01
80.4 4.19E-01
83.4 4.19E-01
86.4 4.20E-01
89.6 4.20E-01
92.8 4.20E-01
96.1 4.21E-01
99.5 4.21E-01
103.1 4.21E-01
106.9 4.21E-01
110.6 4.22E-01
114.6 4.22E-01
118.8 4.22E-01
123.1 4.23E-01
127.5 4.23E-01
132.1 4.23E-01

0.4
Volume acumulado (cm .g )
-1
3

0.3
Modelo NLDFT

0.2

0.1

0.0
0 100
Raio do poro (Å)
 0.1

Volu
0.0
0 100
Raio do poro (Å)
NLDFT
Volume diferencial (cm3.Å-1.g-1)
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
7.02E-05
2.46E-03
2.03E-03
2.14E-03
2.58E-03
5.86E-03
8.37E-03
7.21E-03
7.36E-03
5.77E-03
4.25E-03
3.51E-03
3.25E-03
6.18E-03
1.08E-02
1.06E-02
1.34E-02
1.57E-02
1.30E-02
1.21E-02
1.13E-02
1.65E-02
2.12E-02
2.33E-02
1.80E-02
1.36E-02
1.24E-02
1.51E-02
1.19E-02
1.06E-02
9.79E-03
9.20E-03
6.97E-03
3.38E-03
 3.17E-03
2.80E-03
2.71E-03
2.53E-03
2.27E-03
1.85E-03
1.95E-03
1.52E-03
1.64E-03
1.17E-03
2.87E-04
1.56E-04
1.57E-04
1.56E-04
1.39E-04
1.18E-04
7.68E-05
7.94E-05
1.17E-04
8.43E-05
6.75E-05
7.59E-05
6.70E-05
6.84E-05
6.01E-05
4.28E-05
5.92E-05

0.024
Volume diferencial (cm .Å .g )
-1
-1

0.016
3

Modelo NLDFT

0.008

0.000
100
o poro (Å)
 Volum
0.000
100
o poro (Å)
 Isoterma
Adsorção Dessorção
Pressão relativa (P/P0) Volume adsorvido (cm .g )
3 -1 Pressão relativa (P/P0)
4.55E-02 0.0735 9.88E-01
7.61E-02 0.0742 9.35E-01
1.03E-01 0.0733 8.27E-01
1.54E-01 0.0691 7.26E-01
2.05E-01 0.0655 5.80E-01
2.57E-01 0.0617 4.80E-01
3.07E-01 0.0596 4.40E-01
3.59E-01 0.0564 2.90E-01
5.21E-01 0.0441 1.83E-01
6.81E-01 0.0428 8.64E-02
8.33E-01 0.0682
9.09E-01 0.117
9.88E-01 0.504

0.6
Adsorção
Dessorção
Volume adsorvido (cm.g )
-1
3

0.4
2 -1
Área superficial específica = 0,6 m .g

0.2

0.0
0.0 0.2 0.4 0.6 0.8 1.0
Pressão relativa (P/P0)
Dessorção Modelo BJH
Volume adsorvido (cm3.g-1) Raio do poro (Å) Volume acumulado (cm3.g-1)
0.504 18.44 0.00E+00
0.1713 21.98 0.00E+00
0.091 31.74 0.00E+00
0.0726 50.04 2.86E-05
0.0665 109.29 1.71E-04
0.0641 471.24 7.20E-04
0.0651
0.0743
0.0784
0.0773 0.0008
Modelo BJH 1.5
Volume acumulado (cm.g )
-1

0.0006
3

1.0
0.0004

5.0
0.0002

0.0000 0.0
0 100 200 300 400 500
Raio do poro (Å)
 Distribuição de tamanho de poros
H Modelo NLDFT
Volume diferencial (cm .Å .g ) 3 -1 -1
Raio do poro (Å) Volume acumulado (cm3.g-1)
0.00E+00 10.14 9.70E-05
0.00E+00 10.54 1.01E-04
0.00E+00 10.93 1.02E-04
1.27E-06 11.33 1.05E-04
1.49E-06 11.73 1.08E-04
8.74E-07 12.13 1.08E-04
12.52 1.08E-04
12.92 1.08E-04
13.52 1.08E-04
14.11 1.08E-04
14.71 1.08E-04
H 1.5x10
-6
Volume diferencial (cm.Å .g )

15.30 1.08E-04
-1

15.90 1.08E-04
-1

16.49 1.08E-04
3

-6
17.09 1.08E-04
1.0x10 17.69 1.09E-04
18.28 1.10E-04
18.88 1.11E-04
-7
19.67 1.11E-04
5.0x10 20.47 1.12E-04
21.26 1.12E-04
22.06 1.12E-04
22.85 1.12E-04
0.0 23.64 1.12E-04
0 400 500 24.44 1.12E-04
Å) 25.43 1.12E-04
26.43 1.12E-04
27.42 1.12E-04
28.41 1.12E-04
29.40 1.12E-04
30.40 1.12E-04
31.59 1.12E-04
32.78 1.12E-04
33.97 1.12E-04
35.16 1.12E-04
36.55 1.12E-04
37.94 1.12E-04
39.34 1.12E-04
40.73 1.12E-04
42.31 1.12E-04
43.90 1.12E-04
45.49 1.12E-04
 47.08 1.12E-04
48.87 1.12E-04
50.66 1.12E-04
52.44 1.12E-04
54.43 1.12E-04
56.42 1.12E-04
58.40 1.12E-04
60.59 1.12E-04
62.77 1.12E-04
64.96 1.12E-04
67.34 1.12E-04
69.72 1.12E-04
72.30 1.12E-04
74.89 1.20E-04
77.67 1.30E-04
80.45 1.39E-04
83.43 1.49E-04
86.41 1.58E-04
89.58 1.65E-04
92.76 1.70E-04
96.14 1.76E-04
99.51 1.85E-04
103.09 1.91E-04
106.86 1.96E-04
110.64 2.02E-04
114.61 2.08E-04
118.78 2.14E-04
123.15 2.19E-04
127.52 2.23E-04
132.09 2.28E-04
136.85 2.32E-04
141.82 2.37E-04
146.98 2.41E-04
152.34 2.44E-04
157.71 2.46E-04

-4
2.5x10
1.6x1
e acumulado (cm .g )
-1

Modelo NLDFT
3

-4 1.2x1
2.0x10

8.0x1
-4
1.5x10
Volume acumulado (cm .g
Modelo NLDFT

3
-4 1.2x1
2.0x10

8.0x1
-4
1.5x10
4.0x1

-4
1.0x10 0.0
0 100 200
Raio do poro (Å)
o NLDFT
Volume diferencial (cm3.Å-1.g-1)
1.62E-05
8.97E-06
4.75E-06
5.49E-06
7.24E-06
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
9.95E-07
1.60E-06
1.80E-06
1.42E-06
6.40E-07
3.18E-07
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
 0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
3.32E-06
3.31E-06
3.33E-06
3.29E-06
2.99E-06
2.45E-06
1.62E-06
1.70E-06
2.47E-06
1.75E-06
1.42E-06
1.66E-06
1.32E-06
1.47E-06
1.20E-06
9.19E-07
1.01E-06
9.28E-07
9.72E-07
7.70E-07
5.89E-07
4.15E-07

-5
1.6x10
diferencial (cm .Å .g )
-1
-1

T 1.2x10
-5
3

-6
8.0x10

-6
 -1
T

Volume diferencial (cm .Å

-5
1.2x10

3
-6
8.0x10

-6
4.0x10

0.0
00 200
poro (Å)