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Chemistry (RBK-: Trsra
Chemistry (RBK-: Trsra
Time :3 Hours
€Trsra Rarq (rbk- a4) M.M.: 150
?IJRI ' S rit sfrr.F-d-fr 3i-dt, t50
Note: (i) Attcmpt five questions. A1l qucstions carry equal marks. Question number I is compulsory. Ansrver
any two questions frorn part I and tr,vo queslions from part II. l'he parts of the same questions must be answered
logelher and nust not be interposed bellvcen answers 1o olhcr queslions.
(ii) In case of any discrepancy in the English and Hindiversions, English version willbe taken as final.
*e' (i)ufu qea 6eT of z+aft t 3i6 sma Bt sed ?iwr r s{GrorS tl anor r * d se+ a?Tr anor z *
d se* 6r sr{ tr uo qeq d q:.aft eiefr 6T Jcrrs tr6 *|q *r uo qea * eie} 6-r =-a-r qst qea d siei
l_
cp ___ _ _:_ _______\
dlr.q ol c'l rtl<l I
tii) sfr 3iffi Ed frd Ffi+r fr ot-€ ffi a, fr siffi ftarlq sift-n aral qrrrrlr I
b) *dr{{ s{rfl{nqq
c)'ttNlytR Sqi
d) sss
e) da be seTrE
g sre#a ziqd-d
g; ordFro Egd-6
h) *iw doqur
Part -I (aror-t )
Q2 a) The potential energy of electron in H atom is -1.70 ev. Find the excited state of the electron'l (t)
6T*+d-d qrdTIE A gffid 6t ft€rfuq s-of trr qra-1.70ev t: Fdd d sekd 3{a-+eil s6 otH,
(b) Oxygen molecule is paramagnetic. Explain on the basis of Molecular Orbital Theory (MOT) (5)
3fffi6-d srg 3rggrq-+tq | 3irFr6 ereffi k€ia (MOT) snrrru q{ ?ffiSrg} |
t d
c) Which compounds among the following will give green colour in its flame test (5)
i) MgCl, ii) BaCl, iii) NaCl iv) CaCl,
Frqfrfua dffi e A 6)'4 trr dlFro wrar qSa"r d a* t-rr *rn,
i) MgCl, ii) BaCl, iii) NaCl iv) CaCl,
04/csfl4 l. Cont.
I
(s)
(e) Explain in brief Bragg's I.aw'
idt + h{n Ei dfhq fr sr€g} |
(s)
(f) Explaintransition contraction'
d6E"T ti€Ea $trgrs* |
i) Fe+ Atra
ii) Ca slt{et 6r I.P' (en+a-a ftro)
reacttons (2x5=10)
(b) Explain the increase / decrease in entropy in the following
ii)tr6Mq*sordrq0.K*tts.Katb'{d..nqrm.}r
(10)
theory'
c) Explain collision theory and transition state
daq- frr€id ' ?i@-dur ffi Rr<id o1 wrgrg* r
(2x5=10)
Q 4. Writc short notes on
i) Chemical potential and Gibb's-Duham cquation'
ir) d-Orbital spiiaing and geometry of co-ordinate complexes'
(2x5=10)
(b) ExPlain the following
Cont.
2.
04lcslt4
Part - II(rrur-z)
i; MlM $fs{B-qr
ii) Rffi-fuq-d 3r|arbqr
ch3
(5x3:15)
i)
-/ /\i I cooNa + NaoH [cao] , ?
\v2 I
Sunlight
ii) .^..'
!,1
+ 3ct, -{-
O
(
Br
g4tcsn4 3. Cont,
ffifu-o srlarfu-qrs* 6] Wf sffffir
ch3
i) iil cooxa r-NaoH tc9l > 'l
v
/t-\ qdrotet - a
ii) {l + 3c1, [-
!
Br
-)',
iii) --_.- 11--Y' ?. + KBr
OCh,
KNH, '
iv) (A) zn , 1B) -g#- cH,cno
-
fa) (B)
v) cH,cooo,
-t#-- #
Q 7. Draw the chemical structures of the fbllowings
a) Polystyrene and lerylene (3x5=15)
b) Teflon and Rayon
a4tcsn4 4.