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Capstone Design Project For Plant Design Steam Methane Reforming Plant
Capstone Design Project For Plant Design Steam Methane Reforming Plant
Capstone Design Project For Plant Design Steam Methane Reforming Plant
A Project Proposal
Presented to the Faculty of
College of Engineering, Architecture and Fine Arts
Batangas State University
Main Campus II
Alangilan, Batangas City
In Partial Fulfillment
By:
Cuadrasal, Aniemhar D.
PetE-5201
April 2019
CHAPTER I
DESIGN BACKGROUND
the periodic table. Its monatomic form (H) is the most abundant chemical
molecular formula H2. Since hydrogen readily forms covalent compounds with
which reacts steam at high temperature and pressure with methane in the
Small-scale steam reforming units to supply fuel cells are currently the subject
HYDROGEN MARKET
DEMAND
fuelling stations in the region. These aspects are pushing the growth of
the hydrogen market in Asia Pacific. According to the analysis from the
the total market share in the coming years. In 2017, the hydrogen
SUPPLY
with major vendors such as Air Liquide, Air Products and Chemicals,
Air Liquide
merchant and offers its services in welding, diving, and in the global
Hydrogenics
Messer Group
Messer Group offers industrial, medical, and specialty gases to
CH4 0.8532
CO2 0.0221
C2H6 0.0705
C3H8 0.0273
i-Butane 0.0055
n-Butane 0.0094
i-Pentan 0.0027
n-Pentan 0.0027
n-Hexane 0.0018
n-Heptane 0.0013
n-Octane 0.0004
N2 0.0004
some of the biggest industries in the Philippines like Pilipinas Shell Petroleum
Raw materials such as steam and natural gas can be easily acquired.
Steam can be produced by pumping seawater from the sea nearby while
natural gas can be acquired from Malampaya Onshore Gas Plant. Natural gas
The proposed location also has a good distance from residential areas
which decreases the likelihood for disturbance from plant processes. In turn,
the plant can open numerous job opportunities for the residents nearby.
FUEL SOURCE
The fuel of the plant will come from the plant itself. Waste gases and
some natural gas from the supply will be used. Utilization of heat from the
process will be maximized to improve the plant’s efficiency and reduce its fuel
consumption and emission. The electrical energy requirement of the plant will
Specifically, this study aims to meet the following objectives for the
design
project.
requirements.
the following:
assumptions related to the technical aspects and requirements needed for the
design of the steam methane reforming plant. Standards were used to come
capture from the syngas stream. The heat required in the reactor is delivered
by a furnace burning the process tail gas as well as additional natural gas if
needed.
B. Design Specification of each Equipment
methane prior to the main reforming reactor. The pre-reforming reactor usually
steam reforming unit. The temperature is normally in the range from 350– 550
°C. There are several benefits to pre-reforming, but most important is the
(SMR) are the temperature range and the method of heat transfer. Where the
reactor tubes and burners, the GHR works as a heat exchanger, absorbing
Efficiency 100%
the use of steam methane reforming (SMR). The reaction is endothermic and
converts steam and methane into H2 and CO. The reaction is a catalytic
efficient and have sufficient activity. When more activity is needed, a more
noble catalyst can be used. Nobel catalysts provide higher activities and faster
reactions but are very expensive. The reactor consists of several reactor
tubes filled with reforming catalysts and kept in a furnace that provides the
Efficiency 100%
After the reforming process, the syngas undergoes a water gas shift,
controlled by equilibrium.
done in two steps, a high temperature shift (HTS) and a low temperature shift
(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to
lower limit is set due to the water dew point of the gas. Condensation
Efficiency 100%
Efficiency 100%
CO2 ABSORPER
After the WGS, hydrogen and CO2 are produced and have to be
separated and purified. Concepts for CO2 separation are presented in this
commonly used to remove CO2 from NG [8]. The liquid solvent can be
solvents react with CO2 and require heat to activate the reaction. Chemical
solvents offer fast reaction rates which results in smaller plant size. Physical
solvents do not react but dissolve CO2 and require less heat than chemical
compared to physical solvents and are therefore preferred at low CO2 partial
pressures. The chemical solvents will begin to saturate with increasing CO2
partial pressures and physical solvents are therefore preferred at high CO2
partial pressures. The CO2 recovery and purity will depend on the syngas
composition and various solvents may be optimal for CO2 separation. Studies
have shown that MDEA can capture as much as 95% of the CO2 with a purity
of above 99%.
hydrogen while adsorbing CO2 and other impurities. The pressure inside the
Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits
COMPRESSOR
blades and stationary vanes. At the end of the compressor, before reaching
temperature by compression.
specifications.
Type Centrifugal
WATER PUMP
The pumps are installed for the circulation of water for steam
generation.
Motor 60 Hz
GAS EXPANDER
required heat by burning NG and the tail gas with air. The required air is
while the NG and tail gas is heated to a temperature of 500°C before entering
the furnace. Post combustion, the flue gas leaves the furnace at a
Table 9. Furnace
S + NG = M1
Steam= 2,722 kg/hr
Steam
GHR M1 100%
NG NG= 9,903 kg/hr
M1 + Steam = M2
M1 M1=12,625 kg/hr
SMR M2 100% Steam= 26,818 kg/hr
Steam M2=39,443 kg/hr
M2 = M3 + H20
M2=39,443 kg/hr
M2 M3
WGS 100% M3=29,908 kg/hr
H20= 9,535 kg/hr
H20
M3 M4 M3 + CO2 = M4
CO2 M3=29,908 kg/hr
100%
Absorber CO2=23,450 kg/hr
CO2 M4= 6,458 kg/hr
M4 = H2 + M5
M4 M5 M4=6,458 kg/hr
PSA 100% H2=3,848 kg/hr
M5= 2,610 kg/hr
H2
M5 + A + NG = FG + W
M5 M5= 2,610 kg/hr
Air
Flue Gas Air=60,957 kg/hr
NG
Furnace 100% NG=2,199 kg/hr
Waste
Flue Gas= 65,766 kg/hr
Waste = 0 kg/hr
T2NG = 773.15 K
Tcombustion = 1273.15 K
𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕
Wnet =0.37495 MW
1MJ/hr = .000277777778 MW
Solution:
𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟖𝟏𝟗𝟗
𝑴𝑱 𝒌𝒈 𝟎. 𝟑𝟕𝟒𝟓𝟗𝟓 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟐𝟏𝟎𝟐 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓
Figure 14. Plant Layout for Design Option 1
DESIGN OPTION 2 (SMR+)
In order to further reduce the carbon emissions, the natural gas feed to
the furnace is replaced by produced hydrogen. Thus, the CO2 emissions per
carbon-lean solution.
achieve higher energy efficiencies with SMR+, but that would result in
methane prior to the main reforming reactor. The pre-reforming reactor usually
steam reforming unit. The temperature is normally in the range from 350– 550
°C. There are several benefits to pre-reforming, but most important is the
(SMR) are the temperature range and the method of heat transfer. Where the
reactor tubes and burners, the GHR works as a heat exchanger, absorbing
Efficiency 100%
the use of steam methane reforming (SMR). The reaction is endothermic and
converts steam and methane into H2 and CO. The reaction is a catalytic
efficient and have sufficient activity. When more activity is needed, a more
noble catalyst can be used. Nobel catalysts provide higher activities and faster
reactions but are very expensive. The reactor consists of several reactor
tubes filled with reforming catalysts and kept in a furnace that provides the
Efficiency 100%
After the reforming process, the syngas undergoes a water gas shift,
controlled by equilibrium.
done in two steps, a high temperature shift (HTS) and a low temperature shift
(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to
lower limit is set due to the water dew point of the gas. Condensation
Efficiency 100%
Efficiency 100%
CO2 ABSORPER
After the WGS, hydrogen and CO2 are produced and have to be
separated and purified. Concepts for CO2 separation are presented in this
commonly used to remove CO2 from NG [8]. The liquid solvent can be
solvents react with CO2 and require heat to activate the reaction. Chemical
solvents offer fast reaction rates which results in smaller plant size. Physical
solvents do not react but dissolve CO2 and require less heat than chemical
compared to physical solvents and are therefore preferred at low CO2 partial
pressures. The chemical solvents will begin to saturate with increasing CO2
partial pressures and physical solvents are therefore preferred at high CO2
partial pressures. The CO2 recovery and purity will depend on the syngas
composition and various solvents may be optimal for CO2 separation. Studies
have shown that MDEA can capture as much as 95% of the CO2 with a purity
of above 99%.
hydrogen while adsorbing CO2 and other impurities. The pressure inside the
Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits
COMPRESSOR
blades and stationary vanes. At the end of the compressor, before reaching
temperature by compression.
specifications.
Type Centrifugal
WATER PUMP
The pumps are installed for the circulation of water for steam
generation.
Motor 60 Hz
GAS EXPANDER
required heat by burning NG and the tail gas with air. The required air is
while the NG and tail gas is heated to a temperature of 500°C before entering
the furnace. Post combustion, the flue gas leaves the furnace at a
S + NG = M1
Steam
Steam= 3,498 kg/hr
GHR M1 100%
NG NG= 12,719 kg/hr
M1= 16,217 kg/hr
M1 + Steam = M2
M1 M1=16,217 kg/hr
SMR M2 100% Steam= 34,444 kg/hr
Steam M2=50,661 kg/hr
M2 = M3 + H20
M2=50,661 kg/hr
M2 M3
WGS 100% M3=37,316 kg/hr
H20= 13,345 kg/hr
H20
M3 M4 M3 + CO2 = M4
CO2 M3=37,316 kg/hr
100%
Absorber CO2=30,115 kg/hr
CO2 M4= 7,201 kg/hr
M4 = H2 + M5
M4=7,201kg/hr
M4 M5
PSA 100% H2=3,848 kg/hr
M5= 3,353 kg/hr
H2
M5 + A + NG = FG + W
M5 M5= 3,353kg/hr
Air
Flue Gas Air=71,231kg/hr
H2
Furnace 100% H2=1,094 kg/hr
Waste
Flue Gas= 75678 kg/hr
Waste = 0 kg/hr
T2 = 673.15 K
Tcombustion = 1273.15 K
𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕
mNG = 12,719kg/hr
Wnet =0.4248 MW
1MJ/hr = .000277777778 MW
Solution:
𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟕𝟖𝟎
𝑴𝑱 𝒌𝒈 𝟎. 𝟒𝟐𝟒𝟖 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟐𝟕𝟏𝟗 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓
both the POX and the SMR reactions are active simultaneously. This concept
also need pure oxygen input as well as a catalyst bed in the steam reforming
section of the reactor. The core benefits of this system is that the heat
reaction.
methane prior to the main reforming reactor. The pre-reforming reactor usually
steam reforming unit. The temperature is normally in the range from 350– 550
°C. There are several benefits to pre-reforming, but most important is the
(SMR) are the temperature range and the method of heat transfer. Where the
reactor tubes and burners, the GHR works as a heat exchanger, absorbing
Efficiency 100%
The ATR reactors usually operate at temperatures between 900-1150 °C, with
pressure levels in the range 1 to 80 bar existing today. Figure below shows
the principles of the ATR reactor, with the different inputs and reaction zones.
No specific range was found for the typical energy efficiency of ATR, but it
After the reforming process, the syngas undergoes a water gas shift,
controlled by equilibrium.
done in two steps, a high temperature shift (HTS) and a low temperature shift
(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to
lower limit is set due to the water dew point of the gas. Condensation
Efficiency 100%
CO2 ABSORPER
After the WGS, hydrogen and CO2 are produced and have to be
separated and purified. Concepts for CO2 separation are presented in this
commonly used to remove CO2 from NG [8]. The liquid solvent can be
solvents react with CO2 and require heat to activate the reaction. Chemical
solvents offer fast reaction rates which results in smaller plant size. Physical
solvents do not react but dissolve CO2 and require less heat than chemical
compared to physical solvents and are therefore preferred at low CO2 partial
pressures. The chemical solvents will begin to saturate with increasing CO2
partial pressures and physical solvents are therefore preferred at high CO2
partial pressures. The CO2 recovery and purity will depend on the syngas
composition and various solvents may be optimal for CO2 separation. Studies
have shown that MDEA can capture as much as 95% of the CO2 with a purity
of above 99%.
Figure 27. CO2 Absorper
hydrogen while adsorbing CO2 and other impurities. The pressure inside the
Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits
H2 Purity 99.999%
COMPRESSOR
Air is drawn in and compressed when passing through rows of rotating
blades and stationary vanes. At the end of the compressor, before reaching
temperature by compression.
specifications.
Type Centrifugal
WATER PUMP
The pumps are installed for the circulation of water for steam
generation.
Motor 60 Hz
GAS EXPANDER
heat by burning NG and the tail gas with air. The required air is heated and
supplied at a temperature of 335°C and a pressure of 1.2 bar while the NG and
tail gas is heated to a temperature of 500°C before entering the furnace. Post
combustion, the flue gas leaves the furnace at a temperature of 1000°C and at
atmospheric pressure. The flue gas is cooled down to 100°C supplying heat to
S + NG = M1
Steam
Steam= 3,241 kg/hr
GHR M1 100%
NG NG= 11,787 kg/hr
M1= 15,028 kg/hr
M1 + Steam + O2 = M2
M1=15,028 kg/hr
M1 O2=11,822 kg/hr
ATR O2 M2 100%
Steam Steam= 15,449 kg/hr
M2= 42,299 kg/hr
M2 + Steam = M3 + H20
Steam
Steam=1,159 kg/hr
M2 M3 M2=42,299 kg/hr
WGS 100%
M3=37,768 kg/hr
H20 H20= 5,690 kg/hr
M3 M4 M3 = M4 + CO2
CO2 M3=37,768 kg/hr
100%
Absorber CO2=31,816 kg/hr
CO2 M4=5,952 kg/hr
M4 = H2 + M5
M4 M5 M4=5,952 kg/hr
PSA1 100% H2=3,498 kg/hr
M5= 2,454 kg/hr
H2
M5 = H2 + M6
M5 M6 M5=2,454 kg/hr
PSA2 100% H2=350 kg/hr
M6= 2,104 kg/hr
H2
M6 + A = FG + W
M6
M6= 2,104kg/hr
Flue Gas
Air Air=4830/hr
Furnace 100%
Flue Gas= 6934 kg/hr
Waste Waste = 0 kg/hr
T2NG = 773.15 K
Tcombustion = 1273.15 K
𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕
Wnet = 5.0055 MW
1MJ/hr = .000277777778 MW
Solution:
𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟖𝟏𝟕
𝑴𝑱 𝒌𝒈 𝟓. 𝟎𝟎𝟓 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟏𝟕𝟖𝟕 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓
Figure 33. Plant Layout for Design Option 3
CHAPTER IV
increased investment cost and higher expenditure cost. The main objective of
(OPEX), and economic indicators such as net present value, payback period,
and rate of investment. A sensitivity analysis will also be done to highlight how
Philippines. In this sub-chapter, the price at which the produced hydrogen will be
the range from 52.2 ₱/kgH2 of hydrogen produced to 112.4 ₱/kgH2 in 2030
same study concluded that a marginal cost of 118.3 – 236.5 ₱/kgH2 is what to be
the expected cost in the current market. Hence, based on then conservative
liquefaction, storage, and transportation costs, a production price below 124.1
(Navigant Research)
2005 0.18
2006 0.26
2007 0.33
2008 0.51
2009 0.65
2010 0.81
2011 1.01
2012 1.13
2013 1.48
2014 1.56
Chart Title
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
2008 2010 2012 2014 2016 2018 2020
Pacific
to the improvements in Fuel Cell Technology which paves the way to various
markets.
for the future. Arithmetic straight-line method assumes that the annual increase
Formula:
𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1
Where:
𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1
Yc = initial value, Yn = final value, Yi = value for the year past, N = number
of years
1.56 − 0.18
𝑎=
10 − 1
𝑎 = 0.1533
Chart Title
3.5
2.5
1.5
0.5
0
2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029
demand
2028.
(Navigant Research)
2009 0.17
2010 0.25
2011 0.31
2012 0.48
2013 0.63
2014 0.75
2015 0.98
2016 1.12
2017 1.25
2018 1.48
Chart Title
1.6
1.4
1.2
0.8
0.6
0.4
0.2
0
2008 2010 2012 2014 2016 2018 2020
Pacific
for the future. Arithmetic straight-line method assumes that the annual increase
Formula:
𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1
Where:
𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1
Yc = initial value, Yn = final value, Yi = value for the year past, N = number
of years
2.5
1.5
0.5
0
2018 2020 2022 2024 2026 2028 2030
2028.
Unsatisfied
Year Demand, MMT Supply, MMT
Demand
Supply Demand
Demand
Based on the projected annual unsatisfied demand, the proposed plant
will assume a 20% market share in year 2028 where the biggest unsatisfied
demand exists.
2019 0.0877 - -
2020 0.0954 - -
2021 0.1031 - -
2022 0.1092 - -
The proposed plant will be constructed in 2020 until 2022. The plant will
be operational by the year 2023 and thus start the production. The plant will be
operating 345 days a year. The 20-day allotment is for plant shutdown for regular
maintenance to ensure the efficiency and the overall safety of the plant.
for the installed process equipment with all auxiliaries that are needed for
foundations, and site preparation are typical examples of costs included in the
Fixed capital required for construction overhead and for all plant
components that are not directly related to the process operation is designated
and waste-disposal facilities, shops, and other permanent parts of the plant. The
I. Direct Costs
1. Purchased Equipment
Table 40. Estimation of Purchased Equipment Cost for SMR and SMR
Plus
Equipment No. of Unit Price Cost (Php) Tax (12%) Price (Php)
Units (Php)
Heat
12 1,040,000 12,480,000 1,497,600 13,977,600
Exchanger
Steam
Reformer
Absorber
Water Gas
Reactor
Spherical
5 23,400,000 117,000,000 14,040,000 131,040,000
Tank
Total 966,003,584
Equipment No. of Unit Price Cost (Php) Tax (12%) Price (Php)
Units (Php)
Heat
15 1,040,000 12,480,000 1,497,600 13,977,600
Exchanger
Pressure
Absorber
Reactor
Gas Heated
2 52,000,000 104,000,000 12,480,000 116,480,000
Reformer
Autothermal
1 52,000,000 52,000,000 6,240,000 58,240,000
Reformer
Spherical
5 23,400,000 117,000,000 14,040,000 131,040,000
Tank
Total 1,023,137,024
March 3, 2019 (1 usd = 52 php) and the current tax rate of 12% has been
2. Equipment Installation
equipment costs.
3. Insulation Costs
When very high or low temperatures are involved, insulation factors
The total cost for the labor and materials required for insulating
instrumentation cost.
5. Piping Costs
The cost for piping covers labor, valves, fittings, pipe, supports, and
other items involved in the complete erection of all piping used directly in
product, finished product, steam, water, air, sewer, and other process
piping.
labor and materials for power and lighting, with building-service lighting
connected with the plant. Costs for plumbing, heating, lighting, ventilation,
8. Yard Improvements
cost.
9. Service Facilities
Utilities for supplying steam, water, power, compressed air, and fuel
are part of the service facilities of an industrial plant. Waste disposal, fire
protection, and miscellaneous service items, such as shop, first aid, and
cafeteria equipment and facilities, require capital investments which are
10. Land
The total cost of land is influenced by the value of land where plant
is located and other fees which include title fees, legal fees, survey costs,
zoning fees, site preparation costs and etc. The value of land in
on municipal inquiry.
J. Indirect Costs
2. Contractor’s Fee
3. Construction Expense
taxes and insurance, and other construction overhead. This expense item
4. Contingencies
from 5 to 15 percent of the direct costs are commonly used, with 8 percent
K. Working Capital
wages, and raw-material purchases, (5) accounts payable, and (6) taxes
payable.
different companies, but most fluid chemical plants use an initial working
tons of hydrogen gas and operates 345 days per year. The table shows
various costs constituting the total capital investment for the proposed
plant.
Table 42. Estimation of Total Capital Investment for SMR and SMR
Plus
Land 650,000,000.00
Cost Factor,
INDIRECT COST
TDC
Land 650,000,000.00
Cost Factor,
INDIRECT COST
TDC
facilities, and the cost to sustain its operation. It is the sum of the fixed
1. Raw Materials
The cost of the raw material for hydrogen production are calculated using the
(markets.businessinsider.com)
Annual
Cost per Unit
Consumption
Design Option (Php per metric Total Cost (Php)
(metric tons per
ton)
year)
Table shows the annual cost of natural gas based on the annual consumption
of the plant.
2. Operating Labor
The cost of labor is the sum of all wages paid to employees, as well as
the cost of employee benefits and payroll taxes paid by an employer. The
Daily Basic Pay of Wage and Salary Workers by Major Occupation Group,
Philippines (2016-2018)”.
The proposed plant will have a total of seven (7) major departments
them are the best fit for a designated position. Potential employees will
and health care insurance, tuition assistance plan, and retirement are
Table 45. Estimation of the Total Labor Cost for Human Resource
Department
Officer
Officer
Total 17 2,687,801.98
as payroll, debts, and taxes. To secure that there are sufficient funds
Department
Salary Salary
Manager
Accountant
Officer
Manager
Master
Clerk
Staff
Total 14 2,988,361.24
Table 46 shows the estimated total labor costs of Finance
increase market share and to generate revenue. First and foremost, the
the company.
But since the market can be unpredictable, finding new and creative ways
Table 47. Estimation of the Total Labor Cost for Marketing and Sales
Department
Manager
Officer
and
Promotion
Officer
Staff
and
Promotion
Staff
Total 14 2,781,487.02
formulating a new product. The activities of the department are divided into two
phases namely, research phase and development phase. In the research phase,
methods prior to developing products that will satisfy the needs of consumers.
theories presented during the research phase into actual work. The department
takes into account product specifications, production costs, and a production time
line.
product quality; increased market competition due to new trends within the
Table 48. Estimation of the Total Labor Cost for Research and
Development Department
Salary Salary
and
Development
Manager
Developer
Developer
Researcher
Researcher
Total 18 2,781,487.02
product from the available raw materials. It oversees that finished goods
Department
Salary Salary
Manager
Head
Control Head
Head
Head
Head
Staff
Control Staff
Staff
Staff
measures in assuring that finished goods passed necessary quality tests and
standards before ultimately reaching the market. The department targets zero
defect and a hundred percent quality products that will bring long-term revenue
and profitability, maintain customer satisfaction and loyalty, and lessen the risk
keeping the business on the cutting edge through constant drive for development
in the industry.
Salary Salary
and Control
Manager
Assurance
and Control
Staff
Total 6 1,656,083.00
2.7 Others
a. Plant Manager
of employees.
Manager
Salary
Manager
Total 1 707,497.00
b. Legal Counsel
identified risks that affects the profit line of the company within the
Counsel
Quantity Daily Annual Total
Salary Salary
Counsel
Total 1 1,312,500.00
Finance 2,988,361.24
Department
Development
Operations 17,759,203.71
Others 2,019,997
Total 32,674,420.97
Table 53 shows the total labor cost for the proposed SMR plant.
3. Direct Supervisory and Clerical Labor
always necessary. The estimate of the cost of this type of labor is linked
with the total amount of operating labor, product quality standards, and
4. Utilities
reforming such as electricity, process and cooling water, fuel (diesel and
and source.
4.1 Fuel
Heat Demand
and 700°C):
Total 350.39
Heat Utilized
Total 217.44
A total heat demand of 350.29 GJ/hr for SMR and SMR plus
MJ/m3 GJ/hr
Heat Demand
and 700°C):
Total 451.66
Heat Utilized
Total 275.45
Heat Demand
500°C):
Total 163.96
Heat Utilized
Intercooling in two-stage oxygen 2.86
compression (277-25°C):
(1000-100°C)
Total 168.89
MJ/m3 GJ/hr
Natural
8214 0.8 82.7 4.92
Gas
𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 =
4.2 Electricity
Batangas.
𝑞𝜌𝑔ℎ
𝑃=
3.6𝑥10^6
Fluid Volumetric
Wattage, Annual Cost,
Equipment Head Density, Flow Rate,
kW Php
kg per m3/hr
m3
Compressor
18000 1.225 74762.325 4492.19 1,131,610.844
-1
Total 1,330,003.558
ATR
Fluid Volumetri
m3 m3/hr
1800 122,311.37
Expander – 1 0.8 13096.67 485.36259
0
1800 45,100,244.83
Pump -3 1000 1287.78 526.38007
0
Total 119,119,940.00
that the plant is running 24 hours a day and 340 days a year.
4.3 Water
Water that will be used for the process will be provided by West
be done to give way for the maintenance and repairs of the plant along
with its equipment and facilities. The total plant cost per year for
6. Operating Supplies
the operating supplies costs. The costs for these materials cannot be
expenses. The annual expenses for these supplies are 15 percent of the
7. Laboratory Charges
B. Fixed Charges
Certain expenses are always present in the industrial plan whether or
not the manufacturing process is in operation. Costs that are invariant with
These include costs for depreciation, local property taxes, and insurance.
1. Depreciation
assumed to occur throughout the usual life of the material possessions. This
𝑉 − 𝑆𝑉
𝑑=
𝑛
Table 62. Estimation of the Total Depreciation Cost for SMR and
SMR Plus
Equipment
Instrumentation and 125,580,465.90 12,558,046.59 8 14,127,802.41
Controls
Equipment and
Materials
Total 100,488,522.8
Controls
Equipment and
Materials
Table 63 shows the total annual depreciation cost using straight line
method. Estimated life years and salvage value was courtesy of M. S. Peters &
The asset value (or book value) of the equipment at any time during the
𝐴𝑉 = 𝑉 − 𝑎𝐷
Depreciation
Purchased
28,980,107.52 80,913,140.31 937,023,476.5 908,043,369 879,063,261.4 850,083,153.9
Equipment
Instrumentation
42,383,407.25 10,518,708.24 334,357,990.6 291,974,583.3 249,591,176.1 207,207,768.8
and Controls
Electrical
Materials
Yard
19,561,572.58 8,091,314.03 415,140,040.2 395,578,467.6 376,016,895.1 356,455,322.5
Improvements
Purchased
28,980,107.52 821,103,046.4 792,122,938.9 763,142,831.4 734,162,723.8 705,182,616.3
Equipment
Instrumentation
42,383,407.25 164,824,361.6 122,440,954.3 80,057,547.05 37,674,139.8 -
and Controls
Electrical
Materials
Yard
19,561,572.58 336,893,749.9 317,332,177.3 297,770,604.7 278,209,032.2 258,647,459.6
Improvements
(1991). Plant Design and Economics for Chemical Engineers. McGraw-Hill Inc.
Singapore.
2. Property Taxes
individual cities and towns may have special property taxes for industrial
The legal basis for real property tax is in Title II of the Local
government units the power to create local and external revenue sources
such as the property tax, business tax, professional tax, amusement tax
and other fees and charges. RA 7160 also established limitations such as
Real property tax rate for most cities and municipalities in Metro
the taxable value of the property, is the fair market value multiplied by the
assessment level.
Assessment level is the amount applied to the fair market value to
e (Php)
0 0
s 0 0
Total 11,232,630.8
Table 65 shows the total property tax considering the local tax code
3. Insurance
unforeseen developments.
buildings are necessary for many of the general plant services, and the fixed
charges and direct costs for these items are part of the plant-overhead costs.
Plant overhead cost for chemical plants is about 50% of the total expense for
operating labor.
D. General Expenses
D.1 Administrative
Product costs are the costs required for the manufacturing of the
Labor 0.15 OL
Utilities 88,805,710.71
B. Fixed Charges
100,488,522.8
Depreciation
D. General Expenses
Labor 0.15 OL
Utilities 1,330,003.56
B. Fixed Charges
100,488,522.8
Depreciation
174,527,155.77
D. General Expenses
Labor 0.15 OL
Utilities 122,357,100.40
B. Fixed Charges
100,488,522.8
Depreciation
SMR Plus is by far the most economical option. The evaluation of the
basis.
F. Sensitivity Analysis
on one or more input variables, such as the effect that changes in interest
1. Primary Investment
SMR 1,370,000,000.00
ATR 1,500,000,000.00
2. Loan
options will be loaned from Banco de Oro. The company's land, buildings,
Ordinary Annuity
𝐴[(1 + 𝑖)𝑛 − 1]
𝑃1 =
𝑖(1 + 𝑖)
i = interest
P1 = 6.0009A
Deferred Annuity
𝑃1 = 𝑃2(1 + 𝑖)𝑚
m = deferred period
A = 855,980,522.90
3. Annual Sales
Hydrogen
Production, kg per kg
annual H2 production.
Table 71. Variables for Total Fuel Cost Estimation for SMR
Plus
MJ/m3 GJ/hr
= 3,755,440,000 – 115,939,032.39
3,639,500,968.00 Php
Carbon Dioxide
SMR 4,013,765,200.00
ATR 3,793,973,968.00
Table 73 shows that SMR produces the most amount of sales per
year.
Balance
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Expenses
Development
Outflows
Balance
2024
Balance
Cash Inflow 3822576940 4,023,765,200 4224953460
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2025
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Distribution Cost 23453079.5 24,687,452.10 25921824.71
Development
Outflows
Balance
2026
Balance
Loan Proceeds
Inflow
Cash Outflows
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Balance
2027
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
Supplies
Charges
Expenses
Development
Outflows
Balance
2028
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Expenses
Development
Outflows
Balance
2029
Balance
Cash Inflow 3822576940 4,023,765,200 4224953460
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2030
Balance
Loan Proceeds
Inflow
Cash Outflows
Raw Material 738882276.6 777,770,817.50 816659358.4
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2023
Balance
Inflow
Cash Outflows
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Balance
2024
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
Supplies
Charges
Expenses
Development
Outflows
Balance
2025
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Expenses
Development
Outflows
Balance
2026
Balance
Cash Inflow 3771738420 3,970,250,968 4168763516
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2027
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Distribution Cost 23453079.5 24,687,452.10 25921824.71
Development
Outflows
Balance
2028
Balance
Loan Proceeds
Inflow
Cash Outflows
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Balance
2029
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
Supplies
Charges
Expenses
Development
Outflows
Balance
2030
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Expenses
Development
Outflows
Balance
2023
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2024
Balance
Loan Proceeds
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Development
Outflows
Balance
2025
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Total Cash 2242569311 2,360,599,274.87 2478629239
Outflows
Balance
2026
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2027
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Expenses
Development
Outflows
Balance
2028
Balance
Cash Inflow 3604275270 3,793,973,968 3983672666
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Outflows
Balance
2029
Balance
Loan Proceeds
Inflow
Cash Outflows
Supervisory and
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Distribution Cost 22620755.37 23,811,321.44 25001887.51
Development
Outflows
Balance
2030
Balance
Loan Proceeds
Inflow
Cash Outflows
Clerical Labor
and Repairs
Supplies
Charges
Expenses
Development
Balance
G. Payback Period
necessary to recover the original capital investment in the form of cash flow to
Table 76. Estimation of the Net Income per year for SMR
Table 76 shows the estimation of the net income for SMR. Cash
inflow and outflow are from the sensibility study performed. Payback
5,477,642,247.85
=
1,702,975,128.00
Table 77. Estimation of the Net Income per year for SMR Plus
Table 77 shows the estimation of the net income for SMR Plus.
Cash inflow and outflow are from the sensibility study performed. Payback
5,477,642,247.85
=
1,653,637,775
Table 78. Estimation of the Net Income per year for ATR
Table 78 shows the estimation of the net income for ATR. Cash
inflow and outflow are from the sensibility study performed. Payback
5,477,642,247.85
=
1,433,374,693
times. The present value of the cash flow depends on the interval of time
between now and the cash flow. It also depends on the discount rate. NPV
accounts for the time value of money. NPV is given by the equation:
𝑡
𝐶𝑡
∑ − 𝐶𝑜
(1 + 𝑟)8
𝑡=1
Ct = Net Cash Inflow
r = Discount rate
t = Number of Periods
Ct Co r t NPV
-
SMR 1,433,374,69 5,477,642,247.85
10% 8 128,203
Plus 3
,264.7
365,296
ATR 1,653,637,775 5,806,176,973.00 10% 8
,836.8
the project or investment exceeds the anticipated cost while the one with
negative value will result in a net loss. Therefore, SMR Plus will not be
pursued.
I. Return on Investment For SMR
= 1,702,975,128.00/5,477,642,247.85 ∗ 100
= 31.09%
The proposed SMR plant will have a rate of investment of 31.09% per year.
CHAPTER V
and all of the community, and the proper mitigation to it, complying with
A. Design option 1
create job opportunities to the people within the area. This will greatly improve
the employment rate and thus decreasing the number of unemployed people
B. Design option 2
Barangay Tabangao and its municipality. This project will provide more
consideration. The greater the information given, the greater the acceptance.
C. Design option 3
There are several benefits that can be acquired during the construction of
steam methane reforming plant. It would create an average around 500 new
jobs during the construction and operation stage. These data are general for
a regular plant but there are many more site-related workers that are difficult
possible to have highly qualified staff on the site, which improves safety,
economic benefit.
evaluate the project likely impacts on the environment. One of its key objectives
LAWS
Statement
The law requires private corporations, firms or entities including
unlawful for any person to cause, suffer or permit the disposal of sewage,
E. Republic Act No. 9275: The Philippine Clean Water Act of 2004
sources. The water quality standards and regulations and the civil liability
formulate and apply standards for the transport and disposal of effluent,
Management Act
This Act makes provision for the efficient solid waste management,
for the volume reduction of the waste, its environment friendly disposal,
of solid waste
water quality within their territorial jurisdictions. (Sec. 20) Local Government Units
are the key players in the Water Quality Management Areas designated by
DENR in accordance with Sec. 5 of the Clean Water Act and its IRR
Waste Management
The proposed plant is set to follow the Presidential Decree No. 856
(Sanitation Code of the Philippines) and Republic Act no. 9003 (Ecological Solid
Waste Management Act) that covers the handling of solid waste disposal.
Social and Environmental Impacts
Hydrogen could have the potential to reshape the entire energy industry.
greenhouse gas emissions. If vehicles were all run on hydrogen fuel cells, it
would be a huge step towards solving air pollution problems in cities. Emissions
vehicles were fueled by hydrogen. According to the EPA, vehicles in the U.S.
account for 78% of carbon monoxide emissions, 45% of NOx, and 37% of
Technologies are emerging to isolate this carbon dioxide from the atmosphere by
effects of carbon sequestration and storage security are not entirely known.
water gas
GENERAL USE: Some see hydrogen gas as the clean fuel of the future –
energy and are now being used in some buses and cars. In the chemical industry
it is used to make ammonia for agricultural fertiliser (the Haber process) and
and pharmaceuticals. It is also used to remove sulfur from fuels during the oil-
form fats, for example to make margarine. In the glass industry hydrogen is used
industry it is used as a flushing gas during the manufacture of silicon chips. The
low density of hydrogen made it a natural choice for one of its first practical uses
toxic, nonmetallic, highly combustible diatomic gas with the molecular formula
H2.
of the cylinder of Hydrogen can cause the cylinder to rupture without activating
the cylinder’s relief devices. Provide adequate fire protection during emergency
response situations.
disturbed.
disturbed respiration.
of consciousness.
Victim(s) must be taken for medical attention. Rescuers should be taken for
other health professional with victim(s). In case of frostbite, place the frostbitten
part in warm water. DO NOT USE HOT WATER. If warm water is not available,
the fingers or hands are frostbitten, place the affected area of the body in the
armpit. Encourage victim to gently exercise the affected part while being warmed.
and pressure.
4. FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): 4.0% Upper (UEL):
shutting-off the source of the gas. Use water spray to cool fire-exposed
extreme explosion hazard exists in areas in which the gas has been released,
but the material has not yet ignited. Hydrogen burns with an almost invisible blue
flame.
Escaping gas may ignite spontaneously. Hydrogen has a low ignition energy.
Fireball forms if gas cloud ignites immediately after release. Forms explosive
personnel from danger area. Immediately deluge cylinders with water from
maximum distance until cool; then move them away from fire area if without risk.
Continue cooling water spray while moving cylinders. Do not extinguish flames
apparatus may be required by rescue workers. On-site fire brigades must comply
Specific Physical and Chemical Hazards: Heat of fire can build pressure in
cylinder and cause it to rupture. Hydrogen cylinders are equipped with a pressure
gas may spread from leak, creating an explosive re-ignition hazard. Vapors can
product handling point. Explosive atmospheres may linger. Before entering area,
5. ACCIDENTAL MEASURES
should be used. In case of a release, clear the affected area and protect people.
tools and equipment. Locate and seal the source of the leaking gas. Protect
personnel attempting the shut-off with water-spray. Allow the gas, which is lighter
than air, to dissipate. Monitor the surrounding area for combustible gas levels
and oxygen. Combustible gas concentration must be below 10% of the LEL (LEL
= 4.0%) prior to entry of response personnel. The atmosphere must have at least
19.5 percent oxygen before personnel can be allowed in the area without Self-
Contained Breathing Apparatus. Attempt to close the main source valve prior to
entering the area. If this does not stop the release (or if it is not possible to reach
the valve), allow the gas to release in-place or remove it to a safe area and allow
RESPONSE TO CRYOGENIC RELEASE: Clear the affected area and allow the
liquid to evaporate and the gas to dissipate. After the gas is formed, follow the
instructions provided in the previous paragraph. If the area must be entered by
emergency personnel, SCBA, Kevlar gloves, and appropriate foot and leg
all personnel from danger area. Use self-contained breathing apparatus where
needed. Approach suspected leak area with caution. Remove all sources of
ignition if without risk. Reduce gas with fog or fine water spray. Shut off flow if
gas may spread from leak. Before entering area, especially confined areas,
with federal, state, and local regulations. If necessary, call your local supplier for
assistance.
well-ventilated areas away from sources of heat. Compressed gases can present
significant safety hazards. Store containers away from heavily trafficked areas
and emergency exits. Post “No Smoking or Open Flames” signs in storage or use
appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s
greater than the LEL will immediately be generated near the vicinity of the
Dewar, creating an extreme fire and explosion hazard. This gas is lighter than air
cylinders against physical damage. Store in cool, dry, well-ventilated area, away
from sources of heat, ignition and direct sunlight. Do not allow area where
cylinders are stored to exceed 52°C (125°F). Isolate from oxidizers such as
oxygen, chlorine, or fluorine. Use a check valve or trap in the discharge line to
prevent hazardous backflow. Post “No Smoking or Open Flame” signs in storage
and use areas. Cylinders should be stored upright and be firmly secured to
prevent falling or being knocked over. Cylinders can be stored in the open, but in
such cases, should be protected against extremes of weather and from the
dampness of the ground to prevent rusting. Never tamper with pressure relief
are being used: Before Use: Move cylinders with a suitable hand-truck. Do not
drag, slide or roll cylinders. Do not drop cylinders or permit them to strike each
other. Secure cylinders firmly. Leave the valve protection cap, if provided, in-
place until cylinder is ready for use. During Use: Use designated CGA fittings and
other support equipment. Do not use adapters. Do not heat cylinder by any
means to increase the discharge rate of the product from the cylinder. Use check
valve or trap in discharge line to prevent hazardous backflow into the cylinder. Do
not use oils or grease on gas-handling fittings or equipment. After Use: Close
main cylinder valve. Replace valve protection cap, if provided. Mark empty
cylinders “EMPTY”.
Skin Protection: Wear work gloves for cylinder handling and metatarsal shoes
electrical parts.
cylinders of Hydrogen. Use low temperature protective gloves (e.g., Kevlar) when
items. If a hazard of injury to the feet exists due to falling objects, rolling objects,
where objects may pierce the soles of the feet or where employee’s feet may be
ODOR: Odorless
LIQUID DENSITY at boiling point and 1 atm: 4.43 lb/ft3 (70.96 kg/m3)
VAPOR DENSITY at 70°F (21.1°C) and 1 atm: 0.0052 lb/ft3 (0.083 kg/m3)
MOLECULAR FORMULA: H2
9. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are no specific toxicology data for Hydrogen. Hydrogen
agencies.
repeated exposure.
locally.
The following selected regulatory requirements may apply to this product. Not all
such requirements are identified. Users of this product are solely responsible for
TPQ: None
FIRE: Yes
alkaline effluents and used under supercritical conditions for purifying or dying
polymer, animal or vegetal fibres. ndustrially, carbon dioxide is typically used for
process control, examples of which include the use of carbon dioxide for red
fume suppression during scrap and carbon charging, for nitrogen pick-up
reduction during electric arc furnace tapping and for bottom stirring. In non-
ferrous metallurgy, carbon dioxide is used for fume suppression during ladle
is used to enhance the recovery of oil from wells where primary and secondary
Main Hazards: Carbon dioxide does not support life. It can act as a simple
asphyxiant by diluting the concentration of oxygen in air below the levels
lower levels.
the central nervous system. Increases in heart rate and blood pressure have
steel materials.
stimulate the respiratory centre, thereby controlling the volume and rate of
vital constituent of the acid-base mechanism that controls the pH of the blood.
result in one minute or less. Impairment in performance has been noted during
Specific Hazards: Carbon dioxide does not support life. It can act as a simple
asphyxiant by diluting the concentration of oxygen in the air below the levels to
support life.
Emergency Actions: If possible, shut off the source of excess carbon dioxide.
Evacuate area. All cylinders should be removed from the vicinity of the fire.
Cylinders that cannot be removed should be cooled with water from a safe
distance. Cylinders that have been exposed to excessive heat should be clearly
Personal Precautions: Do not enter any area where carbon dioxide has been
Small Spills: Shut off the source of escaping carbon dioxide. Ventilate the area.
Large Spills: Evacuate the area. Shut off the source of the spill if this can be
done without risk. Restrict access to the area until completion of the cleanup
Do not allow cylinders to slide or come into contact with sharp edges. Carbon
secured in order to prevent them from being knocked over. Use a “first-in first-
out” inventory system to prevent full cylinders from being stored for excessive
avoid any areas where spillage has taken place. Only enter once testing has
proved the atmosphere to be safe, and remember that gas is heavier than air.
Engineering Control Measures: Engineering control measures are preferred to
Ensure that sufficient fresh air enters at, or near, floor level.
worn when entering area where oxygen depletion may have occurred. Safety
goggles, gloves and shoes, or boots, should be worn when handling cylinders.
Colour: Acidic
Odour: None
controlled conditions. The gas supplier should only handle large amounts.
Disposal of Packaging: The gas supplier must only handle the disposal of
cylinders.
ROAD TRANSPORTATION
UN No: 1013
SEA TRANSPORTATION
IMDG: 101
Methods
The solid wastes of the company are generated from the offices, cafeteria,
clinic, dormitory and laboratory. This includes food wastes, plastics, bottles,
papers, laboratory containers, medical wastes and other solid wastes not
aforementioned.
wastes in the laboratory to the bins. The solid chemical waste containers in the
laboratory should have labels and must be kept sealed and closed at all times.
the laboratories and other work areas. The filled waste containers is then
Segregation
providing separate waste bins for papers, recyclable plastic bottles, plastics, food
wastes, compost, and laboratory wastes placed on different areas of the plant.
The residual wastes coming from the air filter and dirt from each facility also have
the company in order to provide a cleaner and friendlier environment for the
entire plant.
Figure 42. Material Recovery Facility (MFR) Segregation Flow
The waste materials collected within the entire plant are unloaded and
placed on the Materials Recovery Facility of the plant where the recyclable
materials generated are sorted using manual and automatic labor and are
recovered prior to disposal. In the MRF, the materials collected have separate
The Material Recovery Facility (MRF), the wastes will be sorted into their
respective types. The company will sell the recyclable materials such as papers
reprocess the wastes to create new products. For the food wastes, compost,
residual wastes, and other non-recyclable materials, they will be collected and
thrown away into landfill or composts pits through their appropriate collections.
The proposed plant will be under the SGS Philippines via SGS
environmental waste management services that can help us to recycle, treat and
regulatory requirements.
Waste reconditioning
Waste care
and efficiently. This ensures that the products are back in the supply chain as
soon as possible and the waste management processes are enhancing the
WASTEWATER MANAGEMENT
Wastewater pond aeration systems provide reliable, low cost, and relatively low
2011). The most common types of pond aeration systems are surface aerators
and diffused aerators. For the treatment of wastewater generated by the plant,
In diffused aeration system, infused air or oxygen is utilized into the pond. A tube
near the bottom and can be taken out while cleaning. The air comes out through
the holes with great force and agitates the sewage. The set up involves air
compressor that pushes air through tubing down to diffuses located and the
bottom of the pond where bubbles are released into the pond. This provides
biodegrading to occur which breaks down the organic matter containing carbon
to form carbon dioxide and water. In diffused aeration process, larger/ deeper
Diffused aeration process allows the treated wastewater to be safely used for
gardening or lawn watering and can even be recycled for toilet flushing within the
plant.
CHAPTER VI
This chapter covers the evaluation of the three design options presented
option. The best design option is been selected using design philosophies such
The following are the realistic constraints that have taken into account in
1. Technical
PEE 82 % 78 % 82%
2. Economics
For the economics area, Net Present value was used as parameter
3. Environmental
constraints above in order to come up with the best design option by determining
the lowest possible value for the three design option in each parameter. The
highest.
Table 83. Summary of Multiple Realistic Constraints
NPV 7 3 5
LOE 7 8 9
Results
The table below shows the lowest value for each design option.
DO1(SMR) 7
DO2(SMR+) 3
DO3(ATR) 5
Based on the Worst Case Design Philosophy, the designers found out that
Design Option 1(SMR) is the best design option to be used in the selection of
constraints above in order to come up with the best design option by determining
the degree of importance of each parameter and multiplying it to each value. The
Importance
NPV 7 3 5 5
LOE 7 8 9 4
Results
The table below shows the lowest value for each design option.
out that Design Option 1(SMR) is still the best design option to be used in the
selection of Steam Methane Reforming Plant among the three design options.
CHAPTER VII
ensure its profitability and efficiency. Different aspects are considered for the
A. Pre-Operation Period
2. Geographical Study
Selecting the best plant location is crucial as it will be the site where all
major manufacturing operations will take place. There are salient factors
determine the optimal plant location. The usual aim is to select a location
that will result in the lowest average cost of the products, delivered to retail
outlets. There may be other social or political objectives such as
basis plant location within a country are likely to be preferred for reasons
plant must be erected near the source of raw materials. The rationale
2.2 Accessibility
the cost of product distribution and the required time for shipping.
goods from manufacturers that are within their reach. It is also ideal
2.4 Labor
turnover rates among the workers, and variations in the skill and
from the outside the site, but there should be an adequate pool of
maintenance.
imperative.
facilities are compliant with the enacted laws such as the Republic Act No.
9275 (Philippine Clean Water Act of 2004), Republic Act No. 8749
(Philippine Clean Air Act of 1999), Republic Act No. 9003 (Ecological Solid
Waste Management Act of 2000) and DAO No. 2016-08 (Water Quality
The air quality in the manufacturing area of the SMR plant can affect
The proposed SMR plant is set to follow the Presidential Decree No.
856 (Sanitation Code of the Philippines) and Republic Act no. 9003
of the water from the Clark Freeport Zone in compliance with the
Republic Act No. 9275 or the Philippine Clean Water Act of 2004 and
the DAO 2016-08 or the Water Quality Guidelines and General Effluent
Standards of 2016.
4. Financial Study
investment.
5. Technical Study
the design of the steam methane reforming plant. Standards were used to
B. Operation Period
The proposed SMR plant is planned to operate three hundred forty (340)
days a year, seven (7) days a week, and twenty-four (24) hours a day.
shutdown will be conducted every start of May every year to avoid extreme
and efficiently.
The proposed SMR plant will have a total of 170 workers from seven (7)
to Friday, 7:00 A.M. to 4:00 P.M. Two fifteen (15) minute breaks are allotted
one in the morning and one in the afternoon. There will be allotted lunch
Sunday. Three shifts are available: 1.) from 6:00 A.M. to 2:00 P.M. 2.) from
2:00 P.M. to 10:00 P.M. and, 3.) from 10:00 P.M. to 6:00 A.M. Quarterly
rotational shiftwork will be observed. The first team in the first shift will have a
break from 9:00 A.M. until 10:00 A.M. while the second team will have a
break from 10:00 A.M. until 11:00 A.M. On the other hand, the first team of
the second shift will have a break from 5:00 P.M. until 6:00 P.M. while the
second team will have a break from 6:00 P.M. until 7:00 P.M. Finally, the first
team in the third shift will have a break from 1:00 A.M. until 2:00 A.M. while
the second team will have a break from 2:00 A.M. to 3:00 A.M.
Presidential Decree No. 442 or The Labor Code of the Philippines. Failure to
The proposed SMR plant will have a dedicated for quality assurance and
strict measures in assuring that finished goods passed necessary quality tests
and standards before ultimately reaching the market. The department targets
zero defect and a hundred percent quality products that will bring long-term
lessen the risk and cost of replacing defective goods. The department is also
responsible in keeping the business on the cutting edge through constant
E. Time Table
Gantt chart will be used and done to evaluate and plan the activities prior
to the operation period. This is to help the project to be in track in all of its
This chapter summarizes the overall rundown of the results and details
regarding the chosen design option, and includes the summary of findings,
Reforming Plant.
Summary of Findings
The following are the findings relative to the design options chosen for the
1. SMR(DO1) and ATR(DO3) are the most energy efficient design options for
82%. ATR(DO3) has the most potential of further emission reduction but
3. The SMR(DO1) will be the chosen design option for the development of a
previous chapter.
4. The designed Steam Methane Reforming plant will use 9,903 kg/hr
raw material to produce a 31400 tons/ year of H2. The steam methane
reforming process is divided into five main sections: pre-reforming, steam
Shifter, CO2 Absorber, Pressure swing Absorber and Furnace will be the
3.22 years. The Net present value of the power plant after 8 years of
Conclusion
Based on the data gathered, the proponents have come up with the
following conclusions:
emissions from fossil resources, integrate renewables with the society and
significantly.
2. This production plant will be the first hydrogen producing plant in the
health and safety regarding proper wearing of PPE, hazard present in the
scenarios. The management of the plant will have a mitigation plan in the
Recommendation
of the plant.
3. Future researchers must conduct a study for the improvement of the
layout that will utilize the space considering its economic aspects.
5. Future researchers must look for significant ideas that could reduce the
V. Åtland and D. Jakobsen, “Value chains for hydrogen export from Norway,”
Jakobsen, D., & Åtland, V. (2016). Concepts for large scale hydrogen
Forni, A. (2017, July 5). A Roadmap to the Coming Hydrogen Economy in One
and-views/a-roadmap-to-the-coming-hydrogen-economy-in-one-chart
https://www.investopedia.com/dictionary/
statistics/statistical-tables
<http://www.alibaba.com>.
Typical Sigle Stage Pump Curve [Digital image]. (2012). Retrieved April 14,
2019, from
https://www.google.com.ph/url?sa=i&source=images=https://www.pumpsandsyst
ems.com/pumps/june-2016-understanding-pump-
curves&psig=AOvVaw0gjR_FPnRfe6oI4A1Oca5_&ust=1555329562047289
Centrifugal Compressor Performance Curve [Digital image]. (2013). Retrieved
Natural Gas Price. (2019). Retrieved April 14, 2019, from natural Gas Global
Price. (2019). Retrieved April 14, 2019, from Natural Gas Price Chart. (n.d.).
https://markets.businessinsider.com/commodities/natural-gas-price
Hydrogen Gas Price. (2019). Retrieved April 14, 2019, from Hydrogen Gas
Global Price. (2019). Retrieved April 14, 2019, from Natural Gas Price Chart.
https://markets.businessinsider.com/commodities/hydrogen-gas-price
Provincial Map showing the location of Batangas City. (2018). Retrieved from
https://maps.google.com.ph/
http://birtaxcalculator.com/calculator.php
“Https://Www.armilcfs.com/Furnaces/.” Https://Www.armilcfs.com/Furnaces/.
“Https://En.wikipedia.org/Wiki/Pressure_swing_adsorption.” Https://En.wikipedia.
org/Wiki/Pressure_swing_adsorption.
“Https://Www.indiamart.com/Proddetail/Industrial-Air-Compressor-
1683993073.Html.” Https://Www.indiamart.com/Proddetail/Industrial-Air-
Compressor-1683993073.Html.
“Https://Www.indiamart.com/Proddetail/Turbo-Expanders-
6498086612.Html.” Https://Www.indiamart.com/Proddetail/Turbo-Expanders-
6498086612.Html.
Appendices
A. Detailed Calculations
GHR
S + NG = M1
SMR
M1 + Steam = M2
M1=16,217 kg/hr
M2=50,661 kg/hr
WGS
M2 = M3 + H20
M2=50,661 kg/hr
M3=37,316 kg/hr
H20= 13,345 kg/hr
CO2 Absorber
M3 + CO2 = M4
M3=37,316 kg/hr
CO2=30,115 kg/hr
PSA
M4 = H2 + M5
M4=7,201kg/hr
H2=3,848 kg/hr
Furnace
M5 + A + NG = FG + W
M5= 3,353kg/hr
Air=71,231kg/hr
H2=1,094 kg/hr
Waste = 0 kg/hr
𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1
Where:
𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1
Yc = initial value, Yn = final value, Yi = value for the year past, N = number
of years
1.56 − 0.18
𝑎=
10 − 1
𝑎 = 0.1533
Loan
Ordinary Annuity
𝐴[(1 + 𝑖)𝑛 − 1]
𝑃1 =
𝑖(1 + 𝑖)
i = interest
𝐴[(1 + 0.0684)8 − 1
𝑃1 =
0.0684(1 + 0.0684)
P1 = 6.0009A
Deferred Annuity
𝑃1 = 𝑃2(1 + 𝑖)𝑚
m = deferred period
6.0009 𝐴 = 4,500,000,000 (1 + 0.0684)2
A = 855,980,522.90
= 3,755,440,000 – 115,939,032.39
5,477,642,247.85
=
1,702,975,128.00
5,477,642,247.85
=
1,433,374,693
Return on Investment
= 1,702,975,128.00/5,477,642,247.85 ∗ 100
= 31.09%
The proposed SMR plant will have a rate of investment of 31.09% per year.
C. Demand Projections
Chart Title
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
2008 2010 2012 2014 2016 2018 2020
Pacific
Chart Title
3.5
2.5
1.5
0.5
0
2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029
demand
Supply Demand
Demand
D. Technical Catalogs
Compressor / Expander
Pump
Heat Exchanger
Reformers
Furnace
Separator
Absorber
Spherical Tank
E. Communication Letters
Batangas City
I, Arman Jade Lazarte, a 5th year Petroleum engineering student of Batangas State University,
together with my groupmates Jessa Mae Punzalan and Aniemhar Cuadrasal wants to have a short
interview with you in compliance with our ongoing plant design project.
The interview will be about our proposed location, which is Tabangao Batangas, regarding its
geographical location and viability, environmental constraints, waste management, land pricing,
and social issues.
In this regard, we would like to ask permission to go to your good office to conduct our interview.
Thank you.
Respectfully yours,