Capstone Design Project For Plant Design Steam Methane Reforming Plant

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CAPSTONE DESIGN PROJECT FOR PLANT DESIGN

STEAM METHANE REFORMING PLANT

A Project Proposal
Presented to the Faculty of
College of Engineering, Architecture and Fine Arts
Batangas State University
Main Campus II
Alangilan, Batangas City

In Partial Fulfillment

Of the Requirements for the Degree of

Bachelor of Science in Petroleum Engineering

By:

Cuadrasal, Aniemhar D.

Lazarte, Arman Jade S.

Punzalan, Jessa Mae B.

PetE-5201

April 2019
CHAPTER I

DESIGN BACKGROUND

Hydrogen is a chemical element with symbol H and atomic number 1.

With a standard atomic weight of 1.008, hydrogen is the lightest element in

the periodic table. Its monatomic form (H) is the most abundant chemical

substance in the Universe, constituting roughly 75% of all baryonic mass. At

standard temperature and pressure, hydrogen is a colorless, odorless,

tasteless, non-toxic, nonmetallic, highly combustible diatomic gas with the

molecular formula H2. Since hydrogen readily forms covalent compounds with

most nonmetallic elements, most of the hydrogen on Earth exists in molecular

forms such as water or organic compounds.

Steam reforming or steam methane reforming is a chemical synthesis

for producing syngas, hydrogen, carbon monoxide from hydrocarbon fuels

such as natural gas. This is achieved in a processing device called a reformer

which reacts steam at high temperature and pressure with methane in the

presence of a nickel catalyst. Steam-methane reforming reaction

CH4 + H2O (+ heat) → CO + 3H2

The steam methane reformer is widely used in industry to make

hydrogen. There is also interest in the development of much smaller units

based on similar technology to produce hydrogen as a feedstock for fuel cells.

Small-scale steam reforming units to supply fuel cells are currently the subject

of research and development, typically involving the reforming of methanol,


but other fuels are also being considered such as propane, gasoline, autogas,

diesel fuel, and ethanol

HYDROGEN MARKET

DEMAND

According to this research report, the global hydrogen market is

anticipated to grow at a robust rate to reach a significant value by the

end of the year of assessment. The hydrogen market has been

experiencing steady growth during the 2012-2016 timeline. It is

projected to grow at a value of 6.1% throughout the period of

assessment, to reach a market value of more than US$ 200 Bn by end

of 2025 from a market valuation of about US$ 130 Bn in 2017.

In the region category, Asia Pacific is expected to be the largest

with a high market attractiveness. This region is characterized by high

demand for hydrogen based fuel vehicles in counties such as Japan. In

addition, automotive manufacturers are planning to establish auto

fuelling stations in the region. These aspects are pushing the growth of

the hydrogen market in Asia Pacific. According to the analysis from the

research report, Asia Pacific is expected to hold more than one-third of

the total market share in the coming years. In 2017, the hydrogen

market in Asia Pacific was valued at about US$ 35 Bn and is estimated

to touch a valuation of more than US$ 70 Bn by the end of the year of

assessment. Moreover, hydrogen market in this region is projected to

grow at the highest rate during the period of forecast.


Figure 1. Global Hydrogen Market Value

The hydrogen market in Europe is the second largest. The

increasing adoption of hydrogen across various industries in Europe

has presented potential opportunities for the growth of the global

market. The hydrogen market in Europe is projected to grow at a value

CAGR of 6.4% throughout the period of assessment.

SUPPLY

The hydrogen generation market size was valued at USD 108.1

billion in 2016 and is predicted to exhibit a CAGR of 5.8% by 2025.

Shifting trends such as rising focus on cleaner energy and favorable

government regulations are encouraging market expansion. Stringent

government regulations to control rampant use of fossil fuels, coupled

with introduction of gas-based fuel cell vehicles, is anticipated to boost

demand for hydrogen over the forecast period.


Figure 2. U.S. Hydrogen Generation Market Size

Based on application, the hydrogen generation market can be

segregated into coal gasification and steam methane reforming. Coal

gasification is slated to be the fastest growing segment in terms of

revenue, with a CAGR of 6.8%.

Figure 3. Global Hydrogen Generation Market Share

Steam methane reforming holds a substantial share in the

application segment. This is among the most used hydrogen production

processes in U.S. In this method, methane containing raw materials

like natural gas is heated to a temperature between 700°C to 1,000°C


The global hydrogen generation market is highly competitive

with major vendors such as Air Liquide, Air Products and Chemicals,

Hydrogenics, Messer Group, and The Linde Group competing on the

basis of price, quality, and market presence.

Air Liquide

Air Liquide is engaged in offering gas services. These gas

services are offered to large industries, healthcare, electronics,

engineering, and construction. The company also acts as an industrial

merchant and offers its services in welding, diving, and in the global

market and technologies segment.

Air Products and Chemicals

Air Products and Chemicals serves its customers on a global

scale with a unique portfolio of products, solutions, and services that

include atmospheric gases, process and specialty gases, electronics

and performance materials, equipment, and services in sectors such as

energy, chemicals, electronics, metals, and manufacturing.

Hydrogenics

Hydrogenics is involved in manufacturing, building, and installing

industrial as well as commercial hydrogen generation, MW-scale

energy storage solutions, and fuel cells. The company is expertise in

hydrogen generation, fueling stations, hydrogen fuel cell vehicles, fuel

cell power generation, and power-to-gas technologies.

Messer Group
Messer Group offers industrial, medical, and specialty gases to

various industries. The company is engaged in the production of

industrial gases such as oxygen, argon, nitrogen, hydrogen, carbon

dioxide, helium, shielding gases for welding, medical gases, specialty

gases, and a wide variety of mixed gases.

The Linde Group

The Linde Group offers gas services to various industries. These

gas services include services to sectors such as healthcare and

engineering. The company also provides logistics services to its

customers. The Linde Group is engaged in the global hydrogen

generation market through its industrial gases product segment.

CH4 0.8532

CO2 0.0221

C2H6 0.0705

C3H8 0.0273

i-Butane 0.0055

n-Butane 0.0094

i-Pentan 0.0027

n-Pentan 0.0027

n-Hexane 0.0018

n-Heptane 0.0013

n-Octane 0.0004

N2 0.0004

Table X. Composition of Natural Gas


LOCATION

Figure 4. Proposed location for the Steam-Methane Reforming Plant

The proposed Steam Methane Reforming Plant will be located at

Brgy.Tabangao, Batangas. Several factors are considered for the selection of

the location such as suitability of land and climate, ease of access to

transport, ease of access of raw materials, and environmental and safety

requirements. An area estimate of thirteen (13) hectares is proposed.

Brgy. Tabangao Batangas is a highly industrialized area which houses

some of the biggest industries in the Philippines like Pilipinas Shell Petroleum

Corporation, Malampaya Onshore Gas Plant, and JG Summit Petrochemical

Corporation. It is easily accessible by road and the depth of sea nearby is

enough for vessels such as ships to dock.

Raw materials such as steam and natural gas can be easily acquired.

Steam can be produced by pumping seawater from the sea nearby while
natural gas can be acquired from Malampaya Onshore Gas Plant. Natural gas

can also be imported from other countries by shipping.

The proposed location also has a good distance from residential areas

which decreases the likelihood for disturbance from plant processes. In turn,

the plant can open numerous job opportunities for the residents nearby.

FUEL SOURCE

The fuel of the plant will come from the plant itself. Waste gases and

some natural gas from the supply will be used. Utilization of heat from the

process will be maximized to improve the plant’s efficiency and reduce its fuel

consumption and emission. The electrical energy requirement of the plant will

be provided by the National Grid Corporation of the Philippines (NGCP).


CHAPTER II

DESIGN OBJECTIVES AND REQUIREMENTS

The principal thrust of this project proposal is to design a Steam

Methane Reforming Plant.

Specifically, this study aims to meet the following objectives for the

proposed plant in order to come up with a feasible and economical project

design

1. To be able to construct three (3) design options following some of

the engineering standards and realistic constraints.

2. To gather data and information needed in relation to technical and

economical aspects that will justify the viability of the proposed

project.

3. To assign the proper technical design specifications for the

equipment of the three design options following standard

requirements.

4. To determine the capacity and efficiency of each of the plant by the

computation of the following:

4.1 Material Balance

4.2 Energy Balance

5. To present acceptable designs having processes that are capable

of operating under conditions which will yield a profit providing an

evaluation and computations of the economical expenditures:


5.1 Capital Expenditures

5.2 Operating Expenditures

5.3 Net Present Values

5.4 Rate of Return

5.5 Payback Period

6. To provide safety and loss prevention in the process designs under

the following:

6.1 Identification and assessment of the hazards;

6.2 Control of hazards;

6.3 Control of the processes; and

6.4 Limitations of the loss

7. To provide a construction management, project scheduling of

assembling each sections of the plant’s manufacturer’s site and the

sequence and arrangement of the major items of equipment given

on the process flow sheet.


CHAPTER III

TECHNICAL DESIGN AND REQUIREMENTS

This chapter presents the data and information as well as the

assumptions related to the technical aspects and requirements needed for the

design of the steam methane reforming plant. Standards were used to come

up with a technically viable design. Technical catalogues were used to

carefully identify the design specifications of each equipment.

DESIGN OPTION 1 (SMR)

A. Process Flow Diagram

Figure 5. Process Flow Diagram for Design Option 1

Design option 1 is a traditional steam reforming (SMR) with carbon

capture from the syngas stream. The heat required in the reactor is delivered

by a furnace burning the process tail gas as well as additional natural gas if

needed.
B. Design Specification of each Equipment

Gas Heated Reformer (GHR) (Pre-Reformer)

The principle of the pre-reformer is to convert heavier hydrocarbons to

methane prior to the main reforming reactor. The pre-reforming reactor usually

contains a nickel catalyst bed and is basically a low temperature adiabatic

steam reforming unit. The temperature is normally in the range from 350– 550

°C. There are several benefits to pre-reforming, but most important is the

enabling of process optimization of methane reforming. This results in lower

feed consumption and hence a smaller reactor size. A sophisticated pre-

reformer is the gas heated reformer (GHR), also referred to as a convective

reformer. What differentiate it from the traditional steam methane reforming

(SMR) are the temperature range and the method of heat transfer. Where the

SMR reactors are heated by external combustion of natural gas in a system of

reactor tubes and burners, the GHR works as a heat exchanger, absorbing

energy by convective heat transfer with another gas.

Figure 6. Gas Heated reformer

Table 1. Design Specification of GHR


Type Gibbs Reactor

Operating Temperature 700ºC

Operating Pressure 25 bar

Efficiency 100%

S/C Ratio: 0.25 Mole-H2O/Mole-C

Steam Methane Reformer (SMR)

A widely used method to produce hydrogen from natural gas (NG) is by

the use of steam methane reforming (SMR). The reaction is endothermic and

converts steam and methane into H2 and CO. The reaction is a catalytic

reaction supported by nickel- based catalysts. Nickel-based catalysts are cost

efficient and have sufficient activity. When more activity is needed, a more

noble catalyst can be used. Nobel catalysts provide higher activities and faster

reactions but are very expensive. The reactor consists of several reactor

tubes filled with reforming catalysts and kept in a furnace that provides the

necessary heat for the reaction to happen.


Figure 7. Steam Methane Reformer

Table 2. Design Specification of GHR

Type Gibbs Reactor

Operating Temperature 950ºC

Operating Pressure 24 bar

Efficiency 100%

S/C Ratio: 3 Mole-H2O/Mole-C

Water Gas Shift (WGS)

After the reforming process, the syngas undergoes a water gas shift,

where the CO is reacted with water, over a catalyst, to produce additional

hydrogen as well as CO2. The process is slightly exothermic and is

controlled by equilibrium.

The equilibrium constant is a function of temperature, meaning the

reaction is favourable at low temperatures. On the other hand, the reaction

rates diminish at low temperatures. Because of this the process is usually

done in two steps, a high temperature shift (HTS) and a low temperature shift

(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to

2-3%, with an inlet temperature between 350-550°C. In the LTS, the CO

concentration is further reduced to 0.2-0.4% at temperatures of 190-250. The

lower limit is set due to the water dew point of the gas. Condensation

could damage the catalysts in the WGS chamber.


Table 3. Design Specification of WGS

Type Equilibrium Reactor

High Temperature WGS

Operating Temperature 320

Operating Pressure 23 bar

Efficiency 100%

Low Temperature WGS

Operating Temperature 190

Operating Pressure 22.5 bar

Efficiency 100%

CO2 ABSORPER

After the WGS, hydrogen and CO2 are produced and have to be

separated and purified. Concepts for CO2 separation are presented in this

section. CO2 absorption is a commercially mature technology and is

commonly used to remove CO2 from NG [8]. The liquid solvent can be

divided into two groups, chemical and physical solvents. Chemical

solvents react with CO2 and require heat to activate the reaction. Chemical

solvents offer fast reaction rates which results in smaller plant size. Physical

solvents do not react but dissolve CO2 and require less heat than chemical

solvents. Chemical solvents have relatively high capacity at low pressure

compared to physical solvents and are therefore preferred at low CO2 partial

pressures. The chemical solvents will begin to saturate with increasing CO2
partial pressures and physical solvents are therefore preferred at high CO2

partial pressures. The CO2 recovery and purity will depend on the syngas

composition and various solvents may be optimal for CO2 separation. Studies

have shown that MDEA can capture as much as 95% of the CO2 with a purity

of above 99%.

Figure 8. CO2 Absorper

Table 4. Design Specification of CO2 Absorper

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 22 bar

CO2 Purity 99.999%

CO2 Recovery Rate 95% mole-basis

Pressure Swing Absorber (PSA)

Over 85% of current global hydrogen production units use PSA

technology for hydrogen purification and is the most used hydrogen

purification technology today. When PSA is used to purify hydrogen, the

syngas is sent through an adsorption column at high pressures letting through

hydrogen while adsorbing CO2 and other impurities. The pressure inside the

column is then lowered near atmospheric pressure desorbing impurities


from the adsorption material. There are usually several columns

operating simultaneous making the hydrogen purification process semi-

continuous. Columns with multiple adsorbents are normally used when

purifying hydrogen. Typical adsorbents are silica gel, alumina, activated

carbon and zeolite. Operating temperature in PSA units is typically ambient

temperature receiving the feed syngas at a pressure between 20-60 bar.

Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits

the unit with pressures between 1-2 bar. The PSA

unit produces hydrogen with a purity up to 99.9999% and with a hydrogen

recovery between 60-95%.

Figure 9. Pressure Swing Absorber

Table 5. Design Specification of Pressure Swing Absorber

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 20 bar

Pressure Tail Gas 2 bar


H2 Purity 99.999%

H2 Recovery Rate 90% mole-basis

COMPRESSOR

Air is drawn in and compressed when passing through rows of rotating

blades and stationary vanes. At the end of the compressor, before reaching

the combustion chamber, the air is compressed to a certain pressure and

temperature by compression.

The H-Series serves the requirements of many industries, from air

separation, chemical, petrochemical, process air etc. It is widely known and

accepted as an efficient, dependable and cost-effective compressor solution

that comes as a standard package but also fully engineered to API

specifications.

Figure 10. Compressor

Table 6. Design Specification of Compressor

Type Centrifugal

Inlet pressure 1 bar

Outlet Pressure 1.2 bar


Inlet Temperature 25ºC

WATER PUMP

The pumps are installed for the circulation of water for steam

generation.

Figure 11. Water Pump

Table 7. Design Specification of Water Pump

Type Water Pump

Inlet Pressure 1 bar

Outlet Pressure 25 bar

Capacity 20000 kg/h

Fluid temperature 25ºC

Motor 60 Hz
GAS EXPANDER

It is a centrifugal or axial-flow turbine, through which a high-

pressure gas is expanded to produce work that is often used to drive

a compressor or generator. Natural Gas is expanded to decrease it feed

pressure going to the pre-reformer.

Figure 12. Gas Expander

Table 8. Design Specification of Expander

Type Gas Expander

Inlet Pressure 50 bar

Outlet Pressure 25 bar

Capacity 15000 m3/h

Fluid temperature 50ºC


FURNACE

The furnace is as mentioned supplying the SMR with the

required heat by burning NG and the tail gas with air. The required air is

heated and supplied at a temperature of 335°C and a pressure of 1.2 bar

while the NG and tail gas is heated to a temperature of 500°C before entering

the furnace. Post combustion, the flue gas leaves the furnace at a

temperature of 1000°C and at atmospheric pressure. The flue gas is cooled

down to 100°C supplying heat to the reforming system.

Figure 13. Furnace

Table 9. Furnace

Type Gibbs Reactor

Operating Pressure 20 bar

Operating Temperature 1000ºC


C. Mass Balance and Energy Balance Computations

Table 10. Mass Balance Calculations for Design Option 1

MASS BALANCE CALCULATIONS


Equipment Diagram Efficiency Computation

S + NG = M1
Steam= 2,722 kg/hr
Steam
GHR M1 100%
NG NG= 9,903 kg/hr

M1= 12,625 kg/hr

M1 + Steam = M2
M1 M1=12,625 kg/hr
SMR M2 100% Steam= 26,818 kg/hr
Steam M2=39,443 kg/hr

M2 = M3 + H20
M2=39,443 kg/hr
M2 M3
WGS 100% M3=29,908 kg/hr
H20= 9,535 kg/hr
H20

M3 M4 M3 + CO2 = M4
CO2 M3=29,908 kg/hr
100%
Absorber CO2=23,450 kg/hr
CO2 M4= 6,458 kg/hr
M4 = H2 + M5
M4 M5 M4=6,458 kg/hr
PSA 100% H2=3,848 kg/hr
M5= 2,610 kg/hr
H2

M5 + A + NG = FG + W
M5 M5= 2,610 kg/hr
Air
Flue Gas Air=60,957 kg/hr
NG
Furnace 100% NG=2,199 kg/hr
Waste
Flue Gas= 65,766 kg/hr
Waste = 0 kg/hr

Table 11. Energy Balance Calculations for Design Option 1

ENERGY BALANCE PREHEATING WATER TO GHR AND SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr &26,818 kg/hr Q = mwaterCp water(t2-t1)
Cp water = 4.184 KJ/Kg K Q =( 2,722 + 26,818 Kg/hr )x 4.19 KJ/Kg K

T1 = 298.15 K
 (623.15K – 298.15K)


Q = 40,226,095 KJ/hr
T2 = 623.15 K


1ST WATER PUMP POWER OUTPUT GOING TO GHR


OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =2,722 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 6338721.4 KJ/hr
DeltaP= 23.897 bar
2nd WATER PUMP POWER OUTPUT GOING TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=26,818 kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =26,818 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 43442319.94 KJ/hr
DeltaP= 23.897 bar
ENERGY BALANCE PREHEATING STREAM TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr Q1 = mwaterCp water(t2-t1)
MNg=9,903kg/hr Q2 = mNGCp NG(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 2,722 Kg/hr)x 2.489 KJ/Kg K
Cp NG = 2.365 KJ/Kg K (673.15K – 623.15K) =338752.9 KJ/hr

T1w = 623.15 K
 Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K


(673.15K –323.15K) = 8197208.25
T1NG = 323.15 K

Qtotal= Q1 + Q2

T2 = 673.15 K
 Qtotal = 8535961.15 KJ/hr

ENERGY BALANCE PREHEATING STREAM TO SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=26,818kg/hr Q1 = mwaterCp water(t2-t1)
Mstream=12,625kg/hr Q2 = mstreamCstream(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 26,818 Kg/hr)x 2.489 KJ/Kg K
Cp stream = 2.365 KJ/Kg K (973.15K – 623.15K) =23362730.51 KJ/hr

T1w = 623.15 K
 Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K


(973.15K –973.15K) = 0 KJ/hr
T1stream = 973.15 K

Qtotal= Q1 + Q2

T2 = 973.15 K
 Qtotal = 23362730.51 KJ/hr

ENERGY BALANCE AT GHR


OPERATING CONDITIONS CALCULATIONS
Mstream=12,625kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 6.354 KJ/Kg K Q =( 12,625 Kg/hr)x 6.354 KJ/Kg K

T1stream = 623.15 K
 (923.15K – 623.15K)


Q= 24067165.74 KJ/hr
T2 = 923.15 K


ENERGY BALANCE AT SMR


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 13.391 KJ/Kg K

T1stream = 923.15 K
 (1223.15K – 923.15K)


Q= 132046176.4KJ/hr
T2 = 1223.15 K


ENERGY BALANCE COOLING OF SMR PRODUCT


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 2.896 KJ/Kg K

T1stream = 1223.15 K
 (593.15K – 1223.15K)


Q= - 71961379.68KJ/hr
T2 = 593.15 K


ENERGY BALANCE AT WATER GAS SHIFTER


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 6.043 KJ/Kg K

T1stream = 593.15 K
 (298.15K – 593.15K)


Q= - 70317498.06KJ/hr
T2 = 298.15 K


ENERGY BALANCE AT CO2 ABSORPTION


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 29,908 Kg/hr)x 13.927 KJ/Kg K

T1stream = 298.15 K
 (388.15K – 298.15K)


Q= 46896802.62 KJ/hr
T2 = 388.15 K


ENERGY BALANCE PREHEATING FURNACE INPUTS


OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q1 = mtailgasCp tailgas(t2-t1)
Mair=60,957kg/hr Q2 = mairCair(t2-t1)
MNG=2,199kg/hr Q3 = mNGCNG(t2-t1)

Cp tail gas = 3.41 KJ/Kg K Q1 =( 2,610 Kg/hr) x3.41 KJ/Kg K


Cp air = 1.0 KJ/Kg K (773.15K – 298.15K) =4233974.82 KJ/hr
Cp NG = 2.365 KJ/Kg K Q2 =( 60,957 Kg/hr)x 1.0 KJ/Kg K

T1tailgas = 298.15 K
 (608.15K –298.15K) = 18896670 KJ/hr


Q3 =( 2,199 Kg/hr)x 2.365KJ/Kg K
T1air = 298.15 K

(773.15K –323.15K) = 2340285 KJ/hr

T1NG = 323.15 K
 Qtotal= Q1 + Q2 + Q3


Qtotal = 25470929.82KJ/hr
T2tailgas = 298.15 K
T2air = 608.15 K

T2NG = 773.15 K
 
 


ENERGY BALANCE AT FURNACE


OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q= 132046176.4 KJ/hr
Mair=60,957kg/hr
MNG=2,199kg/hr

Tcombustion = 1273.15 K


ENERGY BALANCE AT COOLING THE FLUE GAS


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 65,766 Kg/hr)x 1.2869 KJ/Kg K

T1stream = 1273.15 K
 (1273.15.15K – 373.15K)


Q= 76172671.92 KJ/hr
T2 = 373.15 K

D. Plant Energy Efficiency

𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕

LHVH2 = 120 MJ/kg

mH2 =3848 kg/hr

LHVNG = 46.420 MJ/kg

mNG = 12,102 kg/hr

Wnet =0.37495 MW

1MJ/hr = .000277777778 MW

Solution:

𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟖𝟏𝟗𝟗
𝑴𝑱 𝒌𝒈 𝟎. 𝟑𝟕𝟒𝟓𝟗𝟓 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟐𝟏𝟎𝟐 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓
Figure 14. Plant Layout for Design Option 1
DESIGN OPTION 2 (SMR+)

A. Process Flow Diagram

Figure 15. Process Flow Diagram for Design Option 2

In order to further reduce the carbon emissions, the natural gas feed to

the furnace is replaced by produced hydrogen. Thus, the CO2 emissions per

produced hydrogen is further reduced by 60 percent. The carbon captured

accounts for 90 percent of the produced CO2, making SMR+ an interesting

carbon-lean solution.

As mentioned earlier, the concept of SMR+ is to replace the furnace

NG feed with produced hydrogen in order to reduce CO2 emissions. Thus,

the optimal SMR conditions are used in SMR+ as well. It is possible to

achieve higher energy efficiencies with SMR+, but that would result in

increased emissions and the concept would be pointless.


B. Design Specification of each Equipment

Gas Heated Reformer (GHR) (Pre-Reformer)

The principle of the pre-reformer is to convert heavier hydrocarbons to

methane prior to the main reforming reactor. The pre-reforming reactor usually

contains a nickel catalyst bed and is basically a low temperature adiabatic

steam reforming unit. The temperature is normally in the range from 350– 550

°C. There are several benefits to pre-reforming, but most important is the

enabling of process optimization of methane reforming. This results in lower

feed consumption and hence a smaller reactor size. A sophisticated pre-

reformer is the gas heated reformer (GHR), also referred to as a convective

reformer. What differentiate it from the traditional steam methane reforming

(SMR) are the temperature range and the method of heat transfer. Where the

SMR reactors are heated by external combustion of natural gas in a system of

reactor tubes and burners, the GHR works as a heat exchanger, absorbing

energy by convective heat transfer with another gas.

Figure 16. Gas Heated reformer

Table 12. Design Specification of GHR


Type Gibbs Reactor

Operating Temperature 700ºC

Operating Pressure 25 bar

Efficiency 100%

S/C Ratio: 0.25 Mole-H2O/Mole-C

Steam Methane Reformer (SMR)

A widely used method to produce hydrogen from natural gas (NG) is by

the use of steam methane reforming (SMR). The reaction is endothermic and

converts steam and methane into H2 and CO. The reaction is a catalytic

reaction supported by nickel- based catalysts. Nickel-based catalysts are cost

efficient and have sufficient activity. When more activity is needed, a more

noble catalyst can be used. Nobel catalysts provide higher activities and faster

reactions but are very expensive. The reactor consists of several reactor

tubes filled with reforming catalysts and kept in a furnace that provides the

necessary heat for the reaction to happen.


Figure 17. Steam Methane Reformer

Table 13. Design Specification of GHR

Type Gibbs Reactor

Operating Temperature 950ºC

Operating Pressure 24 bar

Efficiency 100%

S/C Ratio: 3 Mole-H2O/Mole-C

Water Gas Shift (WGS)

After the reforming process, the syngas undergoes a water gas shift,

where the CO is reacted with water, over a catalyst, to produce additional

hydrogen as well as CO2. The process is slightly exothermic and is

controlled by equilibrium.

The equilibrium constant is a function of temperature, meaning the

reaction is favourable at low temperatures. On the other hand, the reaction

rates diminish at low temperatures. Because of this the process is usually

done in two steps, a high temperature shift (HTS) and a low temperature shift

(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to

2-3%, with an inlet temperature between 350-550°C. In the LTS, the CO

concentration is further reduced to 0.2-0.4% at temperatures of 190-250. The

lower limit is set due to the water dew point of the gas. Condensation

could damage the catalysts in the WGS chamber.


Table 14. Design Specification of WGS

Type Equilibrium Reactor

High Temperature WGS

Operating Temperature 320

Operating Pressure 23 bar

Efficiency 100%

Low Temperature WGS

Operating Temperature 190

Operating Pressure 22.5 bar

Efficiency 100%

CO2 ABSORPER

After the WGS, hydrogen and CO2 are produced and have to be

separated and purified. Concepts for CO2 separation are presented in this

section. CO2 absorption is a commercially mature technology and is

commonly used to remove CO2 from NG [8]. The liquid solvent can be

divided into two groups, chemical and physical solvents. Chemical

solvents react with CO2 and require heat to activate the reaction. Chemical

solvents offer fast reaction rates which results in smaller plant size. Physical

solvents do not react but dissolve CO2 and require less heat than chemical

solvents. Chemical solvents have relatively high capacity at low pressure

compared to physical solvents and are therefore preferred at low CO2 partial

pressures. The chemical solvents will begin to saturate with increasing CO2
partial pressures and physical solvents are therefore preferred at high CO2

partial pressures. The CO2 recovery and purity will depend on the syngas

composition and various solvents may be optimal for CO2 separation. Studies

have shown that MDEA can capture as much as 95% of the CO2 with a purity

of above 99%.

Figure 18. CO2 Absorper

Table 15. Design Specification of CO2 Absorper

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 22 bar

CO2 Purity 99.999%

CO2 Recovery Rate 95% mole-basis

Pressure Swing Absorber (PSA)

Over 85% of current global hydrogen production units use PSA

technology for hydrogen purification and is the most used hydrogen

purification technology today. When PSA is used to purify hydrogen, the

syngas is sent through an adsorption column at high pressures letting through

hydrogen while adsorbing CO2 and other impurities. The pressure inside the

column is then lowered near atmospheric pressure desorbing impurities


from the adsorption material. There are usually several columns

operating simultaneous making the hydrogen purification process semi-

continuous. Columns with multiple adsorbents are normally used when

purifying hydrogen. Typical adsorbents are silica gel, alumina, activated

carbon and zeolite. Operating temperature in PSA units is typically ambient

temperature receiving the feed syngas at a pressure between 20-60 bar.

Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits

the unit with pressures between 1-2 bar. The PSA

unit produces hydrogen with a purity up to 99.9999% and with a hydrogen

recovery between 60-95%.

Figure 19. Pressure Swing Absorber

Table 16. Design Specification of Pressure Swing Absorber

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 20 bar

Pressure Tail Gas 2 bar


H2 Purity 99.999%

H2 Recovery Rate 90% mole-basis

COMPRESSOR

Air is drawn in and compressed when passing through rows of rotating

blades and stationary vanes. At the end of the compressor, before reaching

the combustion chamber, the air is compressed to a certain pressure and

temperature by compression.

The H-Series serves the requirements of many industries, from air

separation, chemical, petrochemical, process air etc. It is widely known and

accepted as an efficient, dependable and cost-effective compressor solution

that comes as a standard package but also fully engineered to API

specifications.

Figure 20. Compressor

Table 17. Design Specification of Compressor

Type Centrifugal

Inlet pressure 1 bar

Outlet Pressure 1.2 bar


Inlet Temperature 25ºC

WATER PUMP

The pumps are installed for the circulation of water for steam

generation.

Figure 21. Water Pump

Table 18. Design Specification of Water Pump

Type Water Pump

Inlet Pressure 1 bar

Outlet Pressure 25 bar

Capacity 20000 kg/h

Fluid temperature 25ºC

Motor 60 Hz
GAS EXPANDER

It is a centrifugal or axial-flow turbine, through which a high-

pressure gas is expanded to produce work that is often used to drive

a compressor or generator. Natural Gas is expanded to decrease it feed

pressure going to the pre-reformer.

Figure 22. Gas Expander

Table 19. Design Specification of Expander

Type Gas Expander

Inlet Pressure 50 bar

Outlet Pressure 25 bar

Capacity 15000 m3/h

Fluid temperature 50ºC


FURNACE

The furnace is as mentioned supplying the SMR with the

required heat by burning NG and the tail gas with air. The required air is

heated and supplied at a temperature of 335°C and a pressure of 1.2 bar

while the NG and tail gas is heated to a temperature of 500°C before entering

the furnace. Post combustion, the flue gas leaves the furnace at a

temperature of 1000°C and at atmospheric pressure. The flue gas is cooled

down to 100°C supplying heat to the reforming system.

Figure 23. Furnace

Table 20. Furnace

Type Gibbs Reactor

Operating Pressure 20 bar

Operating Temperature 1000ºC


C. Mass Balance and Energy Balance Computations

Table 21. Mass Balance Calculations for Design Option 2

MASS BALANCE CALCULATIONS


Equipment Diagram Efficiency Computation

S + NG = M1
Steam
Steam= 3,498 kg/hr
GHR M1 100%
NG NG= 12,719 kg/hr
M1= 16,217 kg/hr

M1 + Steam = M2
M1 M1=16,217 kg/hr
SMR M2 100% Steam= 34,444 kg/hr
Steam M2=50,661 kg/hr

M2 = M3 + H20
M2=50,661 kg/hr
M2 M3
WGS 100% M3=37,316 kg/hr
H20= 13,345 kg/hr
H20

M3 M4 M3 + CO2 = M4
CO2 M3=37,316 kg/hr
100%
Absorber CO2=30,115 kg/hr
CO2 M4= 7,201 kg/hr

M4 = H2 + M5
M4=7,201kg/hr
M4 M5
PSA 100% H2=3,848 kg/hr
M5= 3,353 kg/hr
H2
M5 + A + NG = FG + W
M5 M5= 3,353kg/hr
Air
Flue Gas Air=71,231kg/hr
H2
Furnace 100% H2=1,094 kg/hr
Waste
Flue Gas= 75678 kg/hr
Waste = 0 kg/hr

Table 22. Energy Balance Calculations for Design Option 2

ENERGY BALANCE PREHEATING WATER TO GHR AND SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=3,498kg/hr &34,444 kg/hr Q = mwaterCp water(t2-t1)
Cp water = 4.184 KJ/Kg K Q =( 37942 Kg/hr )x 4.19 KJ/Kg K

T1 = 298.15 K
 (623.15K – 298.15K)


Q = 51,667,518 KJ/hr
T2 = 623.15 K


1ST WATER PUMP POWER OUTPUT GOING TO GHR


OPERATING CONDITIONS CALCULATIONS
Mwater=3,498kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =3,498 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 8145792.6 KJ/hr
DeltaP= 23.897 bar
2nd WATER PUMP POWER OUTPUT GOING TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=34,444 kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =34,444 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 80209742.8 KJ/hr
DeltaP= 23.897 bar
ENERGY BALANCE PREHEATING STREAM TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr Q1 = mwaterCp water(t2-t1)
MNg=9,903kg/hr Q2 = mNGCp NG(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 2,722 Kg/hr)x 2.489 KJ/Kg K
Cp NG = 2.365 KJ/Kg K (673.15K – 623.15K) =338752.9 KJ/hr
Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K
T1w = 623.15 K
 (673.15K –323.15K) = 8197208.25
Qtotal= Q1 + Q2
T1NG = 323.15 K

Qtotal = 8535961.15 KJ/hr

T2 = 673.15 K


ENERGY BALANCE PREHEATING STREAM TO SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=26,818kg/hr Q1 = mwaterCp water(t2-t1)
Mstream=12,625kg/hr Q2 = mstreamCstream(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 26,818 Kg/hr)x 2.489 KJ/Kg K
Cp stream = 2.365 KJ/Kg K (973.15K – 623.15K) =23362730.51 KJ/hr

T1w = 623.15 K
 Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K


(973.15K –973.15K) = 0 KJ/hr
T1stream = 973.15 K

Qtotal= Q1 + Q2

T2 = 973.15 K
 Qtotal = 23362730.51 KJ/hr

ENERGY BALANCE AT GHR


OPERATING CONDITIONS CALCULATIONS
Mstream=12,625kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 6.354 KJ/Kg K Q =( 12,625 Kg/hr)x 6.354 KJ/Kg K

T1stream = 623.15 K
 (923.15K – 623.15K)


Q= 30901280.34 KJ/hr
T2 = 923.15 K


ENERGY BALANCE AT SMR


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 13.391 KJ/Kg K

T1stream = 923.15 K
 (1223.15K – 923.15K)


Q= 176560274.2 KJ/hr
T2 = 1223.15 K


ENERGY BALANCE COOLING OF SMR PRODUCT


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 2.896 KJ/Kg K
T1stream = 1223.15 K
 (593.15K – 1223.15K)
Q= - 92426782.32 KJ/hr
T2 = 593.15 K


ENERGY BALANCE AT WATER GAS SHIFTER


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 6.043 KJ/Kg K

T1stream = 593.15 K
 (298.15K – 593.15K)


Q= - 70317498.06KJ/hr
T2 = 298.15 K


ENERGY BALANCE AT CO2 ABSORPTION


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 29,908 Kg/hr)x 13.927 KJ/Kg K

T1stream = 298.15 K
 (388.15K – 298.15K)


Q= 90321136.2 KJ/hr
T2 = 388.15 K


ENERGY BALANCE PREHEATING FURNACE INPUTS


OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q1 = mtailgasCp tailgas(t2-t1)
Mair=60,957kg/hr Q2 = mairCair(t2-t1)
MNG=2,199kg/hr Q3 = mNGCNG(t2-t1)

Cp tail gas = 3.41 KJ/Kg K Q1 =( 2,610 Kg/hr) x3.41 KJ/Kg K


Cp air = 1.0 KJ/Kg K (773.15K – 298.15K) =4233974.82 KJ/hr
Cp NG = 2.365 KJ/Kg K Q2 =( 60,957 Kg/hr)x 1.0 KJ/Kg K

T1tailgas = 298.15 K
 (608.15K –298.15K) = 18896670 KJ/hr


Q3 =( 2,199 Kg/hr)x 2.365KJ/Kg K
T1air = 298.15 K

(773.15K –323.15K) = 2340285 KJ/hr

T1NG = 323.15 K
 Qtotal= Q1 + Q2 + Q3


Qtotal = 34355278.82KJ/hr
T2tailgas = 298.15 K
T2air = 608.15 K
T2NG = 773.15 K
 
 


ENERGY BALANCE AT FURNACE


OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q= 176560274.2 KJ/hr
Mair=60,957kg/hr
MNG=2,199kg/hr

Tcombustion = 1273.15 K


ENERGY BALANCE AT COOLING THE FLUE GAS


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 65,766 Kg/hr)x 1.2869 KJ/Kg K

T1stream = 1273.15 K
 (1273.15.15K – 373.15K)


Q= 92703841.02 KJ/hr
T2 = 373.15 K


D. Plant Energy Efficiency

𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕

LHVH2 = 120 MJ/kg

mH2 =3848 kg/hr

LHVNG = 46.420 MJ/kg

mNG = 12,719kg/hr

Wnet =0.4248 MW

1MJ/hr = .000277777778 MW

Solution:
𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟕𝟖𝟎
𝑴𝑱 𝒌𝒈 𝟎. 𝟒𝟐𝟒𝟖 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟐𝟕𝟏𝟗 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓

Figure 24. Plant Layout for Design Option 2


DESIGN OPTION 3

A. Process Flow Diagram (ATR)

Figure 25. Process Flow Diagram for Design Option 3

ATR is a combination of non-catalytic POX and SMR. NG is partially

oxidised in a combustion zone, while steam is injected in a SMR zone. Hence,

both the POX and the SMR reactions are active simultaneously. This concept

also need pure oxygen input as well as a catalyst bed in the steam reforming

section of the reactor. The core benefits of this system is that the heat

generated by the POX reaction is consumed by the endothermic SMR

reaction.

B. Design Specification of each Equipment

Gas Heated Reformer (GHR) (Pre-Reformer)


The principle of the pre-reformer is to convert heavier hydrocarbons to

methane prior to the main reforming reactor. The pre-reforming reactor usually

contains a nickel catalyst bed and is basically a low temperature adiabatic

steam reforming unit. The temperature is normally in the range from 350– 550

°C. There are several benefits to pre-reforming, but most important is the

enabling of process optimization of methane reforming. This results in lower

feed consumption and hence a smaller reactor size. A sophisticated pre-

reformer is the gas heated reformer (GHR), also referred to as a convective

reformer. What differentiate it from the traditional steam methane reforming

(SMR) are the temperature range and the method of heat transfer. Where the

SMR reactors are heated by external combustion of natural gas in a system of

reactor tubes and burners, the GHR works as a heat exchanger, absorbing

energy by convective heat transfer with another gas.

Figure 26. Gas Heated reformer

Table 23. Design Specification of GHR

Type Gibbs Reactor

Operating Temperature 700ºC


Operating Pressure 25 bar

Efficiency 100%

S/C Ratio: 0.25 Mole-H2O/Mole-C

AUTOTHERMAL REFORMER (ATR)

A widely used method to produce hydrogen from natural gas (NG) is by

The ATR reactors usually operate at temperatures between 900-1150 °C, with

pressure levels in the range 1 to 80 bar existing today. Figure below shows

the principles of the ATR reactor, with the different inputs and reaction zones.

No specific range was found for the typical energy efficiency of ATR, but it

should operate with lower energy efficiency than SMR.

Figure 26. ATR Reactor

Table 24. Design Specification of ATR Reactor

Type Gibbs Reactor

Operating Temperature 1020ºC

Operating Pressure 24 bar


Efficiency 100%

S/C Ratio: 1.5 Mole-H2O/Mole-C

Water Gas Shift (WGS)

After the reforming process, the syngas undergoes a water gas shift,

where the CO is reacted with water, over a catalyst, to produce additional

hydrogen as well as CO2. The process is slightly exothermic and is

controlled by equilibrium.

The equilibrium constant is a function of temperature, meaning the

reaction is favourable at low temperatures. On the other hand, the reaction

rates diminish at low temperatures. Because of this the process is usually

done in two steps, a high temperature shift (HTS) and a low temperature shift

(LTS). In the HTS, the mole fraction of CO is reduced from typically 10-13% to

2-3%, with an inlet temperature between 350-550°C. In the LTS, the CO

concentration is further reduced to 0.2-0.4% at temperatures of 190-250. The

lower limit is set due to the water dew point of the gas. Condensation

could damage the catalysts in the WGS chamber.

Table 25. Design Specification of WGS

Type Equilibrium Reactor

High Temperature WGS

Operating Temperature 320

Operating Pressure 23 bar


Efficiency 100%

Low Temperature WGS

Operating Temperature 190

Operating Pressure 22.5 bar

Efficiency 100%

CO2 ABSORPER

After the WGS, hydrogen and CO2 are produced and have to be

separated and purified. Concepts for CO2 separation are presented in this

section. CO2 absorption is a commercially mature technology and is

commonly used to remove CO2 from NG [8]. The liquid solvent can be

divided into two groups, chemical and physical solvents. Chemical

solvents react with CO2 and require heat to activate the reaction. Chemical

solvents offer fast reaction rates which results in smaller plant size. Physical

solvents do not react but dissolve CO2 and require less heat than chemical

solvents. Chemical solvents have relatively high capacity at low pressure

compared to physical solvents and are therefore preferred at low CO2 partial

pressures. The chemical solvents will begin to saturate with increasing CO2

partial pressures and physical solvents are therefore preferred at high CO2

partial pressures. The CO2 recovery and purity will depend on the syngas

composition and various solvents may be optimal for CO2 separation. Studies

have shown that MDEA can capture as much as 95% of the CO2 with a purity

of above 99%.
Figure 27. CO2 Absorper

Table 26. Design Specification of CO2 Absorper

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 22 bar

CO2 Purity 99.999%

CO2 Recovery Rate 95% mole-basis

2 Pressure Swing Absorber (PSA)

Over 85% of current global hydrogen production units use PSA

technology for hydrogen purification and is the most used hydrogen

purification technology today. When PSA is used to purify hydrogen, the

syngas is sent through an adsorption column at high pressures letting through

hydrogen while adsorbing CO2 and other impurities. The pressure inside the

column is then lowered near atmospheric pressure desorbing impurities

from the adsorption material. There are usually several columns

operating simultaneous making the hydrogen purification process semi-

continuous. Columns with multiple adsorbents are normally used when

purifying hydrogen. Typical adsorbents are silica gel, alumina, activated

carbon and zeolite. Operating temperature in PSA units is typically ambient


temperature receiving the feed syngas at a pressure between 20-60 bar.

Hydrogen is purified with a pressure drop between 1-2 bar. The off-gas exits

the unit with pressures between 1-2 bar. The PSA

unit produces hydrogen with a purity up to 99.9999% and with a hydrogen

recovery between 60-95%.

Figure 28. 2 Pressure Swing Absorber

Table 27. Design Specification of 2 Pressure Swing Absorber

Type Component Splitter

Operating Temperature 25ºC

Operating Pressure 20 bar

Pressure Tail Gas 2 bar

H2 Purity 99.999%

H2 Recovery Rate 90% mole-basis

COMPRESSOR
Air is drawn in and compressed when passing through rows of rotating

blades and stationary vanes. At the end of the compressor, before reaching

the combustion chamber, the air is compressed to a certain pressure and

temperature by compression.

The H-Series serves the requirements of many industries, from air

separation, chemical, petrochemical, process air etc. It is widely known and

accepted as an efficient, dependable and cost-effective compressor solution

that comes as a standard package but also fully engineered to API

specifications.

Figure 29. Compressor

Table 28. Design Specification of Compressor

Type Centrifugal

Inlet pressure 1 bar

Outlet Pressure 1.2 bar

Inlet Temperature 25ºC

WATER PUMP
The pumps are installed for the circulation of water for steam

generation.

Figure 30. Water Pump

Table 29. Design Specification of Water Pump

Type Water Pump

Inlet Pressure 1 bar

Outlet Pressure 25 bar

Capacity 20000 kg/h

Fluid temperature 25ºC

Motor 60 Hz
GAS EXPANDER

It is a centrifugal or axial-flow turbine, through which a high-

pressure gas is expanded to produce work that is often used to drive

a compressor or generator. Natural Gas is expanded to decrease it feed

pressure going to the pre-reformer.

Figure 31. Gas Expander

Table 30. Design Specification of Expander

Type Gas Expander

Inlet Pressure 50 bar

Outlet Pressure 25 bar

Capacity 15000 m3/h

Fluid temperature 50ºC


FURNACE

The furnace is as mentioned supplying the SMR with the required

heat by burning NG and the tail gas with air. The required air is heated and

supplied at a temperature of 335°C and a pressure of 1.2 bar while the NG and

tail gas is heated to a temperature of 500°C before entering the furnace. Post

combustion, the flue gas leaves the furnace at a temperature of 1000°C and at

atmospheric pressure. The flue gas is cooled down to 100°C supplying heat to

the reforming system.

Figure 32. Furnace

Table 31. Furnace

Type Gibbs Reactor

Operating Pressure 20 bar

Operating Temperature 1000ºC


C. Mass Balance and Energy Balance Computations

Table 32. Mass Balance Calculations for Design Option 1

MASS BALANCE CALCULATIONS


Equipment Diagram Efficiency Computation

S + NG = M1
Steam
Steam= 3,241 kg/hr
GHR M1 100%
NG NG= 11,787 kg/hr
M1= 15,028 kg/hr

M1 + Steam + O2 = M2
M1=15,028 kg/hr
M1 O2=11,822 kg/hr
ATR O2 M2 100%
Steam Steam= 15,449 kg/hr
M2= 42,299 kg/hr

M2 + Steam = M3 + H20
Steam
Steam=1,159 kg/hr
M2 M3 M2=42,299 kg/hr
WGS 100%
M3=37,768 kg/hr
H20 H20= 5,690 kg/hr

M3 M4 M3 = M4 + CO2
CO2 M3=37,768 kg/hr
100%
Absorber CO2=31,816 kg/hr
CO2 M4=5,952 kg/hr
M4 = H2 + M5
M4 M5 M4=5,952 kg/hr
PSA1 100% H2=3,498 kg/hr
M5= 2,454 kg/hr
H2

M5 = H2 + M6
M5 M6 M5=2,454 kg/hr
PSA2 100% H2=350 kg/hr
M6= 2,104 kg/hr
H2

M6 + A = FG + W
M6
M6= 2,104kg/hr
Flue Gas
Air Air=4830/hr
Furnace 100%
Flue Gas= 6934 kg/hr
Waste Waste = 0 kg/hr

Table 33. Energy Balance Calculations for Design Option 3

ENERGY BALANCE PREHEATING WATER TO GHR AND SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr &26,818 kg/hr Q = mwaterCp water(t2-t1)
Cp water = 4.184 KJ/Kg K Q =( 2,722 + 26,818 Kg/hr )x 4.19 KJ/Kg K

T1 = 298.15 K
 (623.15K – 298.15K)


Q = 60417267.18 KJ/hr
T2 = 623.15 K


1ST WATER PUMP POWER OUTPUT GOING TO GHR


OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =2,722 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 6338721.4 KJ/hr
DeltaP= 23.897 bar
2nd WATER PUMP POWER OUTPUT GOING TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=26,818 kg/hr Q = MD deltaP
Dwater = 1 kg/m3 Q =26,818 kg/hr x1 kg/m3 x (23.287x 100)KPa
Pump effciency = 100 % Q = 43442319.94 KJ/hr
DeltaP= 23.897 bar
ENERGY BALANCE PREHEATING STREAM TO GHR
OPERATING CONDITIONS CALCULATIONS
Mwater=2,722kg/hr Q1 = mwaterCp water(t2-t1)
MNg=9,903kg/hr Q2 = mNGCp NG(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 2,722 Kg/hr)x 2.489 KJ/Kg K
Cp NG = 2.365 KJ/Kg K (673.15K – 623.15K) =338752.9 KJ/hr

T1w = 623.15 K
 Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K


(673.15K –323.15K) = 8197208.25
T1NG = 323.15 K

Qtotal= Q1 + Q2

T2 = 673.15 K
 Qtotal = 12837053.1 KJ/hr

ENERGY BALANCE PREHEATING STREAM TO SMR


OPERATING CONDITIONS CALCULATIONS
Mwater=26,818kg/hr Q1 = mwaterCp water(t2-t1)
Mstream=12,625kg/hr Q2 = mstreamCstream(t2-t1)
Cp water = 4.184 KJ/Kg K Q1 =( 26,818 Kg/hr)x 2.489 KJ/Kg K
Cp stream = 2.365 KJ/Kg K (973.15K – 623.15K) =23362730.51 KJ/hr

T1w = 623.15 K
 Q2 =( 9,903 Kg/hr)x 2.365KJ/Kg K


(973.15K –973.15K) = 0 KJ/hr
T1stream = 973.15 K

Qtotal= Q1 + Q2

T2 = 973.15 K
 Qtotal = 23362730.51 KJ/hr

ENERGY BALANCE AT GHR


OPERATING CONDITIONS CALCULATIONS
Mstream=12,625kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 6.354 KJ/Kg K Q =( 12,625 Kg/hr)x 6.354 KJ/Kg K
T1stream = 623.15 K
 (923.15K – 623.15K)
Q= 28721751.9 KJ/hr
T2 = 923.15 K


ENERGY BALANCE AT SMR


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 13.391 KJ/Kg K

T1stream = 923.15 K
 (1223.15K – 923.15K)


Q= 132046176.4KJ/hr
T2 = 1223.15 K


ENERGY BALANCE COOLING OF ATR PRODUCT


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 2.896 KJ/Kg K

T1stream = 1223.15 K
 (593.15K – 1223.15K)


Q= - 75396907.56KJ/hr
T2 = 593.15 K


ENERGY BALANCE AT WATER GAS SHIFTER


OPERATING CONDITIONS CALCULATIONS
Mstream=39,443 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 39443 Kg/hr)x 6.043 KJ/Kg K

T1stream = 593.15 K
 (298.15K – 593.15K)


Q= - 69892674.72KJ/hr
T2 = 298.15 K


ENERGY BALANCE AT CO2 ABSORPTION


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 29,908 Kg/hr)x 13.927 KJ/Kg K

T1stream = 298.15 K
 (388.15K – 298.15K)


Q= 587364.444 KJ/hr
T2 = 388.15 K

ENERGY BALANCE PREHEATING FURNACE INPUTS
OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q1 = mtailgasCp tailgas(t2-t1)
Mair=60,957kg/hr Q2 = mairCair(t2-t1)
MNG=2,199kg/hr Q3 = mNGCNG(t2-t1)

Cp tail gas = 3.41 KJ/Kg K Q1 =( 2,610 Kg/hr) x3.41 KJ/Kg K


Cp air = 1.0 KJ/Kg K (773.15K – 298.15K) =4233974.82 KJ/hr
Cp NG = 2.365 KJ/Kg K Q2 =( 60,957 Kg/hr)x 1.0 KJ/Kg K

T1tailgas = 298.15 K
 (608.15K –298.15K) = 18896670 KJ/hr


Q3 =( 2,199 Kg/hr)x 2.365KJ/Kg K
T1air = 298.15 K

(773.15K –323.15K) = 2340285 KJ/hr

T1NG = 323.15 K
 Qtotal= Q1 + Q2 + Q3


Qtotal = 3269292.66 KJ/hr
T2tailgas = 298.15 K
T2air = 608.15 K

T2NG = 773.15 K
 
 


ENERGY BALANCE AT TAIL GAS


OPERATING CONDITIONS CALCULATIONS
Mtailgas=2,610kg/hr Q= 18119638.984 KJ/hr
Mair=60,957kg/hr
MNG=2,199kg/hr

Tcombustion = 1273.15 K


ENERGY BALANCE AT COOLING THE FLUE GAS


OPERATING CONDITIONS CALCULATIONS
Mstream=29,908 kg/hr Q = mstreamCstream(t2-t1)
Cp stream = 13.391 KJ/Kg K Q =( 65,766 Kg/hr)x 1.2869 KJ/Kg K

T1stream = 1273.15 K
 (1273.15.15K – 373.15K)


Q= 18119638.98 KJ/hr
T2 = 373.15 K


D. Plant Energy Efficiency

𝑳𝑯𝑽𝑯𝟐 ∗ 𝒎𝑯𝟐
𝜼=
(𝑳𝑯𝑽𝑵𝑮 ∗ 𝒎𝑵𝑮 ) + 𝑾𝒏𝒆𝒕

LHVH2 = 120 MJ/kg

mH2 =3848 kg/hr

LHVNG = 46.420 MJ/kg

mNG = 11,787 kg/hr

Wnet = 5.0055 MW

1MJ/hr = .000277777778 MW

Solution:

𝑴𝑱 𝒌𝒈
𝟏𝟐𝟎 ∗ 𝟑𝟖𝟒𝟖
𝒌𝒈 𝒉𝒓
= 𝟎. 𝟖𝟏𝟕
𝑴𝑱 𝒌𝒈 𝟓. 𝟎𝟎𝟓 𝑴𝑱
𝟒𝟔. 𝟒𝟐𝟎 ∗ 𝟏𝟏𝟕𝟖𝟕 +
𝒉𝒓 𝒉𝒓 𝟎. 𝟎𝟎𝟎𝟐𝟕𝟕𝟕𝟕𝟕𝟕𝟕𝟖 𝒉𝒓
Figure 33. Plant Layout for Design Option 3
CHAPTER IV

ECONOMIC STUDY AND ANALYSIS

An economic study and analysis is necessary to support a potential

investment decision. The improved efficiency of the operation is often related to

increased investment cost and higher expenditure cost. The main objective of

this chapter is to establish the viability of each design option by performing

calculations such as capital expenditures (CAPEX), operating expenditures

(OPEX), and economic indicators such as net present value, payback period,

and rate of investment. A sensitivity analysis will also be done to highlight how

the individual systems are affected by variations in feedstock cost, financial

market situations, and facility design.

A. Price Target of Hydrogen Produced in the Philippines

This study aims to provide the cost of producing Hydrogen in the

Philippines. In this sub-chapter, the price at which the produced hydrogen will be

cost competitive will be determined.

According to the analysis made by V. Atland and D. Jakobsken, it was

estimated that the costs of liquefaction, storage, and transportation would be in

the range from 52.2 ₱/kgH2 of hydrogen produced to 112.4 ₱/kgH2 in 2030

(adjusted to exchange rate as of 22/02/19). The market analysis made by the

same study concluded that a marginal cost of 118.3 – 236.5 ₱/kgH2 is what to be

the expected cost in the current market. Hence, based on then conservative
liquefaction, storage, and transportation costs, a production price below 124.1

₱/kgH2 is necessary in order be competitive in a large-scale market.

B. Historical Demand for Hydrogen

The data presented below is the historical demand of Hydrogen for

Southeast Asia in tons from 2005 to 2015.

Table 34. Historical Demand of Hydrogen in Asia Pacific

(Navigant Research)

Year Net Weight (MMT)

2005 0.18

2006 0.26

2007 0.33

2008 0.51

2009 0.65

2010 0.81

2011 1.01

2012 1.13

2013 1.48

2014 1.56
Chart Title
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
2008 2010 2012 2014 2016 2018 2020

Figure 34. Graphical representation of Hydrogen demand in Asia

Pacific

The demand for Hydrogen is consistently increasing annually. This is due

to the improvements in Fuel Cell Technology which paves the way to various

markets.

The supply for Hydrogen keeps on increasing annually. Technological

advancements in Steam Reforming Technology and increasing demand for

energy had contributed for the upward trend.

C. Future Demand for Hydrogen

Arithmetic straight-line method will be used to project the annual demands

for the future. Arithmetic straight-line method assumes that the annual increase

in the future will remain constant.

Formula:
𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1

Where:

𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1

Yc = initial value, Yn = final value, Yi = value for the year past, N = number

of years

5.5.6 Projected Demand for Hydrogen

1.56 − 0.18
𝑎=
10 − 1

𝑎 = 0.1533

Table 35. Projected values for Hydrogen demand

Year (Yi) a Yc: (Yi-1+a)

2015 0.1533 1.7133

2016 0.1533 1.8666

2017 0.1533 2.0199

2018 0.1533 2.1732

2019 0.1533 2.3265

2020 0.1533 2.4798

2021 0.1533 2.6331

2022 0.1533 2.7864


2023 0.1533 2.9397

2024 0.1533 3.093

Chart Title
3.5

2.5

1.5

0.5

0
2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029

Figure 35. Graphical representation of the projected Hydrogen

demand

The demand, as calculated, keeps an upward slope. Increasing

demand for Hydrogen is estimated to reach 3.093 million metric tons in

2028.

E. Historical Production of Hydrogen


The data presented below is the historical production of Hydrogen for

Southeast Asia in tons from 2005 to 2015.

The data presented below is the historical demand of Hydrogen for

Southeast Asia in tons from 2005 to 2015.

Table 36. Historical Production of Hydrogen in Asia Pacific

(Navigant Research)

Year Net Weight (MMT)

2009 0.17

2010 0.25

2011 0.31

2012 0.48

2013 0.63

2014 0.75

2015 0.98

2016 1.12

2017 1.25

2018 1.48
Chart Title
1.6

1.4

1.2

0.8

0.6

0.4

0.2

0
2008 2010 2012 2014 2016 2018 2020

Figure 36. Graphical representation of Hydrogen Production in Asia

Pacific

The supply for Hydrogen keeps on increasing annually. Technological

advancements in Steam Reforming Technology and increasing demand for

energy had contributed for the upward trend.

F. Future Production of Hydrogen

Arithmetic straight-line method will be used to project the annual demands

for the future. Arithmetic straight-line method assumes that the annual increase

in the future will remain constant.

Formula:

𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1

Where:
𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1

Yc = initial value, Yn = final value, Yi = value for the year past, N = number

of years

Table 37. Projected values for Hydrogen production

Year (Yi) a Yc: (Yi-1+a)

2019 0.1456 1.6256

2020 0.1456 1.7712

2021 0.1456 1.9168

2022 0.1456 2.0624

2023 0.1456 2.208

2024 0.1456 2.3536

2025 0.1456 2.4992

2026 0.1456 2.6448

2027 0.1456 2.7904

2028 0.1456 2.936


Chart Title
3.5

2.5

1.5

0.5

0
2018 2020 2022 2024 2026 2028 2030

Figure 37. Graphical representation of the projected Hydrogen production

The production, as calculated, keeps an upward slope. Increasing

production for Hydrogen is estimated to reach 2.936 million metric tons in

2028.

G. Rated Plant Capacity

Rated plant capacity will be determined by using the calculated future

demand and supply for Hydrogen.

Table 38. Basis for market share projection

Unsatisfied
Year Demand, MMT Supply, MMT
Demand

2019 1.7133 1.6256 0.0877


2020 1.8666 1.7712 0.0954

2021 2.0199 1.9168 0.1031

2022 2.1732 2.0624 0.1092

2023 2.3265 2.208 0.1185

2024 2.4798 2.3536 0.1262

2025 2.6331 2.4992 0.1339

2026 2.7864 2.6448 0.1416

2027 2.9397 2.7904 0.1493

2028 3.093 2.936 0.157

Projected Supply and Demand


3.5
3
2.5
2
1.5
1
0.5
0
2018 2020 2022 2024 2026 2028 2030

Supply Demand

Figure 38. Graphical representation of the projected Hydrogen Supply and

Demand
Based on the projected annual unsatisfied demand, the proposed plant

will assume a 20% market share in year 2028 where the biggest unsatisfied

demand exists.

Plant Capacity = 0.2*0.157

Plant Capacity = 31400 MT per year or 92.3529 tons per day

Table 39. Production plan schedule for Hydrogen

Unsatisfied Daily Annual

Year Demand, Production, Production,

MMT Tons per day Tons per year

2019 0.0877 - -

2020 0.0954 - -

2021 0.1031 - -

2022 0.1092 - -

2023 0.1185 92.3529 31400

2024 0.1262 92.3529 31400

2025 0.1339 92.3529 31400

2026 0.1416 92.3529 31400

2027 0.1493 92.3529 31400


2028 0.157 92.3529 31400

The proposed plant will be constructed in 2020 until 2022. The plant will

be operational by the year 2023 and thus start the production. The plant will be

operating 345 days a year. The 20-day allotment is for plant shutdown for regular

maintenance to ensure the efficiency and the overall safety of the plant.

H. Fixed Capital Investment

Manufacturing fixed-capital investment represents the capital necessary

for the installed process equipment with all auxiliaries that are needed for

complete process operation. Expenses for piping, instruments, insulation,

foundations, and site preparation are typical examples of costs included in the

manufacturing fixed-capital investment.

Fixed capital required for construction overhead and for all plant

components that are not directly related to the process operation is designated

as the nonmanufacturing fixed-capital investment. These plant components

include the land, processing buildings, administrative, and other offices,

warehouses, laboratories transportation, shipping, and receiving facilities, utility

and waste-disposal facilities, shops, and other permanent parts of the plant. The

construction cost consists of field-office and supervision expenses, home-office

expenses, engineering expenses, miscellaneous construction costs, contractor’s

fees, and contingencies. In some cases, construction overhead is proportioned

between manufacturing and nonmanufacturing fixed-capital investment.

𝐹𝑖𝑥𝑒𝑑 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡 = 𝐷𝑖𝑟𝑒𝑐𝑡 𝐶𝑜𝑠𝑡 + 𝐼𝑛𝑑𝑖𝑟𝑒𝑐𝑡 𝐶𝑜𝑠𝑡

I. Direct Costs
1. Purchased Equipment

The listed equipment can be divided into processing equipment,

raw-materials handling and storage equipment, and finished-products

handling and storage equipment.

Table 40. Estimation of Purchased Equipment Cost for SMR and SMR

Plus

Equipment No. of Unit Price Cost (Php) Tax (12%) Price (Php)

Units (Php)

Expander 1 249,600 249,600 29,952 279,552

Compressor 1 249,600 249,600 29,952 279,552

Pump 2 208,000 416,000 49,920 465,920

Heat
12 1,040,000 12,480,000 1,497,600 13,977,600
Exchanger

Steam

Methane 1 52,000,000 52,000,000 6,240,000 58,240,000

Reformer

Prereformer 1 52,000,000 52,000,000 6,240,000 58,240,000

Furnace 1 780,000 780,000 93,600 873,600

Separator 2 1,560,000 3,120,000 374,400 3,494,400

Absorber 1 208,000 208,000 24,960 232,960

Pressure 1 260,000,000 260,000,000 31,200,000 291,200,000


Swing

Absorber

Water Gas

Shift 2 182,000,000 364,000,000 43,680,000 407,680,000

Reactor

Spherical
5 23,400,000 117,000,000 14,040,000 131,040,000
Tank

Total 966,003,584

Table 41. Estimation of Purchased Equipment Cost for ATR

Equipment No. of Unit Price Cost (Php) Tax (12%) Price (Php)

Units (Php)

Expander 2 249,600 249,600 29,952 279,552

Compressor 4 249,600 249,600 29,952 279,552

Pump 3 208,000 416,000 49,920 465,920

Heat
15 1,040,000 12,480,000 1,497,600 13,977,600
Exchanger

Separator 4 1,560,000 3,120,000 374,400 3,494,400

Pressure

Swing 2 260,000,000 260,000,000 31,200,000 291,200,000

Absorber

Water Gas 2 182,000,000 364,000,000 43,680,000 407,680,000


Shift

Reactor

Gas Heated
2 52,000,000 104,000,000 12,480,000 116,480,000
Reformer

Autothermal
1 52,000,000 52,000,000 6,240,000 58,240,000
Reformer

Spherical
5 23,400,000 117,000,000 14,040,000 131,040,000
Tank

Total 1,023,137,024

The dollar to peso conversion is based on the exchange rate as of

March 3, 2019 (1 usd = 52 php) and the current tax rate of 12% has been

used. Using the said conditions, a total purchased equipment cost of

966,003,584 Php has been calculated.

2. Equipment Installation

The installation of equipment involves costs for labor, foundations,

supports, platforms, construction expenses, and other factors directly

related to the erection of purchased equipment

Equipment installation cost accounts for 39 percent of purchased

equipment costs.

3. Insulation Costs
When very high or low temperatures are involved, insulation factors

can become important, and it may be necessary to estimate insulation

costs with a great deal of care.

The total cost for the labor and materials required for insulating

equipment and piping in ordinary chemical plants is approximately 9

percent of the purchased-equipment cost.

4. Instrumentation and Controls

Instrument costs, installation-labor costs, and expenses for auxiliary

equipment and materials constitute the major portion of the capital

investment requires for instrumentation.

For the normal chemical processing plant, a value of 13 percent of

the purchased equipment is normally used to estimate the total

instrumentation cost.

5. Piping Costs

The cost for piping covers labor, valves, fittings, pipe, supports, and

other items involved in the complete erection of all piping used directly in

the process. This includes raw-material, intermediate-product, finished

product, finished product, steam, water, air, sewer, and other process

piping.

Piping costs for fluid processing plants accounts for 66 percent of

the purchased equipment costs.

6. Electrical Installation Costs


The cost for electrical installations consists primarily of installation

labor and materials for power and lighting, with building-service lighting

usually included under the heading of building-and-services costs. In

ordinary chemical plants, electrical-installations cost amounts to 15

percent of the value of all purchased equipment.

7. Building Including Services

The cost for buildings including services consists of expenses for

labor, materials, and supplies involved in the erection of all buildings

connected with the plant. Costs for plumbing, heating, lighting, ventilation,

and similar building services are included.

The cost of buildings including services for fluid processing plant is

45 percent of the total purchased cost.

8. Yard Improvements

Costs for fencing, grading, roads, sidewalks, railroad sidings,

landscaping, and similar items constitute the portion of the capital

investment included in yard improvements. Yard improvements cost for

chemical plants approximates 10 percent of the purchased equipment

cost.

9. Service Facilities

Utilities for supplying steam, water, power, compressed air, and fuel

are part of the service facilities of an industrial plant. Waste disposal, fire

protection, and miscellaneous service items, such as shop, first aid, and
cafeteria equipment and facilities, require capital investments which are

included under the general heading of service facilities cost.

For a small, continuous-process plant, the cost of service facilities,

in terms of capital investment, generally ranges from 8 to 20 percent with

13 percent considered as an average value.

10. Land

The total cost of land is influenced by the value of land where plant

is located and other fees which include title fees, legal fees, survey costs,

zoning fees, site preparation costs and etc. The value of land in

Tabangao, Batangas Industrial Park is Php 5000.00/square meter based

on municipal inquiry.

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = 𝑐𝑜𝑠𝑡 𝑝𝑒𝑟 𝑠𝑞𝑢𝑎𝑟𝑒 𝑚𝑒𝑡𝑒𝑟 ∗ 𝑡𝑜𝑡𝑎𝑙 𝑎𝑟𝑒𝑎

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = (5000 𝑃ℎ𝑝)(130000 𝑚2)

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = 𝑃ℎ𝑝 650,000,000.00

J. Indirect Costs

1. Engineering and Supervision Cost

The costs for construction design and engineering, drafting,

purchasing, accounting, construction, and cost engineering, travel,

reproductions, communications, and home office expense including

overhead constitute the capital investment for engineering and


supervision. This cost is approximately 30 percent of the purchased cost

or 8 percent of the total direct costs of the process plant.

2. Contractor’s Fee

The contractor’s fee varies for different situations, but it can be

estimated to be about 8 percent of the direct plant cost or 1.5 percent of

the fixed-capital investment.

3. Construction Expense

Another expense which is included under indirect plant cost is the

item of construction or field expense and includes temporary construction

and operation, construction tools and rentals, home office personnel

located at the construction site, construction payroll, travel and living,

taxes and insurance, and other construction overhead. This expense item

is occasionally included under equipment installation, or more often under

engineering, supervision, and construction. For ordinary chemical-process


plants, the construction expenses average roughly 10 percent of the total

direct costs for the plant.

4. Contingencies

A contingency factor is usually included in an estimate of capital

investment to compensate for unpredictable events, such as storms,

floods, strikes, price changes, small design changes, errors in estimation,

and other unforeseen expenses, which previous estimates have

statistically shown to be of a recurring nature. Contingency factors ranging

from 5 to 15 percent of the direct costs are commonly used, with 8 percent

being considered a fair average value.

K. Working Capital

The working capital for an industrial plant comprises of the total

amount of money invested in (1) raw materials and supplies carried in

stock, (2) finished products in stock and semi-finished products in the

process of being manufactured, (3) accounts receivable, (4) cash kept on


hand for monthly payment of operating expenses, such as salaries,

wages, and raw-material purchases, (5) accounts payable, and (6) taxes

payable.

The raw-materials inventory included in working capital usually

amounts to a 1-month supply of the raw materials valued at delivered

prices. Finished products in stock and semi-finished products have a value

approximately equal to the total manufacturing cost for 1 month’s

production. Because credit terms extended to customers are usually

based on an allowable 30-day payment period, the working capital

required for accounts receivable ordinarily amounts to the production cost

for 1 month of operation.

The ratio of working capital to total capital investment varies with

different companies, but most fluid chemical plants use an initial working

capital amounting to 86 percent of the total purchased equipment cost.


L. Estimation of Capital Investment

The proposed SMR Plant has an annual capacity of 31400 metric

tons of hydrogen gas and operates 345 days per year. The table shows

various costs constituting the total capital investment for the proposed

plant.
Table 42. Estimation of Total Capital Investment for SMR and SMR

Plus

DIRECT COST Cost Factor, PE Cost

Purchased Equipment 1 966,003,584.00

Equipment Installation 0.39 376,741,397.80

Insulation Costs 0.09 86,940,322.56

Instrumentation and Controls 0.13 125,580,465.90

Piping Costs 0.66 637,562,365.40

Electrical Installation Costs 0.15 144,900,537.60

Building Including Services 0.45 434,701,612.80

Yard Improvements 0.1 96,600,358.40

Service Facilities 0.13 125,580,465.90

Land 650,000,000.00

Total Direct Cost 3,644,611,110.00

Cost Factor,
INDIRECT COST
TDC

Engineering and Supervision 0.08 291,568,888.80

Contractor’s Fee 0.015 54,669,166.65

Construction Expenses 0.1 364,461,111.00

Contingency 0.08 291,568,888.80

Total Indirect Cost 1,002,268,055.00

Fixed Capital Investment 4,646,879,166.00


Working Capital 0.86 PE 830,763,082.20

Total Capital Investment 5,477,642,247.85

Table 43. Estimation of Total Capital Investment for ATR

DIRECT COST Cost Factor, PE Cost

Purchased Equipment 1 1,023,137,024

Equipment Installation 0.39 399,023,439.4

Insulation Costs 0.09 92,082,332.16

Instrumentation and Controls 0.13 133,007,813.1

Piping Costs 0.66 675,270,435.8

Electrical Installation Costs 0.15 153,470,553.6

Building Including Services 0.45 460,411,660.8

Yard Improvements 0.1 102,313,702.4

Service Facilities 0.13 133,007,813.1

Land 650,000,000.00

Total Direct Cost 3,821,724,774

Cost Factor,
INDIRECT COST
TDC

Engineering and Supervision 0.08 335,618,652.30

Contractor’s Fee 0.015 62,928,497.30

Construction Expenses 0.1 419,523,315.30

Contingency 0.08 335,618,652.30


Total Indirect Cost 1,153,689,117.20

Fixed Capital Investment 4,975,413,891.00

Working Capital 0.86 PE 830,763,082.20

Total Capital Investment 5,806,176,973.00

Total capital investment is the amount required for a company to

build a manufacturing plant which includes the procurement necessary

facilities, and the cost to sustain its operation. It is the sum of the fixed

capital investment and working capital investment. The fixed capital

investment is the amount expended for physical equipment and facilities

while working capital investment serves as the fund to purchase raw

materials, products on hand, and for salaries of employees.

5.8 Operational Expenditures (OPEX)

Operating expenditures or OPEX is an ongoing cost for running a

production plant or system. An operating expense is an expense a business

incurs through its normal business operations.

A. Direct Production Costs

Direct production cost is traceable to a specific item, such as a product. It

is the cost of the materials used to create a product.

1. Raw Materials

The cost of the raw material for hydrogen production are calculated using the

current natural gas price as of March 20, 2019.


Table 44. Annual Raw Material Cost for SMR, SMR Plus, and ATR

(markets.businessinsider.com)

Annual
Cost per Unit
Consumption
Design Option (Php per metric Total Cost (Php)
(metric tons per
ton)
year)

SMR 94,681.98 777,770,817.50

SMR Plus 8,214.56 99,506.30 817,400,471.70

ATR 92,214.53 757,501,789.60

Table shows the annual cost of natural gas based on the annual consumption

of the plant.

2. Operating Labor

The cost of labor is the sum of all wages paid to employees, as well as

the cost of employee benefits and payroll taxes paid by an employer. The

salary calculations are based on Philippine Statistics Authority’s “Average

Daily Basic Pay of Wage and Salary Workers by Major Occupation Group,

Philippines (2016-2018)”.
The proposed plant will have a total of seven (7) major departments

namely: (1) Human Resource Department, (2) Finance Department, (3)

Marketing and Sales Department, (4) Research and Development

Department, (5) Operations Department, (6) Quality Assurance and

Quality Control Department.

2.1 Human Resource Department

The Human Resources Department (HRD) is responsible for the

recruitment of qualified employees during the pre-operating period. The HRD

evaluates the applicants’ skills and competency by means of interviews and

giving physical and written examinations in order to determine which among

them are the best fit for a designated position. Potential employees will

undergo initial trainings and career orientation seminars to acquire

preliminary experience before going into the actual field of work.

The HRD serves to maintain a conducive work environment and

harmonious relationships among all the company employees. Compensation,

performance appraisal measures and promotion, and benefits such as life

and health care insurance, tuition assistance plan, and retirement are

covered by the HRD as well.

Table 45. Estimation of the Total Labor Cost for Human Resource

Department

Quantity Daily Salary Annual Salary Total

HR Manager 1 978.35 306,223.55 306,223.55

Secretary 1 862.53 269,971.89 269,971.89


Recruitment 1 582.71 182,388.23 182,388.23

Officer

Training Staff 1 582.71 182,388.23 182,388.23

General Service 1 582.71 182,388.23 182,388.23

Officer

Security 5 462.55 144,778.15 573,890.75

Maintenance 3 358.06 112,072.78 336,218.34

Health Officer 2 582.71 182,388.23 364,776.46

Nurse 2 462.55 144,778.15 289,556.30

Total 17 2,687,801.98

Table 45 shows the estimated total labor costs of Human Resource

Department based on the average salary grades provided by Philippine

Statistics Office assuming 313 work days.

2.2 Finance Department

The Finance Department manages the incoming and outgoing cash

flows. To track all of the financial transactions in the company, the

department conducts bookkeeping which includes both sales and

expenses. The department controls the expenditures and obligations such

as payroll, debts, and taxes. To secure that there are sufficient funds

available, the department provides financial planning and analysis, capital

budgeting, work capital (receivables, payables, and inventory)

management, investment reports, and risk management.


Table 46. Estimation of the Total Labor Cost for Finance

Department

Quantity Daily Annual Total

Salary Salary

Finance 1 978.35 306,223.55 306,223.55

Manager

Secretary 1 862.53 269,971.89 269,971.89

Chief 1 862.53 269,971.89 269,971.89

Accountant

Officer

Book Keeper 1 862.53 269,971.89 269,971.89

Purchasing 1 862.53 269,971.89 269,971.89

Manager

Payroll 1 862.53 269,971.89 269,971.89

Master

Accounting 3 532.06 166,534.78 499,604.34

Clerk

Purchasing 3 532.06 166,534.78 499,604.34

Staff

Payroll Staff 2 532.06 166,534.78 333,069.56

Total 14 2,988,361.24
Table 46 shows the estimated total labor costs of Finance

Department based on the average salary grades provided by Philippine

Statistics Office assuming 313 work days.

2.3 Marketing and Sales Department

The Marketing and Sales Department is the overall responsible for

establishing the name of the company. Creating a good image of the

brand, more importantly on starting business, relies on good marketing to

increase market share and to generate revenue. First and foremost, the

department conducts market research to determine and to set which

marketing strategy will work and will appeal to the consumers. By

understanding customer needs and learning the weaknesses and

strengths of existing competitors, market research can help save money

from doing irrelevant advertisements that won’t contribute to profitability of

the company.

The company can utilize tried and tested methods of marketing

strategy such as studying industry reports, market data on websites, or by

contacting customers and prospects to survey their needs and attitudes.

But since the market can be unpredictable, finding new and creative ways

of product campaigns will always be the main challenge nowadays.

Table 47. Estimation of the Total Labor Cost for Marketing and Sales

Department

Quantity Daily Annual Total


Salary Salary

Marketing 1 978.35 306,223.55 306,223.55

Manager

Secretary 1 862.53 269,971.89 269,971.89

Marketing 1 862.53 269,971.89 269,971.89

Officer

Advertising 1 862.53 269,971.89 269,971.89

and

Promotion

Officer

Marketing 5 532.06 166,534.78 832,673.90

Staff

Advertising 5 532.06 166,534.78 832,673.90

and

Promotion

Staff

Total 14 2,781,487.02

Table 47 shows the estimated total labor costs of Marketing and

Sales Department based on the average salary grades provided by

Philippine Statistics Office assuming 313 work days.

2.4 Research and Development Department


The Research and Development Department holds a vital part in

formulating a new product. The activities of the department are divided into two

phases namely, research phase and development phase. In the research phase,

comprehensive study and analysis are conducted to understand and to discover

methods prior to developing products that will satisfy the needs of consumers.

Meanwhile, the development phase focuses more on transpiring ideas and

theories presented during the research phase into actual work. The department

takes into account product specifications, production costs, and a production time

line.

The department has the rights to make necessary changes or

prospective upgrades in the events of: innovation and improvement of

product quality; increased market competition due to new trends within the

industry; proven faulty manufacturing process; or if the product

effectiveness is of questionable status.

Table 48. Estimation of the Total Labor Cost for Research and

Development Department

Quantity Daily Annual Total

Salary Salary

Research 1 978.35 306,223.55 306,223.55

and

Development

Manager

Secretary 1 862.53 269,971.89 269,971.89


Process 3 862.53 269,971.89 809,915.67

Developer

Product 3 862.53 269,971.89 809,915.67

Developer

Process 5 532.06 166,534.78 832,673.90

Researcher

Product 5 532.06 166,534.78 832,673.90

Researcher

Total 18 2,781,487.02

Table 48 shows the estimated total labor costs of Research and

Development Department based on the average salary grades provided

by Philippine Statistics Office assuming 313 work days.

2.5 Operations Department

The Operations Department is at the core of the company. The

department is in charge of manufacturing the required quantities of finish

product from the available raw materials. It oversees that finished goods

are distributed on-time and on upright condition to market consumers. The

department also runs the day-to-day business of the company such as

operating plant equipment and machineries, purchasing required raw

materials, and delivering finished and tested products to locations

specified by the company.


Table 49. Estimation of the Total Labor Cost for Operations

Department

Quantity Daily Annual Total

Salary Salary

Operations 1 978.35 306,223.55 306,223.55

Manager

Secretary 1 862.53 269,971.89 269,971.89

Engineering 1 862.53 269,971.89 269,971.89

Head

Pollution 1 862.53 269,971.89 269,971.89

Control Head

Process Area 1 862.53 269,971.89 269,971.89

Head

Warehouse 1 862.53 269,971.89 269,971.89

Head

Logistics 1 862.53 269,971.89 269,971.89

Head

Engineering 24 582.71 182,388.23 4,377,317.52

Staff

Pollution 3 582.71 182,388.23 547,164.69

Control Staff

Process Area 45 582.71 182,388.23 8,207,470.35


Staff

Warehouse 6 333.71 104,451.23 626,707.38

Staff

Logistics 6 333.71 104,451.23 626,707.38

Staff

Driver 10 462.55 144,778.15 1,447,781.50

Total 101 17,759,203.71

2.6 Quality Assurance and Quality Control Department

The Quality Assurance and Quality Control Department conducts strict

measures in assuring that finished goods passed necessary quality tests and

standards before ultimately reaching the market. The department targets zero

defect and a hundred percent quality products that will bring long-term revenue

and profitability, maintain customer satisfaction and loyalty, and lessen the risk

and cost of replacing defective goods. The department is also responsible in

keeping the business on the cutting edge through constant drive for development

in the industry.

Table 50. Estimation of the Total Labor Cost for Quality

Assurance and Quality Control Department

Quantity Daily Annual Total

Salary Salary

Quality 1 978.35 306,223.55 306,223.55


Assurance

and Control

Manager

Quality 5 862.53 269,971.89 1,349,859.45

Assurance

and Control

Staff

Total 6 1,656,083.00

Table 50 shows the estimated total labor costs of Quality

Assurance and Quality Control Department based on the average salary

grades provided by Philippine Statistics Office assuming 313 work days.

2.7 Others

a. Plant Manager

The Plant Manager supervises day-to-day operational

activities to ensure optimum plant performance and product quality.

The Plant Manager ensures safety of plant personnel and efficiency

of equipment and processes through implementing strategic goals,

policies, and safety procedures, providing collaborative training

programs, and conducting corrective and preventive maintenance

regularly. It is the task of Plant Manager to allocate resources cost-

effectively, to comply with organizational standards and regulations,


and to order corresponding sanctions for misconduct and violation

of employees.

Table 51. Estimation of the Total Labor Cost for a Plant

Manager

Quantity Daily Salary Annual Total

Salary

Plant 1 2260.37 707,497.00 707,497.00

Manager

Total 1 707,497.00

Table 51 shows the estimated total labor cost of a Plant

Manager based on payscale.com.ph assuming 313 work days.

b. Legal Counsel

The Legal Counsel is responsible for handling the legal matters

associated with the company such as official contracts, deals, and

agreements. The Legal Counsel ensures that the involvement of the

company in any third-party arrangements are in legal terms and

conditions. It is mandatory for the Legal Counsel to study and to advice

identified risks that affects the profit line of the company within the

relative legal frameworks.

Table 52. Estimation of the Total Labor Cost for a Legal

Counsel
Quantity Daily Annual Total

Salary Salary

Legal 1 4193.29 1,312,500.00 1,312,500.00

Counsel

Total 1 1,312,500.00

Table 52 shows the estimated total labor cost of a Legal

Counsel based on payscale.com.ph assuming 313 work days.

Table 53. Estimation of the Total Labor Cost

Department Labor Cost

Human Resource 2,687,801.98

Finance 2,988,361.24

Marketing and Sales 2,781,487.02

Department

Research and 2,781,487.02

Development

Operations 17,759,203.71

Quality Assurance 1,656,083.00

Others 2,019,997

Total 32,674,420.97

Table 53 shows the total labor cost for the proposed SMR plant.
3. Direct Supervisory and Clerical Labor

In a manufacturing operation, direct supervisory and clerical labor is

always necessary. The estimate of the cost of this type of labor is linked

with the total amount of operating labor, product quality standards, and

operation difficulty. Direct supervisory and clerical labor cost averages

around 15% of operating labor cost.

4. Utilities

The costs of the utilities required in the process for steam-methane

reforming such as electricity, process and cooling water, fuel (diesel and

coal) vary widely depending on the amount of consumption, plant location

and source.

4.1 Fuel

Natural gas will be used for heating requirements within the

process. A price of Php 8,214.56 per metric ton was based on

Global Natural Gas Price as of March 20, 2019.

Table 54. Heat Demand and Heat Available in SMR

Heat Demand

Process Value, GJ/hr

Preheating (350 C) 90.01

Preheating Gas input in GHR and SMR (400 31.90

and 700°C):

GHR (700°C): 24.07


SMR (950°C): 132.05

CO2 Absorption (115°C) 46.90

Preheating Furnace inputs (335 and 500°C): 25.47

Total 350.39

Heat Utilized

Cooling the reforming product (950 - 320°C): 71.96

WGS (320 - 25°C): 70.31

Cooling the Flue Gas (1000 - 100°C): 76.17

Total 217.44

Overall Heat Requirement 132.95

A total heat demand of 350.29 GJ/hr for SMR and SMR plus

will be provided by a total of 132.95 GJ/hr. This is made possible

through heat utilization and optimization within the system

Annual Fuel Cost Calculation for SMR:

Table 55. Variables for Total Fuel Cost Estimation

Price, Density, Energy Overall Heat

Php/MT kg/m3 Density, Requirement,

MJ/m3 GJ/hr

Natural 8214 0.8 82.7 132.95


Gas

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 =

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 132950 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


( )( ) (82.7 𝑀𝐽) ( ) ( 𝑑𝑎𝑦 ) ( )
1000 𝑘𝑔 𝑚3 ℎ𝑟 𝑦𝑒𝑎𝑟

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 87,475,707.15𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

A total fuel cost of 87,475,707.15 Php/year is required for

heating requirements of SMR plant.

Table 56. Heat Demand and Heat Available in SMR Plus:

Heat Demand

Process Value, GJ/hr

Preheating (350 C) 115.61

Preheating Gas input in GHR and SMR (400 34.00

and 700°C):

GHR (700°C): 30.90

SMR (950°C): 176.56

CO2 Absorption (115°C) 60.23

Preheating Furnace inputs (335 and 500°C): 34.36

Total 451.66

Heat Utilized

Cooling the reforming product (950 - 320°C): 92.43

WGS (320 - 25°C): 90.32


Cooling the Flue Gas (1000 - 100°C): 92.70

Total 275.45

Overall Heat Requirement 176.21

. A total heat demand of 451.66 GJ/hr for SMR and SMR

plus will be provided by a total of 176.21 GJ/hr. This is made

possible through heat utilization and optimization within the system

Since SMR Plus offers a hydrogen recycle stream as fuel for

the equipment, there will be no fuel cost.

Table 57. Heat Demand and Heat Available in ATR

Heat Demand

Process Value, GJ/hr

Preheating Water (320-350 C): 60.41

Preheating Gas input in GHR (400): 12.84

Preheating oxygen (250°C): 0.33

GHR (700°C): 28.72

CO2 Absorption (115°C) 0.59

Preheating Air and Tail inputs (350 and 2.93

500°C):

Total 163.96

Heat Utilized
Intercooling in two-stage oxygen 2.86

compression (277-25°C):

Cooling the reforming product (1000-320°C): 75.40

WGS (325-25°C): 69.89

Cooling Tail gas before PSA-2 (340-25°C) 2.64

Burning Tail gas and cooling the flue gas 18.12

(1000-100°C)

Total 168.89

Overall Heat Requirement 4.92

A total heat demand of 168.89 GJ/hr for ATR will be

provided by a total of 4.92 GJ/hr. This is made possible through

heat utilization and optimization within the system.

Annual Fuel Cost Calculation for ATR:

Table 58. Variables for Total Fuel Cost Estimation

Price, Density, Energy Overall Heat

Php/MT kg/m3 Density, Requirement,

MJ/m3 GJ/hr

Natural
8214 0.8 82.7 4.92
Gas
𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 =

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 4920 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


( )( ) (82.7 𝑀𝐽) ( ) ( 𝑑𝑎𝑦 ) ( )
1000 𝑘𝑔 𝑚3 ℎ𝑟 𝑦𝑒𝑎𝑟

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 3,237,160.43 𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

A total fuel cost of 3,237,160.43 Php/year is required for

heating requirements of ATR plant.

4.2 Electricity

Electricity demand will be calculated from the power

necessities of the major electrical equipment of the process plant

(pumps, compressors, and expanders). Electricity price of 10.4961

per kWh is based on Meralco’s electricity rate in Tabangao,

Batangas.

Power requirement will be calculated using the formula:

𝑞𝜌𝑔ℎ
𝑃=
3.6𝑥10^6

P = hydraulic power (kW)

q = flow rate (m3/h)

ρ = density of fluid (kg/m3)

g = acceleration of gravity (9.81 m/s2)

h = differential head (m)


p = differential pressure (Pa)

The differential head can be estimated using the pump curve

and the compressor curve:

Figure 39. Pump Curve


Figure 40. Compressor Curve

Table 59. Computation for Total Electricity Consumption for

SMR and SMR Plus

Fluid Volumetric
Wattage, Annual Cost,
Equipment Head Density, Flow Rate,
kW Php
kg per m3/hr
m3

Expander – 1 18000 0.8 11003.33 431.77 108,765.7949

Pump -1 13 1000 2.722 0.10 8,258.78382

Pump -2 13 1000 26.818 0.95 81,368.13537

Compressor
18000 1.225 74762.325 4492.19 1,131,610.844
-1

Total 1,330,003.558

Table 60. Computation for Total Electricity Consumption for

ATR

Fluid Volumetri

Density c Flow Wattage, Annual Cost,


Equipment Head
, kg per Rate, kW Php

m3 m3/hr

1800 122,311.37
Expander – 1 0.8 13096.67 485.36259
0

Pump -1 13 1000 360.11 22.569894 1,933,788.54

Pump - 2 13 1000 1716.55 818.57978 70,135,915.66

1800 45,100,244.83
Pump -3 1000 1287.78 526.38007
0

Compressor -1 1.429 13135.56 869.55338 219,127.45

Compressor -2 1.205 79,145.56 4677.9181 1,178,835.36


Compressor -3 0.09 2726.67 5.0153686 429,716.78

Total 119,119,940.00

Table 60 shows the total electrical consumption presented in

monetary value. The computation above is based on the premise

that the plant is running 24 hours a day and 340 days a year.

4.3 Water

Water that will be used for the process will be provided by West

Philippine Sea to utilize its near-shore location. Water will then be

treated before and after it is used.

4.4 Total Utility Cost

Total utility cost will be calculated by getting the sum of the

calculated utility costs.

Table 61. Total Utility Cost

Fuel Cost, Electricity Total, Php

Php Cost, Php

SMR 87,475,707.15 1,330,003.558 88,805,710.71

SMR Plus 0 1,330,003.558 1,330,003.558

ATR 3,237,160.43 119,119,940.00 122,357,100.40


Table 61 shows that the SMR is the most economical choice in

terms of utilities due to its hydrogen recycle feature.

5. Maintenance and Repairs

Maintenance and repairs will be done in order to ensure efficient

operating condition of the complex. Regular 15-day annual shutdown will

be done to give way for the maintenance and repairs of the plant along

with its equipment and facilities. The total plant cost per year for

maintenance and repairs is roughly 6% of the fixed-capital investment.

6. Operating Supplies

Miscellaneous supplies necessary for effective operation like

charts, test chemicals, custodial supplies and similar supplies comprise

the operating supplies costs. The costs for these materials cannot be

reflected as raw materials cost nor under maintenance and repair

expenses. The annual expenses for these supplies are 15 percent of the

total cost for maintenance and repairs.

7. Laboratory Charges

Laboratory charges are the costs allocated by the company for

control of operations and conducting quality control and assurance of

products through laboratory tests. This cost is estimated as 10-20% of

operating labor cost.

B. Fixed Charges
Certain expenses are always present in the industrial plan whether or

not the manufacturing process is in operation. Costs that are invariant with

the amount of production are designated as fixed costs or fixed charges.

These include costs for depreciation, local property taxes, and insurance.

Expenses of this type are a direct function of the capital investment.

1. Depreciation

Equipment, buildings, and other material objects comprising a

manufacturing plant require an initial investment which must be written off as a

manufacturing expense. In order to write off this cost, a decrease in value is

assumed to occur throughout the usual life of the material possessions. This

decrease in value is designated as depreciation.

In determining the depreciation cost, the straight-line method will be used:

𝑉 − 𝑆𝑉
𝑑=
𝑛

d = annual depreciation, Php per year

V = original value, Php

SV = salvage value, Php

n = service life, years

Table 62. Estimation of the Total Depreciation Cost for SMR and

SMR Plus

Cost (Php) Salvage Value, Life Depreciation

10% (Php) (Years) (Php per year)

Purchased 966,003,584.00 96,600,358.40 30 28,980,107.52

Equipment
Instrumentation and 125,580,465.90 12,558,046.59 8 14,127,802.41

Controls

Piping 637,562,365.40 63,756,236.54 20 28,690,306.44

Electrical 144,900,537.60 14,490,053.76 12 10,867,540.32

Equipment and

Materials

Buildings 434,701,612.80 43,470,161.28 50 7,824,629.03

Yard Improvements 96,600,358.40 9,660,035.84 20 4,347,016.128

Service Facilities 125,580,465.90 12,558,046.59 20 5,651,120.966

Total 100,488,522.8

Table 63. Estimation of the Total Depreciation Cost for ATR

Cost (Php) Salvage Value, Life Depreciation

10% (Php) (Years) (Php per year)

Purchased 1,023,137,024 96,600,358.40 30 30,694,110.72


Equipment

Instrumentation and 133,007,813.10 12,558,046.59 8 14,963,378.97

Controls

Piping 675,270,435.80 63,756,236.54 20 30,387,169.61

Electrical 153,470,553.60 14,490,053.76 12 11,510,291.52

Equipment and

Materials

Buildings 460,411,660.80 43,470,161.28 50 8,287,409.894

Yard Improvements 102,313,702.40 9,660,035.84 20 4,604,116.608

Service Facilities 133,007,813.10 12,558,046.59 20 5,985,351.59


Total 106,431,828.9

Table 63 shows the total annual depreciation cost using straight line

method. Estimated life years and salvage value was courtesy of M. S. Peters &

K. D. Timmerhaus (1991). Plant Design and Economics for Chemical Engineers.

McGraw-Hill Inc. Singapore.

The asset value (or book value) of the equipment at any time during the

service life may be determined from the following equation:

𝐴𝑉 = 𝑉 − 𝑎𝐷

AV = asset or book value, Php

a = number of years in actual use.


Annual 2023 2024 2025 2026 2028

Depreciation

Purchased
28,980,107.52 80,913,140.31 937,023,476.5 908,043,369 879,063,261.4 850,083,153.9
Equipment

Instrumentation
42,383,407.25 10,518,708.24 334,357,990.6 291,974,583.3 249,591,176.1 207,207,768.8
and Controls

Piping 5,651,120.966 25,083,073.50 119,929,344.9 114,278,224 108,627,103 102,975,982

Electrical

Equipment and 47,817,177.41 8,091,314.03 589,745,188 541,928,010.6 494,110,833.2 446,293,655.8

Materials

Buildings 2,608,209.677 23,464,810.69 142,292,327.9 139,684,118.2 137,075,908.6 134,467,698.9

Yard
19,561,572.58 8,091,314.03 415,140,040.2 395,578,467.6 376,016,895.1 356,455,322.5
Improvements

Service Facilities 4,347,016.128 44,502,227.17 92,253,342.27 87,906,326.14 83,559,310.02 79,212,293.89

Table 64. Estimation of the Asset Value for 10 years of operation

Annual 2029 2030 2031 2032 2033


Depreciation

Purchased
28,980,107.52 821,103,046.4 792,122,938.9 763,142,831.4 734,162,723.8 705,182,616.3
Equipment

Instrumentation
42,383,407.25 164,824,361.6 122,440,954.3 80,057,547.05 37,674,139.8 -
and Controls

Piping 5,651,120.966 97,324,861.07 91,673,740.1 86,022,619.14 80,371,498.17 74,720,377.21

Electrical

Equipment and 47,817,177.41 398,476,478.4 350,659,300.9 302,842,123.5 255,024,946.1 207,207,768.7

Materials

Buildings 2,608,209.677 131,859,489.2 129,251,279.5 126,643,069.9 124,034,860.2 121,426,650.5

Yard
19,561,572.58 336,893,749.9 317,332,177.3 297,770,604.7 278,209,032.2 258,647,459.6
Improvements

Service Facilities 4,347,016.128 74,865,277.76 70,518,261.63 66,171,245.5 61,824,229.38 57,477,213.25


Table 64 shows the total asset value from 2023 to 2033. Estimated life

years and salvage value was courtesy of M. S. Peters & K. D. Timmerhaus

(1991). Plant Design and Economics for Chemical Engineers. McGraw-Hill Inc.

Singapore.

2. Property Taxes

Local governments usually have jurisdiction over property taxes,

which are commonly charges on a country basis. In addition to these,

individual cities and towns may have special property taxes for industrial

concerns located within the city limits.

The legal basis for real property tax is in Title II of the Local

Government Code of 1991 or Republic Act 7160. RA 7160 vested local

government units the power to create local and external revenue sources

such as the property tax, business tax, professional tax, amusement tax

and other fees and charges. RA 7160 also established limitations such as

ceiling limits and base rates.

Real property tax will be computed using:

𝑅𝑒𝑎𝑙 𝑃𝑟𝑜𝑝𝑒𝑟𝑡𝑦 𝑇𝑎𝑥 = 𝑅𝑒𝑎𝑙 𝑃𝑟𝑜𝑝𝑒𝑟𝑡𝑦 𝑇𝑎𝑥 𝑅𝑎𝑡𝑒 ∗ 𝐴𝑠𝑠𝑒𝑠𝑠𝑒𝑑 𝑉𝑎𝑙𝑢𝑒

Real property tax rate for most cities and municipalities in Metro

Manila is 2% and 1% for the provinces. The assessed property value, or

the taxable value of the property, is the fair market value multiplied by the

assessment level.
Assessment level is the amount applied to the fair market value to

determine the taxable value of the property. It shall be fixed through

ordinances imposed by the city or provincial government.

Assessment levels used in the calculation are based on “Real

Property Tax Code of the Province of Batangas”.

Table 65. Estimation of Total Property Taxes

Property Assessme Fair Market RPT Assessed Real

nt Level Value (Php) Rat Value (Php) Property Tax

e (Php)

Land 45% 650,000,000.0 1% 292,500,000.0 2,925,000.00

0 0

Buildings 60% 96,600,358.40 1% 57,960,215.04 579,602.15

Machinerie 80% 966,003,584.0 1% 772,802,867.2 7,728,028.67

s 0 0

Total 11,232,630.8

Table 65 shows the total property tax considering the local tax code

of the province of Batangas.

3. Insurance

The annual insurance cost for ordinary industrial concerns is

approximately 1 percent of the capital investment. Despite the fact that


insurance costs may represent only a small fraction of total costs, it is

necessary to consider insurance requirements carefully to make certain

the economic operation of a plant is protected against emergencies or

unforeseen developments.

C. Plant Overhead Costs

The expenditures required for routine plant services are included in

plant overhead costs. Nonmanufacturing machinery, equipment, and

buildings are necessary for many of the general plant services, and the fixed

charges and direct costs for these items are part of the plant-overhead costs.

Plant overhead cost for chemical plants is about 50% of the total expense for

operating labor.

D. General Expenses

In addition to the manufacturing costs, other general expenses are

involved in any company’s operations. These general expenses may be

classified as (1) administrative expenses, (2) distribution and marketing

expenses, and (3) research and development expenses.

D.1 Administrative

Administrative expenses include costs for executive and clerical

wages, office supplies, engineering and legal expenses, upkeep on

office buildings, and general communications. Administrative cost is

about 20% of the total operating labor.

D.2 Distribution and Marketing


Distribution and marketing expenses are costs incurred in the

process of selling and distributing the various products. These costs

include expenditures for materials handling, containers, shipping, sales

offices, salesmen, technical sales service, and advertising. Distribution

and marketing cost is about 2% of the direct production cost.

D.3 Research and Development

Research and development expenses are incurred by any

progressive concern which wishes to remain in a competitive industrial

position. These costs are for salaries, wages, special equipment,

research facilities, and consultant fees related to developing new ideas

or improved processes. Research and development cost is about 2%

of the direct production cost.

E. Total Production Cost / OPEX

Product costs are the costs required for the manufacturing of the

product. Total product cost is estimated by summing the direct production

cost, fixed charges, plant overhead cost, and general expenses.

Table 66. Estimation of Total Production Cost for SMR

Cost Factor Cost

A. Direct Production Cost

Raw Material 777,770,817.50

Operating Labor 32,674,420.97


Direct Supervisory and Clerical 4,901,163.146

Labor 0.15 OL

Utilities 88,805,710.71

Maintenance and Repairs 0.06 FCI 278,812,750.00

Operating Supplies 0.15 MR 48,140,300.43

Laboratory Charges 0.1 OL 3,267,442.10

Total Direct Production Cost 1,234,372,604.86

B. Fixed Charges

100,488,522.8

Depreciation

Local Taxes 11,232,630.82

Insurance 0.01 FCI 46,468,791.66

C. Plant Overhead Cost 0.5 OL 16,337,210.49

Total Manufacturing Cost 174,527,155.77

D. General Expenses

Administrative Expenses 0.2 OL 6,534,884.19

Distribution Cost 0.02 DPC 24,687,452.1

Research and Development 0.02 DPC 24,687,452.1

Total General Expense 55,909,788.39

Total Production Cost 1,464,809,549.02

Table 67. Estimation of Total Production Cost for SMR Plus


Cost Factor Cost

A. Direct Production Cost

Raw Material 817,400,471.70

Operating Labor 32,674,420.97

Direct Supervisory and Clerical 4,901,163.146

Labor 0.15 OL

Utilities 1,330,003.56

Maintenance and Repairs 0.06 FCI 320,935,336.20

Operating Supplies 0.15 MR 48,140,300.43

Laboratory Charges 0.1 OLs 4,814,030.04

Total Direct Production Cost 1,230,195,726.05

B. Fixed Charges

100,488,522.8

Depreciation

Local Taxes 11,232,630.82

Insurance 0.01 FCI 46,468,791.66

C. Plant Overhead Cost 0.5 OL 16,337,210.49

174,527,155.77

Total Manufacturing Cost

D. General Expenses

Administrative Expenses 0.2 OL 6,534,884.19

Distribution Cost 0.02 DPC 24,687,452.1

Research and Development 0.02 DPC 24,687,452.1


Total General Expense 55,909,788.39

Total Production Cost 1,460,632,670.21

Table 68. Estimation of Total Production Cost for ATR

Cost Factor Cost

A. Direct Production Cost

Raw Material 757,501,789.60

Operating Labor 32,674,420.97

Direct Supervisory and Clerical 4,901,163.146

Labor 0.15 OL

Utilities 122,357,100.40

Maintenance and Repairs 0.06 FCI 298,524,833.5

Operating Supplies 0.15 MR 48,140,300.43

Laboratory Charges 0.1 OLs 4,814,030.04

Total Direct Production Cost 1,190,566,071.84

B. Fixed Charges

100,488,522.8

Depreciation

Local Taxes 11,232,630.82

Insurance 0.01 FCI 53,489,222.70

C. Plant Overhead Cost 0.5 OL 16,337,210.49

Total Manufacturing Cost 232,407,675.51


D. General Expenses

Administrative Expenses 0.2 OL 6,534,884.19

Distribution Cost 0.02 DPC 23,811,321.44

Research and Development 0.02 DPC 23,811,321.44

Total General Expense 54,157,527.07

Total Production Cost 1,504,618,751.97

As a result of the evaluation of the total production cost or OPEX,

SMR Plus is by far the most economical option. The evaluation of the

computation of the total operating expenditure is done in an annual

basis.

F. Sensitivity Analysis

A sensitivity analysis determines how different values of an independent

variable affect a particular dependent variable under a given set of

assumptions. This technique is used within specific boundaries that depend

on one or more input variables, such as the effect that changes in interest

rates (independent variable) has on bond prices (dependent variable).

1. Primary Investment

As per “The Corporation Code of the Philippines”, Section 14, at least

twenty-five (25%) percent of the authorized capital stock of the corporation

must be subscribed, and at least twenty-five (25%) of the total subscription


has been fully paid in actual cash. Conforming to this, the considered initial

capital from investors are as follows:

Table 69. Capital from Investors

Invested Capital, Php

SMR 1,370,000,000.00

SMR Plus 1,370,000,000.00

ATR 1,500,000,000.00

Table 69 shows the primary capital to be invested by the investors as per

“The Corporation Code of the Philippines”, Section 14.

2. Loan

The remaining capital investment of 4,500,000,000.00 Php for all design

options will be loaned from Banco de Oro. The company's land, buildings,

equipment purchased and other assets will be used as collateral.

Ordinary Annuity

𝐴[(1 + 𝑖)𝑛 − 1]
𝑃1 =
𝑖(1 + 𝑖)

i = interest

n = ordinary annuity period


𝐴[(1 + 0.0684)8 − 1
𝑃1 =
0.0684(1 + 0.0684)

P1 = 6.0009A

Deferred Annuity

𝑃1 = 𝑃2(1 + 𝑖)𝑚

m = deferred period

6.0009 𝐴 = 4,500,000,000 (1 + 0.0684)2

A = 855,980,522.90

A total amount of 855,980,522.90 Php will be paid yearly for 8 years as

part of the contract.

3. Annual Sales

 Hydrogen

Table 70. Annual Sales of Hydrogen for SMR and ATR

H2 Annual Price per unit, Php Annual Sales, Php

Production, kg per kg

31400000 119.6 3,755,440,000.00


Since some of the H2 from SMR Plus are recycled back to the

process as fuel, the amount of H2 used as fuel will be deducted to its

annual H2 production.

Table 71. Variables for Total Fuel Cost Estimation for SMR

Plus

Price, Density, Energy Overall Heat

Php/MT kg/m3 Density, Requirement,

MJ/m3 GJ/hr

Natural Gas 8214 0.8 82.7 132.95

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 =

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 176210 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


( )( ) (82.7 𝑀𝐽) ( ) ( 𝑑𝑎𝑦 ) ( )
1000 𝑘𝑔 𝑚3 ℎ𝑟 𝑦𝑒𝑎𝑟

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 115,939,032.39𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

Equivalent Annual Sales = Annual Sales – Annual Fuel Cost

= 3,755,440,000 – 115,939,032.39

Equivalent Annual Sales = 3,639,500,968 Php

The equivalent annual sales of H2 for SMR Plus is

3,639,500,968.00 Php
 Carbon Dioxide

Table 72. Annual Sales of CO2

CO2 Annual Price per unit, Annual Sales,

Production, kg Php per kg Php

SMR 191,352,000.00 1.35 258,325,200.00

SMR Plus 245,000,000.00 1.35 330,750,000.00

ATR 285,436,800.00 1.35 385,339,680.00

 Total Annual Sales

Table 73. Total Annual Sales

Total Annual Sales, Php

SMR 4,013,765,200.00

SMR Plus 3,970,250,968.00

ATR 3,793,973,968.00

Table 73 shows that SMR produces the most amount of sales per

year.

4. Cash Flow Sensitivity Analysis for SMR


2023

Pessimistic Expected Optimistic

Beginning Cash 1301500000 1,370,000,000 1438500000

Balance

Cash Inflow 3813076940 4,013,765,200 4214453460

Loan Proceeds 4275000000 4,500,000,000 4725000000

Total Cash 8088076940 8,513,765,200 8939453460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205


Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 7184826372 7562975128 7941123884

Balance

2024

Pessimistic Expected Optimistic

Beginning Cash 7184826372 7,562,975,128 7941123884

Balance
Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24


Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 8802652743 9265950256 9729247769

Balance

2025

Pessimistic Expected Optimistic

Beginning Cash 8802652743 9,265,950,256 9729247769

Balance

Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow
Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses
Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 10420479115 10968925384 11517371653

Balance

2026

Pessimistic Expected Optimistic

Beginning Cash 10420479115 10,968,925,384 11517371653

Balance

Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308


Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576


Outflows

Ending Cash 12038305487 12671900512 13305495538

Balance

2027

Pessimistic Expected Optimistic

Beginning Cash 12038305487 12,671,900,512 13305495538

Balance

Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5


and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 13656131858 14374875640 15093619422

Balance
2028

Pessimistic Expected Optimistic

Beginning Cash 13656131858 14,374,875,640 15093619422

Balance

Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205


Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 15273958230 16077850768 16881743307

Balance

2029

Pessimistic Expected Optimistic

Beginning Cash 15273958230 16,077,850,768 16881743307

Balance
Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows

Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24


Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 16891784602 17780825897 18669867191

Balance

2030

Pessimistic Expected Optimistic

Beginning Cash 16891784602 17,780,825,897 18669867191

Balance

Cash Inflow 3822576940 4,023,765,200 4224953460

Loan Proceeds

Total Cash 3822576940 4,023,765,200 4224953460

Inflow

Cash Outflows
Raw Material 738882276.6 777,770,817.50 816659358.4

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.993 4,901,163.15 5146221.308

Supervisory and

Clerical Labor

Utilities 84365425.17 88,805,710.71 93245996.25

Maintenance 264872112.5 278,812,750.00 292753387.5

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 3104069.995 3,267,442.10 3430814.205

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71


Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2204750568 2,320,790,071.92 2436829576

Outflows

Ending Cash 18509610973 19483801025 20457991076

Balance

5. Table 74. Cash Flow Sensitivity Analysis for SMR Plus

2023

Pessimistic Expected Optimistic

Beginning Cash 1301500000 1,370,000,000 1438500000

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds 4275000000 4,500,000,000 4725000000

Total Cash 8046738420 8,470,250,968 8893763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303


Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853


Outflows

Ending Cash 7147455886 7523637775 7899819664

Balance

2024

Pessimistic Expected Optimistic

Beginning Cash 7147455886 7,523,637,775 7899819664

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103


and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 8718411772 9177275550 9636139327

Balance
2025

Pessimistic Expected Optimistic

Beginning Cash 8718411772 9,177,275,550 9636139327

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542


Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 10289367658 10830913325 11372458991

Balance

2026

Pessimistic Expected Optimistic

Beginning Cash 10289367658 10,830,913,325 11372458991

Balance
Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24


Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 11860323545 12484551100 13108778655

Balance

2027

Pessimistic Expected Optimistic

Beginning Cash 11860323545 12,484,551,100 13108778655

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow
Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses
Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 13431279431 14138188874 14845098318

Balance

2028

Pessimistic Expected Optimistic

Beginning Cash 13431279431 14,138,188,874 14845098318

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303


Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853


Outflows

Ending Cash 15002235317 15791826649 16581417982

Balance

2029

Pessimistic Expected Optimistic

Beginning Cash 15002235317 15,791,826,649 16581417982

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103


and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 16573191203 17445464424 18317737645

Balance
2030

Pessimistic Expected Optimistic

Beginning Cash 16573191203 17,445,464,424 18317737645

Balance

Cash Inflow 3771738420 3,970,250,968 4168763516

Loan Proceeds

Total Cash 3771738420 3,970,250,968 4168763516

Inflow

Cash Outflows

Raw Material 776530448.1 817,400,471.70 858270495.3

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 1263503.382 1,330,003.56 1396503.738

Maintenance 304888569.4 320,935,336.20 336982103

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542


Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 44145352.08 46,468,791.66 48792231.24

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 23453079.5 24,687,452.10 25921824.71

Research and 23453079.5 24,687,452.10 25921824.71

Development

Total Cash 2200782533 2,316,613,193.11 2432443853

Outflows

Ending Cash 18144147089 19099102199 20054057309

Balance

6. Table 75. Cash Flow Sensitivity Analysis for ATR

2023

Pessimistic Expected Optimistic

Beginning Cash 1425000000 1,500,000,000 1575000000


Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds 4275000000 4,500,000,000 4725000000

Total Cash 7879275270 8,293,973,968 8708672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36


Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 7061705958 7433374693 7805043428

Balance

2024

Pessimistic Expected Optimistic

Beginning Cash 7061705958 7,433,374,693 7805043428

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666


Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4


Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 8423411917 8866749386 9310086856

Balance

2025

Pessimistic Expected Optimistic

Beginning Cash 8423411917 8,866,749,386 9310086856

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02


Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development
Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 9785117875 10300124079 10815130283

Balance

2026

Pessimistic Expected Optimistic

Beginning Cash 9785117875 10,300,124,079 10815130283

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4


Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 11146823834 11733498773 12320173711

Balance
2027

Pessimistic Expected Optimistic

Beginning Cash 11146823834 11,733,498,773 12320173711

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542


Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 12508529792 13166873466 13825217139

Balance

2028

Pessimistic Expected Optimistic

Beginning Cash 12508529792 13,166,873,466 13825217139

Balance
Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84


Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 13870235751 14600248159 15330260567

Balance

2029

Pessimistic Expected Optimistic

Beginning Cash 13870235751 14,600,248,159 15330260567

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow
Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303

Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses
Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239

Outflows

Ending Cash 15231941709 16033622852 16835303995

Balance

2030

Pessimistic Expected Optimistic

Beginning Cash 15231941709 16,033,622,852 16835303995

Balance

Cash Inflow 3604275270 3,793,973,968 3983672666

Loan Proceeds

Total Cash 3604275270 3,793,973,968 3983672666

Inflow

Cash Outflows

Raw Material 719626700.1 757,501,789.60 795376879.1

Operating Labor 31040699.92 32,674,420.97 34308142.02

Direct 4656104.989 4,901,163.15 5146221.303


Supervisory and

Clerical Labor

Utilities 116239245.4 122,357,100.40 128474955.4

Maintenance 283598591.8 298,524,833.50 313451075.2

and Repairs

Operating 45733285.41 48,140,300.43 50547315.45

Supplies

Laboratory 4573328.538 4,814,030.04 5054731.542

Charges

Depreciation 95464096.66 100,488,522.80 105512948.9

Local Taxes 10670999.28 11,232,630.82 11794262.36

Insurance 50814761.57 53,489,222.70 56163683.84

Loan Payment 813181496.8 855,980,522.90 898779549

Overhead Cost 15520349.97 16,337,210.49 17154071.01

Administrative 6208139.981 6,534,884.19 6861628.4

Expenses

Distribution Cost 22620755.37 23,811,321.44 25001887.51

Research and 22620755.37 23,811,321.44 25001887.51

Development

Total Cash 2242569311 2,360,599,274.87 2478629239


Outflows

Ending Cash 16593647668 17466997545 18340347422

Balance

G. Payback Period

Payback period is defined as the minimum length of time theoretically

necessary to recover the original capital investment in the form of cash flow to

the project based on total income minus all costs.

1. Payback Period for SMR

Table 76. Estimation of the Net Income per year for SMR

Cash Inflow Cash Outflow Net Income

2023 4,023,765,200 2,320,790,071.92 1,702,975,128

2024 4,023,765,200 2,320,790,071.92 1,702,975,128

2025 4,023,765,200 2,320,790,071.92 1,702,975,128

2026 4,023,765,200 2,320,790,071.92 1,702,975,128

2027 4,023,765,200 2,320,790,071.92 1,702,975,128

2028 4,023,765,200 2,320,790,071.92 1,702,975,128

2029 4,023,765,200 2,320,790,071.92 1,702,975,128


2030 4,023,765,200 2,320,790,071.92 1,702,975,128

Table 76 shows the estimation of the net income for SMR. Cash

inflow and outflow are from the sensibility study performed. Payback

period will then be calculated using:

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟

5,477,642,247.85
=
1,702,975,128.00

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟑. 𝟐𝟐 𝒚𝒆𝒂𝒓𝒔

2. Payback Period for SMR Plus

Table 77. Estimation of the Net Income per year for SMR Plus

Cash Inflow Cash Outflow Net Income

2023 3,970,250,968 2,316,613,193.11 1,653,637,775

2024 3,970,250,968 2,316,613,193.11 1,653,637,775

2025 3,970,250,968 2,316,613,193.11 1,653,637,775

2026 3,970,250,968 2,316,613,193.11 1,653,637,775

2027 3,970,250,968 2,316,613,193.11 1,653,637,775


2028 3,970,250,968 2,316,613,193.11 1,653,637,775

2029 3,970,250,968 2,316,613,193.11 1,653,637,775

2030 3,970,250,968 2,316,613,193.11 1,653,637,775

Table 77 shows the estimation of the net income for SMR Plus.

Cash inflow and outflow are from the sensibility study performed. Payback

period will then be calculated using:

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟

5,477,642,247.85
=
1,653,637,775

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟑. 𝟑𝟏 𝒚𝒆𝒂𝒓𝒔

3. Payback Period for ATR

Table 78. Estimation of the Net Income per year for ATR

Cash Inflow Cash Outflow Net Income

2023 3,793,973,968 2,360,599,274.87 1,433,374,693

2024 3,793,973,968 2,360,599,274.87 1,433,374,693

2025 3,793,973,968 2,360,599,274.87 1,433,374,693

2026 3,793,973,968 2,360,599,274.87 1,433,374,693


2027 3,793,973,968 2,360,599,274.87 1,433,374,693

2028 3,793,973,968 2,360,599,274.87 1,433,374,693

2029 3,793,973,968 2,360,599,274.87 1,433,374,693

2030 3,793,973,968 2,360,599,274.87 1,433,374,693

Table 78 shows the estimation of the net income for ATR. Cash

inflow and outflow are from the sensibility study performed. Payback

period will then be calculated using:

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟

5,477,642,247.85
=
1,433,374,693

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟒. 𝟎𝟓 𝒚𝒆𝒂𝒓𝒔

H. Net Present Value

Net present value applies to a series of cash flows occurring at different

times. The present value of the cash flow depends on the interval of time

between now and the cash flow. It also depends on the discount rate. NPV

accounts for the time value of money. NPV is given by the equation:

𝑡
𝐶𝑡
∑ − 𝐶𝑜
(1 + 𝑟)8
𝑡=1
Ct = Net Cash Inflow

Co = Total Capital Investment

r = Discount rate

t = Number of Periods

Table 79. Estimation of the Net Present Value

Ct Co r t NPV

1,702,975,12 5,477,642,247.85 877,961


SMR 10% 8
8 ,476.4

-
SMR 1,433,374,69 5,477,642,247.85
10% 8 128,203
Plus 3
,264.7

365,296
ATR 1,653,637,775 5,806,176,973.00 10% 8
,836.8

A positive NPV indicates that the projected earnings generated by

the project or investment exceeds the anticipated cost while the one with

negative value will result in a net loss. Therefore, SMR Plus will not be

pursued.
I. Return on Investment For SMR

ROI (Return on Investment) measures the gain or loss generated on an

investment relative to the amount of money invested. ROI is usually expressed

as a percentage and is typically used for personal financial decisions, to compare

a company's profitability or to compare the efficiency of different investments.

ROI = (Net Profit / Total Investment) * 100

= 1,702,975,128.00/5,477,642,247.85 ∗ 100

= 31.09%

The proposed SMR plant will have a rate of investment of 31.09% per year.
CHAPTER V

ENVIRONMENTAL MANAGEMENT OF THE PROJECT

This chapter includes different impacts of Hydrogen production to humans

and all of the community, and the proper mitigation to it, complying with

environmental impact assessment (EIA) procedure.

Socio-Economic Benefits for each Design Option

This section presents the socio-economic benefits of the project.

A. Design option 1

The construction and development of steam methane reforming plant will

create job opportunities to the people within the area. This will greatly improve

the employment rate and thus decreasing the number of unemployed people

in the country. During the operation stage there would be approximately of

170 permanent staff members (managing operation and maintenance).

B. Design option 2

The Steam methane reforming plant provides socio-economic benefits to

Barangay Tabangao and its municipality. This project will provide more

knowledge and experience about steam reforming plant. Because of their

negative impact on the environment, public opinion should be taken into

consideration. The greater the information given, the greater the acceptance.
C. Design option 3

There are several benefits that can be acquired during the construction of

steam methane reforming plant. It would create an average around 500 new

jobs during the construction and operation stage. These data are general for

a regular plant but there are many more site-related workers that are difficult

to quantify: staff in charge of equipment suppliers, manufacturers and nuclear

fuel suppliers, staff from the regulatory institution or from engineering

companies, research groups, and etcetera. Ongoing training plans make it

possible to have highly qualified staff on the site, which improves safety,

availability and economic efficiency while guaranteeing quality execution of

safety-related tasks. So this power plant would leave a positive socio-

economic benefit.

Environmental Impact Assessment (EIA)

The main objective of the Environmental Impact Assessment is to

evaluate the project likely impacts on the environment. One of its key objectives

is to assist in ensuring environmentally and socially sound management of the

project during its lifecycle.

LAWS

A. Presidential Decree (PD) 1586: Philippine Environmental Impact

Statement
The law requires private corporations, firms or entities including

agencies and instrumentalities of the government to prepare an

environmental impact statement (EIS) for every proposed project and

undertaking which significantly affect the quality of the environment. The

EIS is a document that provides a comprehensive study of the significant

impact on the environment.

D. NATIONAL PLUMBING CODE 1993-1994 REVISION

ARTICLE I - DISPOSAL OF LIQUID WASTE P-1. It shall be

unlawful for any person to cause, suffer or permit the disposal of sewage,

human excrement or other liquid wastes, in any place or manner except

through and by means of an approved plumbing and drainage system,

installed and maintained in accordance with the provisions of this Code.

E. Republic Act No. 9275: The Philippine Clean Water Act of 2004

The law applies to water quality management in all water bodies. It

primarily applies to the abatement and control of pollution from land-based

sources. The water quality standards and regulations and the civil liability

and penal provisions under the law shall be enforced irrespective of

sources of pollution (Section 3).

In addition to regulating pollution of water bodies, DENR shall

formulate and apply standards for the transport and disposal of effluent,

sewage and septage offsite, whether offshore or on land as well as

disposal of individual wastewater on land. The Department of Agriculture


(DA) shall develop guidelines for re-use of wastewater for irrigation

purposes or as soil conditioner or fertilizer (Rule 3.1).

F. Republic Act (RA) 9003: Philippine Ecological Solid Waste

Management Act

This Act makes provision for the efficient solid waste management,

for the volume reduction of the waste, its environment friendly disposal,

composting, recycling, re-use, recovery, green charcoal process; for the

collection, treatment and disposal in environmentally sound solid waste

management facilities whereas it shall be possible to correctly dispose the

proper segregation, collection, transport, storage, treatment and disposal

of solid waste

LGUs Role under the Clean Water Act

LGUs shall share the responsibility in the management and improvement of

water quality within their territorial jurisdictions. (Sec. 20) Local Government Units

are the key players in the Water Quality Management Areas designated by

DENR in accordance with Sec. 5 of the Clean Water Act and its IRR

Waste Management

The proposed plant is set to follow the Presidential Decree No. 856

(Sanitation Code of the Philippines) and Republic Act no. 9003 (Ecological Solid

Waste Management Act) that covers the handling of solid waste disposal.
Social and Environmental Impacts

Hydrogen could have the potential to reshape the entire energy industry.

Environmental benefits are obvious. Whether hydrogen is combusted or

consumed in a fuel cell, it directly produces almost no local air pollutants or

greenhouse gas emissions. If vehicles were all run on hydrogen fuel cells, it

would be a huge step towards solving air pollution problems in cities. Emissions

of volatile organic compounds (VOCs, the precursors of ozone), SOx, NOx,

carbon monoxide, and particulate matter could be dramatically reduced if all

vehicles were fueled by hydrogen. According to the EPA, vehicles in the U.S.

account for 78% of carbon monoxide emissions, 45% of NOx, and 37% of

VOCs.These pollutants lead to human health and visibility problems.

Although no greenhouse gasses are released to the atmosphere when hydrogen

is consumed, some production methods do release greenhouse gasses into the

atmosphere. However, when carbon-based fuels are reformed or gasified to

produce hydrogen, a stream of nearly pure carbon dioxide is easily produced as

a byproduct. These technologies effectively decarbonize the fossil fuels.

Technologies are emerging to isolate this carbon dioxide from the atmosphere by

sequestering it in the ocean or in geological formations; however, the long-term

effects of carbon sequestration and storage security are not entirely known.

Material Safety Data Sheet


1. Chemical Products and Compositions

PRODUCT IDENTIFIER: Hydrogen

PRODUCT SYNONYMS: Dihydrogen, parahydrogen, refrigerant gas R702,

water gas

GENERAL USE: Some see hydrogen gas as the clean fuel of the future –

generated from water and returning to water when it is oxidised. Hydrogen-

powered fuel cells are increasingly being seen as ‘pollution-free’ sources of

energy and are now being used in some buses and cars. In the chemical industry

it is used to make ammonia for agricultural fertiliser (the Haber process) and

cyclohexane and methanol, which are intermediates in the production of plastics

and pharmaceuticals. It is also used to remove sulfur from fuels during the oil-

refining process. Large quantities of hydrogen are used to hydrogenate oils to

form fats, for example to make margarine. In the glass industry hydrogen is used

as a protective atmosphere for making flat glass sheets. In the electronics

industry it is used as a flushing gas during the manufacture of silicon chips. The

low density of hydrogen made it a natural choice for one of its first practical uses

– filling balloons and airships.

PRODUCT DESCRIPTION: hydrogen is a colorless, odorless, tasteless, non-

toxic, nonmetallic, highly combustible diatomic gas with the molecular formula

H2.

2. Hazards Identification/Emergency Overview

Hydrogen is a colorless, odorless, flammable gas or a colorless, odorless,


cryogenic liquid. The main health hazard associated with releases of this gas is

asphyxiation, by displacement of oxygen. The liquefied gas can cause frostbite to

any contaminated tissue. Hydrogen poses a serious fire hazard when it is

accidentally released. Flame or high temperature impinging on a localized area

of the cylinder of Hydrogen can cause the cylinder to rupture without activating

the cylinder’s relief devices. Provide adequate fire protection during emergency

response situations.

Figure 41. HYDROGEN GAS


OSHA REGULATORY STATUS: This material is considered hazardous by the

OSHA Hazard Communications Standard (29 CFR 1910.1200).

POTENTIAL HEALTH EFFECTS

Effects of a Single (Acute) Overexposure

Inhalation: Asphyxiant. Effects are due to lack of oxygen. Moderate

concentrations may cause headache, drowsiness, dizziness, excitation, excess

salivation, vomiting, and unconsciousness. Lack of oxygen can kill.

Skin Contact: No harm expected

Swallowing: An unlikely route of exposure; this product is a gas at normal

temperature and pressure.

Eye Contact: No harm expected.

Effects of Repeated (Chronic) Overexposure: No harm expected.

Medical Conditions Aggravated by Overexposure: The toxicology and the

physical and chemical properties of hydrogen suggest that overexposure is

unlikely to aggravate existing medical conditions.

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most

significant route of overexposure for this gas is by inhalation. The following

paragraphs describe symptoms of exposure by route of exposure.

CONCENTRATION SYMPTOMS OF EXPOSURE


12-16% Oxygen: Breathing and pulse rate increased,

muscular coordination slightly

disturbed.

10-14% Oxygen: Emotional upset, abnormal fatigue,

disturbed respiration.

6-10% Oxygen: Nausea and vomiting, collapse or loss

of consciousness.

Below 6%: Convulsive movements, possible

respiratory collapse, and death.

3. First Aid Measures

Remove victim(s) to a safe location. Trained personnel should administer

supplemental oxygen and/or cardiopulmonary resuscitation, if necessary.

Victim(s) must be taken for medical attention. Rescuers should be taken for

medical attention, if necessary. Take copy of label and MSDS to physician or

other health professional with victim(s). In case of frostbite, place the frostbitten

part in warm water. DO NOT USE HOT WATER. If warm water is not available,

or is impractical to use, wrap the affected parts gently in blankets. Alternatively, if

the fingers or hands are frostbitten, place the affected area of the body in the

armpit. Encourage victim to gently exercise the affected part while being warmed.

Seek immediate medical attention.


INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If

breathing is difficult, qualified personnel may give oxygen. Call a physician.

SKIN: An unlikely route of exposure. This product is a gas at normal temperature

and pressure.

SWALLOWING: An unlikely route of exposure. This product is a gas at normal

temperature and pressure.

EYE CONTACT: An unlikely route of exposure. This product is a gas at normal

temperature and pressure.

4. FIRE-FIGHTING MEASURES

FLASH POINT: Not applicable.

AUTOIGNITION TEMPERATURE: 571°C (1060°F)

FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): 4.0% Upper (UEL):

75.0% FIRE EXTINGUISHING MATERIALS: Extinguish fires of this gas by

shutting-off the source of the gas. Use water spray to cool fire-exposed

structures and equipment. UNUSUAL FIRE AND EXPLOSION HAZARDS: An

extreme explosion hazard exists in areas in which the gas has been released,

but the material has not yet ignited. Hydrogen burns with an almost invisible blue

flame.

FLAMMABLE PROPERTIES: Flammable gas. Flame is nearly invisible.

Escaping gas may ignite spontaneously. Hydrogen has a low ignition energy.
Fireball forms if gas cloud ignites immediately after release. Forms explosive

mixtures with air and oxidizing agents.

SUITABLE EXTINGUISHING MEDIA: CO2, dry chemical, water spray, or fog

PRODUCTS OF COMBUSTION: Water (H2O)

PROTECTION OF FIREFIGHTERS: Flammable high-pressure gas. Evacuate all

personnel from danger area. Immediately deluge cylinders with water from

maximum distance until cool; then move them away from fire area if without risk.

Continue cooling water spray while moving cylinders. Do not extinguish flames

emitted from cylinders; allow them to burn out. Self-contained breathing

apparatus may be required by rescue workers. On-site fire brigades must comply

with OSHA 29 CFR 1910.156.

Specific Physical and Chemical Hazards: Heat of fire can build pressure in

cylinder and cause it to rupture. Hydrogen cylinders are equipped with a pressure

relief device. (Exceptions may exist where authorized by DOT.) No part of a

cylinder should be subjected to a temperature higher than 125°F (52°C). If

venting or leaking hydrogen catches fire, do not extinguish flames. Flammable

gas may spread from leak, creating an explosive re-ignition hazard. Vapors can

be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical

equipment, static discharge, or other ignition sources at locations distant from

product handling point. Explosive atmospheres may linger. Before entering area,

especially confined areas, check atmosphere with approved explosion meter.


Protective Equipment and Precautions for Firefighters: Firefighters should

wear self-contained breathing apparatus and full fire-fighting turnout gear.

5. ACCIDENTAL MEASURES

SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to

by trained personnel using preplanned procedures. Proper protective equipment

should be used. In case of a release, clear the affected area and protect people.

Adequate fire protection must be provided. Minimum Personal Protective

Equipment should be Level B: fire-retardant protective clothing, mechanically-

resistant gloves and Self-Contained Breathing Apparatus. Use only non-sparking

tools and equipment. Locate and seal the source of the leaking gas. Protect

personnel attempting the shut-off with water-spray. Allow the gas, which is lighter

than air, to dissipate. Monitor the surrounding area for combustible gas levels

and oxygen. Combustible gas concentration must be below 10% of the LEL (LEL

= 4.0%) prior to entry of response personnel. The atmosphere must have at least

19.5 percent oxygen before personnel can be allowed in the area without Self-

Contained Breathing Apparatus. Attempt to close the main source valve prior to

entering the area. If this does not stop the release (or if it is not possible to reach

the valve), allow the gas to release in-place or remove it to a safe area and allow

the gas to be released there.

RESPONSE TO CRYOGENIC RELEASE: Clear the affected area and allow the

liquid to evaporate and the gas to dissipate. After the gas is formed, follow the
instructions provided in the previous paragraph. If the area must be entered by

emergency personnel, SCBA, Kevlar gloves, and appropriate foot and leg

protection must be worn. This is an extremely flammable gas. Protection of all

personnel and the area must be maintained.

Personal Precautions: Forms explosive mixtures with air. Immediately evacuate

all personnel from danger area. Use self-contained breathing apparatus where

needed. Approach suspected leak area with caution. Remove all sources of

ignition if without risk. Reduce gas with fog or fine water spray. Shut off flow if

without risk. Ventilate area or move cylinder to a well-ventilated area. Flammable

gas may spread from leak. Before entering area, especially confined areas,

check atmosphere with an appropriate device.

Environmental Precautions: Prevent waste from contaminating the surrounding

environment. Keep personnel away. Discard any product, residue, disposable

container, or liner in an environmentally acceptable manner, in full compliance

with federal, state, and local regulations. If necessary, call your local supplier for

assistance.

6. HANDLING AND STORAGE

WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid

getting Hydrogen IN YOU. Do not eat or drink while handling chemicals. Be

aware of any signs of dizziness or fatigue; exposures to fatal concentrations of

Hydrogen could occur without any significant warning symptoms.


STORAGE AND HANDLING PRACTICES: Cylinders should be stored in dry,

well-ventilated areas away from sources of heat. Compressed gases can present

significant safety hazards. Store containers away from heavily trafficked areas

and emergency exits. Post “No Smoking or Open Flames” signs in storage or use

areas. Note: Liquid Hydrogen must always be handled in air-tight systems

specifically designed and installed for liquid Hydrogen, according to the

appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s

internal specifications. Liquid Hydrogen must never be filled into or handled in

open top or loosely capped Dewars. An atmospheric concentration of Hydrogen

greater than the LEL will immediately be generated near the vicinity of the

Dewar, creating an extreme fire and explosion hazard. This gas is lighter than air

and must not be allowed to accumulate in elevated locations.

SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Protect

cylinders against physical damage. Store in cool, dry, well-ventilated area, away

from sources of heat, ignition and direct sunlight. Do not allow area where

cylinders are stored to exceed 52°C (125°F). Isolate from oxidizers such as

oxygen, chlorine, or fluorine. Use a check valve or trap in the discharge line to

prevent hazardous backflow. Post “No Smoking or Open Flame” signs in storage

and use areas. Cylinders should be stored upright and be firmly secured to

prevent falling or being knocked over. Cylinders can be stored in the open, but in

such cases, should be protected against extremes of weather and from the

dampness of the ground to prevent rusting. Never tamper with pressure relief

devices in valves and cylinders. Electrical equipment should be non-sparking or


explosion proof. The following rules are applicable to situations in which cylinders

are being used: Before Use: Move cylinders with a suitable hand-truck. Do not

drag, slide or roll cylinders. Do not drop cylinders or permit them to strike each

other. Secure cylinders firmly. Leave the valve protection cap, if provided, in-

place until cylinder is ready for use. During Use: Use designated CGA fittings and

other support equipment. Do not use adapters. Do not heat cylinder by any

means to increase the discharge rate of the product from the cylinder. Use check

valve or trap in discharge line to prevent hazardous backflow into the cylinder. Do

not use oils or grease on gas-handling fittings or equipment. After Use: Close

main cylinder valve. Replace valve protection cap, if provided. Mark empty

cylinders “EMPTY”.

7. Exposure Controls/Personal Protection

PERSONAL PROTECTIVE EQUIPMENT:

Skin Protection: Wear work gloves for cylinder handling and metatarsal shoes

for cylinder handling. Regardless of protective equipment, never touch live

electrical parts.

Eye/Face Protection: Splash goggles or safety glasses, for protection from

rapidly expanding gases and splashes of liquid Hydrogen.

Respiratory Protection: None required under normal use. An air-supplied

respirator must be used in confined spaces.


HAND PROTECTION: Wear mechanically-resistant gloves when handling

cylinders of Hydrogen. Use low temperature protective gloves (e.g., Kevlar) when

working with containers of Liquid Hydrogen.

BODY PROTECTION: Use body protection appropriate for task. Transfer of

large quantities under pressure may require protective equipment appropriate to

protect employees from splashes of liquefied product, as well as fire retardant

items. If a hazard of injury to the feet exists due to falling objects, rolling objects,

where objects may pierce the soles of the feet or where employee’s feet may be

exposed to electrical hazards, use foot protection.

8. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Colorless gas

ODOR: Odorless

ODOR THRESHOLD: Not applicable.

PHYSICAL STATE: Gas at normal temperature and pressure

pH: Not applicable.

MELTING POINT at 1 atm: -434.56°F (-259.2°C)

BOILING POINT at 1 atm: -422.97°F (-252.76°C)

FLASH POINT (test method): Not available.

EVAPORATION RATE (Butyl Acetate = 1): Not applicable.


FLAMMABILITY: Flammable

FLAMMABLE LIMITS IN AIR, % by volume: LOWER: 4.0% UPPER: 75.0%

LIQUID DENSITY at boiling point and 1 atm: 4.43 lb/ft3 (70.96 kg/m3)

VAPOR PRESSURE at 68°F (20°C): Not applicable.

VAPOR DENSITY at 70°F (21.1°C) and 1 atm: 0.0052 lb/ft3 (0.083 kg/m3)

SPECIFIC GRAVITY (H2O = 1) at 19.4°F (-7°C): Not available.

SPECIFIC GRAVITY (Air = 1) at 32°F (0°C) and 1atm: 0.07

SOLUBILITY IN WATER vol/vol at 60°F (15.6°C) and 1 atm: 0.019

PARTITION COEFFICIENT: n-octanol/water: Not available.

AUTOIGNITION TEMPERATURE: 932°F (500°C)

DECOMPOSITION TEMPERATURE: Not available.

PERCENT VOLATILES BY VOLUME: 100

MOLECULAR WEIGHT: 2.016

MOLECULAR FORMULA: H2

9. TOXICOLOGICAL INFORMATION

TOXICITY DATA: There are no specific toxicology data for Hydrogen. Hydrogen

is a simple asphyxiant, which acts to displace oxygen in the environment.


SUSPECTED CANCER AGENT: Hydrogen is not found on the following lists:

FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC, and therefore is not

considered to be, nor suspected to be a cancer-causing agent by these

agencies.

IRRITANCY OF PRODUCT: Contact with rapidly expanding gases can be

irritating to exposed skin and eyes.

SENSITIZATION OF PRODUCT: Hydrogen is not a sensitizer after prolonged or

repeated exposure.

REPRODUCTIVE TOXICITY INFORMATION: Listed below is information

concerning the effects of Hydrogen on the human reproductive system.

Mutagenicity: Hydrogen is not expected to cause mutagenic effects in humans.

Embryotoxcity: No embryotoxic effects have been described for Hydrogen.

Teratogenicity: Hydrogen is not expected to cause teratogenic effects in

humans. Reproductive Toxicity: Hydrogen is not expected to cause adverse

reproductive effects in humans.

BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure

Indices (BEIs) are not applicable for Hydrogen.

10. ECOLOGICAL INFORMATION

ENVIRONMENTAL STABILITY: Hydrogen occurs naturally in the atmosphere.

The gas will be dissipated rapidly in well-ventilated areas.


EFFECT OF MATERIAL ON PLANTS or ANIMALS: Any adverse effect on

animals would be related to oxygen deficient environments. No adverse effect is

anticipated to occur to plant-life, except for frost produced in the presence of

rapidly expanding gases.

EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available

on the effects of Hydrogen on aquatic life.

11. DISPOSAL CONSIDERATIONS

PREPARING WASTES FOR DISPOSAL: Product removed from the cylinder

must be disposed. Return cylinders with residual product. Do not dispose of

locally.

12. TRANSPORTATION INFORMATION

PROPER SHIPPING NAME: Hydrogen, compressed

HAZARD CLASS NUMBER and DESCRIPTION: 2.1 (Flammable Gas)

UN IDENTIFICATION NUMBER: UN 1049 UN 1966

PACKING GROUP: Not Applicable

DOT LABEL(S) REQUIRED: Class 2.1 (Flammable Gas)

SPECIAL PROVISIONS: None None

EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX: 0.12

ERAP INDEX: 3000


PASSENGER CARRYING SHIP INDEX: Forbidden

PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: Forbidden

13. REGULATORY INFORMATION

The following selected regulatory requirements may apply to this product. Not all

such requirements are identified. Users of this product are solely responsible for

compliance with all applicable federal, state, and local regulations.

EPA (ENVIRONMENTAL PROTECTION AGENCY) CERCLA:

COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND

LIABILITY ACT OF 1980 (40 CFR Parts 117 and 302):

Reportable Quantity (RQ): None

SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:

SECTIONS 302/304: Require emergency planning based on Threshold Planning

Quantity (TPQ) and release reporting based on Reportable Quantities (RQ) of

Extremely Hazardous Substances (EHS) (40 CFR Part 355):

TPQ: None

EHS RQ (40 CFR 355): None

SECTIONS 311/312: Require submission of MSDSs and reporting of chemical

inventories with identification of EPA hazard categories. The hazard categories

for this product are as follows:

IMMEDIATE: No PRESSURE: Yes


DELAYED: No REACTIVITY: Nos

FIRE: Yes

Material Safety Data Sheet

14. Chemical Products and Compositions

PRODUCT IDENTIFIER: Carbon Dioxide

PRODUCT SYNONYMS: Carbonic Acid Gas

GENERAL USE: Carbon dioxide is widely used commercially. It is used in the

chemicals processing industries to control reactor temperatures, to neutralise

alkaline effluents and used under supercritical conditions for purifying or dying

polymer, animal or vegetal fibres. ndustrially, carbon dioxide is typically used for

process control, examples of which include the use of carbon dioxide for red

fume suppression during scrap and carbon charging, for nitrogen pick-up

reduction during electric arc furnace tapping and for bottom stirring. In non-

ferrous metallurgy, carbon dioxide is used for fume suppression during ladle

transfer of matte (Cu/Ni production) or bullion (Zn/Pb production). Carbon dioxide

is used to enhance the recovery of oil from wells where primary and secondary

methods are no longer cost-effective on their own.

PRODUCT DESCRIPTION: Carbon Dioxide is a colorless gas with a density

about 60% higher than that of dry air.

15. Hazards Identification/Emergency Overview

Main Hazards: Carbon dioxide does not support life. It can act as a simple
asphyxiant by diluting the concentration of oxygen in air below the levels

necessary to support life. As it is heavier than air it will tend to concentrate at

lower levels.

Adverse Health Effects: Carbon dioxide acts as a stimulant and depressant on

the central nervous system. Increases in heart rate and blood pressure have

been noted at a concentration of 7.6 percent, and dyspnea (laboured breathing),

headache, dizziness and sweating occur if exposure at that level is prolonged.

Chemical Hazards: Carbon dioxide is relatively non-reactive and non-toxic. In

the presence of moisture it can aggressively bring about corrosion in a variety of

steel materials.

Biological Hazards: The greatest physiological effect of carbon dioxide is to

stimulate the respiratory centre, thereby controlling the volume and rate of

respiration. It is able to cause dilation and constriction of blood vessels and is a

vital constituent of the acid-base mechanism that controls the pH of the blood.

Vapour Inhalation: At concentrations of 10% and above, unconsciousness can

result in one minute or less. Impairment in performance has been noted during

prolonged exposure to concentrations of 3% carbon dioxide even when the

oxygen concentration was 21%.

16. First Aid Measures

Ingestion: Prompt medical attention is mandatory in all cases of overexposure to

carbon dioxide. Rescue personnel should be equipped with selfcontained

breathing apparatus. Gaseous carbon dioxide is an asphyxiant. Concentrations

of 10% or more can produce death or unconsciousness. Lower concentrations


may cause sweating, headache, rapid breathing, increase heartbeat, shortness

of breath, dizziness, mental depression, visual disturbance, shaking. Conscious

persons should be assisted to an uncontaminated area and inhale fresh air.

Quick removal from contaminated area is most important. Unconscious persons

should be removed to an uncontaminated area, given mouth-to-mouth

resuscitation and supplemental oxygen.

17. FIRE-FIGHTING MEASURES

Extinguishing Media: Carbon dioxide is an extinguishing medium.

Specific Hazards: Carbon dioxide does not support life. It can act as a simple

asphyxiant by diluting the concentration of oxygen in the air below the levels to

support life.

Emergency Actions: If possible, shut off the source of excess carbon dioxide.

Evacuate area. All cylinders should be removed from the vicinity of the fire.

Cylinders that cannot be removed should be cooled with water from a safe

distance. Cylinders that have been exposed to excessive heat should be clearly

identified and returned to the supplier.

Protective Clothing: Self-contained breathing apparatus. Safety gloves and

shoes, or boots, should be worn when handling cylinders.

Environmental Precautions: Carbon dioxide is heavier than air and could

accumulate in low-lying areas. Care should be taken when entering a potentially

oxygen deficient environment. If possible, ventilate the affected area.


18. ACCIDENTAL MEASURES

Personal Precautions: Do not enter any area where carbon dioxide has been

spilled unless tests have shown that it is safe to do so.

Environmental Precautions: As carbon dioxide is classified as a “greenhouse”

gas, any spillage should be avoided at all times.

Small Spills: Shut off the source of escaping carbon dioxide. Ventilate the area.

Large Spills: Evacuate the area. Shut off the source of the spill if this can be

done without risk. Restrict access to the area until completion of the cleanup

procedure. Ventilate the area using forced-draught if necessary.

19. HANDLING AND STORAGE

Do not allow cylinders to slide or come into contact with sharp edges. Carbon

dioxide cylinders should be stacked vertically at all times, should be firmly

secured in order to prevent them from being knocked over. Use a “first-in first-

out” inventory system to prevent full cylinders from being stored for excessive

periods of time. Keep out of reach of children.

20. Exposure Controls/Personal Protection

Occupational Exposure Hazards: As carbon dioxide is a simple asphyxiant,

avoid any areas where spillage has taken place. Only enter once testing has

proved the atmosphere to be safe, and remember that gas is heavier than air.
Engineering Control Measures: Engineering control measures are preferred to

reduce exposure to oxygen-depleted atmospheres. General methods include

forceddraught ventilation, separate from other exhaust ventilation systems.

Ensure that sufficient fresh air enters at, or near, floor level.

Personal Protection: Self-contained breathing apparatus should always be

worn when entering area where oxygen depletion may have occurred. Safety

goggles, gloves and shoes, or boots, should be worn when handling cylinders.

21. PHYSICAL AND CHEMICAL PROPERTIES

Chemical Symbol: CO2

Molecular Weight: 44.01

Specific volume @ 20°C & 101,325 kPa: 547 ml/g

Density gas @ 101,325 kPa & 20°C: 1522

Relative density (Air=1) @ 101,325 kPa: None

Colour: Acidic

Odour: None

22. TOXICOLOGICAL INFORMATION

Acute Toxicity: TLV 5000 VPM

23. ECOLOGICAL INFORMATION


Carbon dioxide is heavier than air and can cause pockets of oxygendepleted

atmosphere in low-lying areas. It does not pose a hazard to the ecology.

24. DISPOSAL CONSIDERATIONS

Disposal Methods: Small amounts may be blown to the atmosphere under

controlled conditions. The gas supplier should only handle large amounts.

Disposal of Packaging: The gas supplier must only handle the disposal of

cylinders.

25. TRANSPORTATION INFORMATION

ROAD TRANSPORTATION

UN No: 1013

Erg No: 120

Hazchem warning: 2C Non-flammable Gas

SEA TRANSPORTATION

IMDG: 101

26. REGULATORY INFORMATION


SOLID WASTE MANAGEMENT

Methods

The solid wastes of the company are generated from the offices, cafeteria,

clinic, dormitory and laboratory. This includes food wastes, plastics, bottles,

papers, laboratory containers, medical wastes and other solid wastes not

aforementioned.

Laboratory Hazardous Solid Wastes


The personnel of the Laboratory are responsible for taking the hazardous

wastes in the laboratory to the bins. The solid chemical waste containers in the

laboratory should have labels and must be kept sealed and closed at all times.

The waste chemicals containers should not be allowed to accumulate in

the laboratories and other work areas. The filled waste containers is then

transferred to the Material Recovery Facility (MRF) at a regular collection or as

needed prior to disposal.

Segregation

The segregation of the wastes will be mandated and highly practiced by

providing separate waste bins for papers, recyclable plastic bottles, plastics, food

wastes, compost, and laboratory wastes placed on different areas of the plant.

The residual wastes coming from the air filter and dirt from each facility also have

separate bins. The 5S and 3R’s methodology/system is strictly implemented in

the company in order to provide a cleaner and friendlier environment for the

entire plant.
Figure 42. Material Recovery Facility (MFR) Segregation Flow

The waste materials collected within the entire plant are unloaded and

placed on the Materials Recovery Facility of the plant where the recyclable

materials generated are sorted using manual and automatic labor and are

recovered prior to disposal. In the MRF, the materials collected have separate

storage where it placed and recovered.

 Papers from the offices

 Plastic containers from the cafeteria

 Glass bottles and shards waste from the laboratory

 Metal wastes from the workshop

 Hazardous wastes from the laboratory

 Medical wastes from the clinic

 Food wastes from the cafeteria


 Residual and composts wastes

Figure 43. Waste Bins Types for Effective Segregation

The Material Recovery Facility (MRF), the wastes will be sorted into their

respective types. The company will sell the recyclable materials such as papers

and plastic containers to junk shops or other manufacturers wherein they

reprocess the wastes to create new products. For the food wastes, compost,

residual wastes, and other non-recyclable materials, they will be collected and

thrown away into landfill or composts pits through their appropriate collections.

The proposed plant will be under the SGS Philippines via SGS

environmental waste management services that can help us to recycle, treat and

dispose of our waste to meet the ethical standards as well as governing

regulatory requirements.

Their waste management services include:


 Repack of dangerous waste and products

 Waste reconditioning

 Waste care

Processing is carried out in their licensed treatment plants by their accredited

technicians. In cases of urgent reconditioning of dangerous products –

transferring products from drums to other containers, for example – their

environmental waste teams have the expertise to overcome challenges quickly

and efficiently. This ensures that the products are back in the supply chain as

soon as possible and the waste management processes are enhancing the

business by meeting environmental standards.

WASTEWATER MANAGEMENT

Diffused Pond Aeration

Wastewater pond aeration systems provide reliable, low cost, and relatively low

maintenance treatment for municipal and industrial discharges (US-EPA, August

2011). The most common types of pond aeration systems are surface aerators

and diffused aerators. For the treatment of wastewater generated by the plant,

diffused aeration was selected and used.

In diffused aeration system, infused air or oxygen is utilized into the pond. A tube

diffuser is used which consists of a perforated tube suspended in the wastewater

near the bottom and can be taken out while cleaning. The air comes out through

the holes with great force and agitates the sewage. The set up involves air

compressor that pushes air through tubing down to diffuses located and the
bottom of the pond where bubbles are released into the pond. This provides

oxygen to bacteria for treating and stabilizing the wastewater to allow

biodegrading to occur which breaks down the organic matter containing carbon

to form carbon dioxide and water. In diffused aeration process, larger/ deeper

ponds of more than 8 feet deep is typically used.

Diffused aeration process allows the treated wastewater to be safely used for

gardening or lawn watering and can even be recycled for toilet flushing within the

plant.
CHAPTER VI

PROJECT DESIGN TRADE-OFFS

This chapter covers the evaluation of the three design options presented

in the previous chapter using multiple realistic constraints which includes

technical, economic and environmental constraints in selecting the best design

option. The best design option is been selected using design philosophies such

as Worst Case Design and Pareto Optimum.

A. Multiple Realistic Constraints

The following are the realistic constraints that have taken into account in

order to come up with a conclusion which design option is the best.

1. Technical

For the technical area, plant energy efficiency was used as

parameter in determining the best design option. Based on chapter 3, the

values below are computed:

Table 80. Plant Energy Efficiency

MRC DO1(SMR) DO2(SMR+) DO3(ATR)

PEE 82 % 78 % 82%

2. Economics
For the economics area, Net Present value was used as parameter

in determining the best design option. Based on chapter 4, the values

below are computed:

Table 81. Net Present Value

MRC DO1(SMR) DO2(SMR+) DO3(ATR)

NPV P 877,961,476.4 -P 1287,203,264.4 P 365,296,836.8

3. Environmental

For the environmental area, Level of emission was used as

parameter in determining the best design option. Based on chapter 5, the

values below are computed:

Table 82. Level of Emissions

MRC DO1(SMR) DO2(SMR+) DO3(ATR)

LOE Medium Medium- Low Low

B. Worst Case Design

In this design philosophy, the designers summarize the multiple realistic

constraints above in order to come up with the best design option by determining

the lowest possible value for the three design option in each parameter. The

table shows the summarize values following a scale from 10 -1 as 10 as the

highest.
Table 83. Summary of Multiple Realistic Constraints

MRC DO1(SMR) DO2(SMR+) DO3(ATR)

PEE 8.2 7.8 8.2

NPV 7 3 5

LOE 7 8 9

Results

The table below shows the lowest value for each design option.

Table 84. Summary of Results

Design Option Lowest Value

DO1(SMR) 7

DO2(SMR+) 3

DO3(ATR) 5

Based on the Worst Case Design Philosophy, the designers found out that

Design Option 1(SMR) is the best design option to be used in the selection of

Steam Methane Reforming Plant among the three design options.


B. Pareto Optimum Design

In this design philosophy, the designers summarize the multiple realistic

constraints above in order to come up with the best design option by determining

the degree of importance of each parameter and multiplying it to each value. The

table shows the summarize values following a scale from 10 -1 as 10 as the

highest. Degree of importance uses a scale from 1-5 as 5 as the highest.

Table 85. Summary of Multiple Realistic Constraints

MRC DO1(SMR) DO2(SMR+) DO3(ATR) Degree of

Importance

PEE 8.2 7.8 8.2 3

NPV 7 3 5 5

LOE 7 8 9 4

Results

The table below shows the lowest value for each design option.

Table 86. Summary of Results

Design Option Summation

DO1(SMR) 8.2 (3) + 7 (5) + 7 (4) = 87.6


DO2(SMR+) 7.8 (3) + 3 (5) + 8 (4) = 70.4

DO3(ATR) 8.2 (3) + 5 (5) + 9 (4) = 85.6

Based on the Pareto Optimum Design Philosophy, the designers found

out that Design Option 1(SMR) is still the best design option to be used in the

selection of Steam Methane Reforming Plant among the three design options.
CHAPTER VII

PROJECT CONSTRUCTION AND EXECUTION PLAN

Pre-operation and operation phase planning and management are

covered in this chapter. Proper management of the plant is essential to

ensure its profitability and efficiency. Different aspects are considered for the

execution of the proposed plant.

A. Pre-Operation Period

Construction period spans from December of 2019 to January 2023.

Market feasibility study, geographical study, environmental management

study, financial study, and technical study

1. Market Feasibility Study

A market feasibility study determines the depth and condition of a

particular real estate market and its ability to support a particular

development. The key concern of a market feasibility study for multifamily

development is a project's ultimate marketability.

2. Geographical Study

Selecting the best plant location is crucial as it will be the site where all

major manufacturing operations will take place. There are salient factors

which must be considered, analyzed, and graded first accordingly to

determine the optimal plant location. The usual aim is to select a location

that will result in the lowest average cost of the products, delivered to retail
outlets. There may be other social or political objectives such as

increasing employment in a depressed region. Moreover, on a national

basis plant location within a country are likely to be preferred for reasons

of national security, foreign exchange saving, and increasing employment.

2.1 Raw Materials Availability

Raw materials availability is the foremost deciding factor in

choosing a plant location. Without raw materials, production of a

product from a certain company will cease to survive. Preferably, a

plant must be erected near the source of raw materials. The rationale

is to minimize total transportation costs and to reduce consumption of

time. Other Important points to consider are the supply of raw

materials, price of raw materials, storage requirements and lastly

quality of raw materials.

2.2 Accessibility

Accessibility of the target market is vital in increasing the

profitability of the company. Ease of access to the intermediate

distribution centers or location of the target markets significantly affects

the cost of product distribution and the required time for shipping.

Likewise, potential buyers will be more inclined into buying finished

goods from manufacturers that are within their reach. It is also ideal

that marketing and sales of the product should be down in markets in

which it is widely known and consumed.


2.3 Transportation Facilities

Transportation facilities are of great importance to help purchase

raw materials and to deliver finished products faster and cheaper to

designated locations. Ideally, a plant should have proximity to different

types of transport: road, rail, waterway, or airport. Road transport is

used for local distribution from warehouse. Rail transport is more

economical for longer distance travels. Air transport is convenient and

efficient for the movement of personnel and supplies. Good condition

of national roads, bridges, airports and other industrial transportation

facilities should be ensured.

2.4 Labor

The type and supply of labor available in the vicinity of a proposed

plant site must be examined. Consideration should be given to

prevailing pay scales, restrictions on number of hours worked per

week, competing industries that can cause dissatisfaction or high

turnover rates among the workers, and variations in the skill and

productivity of the workers. Skilled operators will usually be brought in

from the outside the site, but there should be an adequate pool of

unskilled labors available locally; and labors suitable for training to

operate the plant. Skilled engineers will be needed for plant

maintenance.

2.5 Utilities Availability


One major factor in the choice of plant location is the availability of

utilities to maintain smooth and continuous plant operation. The plant

relies to sufficient supply of electricity and water hence selecting a site

which has minimal risks of power interruptions and water shortage is

imperative.

2.6 Climatic Condition

If the plant is located in a cold climate, costs may be increased by

the necessity for construction of protective shelters around the process

equipment, and special cooling towers or air conditioning equipment

may be required if the prevailing temperatures are high. Excessive

humidity or extremes of hot or cold weather can have a serious effect

on the economic operation of a plant, and these factors should be

examined when a plant site is selected.

3. Environmental Management Study

As stated in the local and international environmental laws, a proper

waste treatment and disposal must be administered effectively and

efficiently in accordance with the standards set by the local and

international government and agencies. This is to ensure the entire plant

facilities are compliant with the enacted laws such as the Republic Act No.

9275 (Philippine Clean Water Act of 2004), Republic Act No. 8749

(Philippine Clean Air Act of 1999), Republic Act No. 9003 (Ecological Solid
Waste Management Act of 2000) and DAO No. 2016-08 (Water Quality

Guidelines and General Effluent Standards of 2016).

Environmental constraints that must be managed are as follows:

3.1 Airborne Emission Management

The air quality in the manufacturing area of the SMR plant can affect

the health of the company’s workforce. A polluted environment can

undermine the competitiveness and destroy the company’s quality.

3.2 Solid Waste Management

The goal in solid waste management is to reduce and eliminate the

adverse effects of waste materials on human health and environment to

support economic development and productivity.

The proposed SMR plant is set to follow the Presidential Decree No.

856 (Sanitation Code of the Philippines) and Republic Act no. 9003

(Ecological Solid Waste Management Act) that covers the handling of

solid waste disposal.

3.3 Wastewater Management

A wastewater treatment facility treatment facility treating industrial

effluent that complies with the environmental regulation of the

Philippine Economic Zone Authority (PEZA) which monitors the quality

of the water from the Clark Freeport Zone in compliance with the

Republic Act No. 9275 or the Philippine Clean Water Act of 2004 and
the DAO 2016-08 or the Water Quality Guidelines and General Effluent

Standards of 2016.

4. Financial Study

Financial analysis is the process of evaluating businesses, projects,

budgets and other finance-related entities to determine their performance

and suitability. Typically, financial analysis is used to analyze whether an

entity is stable, solvent, liquid or profitable enough to warrant a monetary

investment.

5. Technical Study

Technical study involves thedata and information as well as the

assumptions related to the technical aspects and requirements needed for

the design of the steam methane reforming plant. Standards were used to

come up with a technically viable design. Technical catalogues were used

to carefully identify the design specifications of each equipment.

The allotted construction period must be utilized and maximized

accordingly to ensure maximum productivity. Time must be considered as a

non-physical resource that must be used appropriately.

B. Operation Period

The proposed SMR plant is planned to operate three hundred forty (340)

days a year, seven (7) days a week, and twenty-four (24) hours a day.

Twenty-five (25) day shutdown will be conducted annually for necessary


maintenance and repairs, and to evaluate problems within the plant. Annual

shutdown will be conducted every start of May every year to avoid extreme

weather that is critical to the following operation. Extensive planning is to be

conducted prior to shutdown to ensure that resources will be utilized properly

and efficiently.

C. Employee Work Schedule

The proposed SMR plant will have a total of 170 workers from seven (7)

departments namely: Human Resources, Research and Development,

Operations, Quality Assurance and Quality Control, Finance, and Marketing.

Table 87. Administration Employees’ Work Schedule

Administration Employees' Work Schedule


7:00
7:15
7:30
7:45
8:00
8:15
8:30
8:45
9:00
Morning Break
9:15
9:30
9:45
10:00
10:15
10:30
10:45
11:00
11:15
11:30
11:45
12:00 Lunch Break
12:15
12:30
12:45
1:00
1:15
1:30
1:45
2:00
2:15
2:30
2:45
Afternoon Break
3:00
3:15
3:30
3:45
4:00

Administration employees have a weekday work schedule, from Monday

to Friday, 7:00 A.M. to 4:00 P.M. Two fifteen (15) minute breaks are allotted

one in the morning and one in the afternoon. There will be allotted lunch

break of one (1) hour from 11:30 A.M. to 12:30 P.M.


Shift A Shift B Shift C
6:00 2:00 10:00
6:15 2:15 10:15
6:30 2:30 10:30
6:45 2:45 10:45
7:00 3:00 11:00
7:15 3:15 11:15
7:30 3:30 11:30
7:45 3:45 11:45
8:00 4:00 12:00
8:15 4:15 12:15
8:30 4:30 12:30
8:45 4:45 12:45
9:00 5:00 1:00
9:15 5:15 1:15
Team 1's Break Team 1's Break Team 1's Break
9:30 5:30 1:30
9:45 5:45 1:45
10:00 6:00 2:00
10:15 6:15 2:15
10:30 6:30 2:30
Team 2's Break Team 2's Break Team 2's Break
10:45 6:45 2:45
11:00 7:00 3:00
11:15 7:15 3:15
11:30 7:30 3:30
11:45 7:45 3:45
12:00 8:00 4:00
12:15 8:15 4:15
12:30 8:30 4:30
12:45 8:45 4:45
1:00 9:00 5:00
1:15 9:15 5:15
1:30 9:30 5:30
1:45 9:45 5:45
2:00 10:00 6:00
Table 88. Field Worker’s Work Schedule
On-site production workers are required to report on duty from Monday to

Sunday. Three shifts are available: 1.) from 6:00 A.M. to 2:00 P.M. 2.) from

2:00 P.M. to 10:00 P.M. and, 3.) from 10:00 P.M. to 6:00 A.M. Quarterly

rotational shiftwork will be observed. The first team in the first shift will have a

break from 9:00 A.M. until 10:00 A.M. while the second team will have a

break from 10:00 A.M. until 11:00 A.M. On the other hand, the first team of

the second shift will have a break from 5:00 P.M. until 6:00 P.M. while the

second team will have a break from 6:00 P.M. until 7:00 P.M. Finally, the first

team in the third shift will have a break from 1:00 A.M. until 2:00 A.M. while

the second team will have a break from 2:00 A.M. to 3:00 A.M.

Employees are expected to manifest punctuality and are obliged to follow

company work ethics and regulations stated by the provision of the

Presidential Decree No. 442 or The Labor Code of the Philippines. Failure to

do so will result to corresponding sanction as prescribed by the management.

D. Quality Assurance and Control

The proposed SMR plant will have a dedicated for quality assurance and

control. The Quality Assurance and Quality Control Department conducts

strict measures in assuring that finished goods passed necessary quality tests

and standards before ultimately reaching the market. The department targets

zero defect and a hundred percent quality products that will bring long-term

revenue and profitability, maintain customer satisfaction and loyalty, and

lessen the risk and cost of replacing defective goods. The department is also
responsible in keeping the business on the cutting edge through constant

drive for development in the industry.

Furthermore, the proposed SMR plant will strive to attain certifications

such as ISO 9001:2008. ISO 9001:2008 is defined as the international

standard that specifies requirements for a quality management system. It

is used to demonstrate the ability to consistently provide products and

services that meet customer and regulatory requirements.

E. Time Table

Gantt chart will be used and done to evaluate and plan the activities prior

to the operation period. This is to help the project to be in track in all of its

plans. A properly scheduled project will be more efficient in terms of time,

labor, and cost.


Table 89. Gantt Chart for the Pre-Operation Phase of SMR Plant
CHAPTER VIII

SUMMARY OF FINDINGS, CONCLUSIONS AND RECOMMENDATIONS

This chapter summarizes the overall rundown of the results and details

regarding the chosen design option, and includes the summary of findings,

conclusion and recommendations for the development of a Steam Methane

Reforming Plant.

Summary of Findings

The following are the findings relative to the design options chosen for the

Steam Methane Reforming Plant were summarized as follows:

1. SMR(DO1) and ATR(DO3) are the most energy efficient design options for

carbon-lean hydrogen production, both with a plant energy efficiency of

82%. ATR(DO3) has the most potential of further emission reduction but

SMR is the most economical design option of the 3 design options.

2. SMR(DO1) is the most cost-efficient design option for large-scale

operation in the Philippines, producing carbon lean hydrogen at a price of

Php 119.6/kg in a 92.352 tons/ day facility.

3. The SMR(DO1) will be the chosen design option for the development of a

Steam Methane Reforming Plant base on the design trade-offs in the

previous chapter.

4. The designed Steam Methane Reforming plant will use 9,903 kg/hr

desulphurized Natural Gas and 29,540 kg/hr demineralized water as its

raw material to produce a 31400 tons/ year of H2. The steam methane
reforming process is divided into five main sections: pre-reforming, steam

reforming, water gas shifting, CO2 absorbtion and pressure swing

adsorption. Gas-heated Reformer, Steam Methane Reformer, Water gas

Shifter, CO2 Absorber, Pressure swing Absorber and Furnace will be the

main equipment’s of the plant.

5. Total Capital Investments will be Php 1,370,000,000.00 with yearly

operating expenditures of Php, 464,809,549.02. The payback period is

3.22 years. The Net present value of the power plant after 8 years of

operation will be Php 877,961,476.4 at 31.09% rate of return.

Conclusion

Based on the data gathered, the proponents have come up with the

following conclusions:

1. Hydrogen is a promising energy carrier with the potential to reduce CO2

emissions from fossil resources, integrate renewables with the society and

replace fossil fuels in the transportation sector. The Idea of a hydrogen-

based energy chain is not new, but with recent developments in

renewable industries and political support, the conditions are improving

significantly.

2. This production plant will be the first hydrogen producing plant in the

Philippines if construction is pursued and the equipments that would be

used will be similar to the standard steam methane reforming plants in


other countries which will make it easier to purchase and acquire spare

parts in the future.

3. The Steam Methane Reforming Plant’s HSE policy shall focus in

operation, maintenance and facilities. The employees will be oriented of

health and safety regarding proper wearing of PPE, hazard present in the

plant and emergency plan procedures for handling sudden or unexpected

scenarios. The management of the plant will have a mitigation plan in the

problem that may affect the environment. The most important

environmental benefit of steam methane reforming is the capability to

capture 72 % CO2 emissions while producing lean and 99.99% hydrogen

at a high volume rate.

Recommendation

For further development of the Steam Methane Reforming Plant,

recommendations are suggested below according to the assumptions,

calculations and conclusions obtained.

1. Additional information and data are required to develop cost-effective,

reliable, emission-compliant systems for steam methane reforming plant

because Philippines is new to this kind of production plant.

2. Periodical check-ups, regular maintenance and inspection of equipment

must be exercised to avoid faulty equipment for the continuous operation

of the plant.
3. Future researchers must conduct a study for the improvement of the

efficiency of the reforming systems suitable for clean fuels production.

4. Future researchers must have a more comprehensive and better plant

layout that will utilize the space considering its economic aspects.

5. Future researchers must look for significant ideas that could reduce the

CO2 emissions.by the plant.


Bibliography

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Appendices

A. Detailed Calculations

Mass Balance Calculations for Design Option 1

GHR

S + NG = M1

Steam= 3,498 kg/hr

NG= 12,719 kg/hr

M1= 16,217 kg/hr

SMR

M1 + Steam = M2

M1=16,217 kg/hr

Steam= 34,444 kg/hr

M2=50,661 kg/hr

WGS

M2 = M3 + H20

M2=50,661 kg/hr

M3=37,316 kg/hr
H20= 13,345 kg/hr

CO2 Absorber

M3 + CO2 = M4

M3=37,316 kg/hr

CO2=30,115 kg/hr

M4= 7,201 kg/hr

PSA

M4 = H2 + M5

M4=7,201kg/hr

H2=3,848 kg/hr

M5= 3,353 kg/hr

Furnace

M5 + A + NG = FG + W

M5= 3,353kg/hr

Air=71,231kg/hr

H2=1,094 kg/hr

Flue Gas= 75678 kg/hr

Waste = 0 kg/hr

Future Demand for Hydrogen

𝑌𝑐 = 𝑎 + 𝑌𝑖 − 1
Where:

𝑌𝑛 − 𝑌𝑐
𝑎=
𝑁−1

Yc = initial value, Yn = final value, Yi = value for the year past, N = number

of years

Projected Demand for Hydrogen

1.56 − 0.18
𝑎=
10 − 1

𝑎 = 0.1533

Total Land Cost

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = 𝑐𝑜𝑠𝑡 𝑝𝑒𝑟 𝑠𝑞𝑢𝑎𝑟𝑒 𝑚𝑒𝑡𝑒𝑟 ∗ 𝑡𝑜𝑡𝑎𝑙 𝑎𝑟𝑒𝑎

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = (5000 𝑃ℎ𝑝)(130000 𝑚2)

𝑇𝑜𝑡𝑎𝑙 𝑙𝑎𝑛𝑑 𝑐𝑜𝑠𝑡 = 𝑃ℎ𝑝 650,000,000.00

Annual Fuel Cost Calculation for SMR:

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 132950 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


=( )( )( )( )( )( )
1000 𝑘𝑔 𝑚3 82.7 𝑀𝐽 ℎ𝑟 𝑑𝑎𝑦 𝑦𝑒𝑎𝑟
𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 87,475,707.15𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

Annual Fuel Cost Calculation for ATR:

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 4920 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


=( )( )( )( )( )( )
1000 𝑘𝑔 𝑚3 82.7 𝑀𝐽 ℎ𝑟 𝑑𝑎𝑦 𝑦𝑒𝑎𝑟

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 3,237,160.43 𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

Loan

Ordinary Annuity

𝐴[(1 + 𝑖)𝑛 − 1]
𝑃1 =
𝑖(1 + 𝑖)

i = interest

n = ordinary annuity period

𝐴[(1 + 0.0684)8 − 1
𝑃1 =
0.0684(1 + 0.0684)

P1 = 6.0009A

Deferred Annuity

𝑃1 = 𝑃2(1 + 𝑖)𝑚

m = deferred period
6.0009 𝐴 = 4,500,000,000 (1 + 0.0684)2

A = 855,980,522.90

Total Fuel Cost Estimation for SMR Plus

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡

8214.56 𝑃ℎ𝑝 0.8 𝑘𝑔 𝑚3 176210 𝑀𝐽 24 ℎ𝑟 345 𝑑𝑎𝑦


=( )( )( )( )( )( )
1000 𝑘𝑔 𝑚3 82.7 𝑀𝐽 ℎ𝑟 𝑑𝑎𝑦 𝑦𝑒𝑎𝑟

𝐴𝑛𝑛𝑢𝑎𝑙 𝐹𝑢𝑒𝑙 𝐶𝑜𝑠𝑡 = 115,939,032.39𝑃ℎ𝑝/𝑦𝑒𝑎𝑟

Equivalent Annual Sales = Annual Sales – Annual Fuel Cost

= 3,755,440,000 – 115,939,032.39

Equivalent Annual Sales = 3,639,500,968 Php

The equivalent annual sales of H2 for SMR Plus is 3,639,500,968.00 Php

Payback Period for SMR

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟

5,477,642,247.85
=
1,702,975,128.00

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟑. 𝟐𝟐 𝒚𝒆𝒂𝒓𝒔

Payback Period for SMR Plus

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟
5,477,642,247.85
=
1,653,637,775

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟑. 𝟑𝟏 𝒚𝒆𝒂𝒓𝒔

Payback Period for ATR

𝑇𝑜𝑡𝑎𝑙 𝐶𝑎𝑝𝑖𝑡𝑎𝑙 𝐼𝑛𝑣𝑒𝑠𝑡𝑚𝑒𝑛𝑡


𝑃𝑎𝑦𝑏𝑎𝑐𝑘 𝑃𝑒𝑟𝑖𝑜𝑑 =
𝑁𝑒𝑡 𝐼𝑛𝑐𝑜𝑚𝑒 𝑝𝑒𝑟 𝑌𝑒𝑎𝑟

5,477,642,247.85
=
1,433,374,693

𝑷𝒂𝒚𝒃𝒂𝒄𝒌 𝑷𝒆𝒓𝒊𝒐𝒅 = 𝟒. 𝟎𝟓 𝒚𝒆𝒂𝒓𝒔

Return on Investment

ROI = (Net Profit / Total Investment) * 100

= 1,702,975,128.00/5,477,642,247.85 ∗ 100

= 31.09%

The proposed SMR plant will have a rate of investment of 31.09% per year.

B. Demand Survey Graphs


We conducted a survey for our proposed plant, which is the steam methane

reforming plant, to Councilor Armando C. Lazarte regarding the environmental

constraints, geographical location and viability of Tabangao Batangas, waste

management, land pricing, and social issues.

C. Demand Projections

Chart Title
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
2008 2010 2012 2014 2016 2018 2020

Figure 34. Graphical representation of Hydrogen demand in Asia

Pacific
Chart Title
3.5

2.5

1.5

0.5

0
2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029

Figure 35. Graphical representation of the projected Hydrogen

demand

Projected Supply and Demand


3.5
3
2.5
2
1.5
1
0.5
0
2018 2020 2022 2024 2026 2028 2030

Supply Demand

Figure 38. Graphical representation of the projected Hydrogen Supply and

Demand
D. Technical Catalogs

Compressor / Expander

Pump
Heat Exchanger

Reformers
Furnace
Separator
Absorber

Pressure Swing Absorber


Water Gas Shift Reactor

Spherical Tank
E. Communication Letters

February 15, 2019

Councilor Armando Lazarte

Batangas City

Dear Councilor Lazarte,

I, Arman Jade Lazarte, a 5th year Petroleum engineering student of Batangas State University,
together with my groupmates Jessa Mae Punzalan and Aniemhar Cuadrasal wants to have a short
interview with you in compliance with our ongoing plant design project.

The interview will be about our proposed location, which is Tabangao Batangas, regarding its
geographical location and viability, environmental constraints, waste management, land pricing,
and social issues.

In this regard, we would like to ask permission to go to your good office to conduct our interview.

Your favorable response regarding this request will be highly appreciated.

Thank you.

Respectfully yours,

ARMAN JADE LAZARTE

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