Chemistry Test Class 11

1.Change in internal energy is a state function while work is not, why?

6. A 1.25g sample of octane (C18 H18 ) is burnt in excess of oxygen in a bomb

calorimeter. The temperature of the calorimeter rises from 294.05 to 300.78K. If
heat capacity of the calorimeter is 8.93 KJ/K. find the heat transferred to
calorimeter.

7. .Calculate the heat of combustion of ethylene (gas) to from CO2 (gas) and
H2O (gas) at 298k and 1 atmospheric pressure. The heats of formation of CO2,
H2O and C2H4 are – 393.7, - 241.8, + 52.3 kJ per mole respectively

8. The reaction C (graphite) + O2 (g) CO2 (g) + 393.5 kJ mol -1 represents the
formation of CO2 and also combustion of carbon. Write the values of
the two processes.

9. The

are given + 61.17kJ /mol and +132 kj-1/mol respectively. Above what
temperature will the reaction be spontaneous?

10. The heats of combustion of C, H2 and CH4 at 298 K and 1 atm are
respectively -393 kJ/mol, -286 kJ/mol and -892 kJ/mol. What is the enthalpy of
formation for CH4?
11. The standard heat of combustion of benzene is -3271 kJ/mol, for CO2 it is -
394 kJ/mol, and for H2O, it is -286 kJ/mol. Calculate the standard heat of
formation of benzene.

12. What is the standard enthalpy of reaction for the reduction of iron(II) oxide
by carbon monoxide?

FeO(s) + CO(g) ---> Fe(s) + CO2(g)

given the following information:

3Fe2O3(s) + CO(g) ---> 2Fe3O4(s) + CO2(g) ΔH = -48.26 kJ

Fe2O3(s) + 3CO(g) ---> 2Fe(s) + 3CO2(g) ΔH = -23.44 kJ

Fe3O4(s) + CO(g) ---> 3FeO(s) + CO2(g) ΔH = +21.79 kJ

13. The heat of combustion for the gases hydrogen, methane and ethane are -
285.8, -890.4 and -1559.9 kJ/mol respectively at 298K. Calculate (at the same
temperature) the heat of reaction for the following reaction:

2CH4(g) ---> C2H6(g) + H2(g)

14. What is the standard enthalpy of reaction for the reduction of iron(II) oxide
by carbon monoxide?

FeO(s) + CO(g) ---> Fe(s) + CO2(g)

given the following information:

3Fe2O3(s) + CO(g) ---> 2Fe3O4(s) + CO2(g) ΔH = -48.26 kJ

Fe2O3(s) + 3CO(g) ---> 2Fe(s) + 3CO2(g) ΔH = -23.44 kJ

Fe3O4(s) + CO(g) ---> 3FeO(s) + CO2(g) ΔH = +21.79 kJ