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Silicone Fluids: Synthesis, Properties Applications and
Silicone Fluids: Synthesis, Properties Applications and
Applications
P. Huber and W.Kaiser Wacker-Chemie GmbH, W. Germany
R r ~R i
I
Figure 3 Dimethylsiloxane
as difunctional unit
C H3 -$ Ii-0[ “i O h - - ; H
CH3 CH3
-
x = 0-ca .2000
viscosity = 0.65-1,000,000 mm2/s
Figure 5 Methylhydrogenpolysioxane
x = 40-90
viscosity = 15-100 mm2/s
Figure 6 Phenylmethylpolysiloxane
CH 3 - SI i - O ~ i - - O ] t ~ i - 0 r i - C
I H
CH3 C6H.5 n CH3 mCH3
viscosity up to IO,OOO mm2/s
1
CH3 KH3 1 YH3
C H 3 - 7 i - O t T i - O T S i - C HI 3
LR1
polyoxypropylene unit CHCHZO
[LH3
ACH2)3 - polyoxyethylene
-@H2)3 - polyoxypropylene
R 1 can be H or CH3C0 alkyl
Si i-
2CH3CI -+ (CH3)2SiC12 ROCHOW
1 Prefiller
2 Fluidised reactor
3 Cyclone
4 Filter
5 Cooling apparatus
6 Separator
7 Receiver
8 Agitator
8 Cooling apparatus
10 Heater
raw +CHBCl
R R
I I
R-Si-0-Si -R
I I
n 0 0 +-(RzSi0)4,-
I I
R-Si -0-Si-R
I I
R R
112 Hu ber, Kaiser JSL 3-2
I
CH3 m
Figure 14 Hydrosilylationreaction
Pt R,
HSE + CH2=CH/R --+R,CH-CH2-SiE
R
‘
Pt
HCECH 4- H S I --+ H2C=CH-Siz
Figure 1 5 Transesterification
(RO),,SiR;fHO
4-x
10 mill.1
1 mill.
500,000
100,000
50,000
10,000
6,000
3,000
1,000
750
500
350
200
100
75
50
40
30
20
15
r
E 10
E
>
._
w
8 6.0
P
.- 5.0
>
4.0
3.0
2.5
2.0
1.5
1 .o
0.9
0.8
0.7
0.6
.-
-20-10 0 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 220
Temperature "C
114 Hu ber, Kaiser J S L 3-2
the prevailing substrates. This effect is mainly used in the paper and
textile industry.
References
1. W. Noll, Chemie und Technologie der Silicone (Chemistry and technology of
silicones), 2nd edition, Weinheim Verlag Chemie, 1968.
2. W. Kuchler, Chemische Technology (Chemical technology), Vol 6, Anorgan.
Technologie I1 (Inorganic technology 11), 4th edition, pp 816-52, by Kaiser
and Riedle.