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STD*BSI BS EN 3978-ENGL 3998 = 1624669 0736932 4 6 4 =

BRITISH STANDARD BS EN
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1978:1998

Copper and copper


alloys - Copper
cathodes

The European Standard EN 1978:1998 has the status of a


British Standard

ICs 77.150.30

Copyright European Committee for Standardization


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= Lb24bb7 0736733 =
~-

STDmBSI B S EN L778-ENGL 1978 3TO

BS EN 19781998

National foreword
This British Standard is the English language version of EN 19781998. Together
with BS EN 19761998 it supersedes BS 6017 1981which is withdrawn.
The UK participation in its preparation was entrusted by Technical Committee
NFE/34, Copper and copper alloys, to Subcommittee N W 1 , Wrought and
unwrought copper and copper alloys, which has the responsibility to:

- aid enquirers to understand the tee


- present to the responsible European committee any enquiries on the
intepretation, or proposais for change, and keep the UK interests informed;
- monitor related intemational and European developments and promulgate
them in the UK.

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A list of organizations represented on this subcommittee can be obtained on request
to its secretary.
Cross-references
The British Standardswhich implement international or European publications
referred to in this document may be found in the BSI Standards Catalogue under the
section entitled “InternationalStandards Correspondence Index”, or by using the
“Find”facility of the BSI Standards Elecb-onic Catalogue.
A British Standard does not purport to include all the necessary provisions of a
contract. Users of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.

Summary of pages
This document comprises a front cover, an inside front cover, the EN title page,
pages 2 to 9 and a back cover.

This British Standard, having Amendments issued since publication


been prepared under the
direction of the Engineering
Sector Board, was published
under the authority of the
Standards Board and comes into
Amd.No. Date
I Text

effect on 15 August 1998

O BSI 1998

ISBN O 580 29726 8


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EUROPEAN nmm EN 1978
NORME EUROPÉENNE
EuROPA[ScHE NORM March 1998

ICs

Descriptors: Copper, copper aiioys, cathodes, designation, chemical composition, dimensions, electrical properties, sampling, tests,
marking

Engbsh version

Copper and copper alloys - Copper cathodes

Cuivre et alliages de cuivre - Cathodes en cuivre Kupfer und Kupferlegierungen - Kupfer-Kathoden

This European Standard was approved by CEN on 28 February 1998.


CEN members are bound to comply with the CENKENELEC Internal Regulations
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which stipulate the conditions for giving this European Standard the status of a
national standard without any alteration. Uptodate lists and bibliographical
references concerning such national standards may be obtained on application to
the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German).
* A version in any other language made by translation under the responsibility of a
M CEN member into its own language and notified to the Central Secretariat has the
*
same status as the official versions.
CEN members are the national standards bodies of Aus- Belgium, Czech
Republic, Denmark, Fïnhd, France, Germany, Greece, Iceland, Ireland, Italy,
Luxembourg, Netherlands, Norwax Portugai, Spain, Sweden, Switzerland and
United Kingdom.

CEN
European Committee for Standardization
Comité Européen de Normahation
Europäisches Komitee fin Normung

Central Secretariat: rue de Stassart 36, B-1060 Brussels

O 1998 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national
Members.
Ref. No. EN 19781998 E
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Page 2
EN 19781998

Foreword Contents
This European Standard has been prepared by page
lèchnical Committee C E N K 133, Copper and copper
alloys, the secretariat of which is held by DIN. Foreword 2
Within its programme of work, Technical Committee Introduction 3
CENiM: 133requested CENiM: 133/WG 1, Unwrought 1 Scope 3
copper products to prepare the following standard: 2 Normative references 3
EN 1978, Copper and C O ~ P Walloys - C O ~ Wcathodes. 3 Definitions 3
This is one of a series of European Standards for
products manufactured from refined copper @es. 3.1 cathode 3
Other products are specified as follows: 3.2 lot (copper cathodes) 3
EN 1976, Copper and copper alloys - Cast unwrought 3.3 bundle 3
copper pmducts. 3.4 sample cathodes 3
EN 1977, CO~PW and cw alloys - Comer dmwiw
3.5 cathode sample 3
stock (&re rod).
This European Standard shall be given the status of a 3.6 bulk sample 3
national standard, either by publication of an identid 3.7 analysis sample 3
text or by endorsement, at the latest by 4 Desiwons 3
September 1998, and conflicting national standards
shall be withdrawn at the latest by September 1998. 4.1 Material 3
According to the CEN/CENELEC Internal Regulations, 4.2 Product 3
the national standards organizations of the following 5 Ordering information 4
countries are bound to implement this European 6 Requirements
Standard: Austria, Belgium, Czech Republic, Denmark,
4
Finland, France, Germany, Greece, Iceland, Ireland, 6.1 Composition 4
Italy, Luxembourg, Netherlands, Norway, Portugal, 6.2 Electrical properties 4
Spain, Sweden, Switzerland and the United Kingdom.
6.3 Dimensions and tolerances 4
6.4 Surface condition 4
7 sampling 6
8 Testmethods 6
8.1 Anaiysis 6
8.2 Electrical resistivity 6
8.3 Retests 6
8.4 Roundhg of results 6
9 Declaration of conformity and
inspection documentation 7
9.1 Declaration of conformity 7
9.2 Inspection documentation 7
10 Marking 10
Annex A (normative) - Methods for use in
cases of dispute, for the samphng of
cathodes and for the preparation of analysis
samples 8
Annex B (informative) - Information on
electrical resistivity and conductivity
relationships 9
Annex C (informative) - Bibliography 9

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S T D - B S I B S EN L978-ENGL 2998 Lb24bb9 0 7 2 6 9 3 6 O O T m

Page 3
EN 19781998

Introduction 3.2
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This standard was prepared to combine the various lot (copper cathodes)
requirements and methods of test for copper cathodes, quantity of copper cathodes weighuig over 25 t and up
previously dealt with in a range of separate national to and including 200 t, consisting of one consignment,
StZUl&ds. or part of one consignment, produced by one refinery
Copper cathodes are intended for melting. 3.3
Cu-CATH-1 (CROOlA) is primarily intended for the
production of high conductivity copper, such as for bundle
drawing stock. Cu-CATH-2 (CR002A) is intended for total amount of a certain number of cathodes,
the production of other wrought products for electrical typically 20 to 60, stacked together and secured,
and general purposes. generally by steel bands
3.4
1 scope sample cathodes
This European Standard specifies the composition and number of cathodes randomly selected from the lot,
property requirements for cathodes of two copper and considered in total to be representative of the lot
grades, designated Cu-CATH-1 (CROOlA) and
CU-CATH-2(CROO2A). 3.6
Annex A (normative) describes methods for sampling cathode sample
cathodes for use in cases of dispute between the portion of one of the sample cathodes (see 3.4)
purchaser and the supplier. Annex B (informative) obtained by systematic cuthng of vertical strips
gives information on the relationships between 3.6
electrical resistivity and conductivity of copper.
bulk sample
sample produced by melting and casting into a suitable
2 Normative references mould (or moulds) the cathode samples (see 3.6)
This European Standard incorporates, by dated or obtained from all the sample cathodes and considered
undated reference, provisions from other publications. to be representative of the lot
These nonnative references are cited at the
appropriate places in the text and the publications are 3.7
listed hereafter. For dated references, subsequent analysis sample
amendments to or revisions of any of these representative fractions of warf taken from the w a
rf
publications apply to this European Standard only arising from driüiig, milling or sawing the bulk sample
when incorporated in it by amendment or revision. For castings (see 3.6)
undated references, the latest edition of the publication
referred to applies.
4 Designations
EN 1655, Copper and copper alloys - Declaratiorn Of
confornitg 4.1 Material
EN 10204,MetaU.ic products - Types of inspection 4.1.1 General
doeumentS.
The material is designated either by symbol or number
IEC 468, Methad of measurement of resistivity of (see "%le 1).
metauic materials.
IS0 1553, UnauOyed copper contuining not less 4.1.2 Sgmbol
than 99,90% of copper- Determination of copper The material symbol designation is based upon the
content -Electrolytic method. designation system given in IS0 1190-1.
NOTE Informative references to documents used in the 4.1.3 Number
preparation of this standard, and cited at the appropriate places in
the text, are listed in a bibliography, see annex C. The material number designation is in accordance with
the system given in EN 1412.
3 Definitions 4.2 Product
For the purposes of this standard, the foliowing The product designation provides a standmdized
defínitions apply pattern of designation from which a rapid and
unequivocal description of a product is conveyed in
3.1 communication. It provides mutuai comprehension at
cathode the international level with regard to products which
fiat, unwrought product made by electrolytic meet the requirements of the relevant European
deposition Standard.

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Page 4
EN 19781998

The product designation is no substitute for the full In addition, the purchaser shall also state on the
content of the standard. enquiry and order any of the following, if required
The product designation for products to this standard e) the dimensions and tolerances requjred, if the
shall consist of: cathodes are to be supplied cut to size (see 6.3);
- denomination (Cathode); f ) whether a declaration of conformity is required
- number of this European Standard (EN 1978); (see 9.1);
- material designation, either symbol or number g) whether an inspection document is required, and
(see Table 1). if so,which type (see 9.2).
The derivation of a product designation is shown in EXAMPLE
the foilowing example. Ordering details for 100 t of cathode conforming to
EXAMPLE EN 1978, in material designated either Cu-CATH-1 or
CROO1A:
Cathode conforming to this standard, in material
designated either CUCATE-1 or CROOlA, shall be 100 t Cathode EN 1978- Cu-CATH-1
designated as follows: or
100 t Cathode EN 1978- CR001A

Cathode EN 1978 - CUCATKl 6 Requirements


or
EN 1978 - CR0OI.A 6.1 Composition

%I
The composition shall conform to the requjrements for
Denomination the appropriate grade given in W l e 1.
Number of this European
6.2 Electrical properties
Standard
Material designation The electrical properties shall conform to the
requirements for the appropriate grade given in
W l e 2. The tests shall be carried out in accordance
5 Ordering information with 8.2.
In order to facilitate the enq*, order and NOTE Mass resistivity is the mandatory electrical property
confirmation of order procedures between the requirement in this standard. The relationship between mass
purchaser and the supplier, the purchaser shall state on resistivity and the corresponding volume resistivity and
conductivity is given in annex B.
his enquiry and order the following information:
a) quantity of product required (mass); 6.3 Dimensions and tolerances
b) denomination (Cathode); The cathodes shall be either whole, or cut to sizes as
agreed between the purchaser and the supplier and
c) number of this European Standard (EN 1978); stated in the purchaser’s order [see Se)].
d) materiai designation (see Table 1).
NOTE It is recommended that the product designation, as 6.4 Surface condition
described in 4.2, is used for items b ) to d). Cathodes shall withstand ordinary handling without
breakage. They shall be reasonably free h m nodules,
outgrowth edges and from all exh-aneous materiah
such as electrolyte residues, dirt, grease and oil.

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STDmBSI B S EN 1978-ENGL 3 9 9 8 L b 2 4 6 6 9 0736738 982

Page 5
EN 19781998

I l

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Copyright European Committee for Standardization


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S T D - B S I BS EN 1978-ENGL 1998 1b24bb9 0 7 1 b î 3 9 8 1 9 m

Page 6
EN 19781998 --```,-`-`,,`,,`,`,,`---

Materirù designation Electrical properties (see NOTE 1)


Symbol Number Mass resistivity Nominal volume Nominal conductivity
resistivity
*n.g/m2 F*n.rn MS/m % IACS
max. ma. mui. min.

CU-CATH-1 CROOIA 0,151 76 (0,017 07) (5~,W (WO)


CU-CATH-2 CR002A I
0,15328 I (0,017 24) I(58,001 (1ow) I I
NOTE 1 Nominal values for volume resistivity and conductivity have been calculated from mass resistivity by methods described in
annex B.
NOTE 2 Because of the i n a c c m i e s involved in the calculations, these nominal values, which are given for guidance purposes, are
enclosed in parentheses.
NOTE 3 For explanation of "'36 IACS,see B.2.

7 sampling 8.2.2 Determination of electrical resistivitg in


For the routine sampling of cathodes for analysis, or cases of dispute
for the routine determination of electrical properties, In cases of dispute the electrical resistivity shall be
the method of sampling SMbe at the discretion of determined on a representative sample from each lot,
selected in accordance with clause 7.
the sampler.
External oxide shall be removed from the test ingot
In cases of dispute concerning the composition, the (see clause 7), which shall then be rolled and/or drawn
cathodes shall be sampled and the analysis samples to 2 mm diameter wire.
prepared in accordance with the procedure described NOTE The sample may be hot worked initiaiiy provided care is
in annexk taken to avoid contamination or excessive oxidation.
In cases of dispute concerning the electrical properl3es, The 2 mm diameter wire shall be degreased and
unless otherwise agreed between the disputing parties annealed at (500 f 10) "C for 30 min in an inert
(see NOTE), the cathodes shall be sampled in atmosphere, and the resistivity test carried out in
accordance with the procedure described in annex k accordance with IEC 468.
The electrical resistivity of each lot in dispute slwü be 8.3 Retests
determined on one of the three test ingots cast from If there is a faiiure of one, or more than one, of the
the bulk sample(s) (see A.6). tests in 8.1 or 8.2, two test samples from the same
NOTE Other sampling methods may be used for obtajning the inspection lot shall be permitted to be selected for
representative sampie(s) for the determination of the electrical retesting the failed property (properties). One of these
resistivity in cases of dispute, subject to agreement between the
disputing parties. test samples shall be taken from the same sampling
unit as that from which the onginal failed test piece
was taken, unless that sampling unit is no longer
8 Test methods available, or has been withdrawn by the supplier.
8.1 Analysis If the test pieces from both test samples pass the
8.1.1 Routine analgsis appropriate test(s),then the inspection lot represented
shall be deemed to conform to the particular
For the routine analysis of cathodes, the methods of requirement(s) of this standard. If a test piece fails a
analysis used shaìl be at the discretion of the analyst. test, the inspection lot represented shall be deemed not
8.1.2 Analysis in cases of dispute to conform to this standard.
In cases of dispute concerning the composition, the 8.4 Rounding of results
analysis shall be determined on the samples selected in For the purpose of determining conformity to the
accordance with clause 7, as follows: limits specified in this standard for composition or for
for copper grade Cu-CATH-1 (CROOIA), the methods electrical resistivity, an observed or a calculated value
of analysis used for the elements listed in W l e 1 obtained from a test shall be rounded in accordance
shail be agreed between the disputing parties; with the following procedure which is based upon the
for copper grade Cu-CATH-2 (CROOa), the copper guidance given in IS0 31-0:1992, annex B. It shall be
shall be determined in accordance with the method rounded in one step to the same number of figures
in IS0 1663. used to express the specified limit in this standard.
The following rules shall be used for rounding:
8.2 Electrical resistivity a) if the figure immediately after the last figure to be
8.2.1 Routine determination of electrical retained is less than 5, the last figure to be retained
resistivity shall be kept unchanged,
For the routine determination of electrical resistivity, b) if the figure immediately after the last figure to be
the methods used shall be at the discretion of the retained is equal to or greater than 5, the last figure
tt?steK to be retained shall be increased by one.

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S T D - B S I B S EN 1974-ENGL L998 - 1624669 0 7 1 6 9 4 0 530

Page 7
EN 19781998

9 Dechation of conformity and 10 Marking


inspection documentation Cathodes, whether fuii-size or cut, shall be assembled
into bundles of suitable weight for handling. Each
9.1 Declaration of conformity bundle shall be marked to idenhfy it with its refinery
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m e n requested bY the Purchaser [ S e501 and Weed source and grade (i.e. the brand).
with the supplier, the supplier shall issue for the No metallic identisring markers shM be directly fixed
product the appropriate declaration of conformity in to the c&,odes.
accordance with EN 1655.
9.2 Inspection documentation
When requested by the purchaser [see Sg)] and agreed
with the supplier, the supplier shall issue for the
product the appropriate inspection document in
accordmce with EN 10204.

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STDmBSI BS EN II778-ENGL 1998 m Lb24667 07Lb94L Y77 m

Page 8
EN 1978:1998

Annex A (normative) b) number consecutively every bundle in the lot.


Randomly select 24 individual bundles by the use of
Methods for use in cases of dispute, for random number tables (see NOTE). Number
the sampling of cathodes and for the sequentially each cathode position within a typical
preparation of analysis samples bundle. By the use of the random number tables,
randomly select one &ode from each randomly
A.l Introduction selected bundle to produce 24 sample cathodes.
A technique is described, which is intended for use in NOTE Published tables of random numbers are available; for
cases of dispute, for the selection of samples from a instance in IS0 2859-0. There is aiso a variety of computer
programs capable of generating random numbers.
consignment of cathodes. The procedures are aiso
described for obtaining from these selected cathode If the lot consists of less than 24 bundles, use
samples, replicate laboratory samples representative of method a). If the lot consists of 24 bundes or more, the
the consignment in a form suitable for analysis and for choice of method is a matter for agreement between
determination of the electrical properties. the purchaser and the supplier. If no specific choice is
made, use methoda).
A.2 Definitions
For the purpose of this method, the definitions in 3.4 A.6 Preparation of cathode samples
to 3.7 apply Individually sample each of the 24 sample cathodes,
selected in accordance with A.4, by cutting a vertical
A.3 Apparatus and reagents strip from each cathode. The stip shall be from such a
A.3.1 Crucible, with a close fitting lid. position that the collection of the 24 strips so cut
represents all points of one, two or three full cathodes,
A.3.2 Hydrochloric ancl,10 % (by volume), including the cathode edges and the hangers. Ensure
commercial grade. that all the vertical strips are of the same width and
A.3.3 Deionized water: are cut sequentially from left to right in the same order
as the sample cathodes were selected.
induction, m resistance, melting
k 3 . 4 Elsckr+ì~
fumace, with provision for an inert internal A.6 Preparation of bulk sample
atmosphere at high temperatures. Prepare a clean crucible (see A.3.1) by melting in it a
A.3.6 Rod. quantity of copper from the lot to be analysed and
discard this melt.
A.3.6 Test ingot m4n&ùìs,
to provide Clean the 24 strips selected in accordance with A.6, by
ingots 20 mm X 20 mm in crosssection and 100 mm immersing them in hydrochloric acid (see A.3.2) at
to 200 mm long.
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ambient temperature for 15 min. Then thoroughly wash


NOTE Other designs of test ingot moulds may be used, subject the cathode strips in deionized water (see A.3.3) and
ta agreement between the purchaser and the supplier.
allow them to m.
A.3.7 DriUing, rniuing m sawing mahine, equipped Depending upon the size of the melting equipment
with carbidetipped cutting tools. adable, proceed according to a) orb) as follows,
A.3.8 Magnet. takjng care to avoid ingress of oxygen into the melt so
as to avoid oxidation of iron and chromium, which
A.4 Selection of sample cathodes could affect the subsequent analysis
A.4.1 Division of a consignment into lots a) place ali the cleaned strips into the cleaned
A.4.1.1 If the consignment of cathodes originates crucible in the furnace (see A.3.4) and heat under
from one reñnery, consider it as one lot if it consists of an inert atmosphere until the sample is melted.
more than 25 t and up to and including 200 t of Thoroughly stir the melt, which constitutes the bulk
cathodes. Subdivide any consignment greater than 200 t sample, with a rod (see A.3.6) and cast it into
into a number of approximately equal lots, each not conventional ingot moulds, pouring three test ingots,
exceeduig 200 t. one each at the beginning, middle and end of the
castjng operation, using the test ingot moulds
A.4.1.2 If the consignment consists of cathodes (see A.3.6);
originating from more than one reñnery, separate it b) if the available furnacdcmcible is not large
into part consignments, each from one refinery, and enough to melt the composite sample then group
divide each part-consignment into lots, as described the 24 strips into two or more batches for melting
inA.4.1.1. and casting, as in A.6a), casting three test ingots
A.4.2 Random sampling of a lot from each batch, as before, into the moulds
Randomly select 24 sample cathodes from each lot (see A.3.6).
using either method a) orb), as follows: Use one of the three test ingots obtained from a) orb)
a) number consecutively every cathode in the lot. for the determination of the eleclxical properties in
Randomly select 24 sample cathodes by the use of cases of dispute (see clause 7).
random number tables (see NOTE);

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Page 9
EN 19781998

A.7 Preparation of aggregate analysis sample B.3 Commercial annealed copper


Sample all the test ingots prepared in accordance IEC 28 states that “the (electrical) conductivity of
with A.6 by àrilüng, milling or sawing. Use carbide commercial annealed copper s h d be expressed as a
tipped tools, t a h g care to avoid overheating and percentage, at 20 O C , of that of standard annealed
consequent oxidation of the chips, to produce an copper given to approximately0,l W , on the
aggregate analysis sample exceeding 600 g of small assumption that “the density of commercial annealed
chips, representative of the bulk sample and hence of copper at 20 O C is 8,89 g/cm3”.
the lot.
B.4 Nominal volume resistivity
Use a magnet to remove carefully any ferrous particles
present in the aggregate sample. The density of commercial copper varies with small
changes in composition, particularly oxygen content.
A.8 Preparation and distribution of analysis Thus, a true volume resistivity can only be calculated
samples from a measured mass resistivity if the true density of
Divide the aggregate analysis sample obtained in the particular sample is known or is measured to the
accordance with A.7 into four portions, each to be a requisite degree of accuracy, i.e. better than 0,1%.
minimum of 150 g. For general purposes, however, a nominal volume
Place each portion into a clean, dry container and resistivity may be calculated using the density
idenfdy the container clearly with the following: of 8,% g/cm3, as referred to in clause B.2, and used in
Table 2.
a) date and place of sampling;
b) detail of the consignmenfflot(s) represented by B.5 Differences between measured and nominal
the sample; values
c) the name of the sampler, If true volume resistivity or true conductivity is
required from measured m a s resistivity and therefore
d) the sample number; actual density is used in calculation, differences of up
e) any other relevant information. to 0,5 % may result between these values and the
Use one of these portions for analysis by the supplier, corresponding nominal values.
one for analysis by the purchaser, reserve one for Conductivity calculated from the ratio of the mass
referee analysis (in case this should become necessary) resistivity of standard annealed copper
* and reserve the fourth for contingencies. (0,153 28 f12.g/m2)to the derived mass resistivity may
m also exhibit a similar disparity.
*
Annex B (informative)
Information on electrical resistivity and Annex C (informative)
conductivity relationships Bibliography
B.1 Mass resistivity In the preparation of this European Standard, use was
made of a number of documents for reference
Determination of cross-sectional areas to the requisite purposes. These informative references are cited at the
degree of accuracy is difficult. Hence, in practice appropriate places in the text and the publications are
nearly all assessments of resistivity are made by listed hereafter.
measuring the resistance, mass, and length of a
representative sample. Mass resistivity can be EN 1412, Copper and copper alloys - European
calculated directly from these values and this gives a numbering system.
true measure of the quality of the copper for carrying IEC 28, IntemationaC standard of resistance for
electric current. copper.
B.2 Standard annealed copper (IACS) IEC 31-0:1992, Quantities and units - Part O: General
pinCiph.
IEC 28 uses evidence from earlier years (see USA
National Bureau of Standards Circular 31,1956, IS0 1190-1, Copper and copper alloys - Code of
superseded by USA National Bureau of Standards oksigmtion - Part 1: Designation of rnatericlls.
Handbook 100,1966) to establish a fixed value for the IS0 2859-0, Sumpzing procedures for in@eCtio?¿by
resistance to flow of an electric current within an attributes - Part O: Introduction to the IS0 2859
imaginary “standard” annealed copper. This is based on attribute sampling C l S m .
a volume resistivity of 1/58 pA2.m or 0,017 241 Ffl.rn
at 20 OC, which is defined as corresponding to a
conductivity of 100 % IACS at 20 O C . The introduction of
the International ohm in 1948 altered the volume
resistivity of standard annealed copper by only 0,049O h
Also on this earlier evidence the standard annealed
copper is allotted a density of 8,89 g/cm3. --```,-`-`,,`,,`,`,,`---

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STD.BS1 BS EN LqiB-ENGL 1998 m Lb24bb9 071b943 2 4 T m

BS EN
1978:1998
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