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Oleoresins
Oleoresins
Chilly oil and oleoresin are extracted by solvent extraction process, Supercritical fluid extraction process
or steam distillation process.
Oleoresins are obtained from spices by extraction with a non-aqueous solvent followed by removal of
the solvent by evaporation. To start with various raw spices are cleaned and then ground to the required
mesh size. Then extraction is undertaken with the help of proper solvent. Solvents that can be used are
hexane, acetone, ethylene dichloride or alcohol. Extraction is done by percolation of the solvents at
room temperature through a bed of ground spice packed in a SS percolator. Then the dark viscous
extract containing not less than 10% of total soluble solids are drawn off and distilled under reduced
pressure to remove the excess of solvent. The essential oil is obtained by steam distillation.
Therefore the capsicum or chilly oleoresin is a viscous liquid derived by polar solvent extraction from
ground powder of any Capsicum species; there are three types of oleoresin: paprika (used for colour),
red pepper (used for colour and pungency), and Capsicum (used for pungency).
A supercritical fluid is any substance at a temperature and pressure above its critical point, where
distinct liquid and gas phases do not exist. In addition, close to the critical point, small changes in
pressure or temperature result in large changes in density, allowing many properties of a supercritical
fluid to be “fine-tuned”.
The advantages of supercritical fluid extraction (compared with liquid extraction) are that it is relatively
rapid because of the low viscosities and high diffusivities associated with supercritical fluids. The
extraction can be selective to some extent by controlling the density of the medium and the extracted
material is easily recovered by simply depressurizing, allowing the supercritical fluid to return to gas
phase and evaporate leaving no or little solvent residues. Carbon dioxide is the most common
supercritical solvent. The use of supercritical fluids is essentially limited to supercritical carbon dioxide
(SCFCO2)extraction since carbon dioxide has the advantages of being inexpensive and nontoxic and
because its critical point is easily reached.