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CSEC Chemistry June 2016 P2
CSEC Chemistry June 2016 P2
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TEST CODE
FORM TP 201605s MAY/JLINE 2016
CHEMISTRY
2 AnswerALL questions.
8 If you use the extrapage(s) you MUST write the question number clearly in
the box provided at the top of the extra page(s) and, where relevant, include
the question part beside the answer.'
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0121202003 I
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AnswerALL questions.
1. (a) A group of students was required to carry out an experiment in order to determine the
melting point of an unknown solid, A. The apparatus was set up as shown in Figure 1.
Thermometer
Boiling tube
with unknown
solid A
Beaker with water
Tripod
Bunsen burner
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Figure 1. Diagram of apparatus set-up
Using the Bunsen burner, the water was heated to 80 "C. The Bunsen burner was turned
off and temperature readings were recorded EVERY minute for 10 minutes. =
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Figure 2 shows some of the thermometer readings recorded during the experiment.
80 70 70 60
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60 50
50 40
Time Temperature
(min) (,c)
0 80
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J 65
4 65
6 64
l0 48 ,h
(4 marks)
(iD Using the data from Table 1, plot the graph of temperature versus time on the grid
provided in Figure 3 on page 7. Five points have already been plotted for you.
Draw a smooth curve through the points to complete the cooling curve for A.
(5 marks)
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(2 marks)
(v) Based on information from the graph plotted in (a) (ii), state the melting point of
A.
(1 mark)
(vi) From the graph plotted in (a) (ii), identifz the time range during which there should
be a mixture of liquid and solid in the boiling tube.
(1 mark)
(vii) State ONE precaution, other than wearing safety apparel, which should be taken
during this experiment to avoid injury to the face or hands.
(1 mark)
Figure 4. Particles of A
L 0121202009 I
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- 10-
In another experiment, the group of students was given another unknown solid, B, and
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asked to identifiz it. They performed a series of tests and made some observations which .{i
are recorded in Table 2. Complete Table 2 by inserting the appropriate inferences. t:\
(8 marks) :11
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TABLE 2: RESULTS OF.TESTS ON UNKNOWN SOLID, B ..r{
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Test Observation Inference
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(i) Place a small portion of A reddish brown gas ..€
solid, B in a test tube and evolved ..E
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heat strongly using a Bunsen _-_+\
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flame. (1 mark)
(2 marks)
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(v) To the third portion of the . Yellow precipitate formed a
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2. (a) Distinguish between an 'oxidizing agent'and a 'reducing agent' in terms of electron gain rlF
or loss. IEi
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(b) Jaden carried out some tests and recorded the observations in Table 3 below. Use the
information in the table to answer the questions that follow.
TABLE 3: OBSERVATIONS
Test Observation
I An aqueous solution of C was Potassium manganate(VlI)
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added to acidified potassium
manganate(Vll).
solution changed from purple to
pale pink.
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2 An aqueous solution of C was Potassium iodide solution changed .lria
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added to a solution ofpotassium from colourless to brown. Ili
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3 A strip of iron was placed into an Blue solution faded and brown
aqueous solution of copper(Il) deposits settled.
sulfate.
4 A strip of silver was placed into Solution remained blue.
an aqueous solution ofcopper(Il)
sulfate.
(1 mark)
With reference to oxidation states, explain EACH of your answers in (b) (ii).
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Test 1:
Test 2
(4 marks)
(iv) Write an ionic equation (with state symbols) for the reaction which took place in
Test 3.
(2 marks)
(v) With reference to the electrochemical series, explain the difference in observations
between Tests 3 and 4.
(4 marks)
Total 15 marks
(2 marks) rle
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(b) Compound P, HrC:CHCH2CH2CH, is a hydrocarbon. .E
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(i) State the name of Compound P.
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(1 mark)
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(iv) Draw the FULLY DISPLAYED structural formulae of Compound P and ONE of
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its isomers.
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Compound P Isomer of Compound P
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- 15 - -l
with hydrogen gas in the presence of a catalyst to form Compound Q
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(iD State ONE physical properry of Compound Q
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AnswerALL questions.
4. (a) Graphite and diamond are two allotropes of carbon. Deflne the term 'allotrope'. Illustrate
your answer by drawing the lattice structures for both diamond and graphite.
Diamond Graphite
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(6 marks)
(b) Like metals, graphite can conduct electricity but diamond cannot conduct electricify,
(2 marks)
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ft. (ii) Explain, in terms of bonding, why graphite conducts electricity but diamond does
NOT conduct electricity.
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Sodium chloride and calcium oxide both have similar giant ionic crystalline structures
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with high melting points. Howeveq the melting point of calcium oxide is higher than that
of sodium chloride. Sketch the lattice structure for sodium chloride and suggest why its
melting point would be lower than that of calcium oxide.
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5. (a) Methane, CHo, is the simplest hydrocarbon known to man.
Identiff the type of bonding present in methane. State a reason for your answer,
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(b) Methane, like other alkanes, is generally unreactive. However, under certain conditions,
= it can undergo reactions with chlorine, Cl, forming carbon tetrachloride, CClo.
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(iD State the type of reaction taking place and identifz the reaction conditions
(2 marks)
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012120201F 2016
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(c) Identiff and draw the structural formulae ofthe alkene and the acid from the list ofmolecular
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formulae given below. .1H
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c4H8' c.H'O, c4H8o2, c4Hroo =
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Alkene Acid:
(4 marks)
(d) For EACH of the following pairs ofcompounds, identifii a test that can be used to distinguish
between them. In your answer, include the expected observation(s).
(2 marks)
Total 15 marks
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6- (a)
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The Caribbean islands are known for their many resources. For example, the ore of
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aluminium is found in Jamaica and Guyana.
(i) Briefly describe the extraction of aluminium from its named ore. Include in your
description ONE ionic equation.
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(5 marks)
(ii) Although aluminium ore is mined in the Caribbean, the extraction of aluminium
usually takes place in other countries. Suggest ONE reason why it may be difficult
to extract aluminium in the Caribbean.
(2 marks)
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(c) "Some metals can be useful to man but yet harmful to the environment." Comment on .:{iE
this statement with reference to mercury. ir=
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(3 marks)
Total 15 marks
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IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORI( ON THIS TEST. i.ll
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012120201F 2016