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HW 1 2018
HW 1 2018
HOMEWORK 01
A. Concentrations, solution preparation and stoichiometric calculation.
Problem 1.32. A bottle of concentrated aqueous sulfuric acid, labeled 98.0 wt% H2SO4, has a
concentration of 18.0 M.
(a) How many milliliters of reagent should be diluted to 1.000 L to give 1.00 M H2SO4?
Solution:
mol 1L
(Molarity)× (molar mass of solute) 18 × × 98.079 g/mol
L 1000 mL
(b) Density = = = 1.80 g/mL
(percent concentration) 98%
Problem 1.33. What is the density of 53.4 wt% aqueous NaOH (FM 40.00) if 16.7 mL of the solution
diluted to 2.00 L gives 0.169 M NaOH?
Solution:
mol 1L
(Molarity) ∗(molar mass of solute) 20.24 × × 40 g/mol
L 1000 mL
Density = = = 1.516 g/mL
(percent concentration) 53.4%
Problem 1.34. How many milliliters of 3.00 M H2SO4 are required to react with 4.35 g of solid
containing 23.2 wt% Ba(NO3)2 if the reaction is Ba2+ + SO42- → BaSO4(s)?
Solution:
1.01 g
nH2 SO4 = nBa(NO3 )2 = 261.34 g/mol = 3.86 × 10-3 mol
3.86 × 10−3
VH2 SO4 solution = mol =1.29 mL
3.00 × 0.001 L/mL
L
Problem 1.35. How many grams of 0.491 wt% aqueous HF are required to provide a 50% excess to
react with 25.0 mL of 0.023 6 M Th4+ by the reaction Th4+ + 4F- → ThF4(s)?
Solution:
70.8 × 10−3
maqueous HF = 0.491%
= 14.4 g
Problem 1.45. Sulfamic acid is a primary standard that can be used to standardize NaOH.
+
H3NSO3- + OH- → H2NSO3- + H2O
Sulfamic acid
FM 97.094
What is the molarity of a sodium hydroxide solution if 34.26 mL react with 0.333 7 g of sulfamic
acid?
Solution:
0.3337 g
nsulfamic acid = = 3.4369 × 10-3 mol = 3.4369 mmol
97.094 g/mol
3.4369 mmol
nNaOH = nOH− = nsulfamic acid Molarity of NaOH solution = 34.26 mL
= 1.003 M
Problem 1.46. Limestone consists mainly of the mineral calcite, CaCO3. The carbonate content of
0.541 3 g of powdered limestone was measured by suspending the powder in water, adding 10.00 mL
of 1.396 M HCl, and heating to dissolve the solid and expel CO2:
Calcium carbonate
FM 100.087
The excess acid required 39.96 mL of 0.100 4 M NaOH for complete titration. Find the weight
percent of calcite in the limestone.
Solution:
0.4978 g
wt% CaCO3 = 0.5413 g × 100% = 91.96%
3. To determine traces of analytes in sample, is it possible to use reagents that are prepared in tap
water?
Dilutions cannot be prepared using tap water. Problems arise if the water used for a dilution is not
of the highest quality – especially if it contains additional analyte or interferences