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DS65 - (1995) Atmospheric Corrosion Investigation of Aluminum-Coated, Zinc-Coated, and Copper-Bearing Steel Wire and Wire Products
DS65 - (1995) Atmospheric Corrosion Investigation of Aluminum-Coated, Zinc-Coated, and Copper-Bearing Steel Wire and Wire Products
-- -
'
A THIRTY-TWO VEAR REPORT
- - -
Atmospheric Corrosion
Investigation of
Aluminum-Coated,
Zinc-Coated, and
Copper-Bearing
Steel Wire and
Wire Products:
A Thirty-Two
Year Report
Beryle G. Sweet
Thomas C. Britton, Jr.
Copyright© 1995 AMERICAN SOCIETY FOR TESTING AND MATERIALS, Philadelphia, PA.
All rights reserved. This material may not be reproduced or copied, in whole or in part, in
any printed, mechanical, electronic, film, or other distribution and storage media, without
the written consent of the publisher.
Photocopy Rights
Printed in Philadelphia, PA
June 1995
Foreword
- --STATE COLLEGE, PA
(40°48' N - 77°52' W)
BRAZOS RIVER
FREEPORT, TEXAS
(28°53' N - 95°22' W)
The authors wish to acknowledge and extend thanks to the following people who
helped with the compilation and peer review of this document:
Author's Commentary
Scope of AS and Authorization 2
TEXT
TABLES
Figs. 1 through 3-0verall views of the Kure Beach, 800 ft (250 m) test
site 49
Fig. 4-Specimen 32, Brazos River site 50
Fig. 5-Specimen 32, Kure Beach 80 ft (25 m) site 50
Fig. 6-Specimen 32, Kure Beach 800 ft (250 m) site 50
Fig. 7-Specimen 32, Manhattan site 50
Fig. 8-Specimen 32, Newark-Kearny site 51
Fig. 9-Specimen 32, Point Reyes site 51
Fig. 10-Specimen 32, State College site 51
Fig. 11-Specimen 33, Brazos River site 52
Fig. 12-Specimen 33, Kure Beach 80 ft (25 m) site 52
Fig. 13-Specimen 33, Kure Beach 800 ft (250 m) site 52
Fig. 14-Specimen 33, Manhattan site 52
Fig. 15-Specimen 33, Newark-Kearny site 53
Fig. 16-Specimen 33, Point Reyes site 53
Fig. 17-Specimen 33, State College site 53
Fig. 18-Specimen 34, Brazos River site 54
Fig. 19-Specimen 34, Kure Beach 800 ft (250 m) site 54
Fig. 20-Specimen 34, Manhattan site 54
Fig. 21-Specimen 34, Newark-Kearny site 55
Fig. 22-Specimen 34, Point Reyes site 55
Fig. 23-Specimen 34, State College site 55
Fig. 24-Specimen 35, Brazos River site 56
Fig. 25-Specimen 35, Kure Beach 800 ft (250 m) site 56
Fig. 26-Specimen 35, Manhattan site 56
Fig. 27-Specimen 35, Newark-Kearny site 57
Fig. 28-Specimen 35, Point Reyes site 57
Fig. 29-Specimen 35, State College site 57
Fig. 30-Specimen 36, Brazos River site 58
Fig. 31-Specimen 36, Kure Beach 80 ft (25 m) site 58
Fig. 32-Specimen 36, Kure Beach 800 ft (250 m) site 58
Fig. 33-Specimen 36, Manhattan site 58
Fig. 34-Specimen 36, Newark-Kearny site 59
Fig. 35-Specimen 36, Newark-Kearny site (cleaned) 59
Fig. 36-Specimen 36, Point Reyes site 59
Fig. 37-Specimen 36, State College site 59
Fig. 38-Specimen 37, Brazos River site 60
Fig. 39-Specimen 37, Kure Beach 80 ft (25 m) site 60
Fig. 40-Specimen 37, Kure Beach 800 ft (250 m) site 60
Fig. 41-Specimen 37, Manhattan site 60
Fig. 42-Specimen 37, Newark-Kearny site 61
Fig. 43-Specimen 37, Newark-Kearny site (cleaned) 61
Fig. 44-Specimen 37, Point Reyes site 61
Fig. 45-Specimen 37, State College site 61
Fig. 46-Specimen 38, Brazos River site 62
Fig. 47-Specimen 38, Kure Beach 80 ft (25 m) site 62
Fig. 48-Specimen 38, Kure Beach 800 ft (250 m) site 62
Fig. 49-Specimen 38, Manhattan site 62
Fig. SO-Specimen 38, Newark-Kearny site 63
Fig. 51-Specimen 38, Newark-Kearny site (cleaned) 63
Fig. 52-Specimen 38, Point Reyes site 63
Fig. 53-Specimen 38, State College site 63
DS65-EB/Jun. 1995
Author's Commentary
Metallic coatings on iron and steel products have been The lead author of this booklet is acknowledged to be a
around ever since the need was recognized to add a degree retired producer of hot-dip aluminum-coated steel wire. In
of corrosion resistance to a material noted for its strength, order to lend balance to the report and ensure that any con-
ductility, and durability. Indeed, zinc coatings in various pro- clusions drawn are unbiased, he insisted upon the appoint-
cesses on iron or steel have been employed since the mid- ment of a user of the product as co-author. That was accom-
l 9th century. plished when Tom Britton of Duke Power Company agreed
It was well into the 20th century before aluminum coat- to fill that role.
ings over steel were perfected. While aluminum powder The peer review required by ASTM proved to be a worth-
coatings were first introduced earlier in the century, it was while undertaking. Composed of a total of eight individuals
not until the 1930s that hot-dip aluminum coatings were in- representing both producer and user interests, plus several
troduced, and then only on sheet steel products. The process staff members of ASTM, this peer group contributed inval-
of hot-dip aluminizing to protect steel wire was first per- uable input which resulted in many clarifications and am-
fected in the late 1940s; the first shipment of a finished prod- plifications to the text and the various tables in the report.
uct being made in 1953, only eight years before the start of Insofar as possible, the annual inspections of the speci-
the atmospheric corrosion tests which are the subject of this mens at the various test sites were conducted by two or more
publication. people to ensure a consensus of opinion on the condition of
As with any new product being offered in the marketplace, the specimens. The authors wish to thank the many individ-
the need was recognized to conduct tests to determine its uals who volunteered their time for this very important task.
advantages, if any, over the traditional product being offered. Without them the compilation of the extensive data in this
While accelerated laboratory tests, such as salt spray, could report would have been impossible.
tell much about a product's corrosion resistance, nothing The primary audience for this publication is perceived to
could take the place of direct exposure in a variety of at- be users, potential users, and specifiers of metallic-coated
mospheres over a long period of time. This became the im- steel wire and wire products. It is hoped that the conclusions
petus for the voluntary efforts which resulted in the launch- drawn in this report will aid them in selecting the product
ing of these tests. which will best serve their requirements for atmospheric
It should be noted here that the placement of zinc-coated corrosion protection.
and copper-bearing bare steel wire and wire products at the
test sites was for the purpose of providing control specimens
against which to compare the performance of aluminum-
coated wire and wire products, since the former products are
considered "grandfather" materials in existence long before Beryle G. Sweet
the introduction of aluminum-coated wire. Lead author
I
Copyright © 1995 by ASTM International www.astm.org
Scope of AS and Authorization
The scope of Committee AS on Metallic-Coated Iron and C. E. Topping, Consumers Power Co.
Steel Products is "The promotion of knowledge, the stimu- L. C. Whitney, Copperweld Steel Co.
lation of research, and the development of standards in the Seven producers contributed the aluminum-coated steel
area of iron and steel products protected against corrosion wire test specimens for the exposure program. These pro-
by use of metallic coatings, and nonmetallic coatings which ducers were:
may be specified for use as supplemental protection. The
types of standards developed include, but are not limited to, Bethlehem Steel Co.
specifications, practices, test methods, and definitions." Sub- Copperweld Steel Co.
committee AOS.15 on Wire Tests is responsible for the per- Keystone Steel & Wire Co.
formance of tests on the atmospheric corrosion of wire and National Standard Co.
wire products, be they bare or metallic-coated. American Chain & Cable Co., Page Steel & Wire Div.
With the June 1959 authorization from the Advisory com- J. A. Roebling's Sons Division
mittee on Corrosion, Subcommittee AOS.15 organized a task United States Steel Corp.
group composed of the following: Copper-bearing steel and zinc-coated steel wires were also
E.G. Baker, Steel Company of Canada provided for comparative purposes. Southern Electrical Co.,
B. A. Beery, American Chain & Cable Co., Page Steel & Division of Olin Mathieson Chemical Corp. contributed to
Wire Division (now Page Aluminized Steel Corp.) the program in the stranding of the steel-reinforced alumi-
W. W. Bradley, Bell Telephone Labs, Inc. num conductors. Performed Line Products Co. supplied the
R. S. Dalrymple, Reynolds Metals Co. dead-end fittings used in the test installations of high-
0. B. Ellis, Armco Steel Corp. strength strand and steel-reinforced aluminum conductors.
P. M. Emmons, Rural Electrification Administration Fabricated items were installed at eight exposure sites. At
E. T. Englehart, Aluminum Company of America four of the sites, unfabricated wires were also exposed. Five
H. H. Hormann, Consolidated Edison of New York types of fabricated wire products are under test. These are
J. B. Horton, Bethlehem Steel Co. barbed wire, chain-link fence fabric, farm-field fence fabric,
R. B. Koontz, National Standard Co. high-strength steel wire strand, and steel-reinforced alumi-
J. B. Kopec, Keystone Steel & Wire Co. num conductor. The latter two products are referred to as
T. A. Lowe, Kaiser Steel & Wire Co. "7-wire strand" in this document. The relative corrosion re-
J. F. Murphy, Olin Mathieson Chemical Corp. sistance of the various test items in the several atmospheres
F. J. Reinhart, U.S. Naval Engineering Laboratory was established by visual inspection of the unfabricated and
J. H. Rigo, United States Steel Corp. (now USX Corp.) fabricated wire items and by periodic determination of per-
T. A. Schneider, J. A. Roebling's Sons Division centile loss in breaking strength of the 0.148 and 0.099 in.
C. W. Straitm~ Detroit Edison Co. (3.76 and 2.51 mm) unfabricated wires.
2
Text
Summary of Results
The wire and wire product specimens were exposed at the to a high of 0.38 oz/ft2-year (116 g/m2 -year) at the Kure
seven U.S. sites in the spring and summer of 1961 and at Beach, North Carolina, 80 ft (25 m) site.
Warrington, England, on 1 March 1964. There were 1520 The corrosion rates of the coatings to complete rust on
unfabricated tension test specimens exposed at each of four aluminum-coated unfabricated wires ranged from 0.01 oz/
sites. To date, 370 have been removed and tested. Wire prod- ft2-year (3 g/m 2 -year) at the Kure Beach, North Carolina, 800
uct specimens (farm-field fence, barbed wire, chain-link ft (250 m) site to 0.03 oz/ft 2 -year (9 g/m 2 -year) at Warring-
fence fabric, and 7-wire strand) were exposed at all eight ton, England. However, complete rust had not been reached
sites. at the 32-year point at Newark-Kearny, New Jersey, and State
The hot dipped aluminum-coated specimens ranged from College, Pennsylvania, on the aluminum-coated unfabricated
0.27 to 0.63 oz/ft 2 (82 to 192 g/m2 ), and the aluminum pow- wires. The corrosion rates on aluminum-coated fabricated
der metallurgy clad specimen ranged from 1.76 to 4.54 oz/ product specimens were all within this same range, with the
ft 2 (537 to 1385 g/m2 ). The hot dipped zinc coatings ranged exception of the Warrington, England, site where the barbed
from 0.36 to 2.81 oz/ft 2 (110 to 857 g/m 2 ), and the electro- wire and chain link fence specimens exhibited a corrosion
plated zinc coatings ranged from 0.87 to 2.98 oz/ft2 (265 to rate to complete rust of 0.04 oz/ft2 -year (12 g/m 2 -year).
The corrosion rates of the coatings to complete rust on
909 g/m 2 ). (Norn: All coating weight values in this document
zinc-coated unfabricated wires ranged from 0.05 oz/ft 2-year)
are expressed in ounces (grams) of aluminum or zinc per
(15 g/m2-year) at the Kure Beach, North Carolina, 800 ft
square foot (square metre) of uncoated wire surface.)
(250 m) site and the State College, Pennsylvania site to 0.17
The corrosion rates of the coatings to initial rust on alu-
oz/ft2 -year (52 g/m2 -year) at Warrington, England. The cor-
minum-coated unfabricated wires ranged from 0.02 oz/ft2 -
rosion rates of the coatings to complete rust on zinc-coated
year (6 g/m2 -year) at Newark-Kearny, New Jersey, to 0.06 fabricated products varied considerably from a low of 0.01
oz/ft 2 -year (18 g/m2 -year) at Warrington, England. In gen- oz/ft2-year (3 g/m2-year) at Manhattan, Kansas, to a high of
eral the corrosion rates of the coatings to initial rust on alu- 0.22 oz/ft 2-year (67 g/m 2-year) at Warrington, England.
minum-coated fabricated product specimens were within The loss in breaking strength over the first 30 years varied
this range at all locations. The corrosion rates of the coatings considerably from a high of 70% for uncoated wires exposed
to initial rust on the zinc-coated unfabricated wires ranged at the Kure Beach, North Carolina, 800 ft (250 m) site and
from 0.06 oz/ft2 -year (18 g/m 2-year) at State College, Penn- 68% for zinc-coated wires exposed at Warrington, England,
sylvania, to 0.20 oz/ft 2-year (61 g/m 2-year) at Warrington, to some slight gain in strength for some of the heavier alu-
England. The corrosion rates of the coatings to initial rust minum-coated specimens. In general, the loss in strength of
on zinc-coated fabricated products varied considerably from aluminum-coated wires was less than that of zinc-coated
a low of 0.02 oz/ft2-year (6 g/m 2-year) at Manhattan, Kansas, wires.
5
Test Plan
The test plan involved the exposure of specimens represent- Electroplated-two coating weight classes
ing the following: Aluminum-coated steel wire
1. Unfabricated Wires-Evaluation by visual observation and Hot dipped-three coating weights
by loss in breaking strength (d) High-strength strand
Number of replicates: 20 Zinc-coated steel wire-Electroplated 0.375 in.
Test length: 39 in. (991 mm) (9.53 mm) strand diameter, 7-wire 0.120 in.
Materials: (3.05 mm)-two coating weights
(a) Bare copper-bearing steel wire 0.148 in. (3.76 mm) Aluminum-coated steel wire-Various processes,
diameter 0.375 in. (9.53 mm) strand diameter, 7-wire
(b) Zinc-coated steel wire 0.148 in. (3.76 mm) diameter 0.120 in. (3.05 mm), and 0.3125 in. (7.94 mm)
Hot dipped strand diameter, 7-wire 0.104 in. (2.64 mm)-
Electroplated range of coating weights
(c) Aluminum-coated steel wire 0.148 in. (3.76 mm) (e) Aluminum conductors, steel reinforced (ACSR)
diameter No. 4-7 I 1 ACSR (See Specification B 232 for
Hot dipped size terminology) in conventional stranding
Powder metallurgical technique and compacted stranding. Zinc-coated, electro-
(d) Aluminum-coated steel wire 0.099 in. (2.51 mm) plated steel core wire and aluminum-coated
diameter steel core wire-various processes
Hot dipped 3. Placement of Specimens-Figures 1 through 3 depict the
Powder metallurgical technique manner in which the unfabricated wire and fabricated
wire products are exposed at the several atmospheric test
2. Fabricated Wire Products-Evaluation by visual obser-
sites. In all instances precautions are taken to eliminate
vation
dissimilar metal contact.
Number of replicates: 1
Test length: 10 ft (3.05 m) Figure 1 illustrates the manner in which the unfabricated
Materials: test wires are racked in groups of 10 on the standard ASTM
(a) Farm-field fence fabric-two sizes: 939-6-11 and pipe stands by insertion into predrilled 1 1I2 in. (38 mm)
939-6-9 (See Specifications A 116 and A 584 for size diameter aluminum rounds, mounted at 30° from horizontal.
terminology) Prior to insertion into the aluminum rounds, both ends of
Zinc-coated steel wire-Hot dipped-two coating the wire were dipped into an adhesive, EC 1099 (product of
weight classes Minnesota Mining and Manufacturing Co.). The aluminum
Aluminum-coated steel wire-Hot dipped rounds are installed at center-to-center distance of approxi-
(b) Barbed wire-12 1 I 2 gage 4-point mately 35 in. (889 mm) to accommodate the coil set of the
Zinc-coated steel wire-Hot dipped-two coating test wires. Each round was predrilled with holes of pre-
weight classes scribed diameters to a 1 /4 in. (6 mm) depth at 2 in. (51 mm)
Aluminum-coated steel wire-Hot dipped-three centers.
coating weights (two specimens have alumi- The high-strength steel strands and the steel reinforced
num alloy barbs) aluminum conductors are supported on braces of 1 1 /4 in.
(c) Chain-link fence fabric-2 in. (51 mm) mesh, 0.148 (32 mm) galvanized pipe, drilled at 3 in. (76 mm) centers for
in. (3.76 mm) diameter wire, 48 in. (1219 mm) high, the strand and 3 3/4 in. (95 mm) centers for the conductors.
twisted top, knuckled bottom The test strands and conductors are outfitted at either end
Zinc-coated steel wire of the test lengths with galvanized or aluminum-coated dead
Hot dipped-two coating weight classes ends, depending upon the contact metal involved.
6
CHAPTER 2: TEST PLAN 7
Fann-field fence and chain-link fencing are erected on dant sunshine as compared to the eastern United States. The
suitable finished fence posts set in typical vertical fashion as elevation is approximately I 100 ft (335 m) above sea level.
shown in Figs. 2 and 3. The barbed wire specimens are The annual average rainfall is 33.52 in. (851 mm).
shown mounted on appropriately finished arms, the alumi-
num fittings in contact with aluminum coated steel, and the
Site No. 5-Newark-Kearny, New Jersey
zinc-coated fittings in contact with zinc-coated steel. Since This severe industrial test site was established in I 956 to
these specimens were installed by professional erectors, they replace the original test site on property owned by the Port
were tensioned to the degree normally encountered in Authority of New York and New Jersey in Newark. The new
service. site was established on 2 July I 970 and is situated on the
4. Test Locations and Exposure Sites-Table I lists the expo- grounds of the Kearny Generation Station of Public Service
sure sites, the assigned site numbers, the exposure dates, Electric and Gas Company. The nonfabricated specimens are
and the type of product, that is, fabricated or unfabri- mounted at an angle of 30° from the horizontal and all spec-
cated. The type of atmosphere at each location is classified imens face the south-southwest at an azimuth of 193° (ele-
in accordance with that set forth in the I 958 Report of vation I I ft (3 m)).
the Advisory Committee on Corrosion. The three major Site No. 6-Point Reyes, California
types are industrial, marine, and rural. A brief description
Point Reyes test site was established in I950 on property
of each site follows.
owned by American Telephone and Telegraph Company and
Site No. 1-Brazas River, Texas is located I930 ft (588 m) from the Pacific Ocean behind low
hills covered with salt grass and bushes. The nonfabricated
In I 952, a test site was established on the Brazos River on
specimens are mounted at an angle of 30° from the horizon-
property owned by the U.S. Anny Corps of Engineers, 3900
tal and all specimens face due west, toward the Pacific
ft (1189 m) northwest of the Gulf of Mexico. The nonfabri-
Ocean. The atmosphere here is characterized by salt spray
cated specimens are mounted at 30° from the horizontal and
and condensation exposure due to westerly winds, dense
all specimens face southeast at an azimuth of I44°. The cli-
fogs, and heavy rains which keep the specimens moist during
mate in this area is noted for its consistently high humidity.
most of the winter. In summer the area is very dry by day
The daytime relative humidity varies between 85 and 93% in
with frequent heavy fogs at night.
the summer and averages 80% in the winter. The night-time
relative humidity is 100% all year with frequent heavy dews. Site No. 7-State College, Pennsylvania
This rural site was established in I 925 and is located on
Sites Nos. 2 and 3-Kure Beach, North Carolina
the campus of Pennsylvania State University, I mile (1.6 km)
The two exposure sites at Kure Beach are under the own- north of State College, Pennsylvania (elevation I 175 ft (358
ership and direction of the LaQue Center for Corrosion Tech- m)). The nonfabricated specimens are mounted 30° from the
nology Inc. and are located on the Cape Fear peninsula I 7 horizontal and all specimens face southeast at an azimuth
miles (27.4 km) southeast of Wilmington, North Carolina. of I47°.
One test site is approximately 800 ft (250 m) and the other
80 ft (25 m) from the Atlantic Ocean. The nonfabricated Site No. 8-Warrington, England
specimens are mounted 30° from the horizontal and all spec- This industrial site was located on the recreation grounds
imens face south at an azimuth of I 77° at the 800 ft (250 m) at Rylands-Whitecross, Ltd. at an elevation of 28 ft (9 m)
site. At the 80 ft (25 m) site, the specimens face the ocean above sea level. The location was at 53° 24' N latitude and
directly at an azimuth of I I0°. The 80 ft (25 m) site is char- 2° 34.5' W longitude. The prevailing wind is southwesterly
acterized by seawater spray falling directly on the test spec- blowing from the town over the site. The exposure racks ran
imens and is considered a severely corrosive marine envi- from east to west and faced south. The town has a diversified
ronment. The 800 ft (250 m) site is considered a moderately industry which includes wire production, light and heavy en-
severe marine environment. gineering, hot-rolled steel products, board and paper mills,
chemical processing, and extensive brewing. The average an-
Site No. 4-Manhattan, Kansas nual sulfur dioxide (S0 2 ) contamination for the years I 964
This rural site is located on the campus of Kansas State through 1973 was 0.065 ppm. The more recent years (1974
University in an agricultural area with very little industrial through 1977) indicated a 50% reduction of S0 2 from the
contamination. It is a continental climate with relatively earlier annual figures. This site was terminated and closed
large diurnal and annual temperature ranges. There is abun- in April 1977 after 13.2 years of exposure (see Table 1).
Description of the Test Specimens
The following information was provided by each manufac- farm-field fence fabric are essentially low-carbon products.
turer for the unfabricated and fabricated wire products Base metal analyses classifies the zinc-coated chain-link
which each supplied: fence fabric as a steel product of lower carbon content than
(a) General description of the coating process. the aluminum-coated steel chain-link fence fabric. The latter
(b) Chemical analysis of the base metal and metallic coating.
utilized steels of medium carbon content.
(c) Weight of metallic coating. The reported coating weights are tabulated in Table 4 and
(d) Mechanical properties of the unfabricated wires.
indicate the range of coating weights observed for the elec-
trolytic and hot dip zinc coatings, and for the two types of
(e) Minimum and maximum coating thicknesses as mea-
aluminum coatings.
sured microscopically.
See Chapter 6 for a listing of current ASTM specifications
(f) Cross-sectional photomicrograph to illustrate structure of
pertaining to the products exposed in this program. No
coating only.
ASTM specifications for aluminum coated wire and wire
Most of the descriptive information which was supplied products were in existence in 1961 when these exposure tests
by the several manufacturers was accepted without verifi- were started, and comparisons to specification requirements
cation. Only the coating weights and mechanical properties which follow are to specifications adopted subsequently.
were rechecked, and any discrepancies were resolved. Of the unfabricated 9 gage zinc-coated wire specimens, the
General descriptions of the coating processes for the test hot-dipped specimen had a coating weight 42.9% over that
wires are summarized in Table 2. According to these descrip- specified in Table 1 of Specification A 641 4 (A 641 M) for
tions the zinc-coated steel wires were processed by conven- Class 1 coating. Of the two electroplated specimens, one had
tional hot dip or electrolytic methods. Aluminum-coated a coating weight 10.0% over that specified in Table 1 of Spec-
steel wires prepared by processes 1, 2, 4, and 5 were coated ification A 641 (A 641 M) for Class 1 coating, while the other
by passage through a molten bath of aluminum or an alu- had a coating weight 5.2% over that specified in Table 1 of
minum-silicon alloy. Except for two processes, 1 and 6, the Specification A 641 (A 641 M) for Class C coating.
steel wires were chemically fluxed prior to passage through Of the three unfabricated 9 gage hot-dipped aluminum-
the molten bath of coating metal. Process 3 utilizes a powder coated specimens, one had a coating weight 32.5% under
metallurgical technique. and one was 20.0% over that specified in Table 2 of Speci-
Table 3 reports the chemical analyses of the base metal for fication A 809. 4 The third specimen had a coating weight
all test specimens, unfabricated, and fabricated. A review of 57.5% over that specified in Table 2 of Specification A 809.
these steel analyses shows the carbon content of the base The one specimen of 9 gage aluminum-coated wire pro-
metal for aluminum coating in a molten bath to be signifi- cessed by the powder metallurgy technique is high carbon
cantly higher than for comparable zinc-coated wire. Starting ACSR wire and had a coating weight of 2.44 oz/ft 2 (745 g/
with a higher carbon content for the aluminum-coated steel m 2), more than seven times the 0.34 oz/ft 2 (104 g/m 2) spec-
wire compensates for the greater reduction in tensile ified in Table 4 of Specification B 341 4 (B 341 M).
strength which is caused by a higher operating temperature With the exception of the chain link fabric specimens, the
for an aluminum bath as compared to a molten zinc bath. heavier zinc coatings were deposited by the electrolytic
The operating temperature for an aluminum bath ranges method as opposed to the hot dip method.
from 1200 to 1300° F (649 to 704° C) whereas the operating Of the two hot-dipped zinc-coated chain link fabric spec-
temperature of a zinc bath varies from 800 to 900° F (427 to imens, one had a coating weight 47.5% over that specified
482° C). in Specification A 392 4 for Class 1 coating, while the other
Low, medium, and high-carbon steel analyses are repre- had a coating weight 40.5% over that specified in Specifica-
sented among the unfabricated wires. Aluminum conductor
steel reinforced (ACSR) core wires and high-strength steel
strand are high-carbon products, while barbed wire and 4
Annual Book of ASTM Standards, Vol. 01.06.
8
CHAPTER 3: DESCRIPTION OF THE TEST SPECIMENS 9
tion A 392 for Class 2 coating. Both of these specimens were specimens were woven from wire that was zinc-coated be-
coated with zinc by the hot dip process after being woven fore fabrication by the electrolytic process.
into chain link fabric. In many cases, this process results in Of the three aluminum-coated chain link fabric specimens,
a heavier deposition of zinc at the wire intersections as com- all were coated by the hot-dip method before weaving. The
pared to the straight portions of the wire in the chain link coating weights were 10.0, 35.0, and 42.5% over that speci-
fabric. fied in Table 2 of Specification A 817 for Type I coating.
Of the two zinc-coated chain link fabric specimens that The aluminum coatings deposited by passage through a
were coated by the electrolytic method, one had a coating molten bath were substantially lighter than those deposited
weight 27.5% over that specified in Table 3 of Specification by the powder metallurgical technique. The range for the
A 817 4 for Type II, Class 1 coating, while the other had a hot-dip aluminum coatings was 0.21 to 0.63 oz/ ft2 (64 to 192
coating weight 11.5% over that specified in Table 3 of Spec- g/m 2 ) as compared to 1.76 to 4.54 oz/ft 2 (537 to 1385 g/m 2 )
ification A 817 for Type II, Class 2 coating. Both of these for the powder applied aluminum coatings.
Coating Data
The weights and analyses of the coating metals as well as nique showed an iron content of less than 1% in the outer
minimum and maximum coating thicknesses are reported in portion of the coating. Wires which were aluminum-coated
Table 5. These are original data as reported at the inception in siliconized aluminum baths had iron contents in the outer
of the program. The coating thicknesses were determined portion of the coatings in excess of 1%. In these instances,
microscopically. Photomicrographs of the wire's cross- the overall range in iron content was 1 to 5%. Aluminum-
sectional area illustrating the structure of the metallic coat- coated steel Specimens 7, 19, 51, 57, and 58, where the entire
ing were published in the 20-year report (STP 585A) and no aluminum coating instead of just the outer portion was an-
attempt is made to reproduce them here. alyzed for iron, had iron contents ranging from approxi-
As shown in Table 5, the coating analyses of the zinc coat- mately 8.75% iron for a 3 to 4% siliconized aluminum coat-
ings for iron range from a trace of iron for the electrolytically ing to an excess of 20% for a siliconized aluminum coating
deposited coatings to a maximum of 15% iron for the hot of approximately 1% silicon. However, as previously noted
dip coatings. Steel wires which were coated with essentially (see footnote a under Table 2) these specimens were dropped
pure aluminum by a hot dip or a powder metallurgical tech- from the program after 5 years.
10
Mechanical Properties
Initial mechanical properties of the nominally sized 0.148 tensile strength of 165 ksi ( 1140 MPa) by utilizing steel with
and 0.099 in. (3.76 and 2.51 mm) unfabricated wires are a chemical analysis of 0.72% carbon.
listed in Table 6. Information tabulated includes wire di- The data on percent elongation in 10 in. (254 mm) indicate
ameter, breaking strength, tensile strength, percent elonga- that significantly lower percent elongations (1.5 to 2.2%) are
tion in 10 in. (254 mm), and percent reduction in area. Cor- associated with the higher tensile strengths of wires alumi-
roded specimens were subsequently mechanically tested for num coated by the powder metallurgical technique. Steel
breaking strength only. wires which were aluminum coated by passage through a
molten bath had percent elongations in 10 in. (254 mm) vary-
The zinc-coated steel wire specimens had tensile strengths
ing from 5.8 to 15.7%. The percent elongations of the zinc-
ranging from 58 to 87 ksi (400 to 600 MPa). All aluminum-
coated steel wires ranged from 5.8 to 11.6%.
coated wires which were coated by passage through a molten
Table 7 records the chemical analyses and physical prop-
bath except for Specimen 6 had tensile strengths ranging erties which were reported for the aluminum conductor
from 59 to 99 ksi (407 to 683 MPa), significantly lower than wires used in the fabrication of the No. 4, 7I1 ACSR con-
those of wires coated by the powder metallurgical technique ventional and compacted conductors. Also listed for com-
(Specimens 8, 21, and 22), which ranged from 101 to 177 parative purposes are the specified minimum values which
ksi (695 to 1220 MPa). Specimen 6 was able to attain its high aluminum wire must meet for this application.
11
Materials and ASTM Specifications
The materials exposed in this program have wide variations 9. A 585 Specification for Aluminum-Coated Steel Barbed
in coating weight due to the many different coating pro- Wire (1968)
cesses employed. Some of these items do not meet the ASTM 10. A 586 Specification for Zinc-Coated Parallel and Helical
specifications which eventually evolved in the aluminum- Steel Wire Structural Strand ( 1968)
coated product line. The following ASTM specifications4 per- 11. A 641 Specification for Zinc-Coated (Galvanized) Carbon
tain to the products exposed in this program. The date of Steel Wire (1971)
12. A 641M Specification for Zinc-Coated (Galvanized) Car-
original issue is given in parentheses. It should be noted that
bon Steel Wire [Metric] (1984)
some of these specifications were not in existence at the time
13. A 809 Specification for Aluminum-Coated (Aluminized)
of initiation of the tests, and that the listing of those ASTM
Carbon Steel Wire (1983)
specifications issued after 1961 does not imply full compli- 14. A 817 Specification for Metallic-Coated Steel Wire for
ance with those specifications. Chain Link Fence Fabric (1983)
1. A 116 Specification for Zinc-Coated (Galvanized) Steel 15. B 341 Specification for Aluminum-Coated (Aluminized)
Woven Wire Fence Fabric (1927) Steel Core Wire for Aluminum Conductors, Steel Rein-
2. A 121 Specification for Zinc-Coated (Galvanized) Steel forced (ACSR) (1963)
Barbed Wire (1928) 16. B 498 5 Specification for Zinc-Coated (Galvanized) Steel
3. A 363 Specification for Zinc-Coated (Galvanized) Steel Core Wire for Aluminum Conductors, Steel Reinforced
(ACSR) (1969)
Overhead Ground Wire Strand (1952)
17. B 498M Specification for Zinc-Coated (Galvanized) Steel
4. A 392 Specification for Zinc-Coated Steel Chain-Link
Core Wire for Aluminum Conductors, Steel Reinforced
Fence Fabric (1955) (ACSR) [Metric] (1983)
5. A 474 Specification for Aluminum-Coated Steel Wire
The first fourteen specifications listed were promulgated
Strand (1962)
by Committee AS, whereas the last three were sponsored by
6. A 475 Specification for Zinc-Coated Steel Wire Strand Committee Bl on Electrical Conductors. Specifications A
(1962) 392 and A 491 are now under the jurisdiction of Committee
7. A 491 Specification for Aluminum-Coated Steel Chain- F14 on Fences.
Link Fence Fabric (1963)
8. A 584 Specification for Aluminum-Coated Steel Woven 5This specification was issued in 1969 to replace Specifications B
12
Inspection of Wire and Wire ProdtJcts
Visual Examination here that the inspection data reflects the average observed
Visual examination of the extent of corrosion was done condition of the entire specimen and not necessarily that of
almost annually. The time of exposure was recorded to the the section of the specimen depicted photographically.
nearest 0.1 year. This report summarizes the observations Absent from the series of photographs are electrogalva-
made over a period of 32 years at all test sites except War- nized Specimens 34 and 35 at the Kure Beach 80 ft (25 m)
rington, England, where the test was terminated after 13.2 site. These specimens reached complete rust at 17 .1 and 23.1
years. Observations were made by one or more inspectors years, respectively, and have been scrapped.
and the consensus was reported. These data have been pub- At the Newark-Kearny site, the three aluminum-coated
lished in ASTM AS reports. 6 A summary of these observa- fabric specimens (Specimens 36, 37, and 38, illustrated in
tions is presented in Tables 8 through 12 covering all but the Figs. 34, 42, and 50, respectively), are coated with a black
ACSR specimens. Table 13 shows the abbreviations and sym- corrosion product. These three specimens were photo-
bols used to describe the nature of the corrosion. The extent graphed a second time after the black corrosion product
of corrosion was estimated in terms of the percent of the was removed on one straight wire segment, to illustrate that
area of the specimen affected. The corrosion rates in terms the aluminum coating was still intact. The cleaned Speci-
of ounces per square foot (grams per square metre) to initial mens 36, 37, and 38 are depicted in Figs. 35, 43, and 51,
rust (CIR) and to complete rust (CCR) were calculated as respectively.
follows:
weight of coating oz/ft2 (g/m2 ) Analysis
(a) CIR= ... l
years to m1ua rust
The average corrosion rate to initial rust for each alumi-
(b) CCR = weight of coating oz/ft2 (g/m
2
)
num-coated product and each zinc-coated product is shown
years to complete rust in Tables 14 and 16. The average corrosion rate to complete
rust for each aluminum-coated product and each zinc-
The CIR and CCR values are not intended to constitute a coated product is shown in Tables 15 and 17. An all-products
valid comparison between aluminum-coated and zinc-coated average and standard deviation for each location are also
steel wire products. Metallic coatings are expressed custom- shown. The all-products average corrosion rates and stan-
arily in terms of unit weight ratherthan thickness; therefore,
dard deviations were calculated using the individual corro-
the CIR and CCR values have been calculated in terms of
sion rates for each product at each location from Tables 8
unit weight.
through 12. The standard deviation is a measure of the
In 1991, the 30th anniversary year of the exposure tests, a
project was undertaken to photograph all of the chain link spread of the individual results around the average. The
fabric specimens at each of the seven active test sites. The large standard deviations for the all products averages are
photographs are reproduced here as Figs. 4 through 53. They not surprising considering the large differences among the
are grouped by specimen number at each test site. individual product averages. Therefore, caution should be
Beneath the caption on each photograph, the 30-year used in the interpretation of these average rates. All the data
(1991) inspection data are reproduced. It should be noted necessary for a more in-depth analysis are contained within
this report.
6
Reports of Subcommittee AOS.15 on Wire Tests, as published in Steel Reinforced Aluminum Conductors
Proceedings, American Society for Testing and Materials, through
1977, and from 1980 through present as published annually in the The aluminum conductor steel reinforced (ACSR) speci-
minutes. mens at the Kure Beach, North Carolina, 80 ft (25 m) ex-
13
14 ATMOSPHERIC CORROSION INVESTIGATION
posure site are showing signs of corrosion of the internal or broken strands. The aluminum-coated core wire speci-
steel core wire. As detailed earlier in this report, there are a mens appear in excellent condition with no corrosion prod-
total of twelve conductor specimeps exposed at each site, in uct in the interstices.
two styles of six each, conventional stranding and compacted The Point Reyes, California, ACSR specimens appear in
stranding. In both styles, seven all-aluminum wires surround good to excellent condition. The zinc-coated core wire spec-
a single steel core wire. The specimens are summarized in imens appear in good condition with the interstices com-
Table 18 by style, core wire coating metal and weights, and pletely filled with white corrosion product. This condition
the coating method. was first noted in 1975. The aluminum-coated core wire
Because of the surrounding aluminum wires, direct obser- specimens appear in excellent condition with some partial
vation of the zinc or aluminum coated steel core wire is not filling of the interstices on the compacted strand conductors,
possible. Indirect observation is made by noting the presence Nos. 53 to 57. There are no reported bulges or broken
of corrosion products in the interstices or cracks between strands on any specimens.
the outer all-aluminum strands and the appearance of bulges At Brazos River, Texas, thP. interstices are partially to com-
produced by internal expansion of corrosion products from pletely filled but the inspector cannot distinguish any differ-
the core wire. The terms "fair," "good," and "excellent" are ence in appearance between the two core wire coating types.
qualitative and refer to the specimen's current appearance as 1983 was the first year that reported the interstices partially
compared to its original new condition. filled. There are no reported bulges or broken strands.
At the Kure Beach, North Carolina, 80 ft (25 m) site, after The Newark-Kearny, New Jersey, specimens are reported
32 years' of exposure, the zinc-coated core wire Specimens as all 100 G with some black staining and no comment of
46 and 52 are showing serious signs of internal corrosion. bulges or broken strands.
The conventional stranded ACSR, Specimen 46, has three At State College, Pennsylvania, there are no indications of
broken outside strands. The compacted strand ACSR. Spec- corrosion and no mention of bulges or broken strands.
imen 52, has similar broken strands and a single bulge. A The Manhattan, Kansas, site reports that all the conductor
review of the yearly reports shows the following progression; specimens appear 60 M and 40 St. It does not indicate the
in 1974 both specimens have the interstices filled with white nature and location of the stain. There are no reported
corrosion product and Specimen 52 has a single bulge at one bulges or broken strands. The first appearance of stain was
end, in 1985 broken strands are reported on Specimen 52, in 1981 on the compacted conductor specimens, Nos. 52 to
and in 1990 broken strands are reported on Specimen 46. 57. In 1989, the conventional specimens were reported as 90
The aluminum-coated steel core wire specimens, Nos. 4 7 M and 10 St, and the compacted specimens were reported
through 51 and 53 through 57, appear in fair condition with 80 M and 20 St. From 1990 to the present, the inspectors
the interstices filled with white corrosion product but with have reported 60 M and 40 St.
no bulges or broken strands. In summary, the indirect visual indications of corrosion of
The Kure Beach, North Carolina, 800 ft (250 m) ACSR the ACSR core wire at the Kure Beach 80 ft (25 m) and 800
specimens appear in fair to excellent condition. The zinc- ft (250 m) and Point Reyes sites suggest that aluminum-
coated core wire specimens appear in fair condition with the coated core wire resists corrosion better than zinc-coated
interstices filled with white corrosion product but no bulges steel core wire at marine coastal sites.
Breaking Strength Loss
At four of the eight exposure sites, unfabricated tension test Newark-Kearny, that is, 4.47 /0.76 = 5.9. The maximum dif-
specimens were exposed, and 370 of the original specimens ferences for zinc-coated wires were a ratio of 6.8: 1 for War-
exposed in 1961 (1964 at Warrington) have been removed rington and Newark-Kearny for Code 2 and 12.2: 1 for
and tested for breaking strength. Tables 19 through 35 tab- Warrington and Kure Beach for Code 3.
ulate the results through the 30-year period 1961to1991. At two sites, Kure Beach and Warrington, Code 1 wire per-
Although the data are minimal, statistically meaningful re- formed better than Code 2 wire. However, the light zinc coat
sults were obtained from fourteen location-code number on Code 2 wire offered only a few years of protection. Past
sets. Table 36 tabulates the linear regression equation and that point the comparison is between an uncoated copper-
the coefficient of linear correlation for each set. The coeffi- bearing steel and an uncoated noncopper-bearing steel. It
cient of linear correlation is the measure of the strength of appears that the copper-bearing wire, Code 1, outperformed
the linear relationship between two variables. Higher or- the noncopper-bearing wire, Code 2.
dered equations were considered but rejected, based on the At all four sites the Code 3, 9 gage 0.99 oz/ft 2 (302 g/m 2 )
good results obtained by the linear assumption as indicated zinc-coated wire had sufficient data to establish significant
by the high correlation coefficients. The two variables used but questionable equations. Note that the maximum loss in
in the analysis were the total years of exposure (years ex- strength at Kure Beach and State College are 10.4 and
posed) and the percent loss in breaking strength (loss per- 14.3%, respectively. It is quite possible that until a significant
cent). Because no loss in breaking strength was expected be- loss in strength has been observed, there will not be suffi-
fore initial rust occurred, an initial point of years to initial cient data to determine the true rate of loss of strength.
rust and zero percent loss in breaking strength was added to At the Warrington site Code 11, 9 gage, 0.27 oz/ft2 (82 g/
each data set. An alternate initial point, years to complete m 2 ) aluminum-coated wire, and Code 17, 12 112 gage, 0.29
rust and zero percent loss, was considered but rejected be- oz/ft2 (88 g/m 2 ) aluminum-coated wire had sufficient data
cause of the possibility of loss in strength between initial and to establish meaningful equations. At this site, the Code 11
complete rust, particularly for the aluminum-coated wires. wire outperformed the Code 17 wire. This result indicates
For three data sets, points not consistent with the data were that the rate of loss of breaking strengths per year for
removed before the linear equations were generated. These aluminum-coated wire decreased with increased wire di-
points are indicated in the notes with Table 36. ameter, which is expected since corrosion is proportional to
The statistical analysis of the tensile data showed that the cross-sectional area. Therefore, smaller diameter wires will
percent loss in breaking strength for bare, zinc-coated, and lose more area at the same corrosion rate and thus lose more
aluminum-coated wires increased linearly with the years of strength.
exposure. While the conclusions drawn here are based on a small
At all four sites Code 1, 9 gage bare copper-bearing wire, sample, they are supported by the earlier work done by
Code 2, 9 gage wire with 0.5 oz/ft2 (153 g/m2 ) zinc coating Reinhart. 7
and Code 3, 9 gage wire with 0.99 oz/ft2 (303 g/m2 ) zinc
Breaking Strengths
coating had sufficient data to establish a meaningful
equation. Tables 19 through 35 give a summary of breaking strengths
The rate of loss of breaking strengths per year is the slope on specimens removed during the 30 year period 1961
of the calculated line. For uncoated and zinc-coated wire the through 1991.
rates were different for different locations. The maximum
difference for bare wire was a ratio of 5.9: 1 for Warrington 7
Reinhart, F. M., Twenty-Year Atmospheric Corrosion Investigation
and Newark-Kearny and is calculated as the ratio of the of Zinc-Coated and Uncoated Wire and Wire Products, ASTM STP 290,
slopes of the linear equations in Table 36 of Warrington to American Society for Testing and Materials, 1961.
15
Summary
This atmospheric exposure investigation of aluminum- 4. Based on the average CCR for all aluminum-coated prod-
coated and zinc-coated wire and wire products was author- ucts, the Warrington site has the highest corrosion rate
ized by ASTM Committee AS on Metallic-Coated Iron and and the Manhattan and Newark-Kearny sites have the
Steel Products and was conducted by its Subcommittee lowest. For zinc-coated products, the Warrington site has
AOS.15 on Wire Tests. The data for the 32-year exposure in the highest corrosion rate and the Manhattan site has the
the United States and 13-year exposure in England were the lowest.
basis of this report. 5. The statistical analysis of the tension data showed a linear
The following information is summarized from the visual relationship between the percent loss of breaking strength
observations and the tension tests on unfabricated and fab- and years of exposure.
ricated wire and wire products: 6. The rates of loss of breaking strength per year for un-
coated and zinc-coated wire were different for different
locations. The maximum difference for bare wire was a
1. The average corrosion rates to initial rusting (CIR) were ratio of 5.9: 1 for Warrington and Newark-Kearny. The
less for aluminum-coated products (Table 14) than for maximum differences for zinc-coated wires were a ratio
zinc-coated products (Table 16). of 6.8: 1 for Warrington and Newark-Kearny for Code 2
2. Likewise, the average corrosion rates to complete rust and 12.2: 1 for Warrington and Kure Beach-800 ft (250 m)
(CCR) were less for aluminum-coated products (Table 15) for Code 3.
than for zinc-coated products (Table 17). 7. The rate of loss of breaking strength per year for zinc-
3. Based on the average CIR for all aluminum-coated prod- coated wire decreased with increase in coating weight.
ucts, the Warrington site has the highest corrosion rate 8. The aluminum-coated steel core wire (ACSR) resists cor-
and the Manhattan, Newark-Kearny, and Point Reyes sites rosion in coastal environments better than the zinc-coated
have the lowest. For zinc-coated products, the Warrington steel core wire.
site has the highest corrosion rate and the Manhattan site 9. The copper-bearing steel (0.23% copper) wire is more re-
has the lowest. sistant to corrosion than the low copper steel (0.03% cop-
per) wire.
16
Tables
TABLES 19
Wire No. and Coatina Kure Beach, NC l800 ftl Newark-K•mv. NJ State Coll......., PA Warrlnaton, Enaland"
32-Year 32-Year 32-Year 32-Year
No.~. a- azllt2 Condition IR CIR CR CCR Condition IR CIR CR CCR Condition IR CIR CR CCR Condition IR CIR CR CCR
2 Zn 9 0.50 Scrapped 5.0 0.100 9.1 0.055 100R 3.0 0.187 3.9 0.128 100R 7.9 0.063 9.8 0.051 2.8 0.179 3.8 0.132
3 Zn 9 0.99 100R 9.1 0.109 28.1 0.035 100R 5.9 0.168 6.9 0.143 100R 17.0 0.058 22 0.045 4.7 0.211 4.7 0.211
4 Zn 9 2.84 95Y«:,5Y 23.1 0.123 100R 15.8 0.180 22 0.129 1000 13.2 0.215
5 Al 9 0.52 80G,10wc, 95blk, 27.1 O.Q19 10G,70Y, 9.8 0.053 7.8 0.067
10Y,trPPR 5PPR 20PPR
6 Al 9 0.54 85G,10wc, 32.3 0.017 80blk, 1Obrst, 25.0 0.022 5G,60Y, 8.9 0.061 10.9 0.050
4Y,1PPR 10PHR 35PPR
9 Al 9 0.48 80G,20wc, 95blk,5PPR 28.3 0.017 85G,13st, 21.0 0.023 8.5 0.056
trY,trPPR 2PPR
10 Al 9 0.51 80G,20wc, 85blk, 26.4 O.Q19 60G,10Y, 8.9 0.057 7.8 0.065
trY,trPPR 15PHR 30PHR
11 Al 9 0.27 70G,10wc, 10.0 0.027 40blk, 10brst, 8.9 0.030 25G,35Y, 8.9 0.030 4.7 0.057 8.5 0.032
20R SOPHR 40R
12 Al 9 0.48 40G,45wc, 20.2 0.024 85blk, 26.4 0.018 55G,30Y, 11.0 0.044 9.4 0.051
15R 15PPR 15PPR
17 Al 12 112 0.29 100R 10.0 0.029 32.3 0.009 50blk,25PPR, 19.1 O.Q15 30G,40Y, 8.9 0.033 4.7 0.062 7.8 0.037
25PHR 30PPR
18 Al 12 112 0.43 60G,40wc, 90blk, 25.0 0.017 40G,40Y, 9.8 0.044 5.8 0.074
trPPR 10PPR 20PPR
20 Al 12 112 0.37 20wc,80R 9.1 0.041 90blk, 19.1 O.Q19 SOY, 8.9 0.042 5.8 0.064
10PHR 20PPR,30R
•Abbreviations and symbols nplalned In Table 13. Figures preceding abbreviations are - . percentages.
" 1 azllt2 • 305.15 g/m2
• WM'lngton, England slfll dosed In 1977; ollMI' s1119s 91111 active.
~Copper-bearing ....
TABLE 9-1961 exposure of zinc and aluminum coated farm-field fence" average of observed years until initial rust (IR) and complete rust (CR) or condition after
approximately 32-years exposure and calculated corrosion rates (ounces per square foot per year)b to initial rust (CIR) and to complete rust (CCR).
l'enceNumber Kurw ISeech, NC Kure ISeech, NC
encl eo.tlna Brazos Rlv9r TX 80ft Manhattan KS
-
IOOft
Com- O'ZI 32-Y•r 32-Y•r 32-Y•r 32-Y•r
No. Ina ltl9m tr- Condition IR CIR CR CCR Condition IR CIR CR CCR Condition IR CIR CR CCR Condition IR CIR CR CCR
24 Zn Top 9 0.49 100R 3.2 0.153 7.1 O.Oll 100R 3 0.113 1.3 0.078 100R 5 O.DN 7.3 0.087 10Y,llOR 25 0.020
Line 11 0.42 100R 1.2 o.350 7.1 0.058 100R 2 0.210 7.3 o.osa 100R 4 0.105 9.1 0.048 SY, flSR 2S 0.017
Slay 11 Q.311 100R 2.2 0.114 7.1 0.051 100R 2 0.180 7.3 0.049 100R 4 O.OllO 7.3 0.049 100R 21.1 0.017. 32.1 0.011
l!!la9Dm 9 0.48 100R 4.2 0.117 u 0.053 100R 4 0.123 7.3 0.087 100R 10 0.049 15 0.033 100Y
- .
Cut
l!nds 100R 1.2 4.2 100R 4. 7.3 100R 7.3 7.3 100R 21.1 25
21 Zn 'top 9 1.00 100R 10.3 0.097 20.a 0.048 100R 2 0.500 15 0.087 100R 5 0.200 19.1 0.052 950,SY
Une 9 1.00 1001'1 10.3 0.097 19 0.053 100R 4 0.250 15 0.087 100R 7.9 0.127 29.2 0.034 900, 10Y
Slay 9 0.99 100R u 0.108 13.3 0.074 100R 4 0.248 15 o.oee 100R 5 0.198 19.1 0.052 900, 10Y
8ollDln 9 1.00 100R 10.3 0.097 22.2 0.045 100R 7.3 0.137 15 0.087 10Q, 10wc, 24.2 0.041 950,SY
SOR
W111J!9
Cut
- . 100R 10.3 22.2 100R 2 15 100R 7.3 22.2 850, 1SY
l!nds - . 100R 1.2 a.2 100R 7.3 a 100R 9.1 22.2 7SY,2SR 29.1
211 Al Top 9 0.43 SOR u 0.048 • 100R 9.1 0.047 15 0.029 10Y, llOR 11 0.039 15M, as.t
Une 11 0.38 10R 19 0.020 • 100R 9.1 0.042 15 0.025 SM, 35GI, 11 0.035 eoM,4o.t
40wc,10Y,10R
Stay 11 0.27 100R 2.2 0.123 10.3 0.028 100R u 0.043 12 0.023 100R 10 0.027 32.3 0.008 10M, llOst
d
ISallDm 9 0.43 10R 11.3 0.038 100R 11 0.039 15 0.029 70M,20Y, 29.2 0.015 ISM, 1511
10R
W111P9
Cut
- - 100R 3.2 10.3 100R 1.3 9.1 100R 9.1 29.2 90Y, 10R 27.1
l!nds - - 100R 1.2 3.2 100R 7.3 a 100R 2 15 100R 1.1 14.2
• Abbrevl8llons end aymbola explained In Teble 13. l'lg- preceding •bbrevl8tlone erw ~ percentagee.
1 Olliff- 305.15 g/m 2
b
'Werringllln, l!nglend •closed
•Semple flllled belbre CR.
In 1977; a11w .,._ dll ec:llve.
TABLE 9-Continued.
Fera Number
•ndc-lllMI ~rk-KMmVNJ Point Reves.CA Stldl Col.._ PA Wmlnaton. E......i.n.f'
eo.t- ad 32-YMr 32-Y- 32.y.., 32-Y•r
No. Inn llilln ~ tt3 Condition IR CIR CR CCR Condition IR CIR CR CCR Condition IR ~ CR CCR Condition IR ~ CR CCR
24 Zn Top 9 0.49 100R 3 0.163 3.9 0.126 100R 18 0.031 202 0.024 100R 8.9 0.071 9.8 o.oso 1.8 02n 3.8 0.129
LN 11 0.42 100R 3 0.140 4.9 0.086 100R 6.3 0.087 17.8 0.024 100R 7.9 0.053 11 0.038 1.8 0.233 3.8 0.111
si.y 11 0.36 100R 1.9 0.189 4.9 0.073 100R 10.3 0.035 14.3 0.025 100R 8.9 0.052 8.9 0.CMO 1.8 0200 3.8 0.095
Boeom 9 0.49 100R 5.9 0.083 8.9 0.071 100R 20.2 0.024 • 100R 9.8 o.oso 13.8• 0.038 1.8 o.2n 3.8 0.129
Wl'8p9
Cut
- - 100R 3 4.9 100R 12.1 14.3 100R 5.9 11 1.8 3.8
Ends - - 100R 1.9 5.9 100R 10.3 14.3 100R 5.9 7.9 0.8 3.8
25 Zn Top 9 1.00 100R 4.9 0.204 8.9 0.145 100R 14.3 0.070 202 o.oso 100R 15.8 0.063 23 0.043 3.8 0.263 3.8 0.263
LN 9 1.00 100R 4.9 0.204 8.9 0.145 5wc,95R 10.3 0.097 100R 15.8 0.083 24 0.042 3.8 0.263 4.7 0.213
si.y 9 0.99 100R 4.9 0.202 8.9 0.111 100R 8.3 0.157 212 0.047 100R 14.9 0.068 23 0.043 3.8 0.261 3.8 0.261
Boeom 9 1.00 100R 8.9 0.145 8.9 0.112 70wc,30R 23.2 0.043 80Y,40R 23 0.043 3.8 0.263 8.9 0.145
Wraps
Cut
- - 100R 5.9 8.9 5wc,95R 10.3 5Y,95R 24 3.8 3.8
Ends - - 100R 3 7.9 100R 6.3 10.3 100R 7.9 7.9 2.8 3.8
26 Al Top 9 0.43 90blk, 27.1 0.018 90wc:, 10R 202 0.021 85G, 15PPR 11 0.039 7.8 0.055
10PHR
LN 11 0.38 85blk, 25 0.015 90wc:, 10R 20.2 0.019 900, 10PPR 9.8 0.039 7.8 0.049
15PPR
si.y 11 027 80blk, 15.8 0.017 100R 8.3 0.033 17.8 OD15 100R 9.8 0.028 24 0.011 5.8 0.047 7.8 0.035
20PPR
Boeom 9 0.43 80blk, 9.8 0.044 95wc,5R 20.2 0.021 95G,5PPR 23 0.019 7.8 0.055
20PPR
Wraps
Cut
- - 75blk,
25PPR
20.2 100R 8.3 10.3 10Y,90R 7.9 24 8.9 7.8
• Abbreviations end symbols explelned In Table 13. Figures Pf9C*llng ebbrevtetlona era eveniga percentages.
• 1 azm2- 305.15 glm2
• Wlrringlon, Engllnd 1118 doNd In 1977; otier lhs 111111 ectlvw.
• Semple fllled befor9 CR.
TABLE 10-1961 exposure of zinc and aluminum coated lyman 4-point barbed wire" average of observed years until initial rust (IR) and complete rust (CR) or condition
after approximately 32-years exposure and calculated corrosion rates (ounces per square foot per year)b to initial rust (CIR) and to complete rust (CCR).
WlrwNo. lr.-~.TX Kin llemch, NC Kure llemch, NC Mmni.ti.n,KS
uclc-M.... IOft IOOft
Coel- oz/ 32-Y- 32-Y- 32.y.., '32·Y•r
...,. a.- ~
No.
...
Ina Condlllan IR CIR CR cc:R Candltlon IR CIR CR cc:R Condlllon IR CIR CR cc:R Condlllan R CIR CR cc:R
27 Zn 12.5 0.43 1.2 G.351 7.1 O.Ol1 .. 0.10I 7.3 0.058 .. 0.10I 8 0.054 100R 20.1 0.021 25 0.017
u
28 Zn ...
berb
12.5 0.17
1.2
8.3
G.358
0.114 20.1
0.088
0.047
1.2
..
D.358
0.243
7.3
18
0.058
O.Ol1 u
2 0.215
0.154
7.3
17.1
0.058
0.057
100R
ll00, 10Y
13.2 0.033 11.3 0.022
o.eoe
21 Al ...
berb
12.5 0.25
1.2
7.1 0.035
20.8
1.....
0.047
0.017 7.3
1 0.170
0.034
18
10
O.Ol1
0.025
8.3
7.3
0.154
0.034
17.1
22.2
0.057
0.011
IOQ,1SY,
5R
•.7W.
20Y
25.8 0.038
berb 1.2 0.208 8.3 0.040 1.2 0.208 8 0.031 2 0.125 18 0.018 5M,7W, 13.2 0.011
20R
30 Al lne 12.5 O..C2 8.3 O.Ol7 • 1.1 0.048 • 750,20M:, 7.3 0.058 1SM,85et
SY, trft
Al berb
31 Al ... 12.5 0.31 8.3 O.Ol2 20 0.018 8.3 O.Ol2 • 10Y, 75-,
15R
7.3 0.053 15M, 85et
Al berb
27 Zn 12.5 0.43 3 0.143 3.1 0.110 13.1 0.033 10 0.030 5.11 0.073 1.8 0.044 2.8 0.15.c 3.8 0.113
berb u 0.221 3.1 0.110 11.8 0.044 1.8 0.044 5.1 o.on 7.1 0.054 0.8 0.538 3.8 0.113
28 Zn fine 12.5 0.17 ...I 0.1• u 0.1 .. 1 ...2 0.231 10.3 0.09.c 11.1 0.051 2.. 0.040 3.1 0.255 ... 7 0.208
berb 3.1 0.241 u 0.1 ..1 ...2 0.231 1.8 O.Oll 13.8 0.070 23 0.042 0.8 1.213 3.8 0.255
21 Al line 12.5 0.25 20PHR, 111.1 0.013 5.3 0.047 20.2 0.012 IOY, I.II 0.021 5.8 0.043 5.1 0.043
20lnt,90blk 20PPR,20R
u
30 Al ...
berb
12.5 O..C2
«lblk, «IR
20tnt
IOblk,
10PPR
1.8
27.1
0.028
0.015 15-,SR
1.2
11
0.208
0.038
11 0.023 100R
351t, 35Y,
20PPR, 10R
u
0.028
0.047
32.1 O.OOI 0.8
7.1
0.313
0.054
5.8 0.043
31 Al ...
Al berb
Al berb
ISwbs 100R 11.3 0.190 111 0.093 burled 11 0.1111 100R 11.3 0.2111 22.2 o.oao 33Q,117Y
32 Zn II 1.77 Unks 100R 11.3 0.190 31.2 0.057 100R 4 0.443 211.2 0.081 100R 5 0.354 32.3 0.055 400, llOY
l!lwba llO.M:,20R 111 0.148 burled 100R 7.3 0.3115 32.3 0.087 37Q, IS3Y
33 Zn II 2.111 Unks 40wc, llOR 111 0.148 100R 7.3 0.3115 32.3 0.087 10Q,30M:, 7.3 0.3115 400,llOY
llOR
Knuckln burled 100R 7.3 0.3115 32.3 0.087 burled 400,llOY
a.rt. 10wc, llOR 11.2 0.1117 100R 7.3 0.210 211.2 0.052 500, SOY
34 Zn II 1.53 Links 10wc,llOR 20.11 0.074 4 0.383 17.1 O.Olll SQ,35wc, 11 0.1311 1000
llOR
Knuckles burled 20.11 0.074 4 0.383 17.1 0.089 burled 1000
l!lwba llOwc, 10R 20.11 0.107 100R 11.1 0.245 32.3 O.Ollll llOQ, 40Y
35 Zn II 2.23 Unks 95wc, 15R 20.11 0.107 5 0.448 23.1 0.097 100,llONc, 111.2 0.1111 1000
30R
Knuckles burled 5 0.448 23.1 0.097 burled 1000
a.rt. 100R 10.3 0.055 22.2 0.028 burled 20wc,10Y, 7.3 0.0711 10M,35Y, 111.3 0.030
70R 55R
311 Al II 0.57 Unks ISQ,15wc. 20.11 0.027 bM,400, 10 0.057 10M,780, 21.2 0.027 35M,ISQ
20R 20Y,40R 10wc,2R
Knuckles burilld 100R 11.3 0.090 20.2 0.0211 burilld 35M,llSO
.,.. 100R 10.3 0.043 14.4 0.031 100R 11.3 0.070 211.1 0.0111 20Y,2W, 111.3 0.023
55R
37 Al II 0.44 Unks 150,llOwc, 111 0.023 II 0.055 SM,740, 21.2 0.021 40M,eo.t
25R 20wc,1R
Knuckln burled 7.3 0.080 30.2 0.015 burilld 40M, eo.t
.,.. 100R 10.3 0.052 22.2 0.024 burled 111.2 0.0211 20Q,20wc, 7.3 0.074 ..a.t,52R 111.3 0.0211
10Y,50R
38 Al II 0.54 Unks llOQ,30wc, 20.11 0.029 250,25Y, 11.1 O.OSll 10M,500. 11 0.049 40M,eo.t
10R SOR 40wc,trY,trfll
Knuckles burilld 100R 7.3 0.074 25.1 0.022 burled 40Meo.t
Bart. 100R u 0.1911 28.3 0.083 SOllw:, SOR 11.8 0.181 70Y,30R 28 0.083 7.8 0.227
32 Zn II 1.77 Unb 100R 8.11 0.257 23 0.077 40M:.llOR 11.8 0.181 5Y,llSR 14.11 0.1111 4.7 0.3n 8.5 0.208
Knuckle. burled 11.11 0.1411 100WI:· 11.8 0.181 50,SY,llOR 14.11 0.1111 5.8 0.305 11.4 o.1ee
Barba 100R 11.8 0.287 28.3 0.089 75'M:. 25R 22.4 0.125 1000 7.8 0.3IO 11.4 0.2911
33 Zn II 2.81 Unb 100R u 0.318 28.3 O.Ollll llSwc.SPPR 24.3 0.118 50, 115Y 8.11 0.407 11.4 0.21111
Knucldee burled 115wc,SR 211.1 0.097 10, llllY 7.8 0.3IO 11.4 0.21111
Barba 100R 5.11 0.2511 u o.1n SoM:, llSR 20.2 0.078 1000 8.11 0.222 7.8 0.11MS
34 Zn II 1.53 Llnb 100R 5.11 0.2511 23 0.0117 200, 25'M:, 17.8 0.087 1000 u 0.222 11.4 0.183
55R
Knuckle. 100R 11 0.1311 23 0.0117 85'M:, 35R 20.2 0.078 500,50R 22 0.070 8.11 0.222 8.5 0.180
Barbe 100R 8.11 0.251 111.1 0.117 llSwc,SPPR 24.3 0.092 1000 8.5 0.282
35 Zn II 2.23 Unb 100R u 0.251 23 0.097 200, 72wc, 24.3 0.092 1000 7.8 0.2•
8R
Knuckle. 100R 111.1 0.117 23 0.097 llOM:, 10R 24.3 0.082 950, SR 32.1 O.OISll 10.11 0.205 13.2 0.1911
Barba e!iblk, 211.2 0.015 20M:,llOR 10.3 0.043 80G,20Y 8.5 0.052
15PPR
37 Al II 0.44 Unb .llQblk, 28.4 0.017 llSwc,SPPR 24.3 0.018 850,20Y, u 0.049 8.5 0.052
10PPR 15PPR
Knuckle. burled 11.8 0.045 llOM:,10R 23.2 0.0111 150,75Y, 8.11 0.049 10.11 0.040
10PPR
Barba 100blk 111.1 0.028 85'M:, 1SR 11 0.049 950,SY 7.8 0.089 13.2 0.041
38 Al II 0.54 Unb 100blk 24.1 0.022 115wc,SPPR 24.3 0.022 eoG,SY, 8.11 0.081 7.8 0.089
15PPR
Knuckle. burled 11.8 0.055 100wc,trR 700,2SY, 11.8 0.055 7.8 0.089
5PPR
•Abbreviations and armbam explalMd In Table 13. l"lg- pracedlng abbra¥latlol• - - . . . . ,__,mg•.
~ 1 ozlfi'- 305.15 gJm2
•werrtngton, l!!ngland • c1oeec11n 111n; ,,._..,... dll 8Cl!Ye.
• Sample flllled befDr9 CR.
TABLE 12-1961 exposure of zinc and aluminum coated 7-wire strand' average of observed years until initial rust (IR) and complete rust
(CR) or condition after approximately 32-years exposure and calculated corrosion rates (ounces per square foot per year)1' to initial rust (CIR)
and to complete rust (CCR).
-
SlrandNu- a.-Rlwr, TX Kure llMch, NC Kure llNc:h, NC Ma,,,,_n, KS
end Cooitina 9011 80()11
Colt- oz} 32-Y- 32-Y- 32-Y•r 32-Y-
No. Ina Sin. rr Condition IR CIR CR CCR Condition IR CIR CR CCR Candllan IR CIR CR CCR COndition IR CIR CR CCR
39 Zn 3ltf' 0.8'1 500,"5wc, 31.2 0.032 «>we, 7.3 0.138 300,llOM:, 20.2 0.049 500,!IOY
trY,5R 90R trY,10R
40 ?n 3ltf' 2.118 411G,"5wc, 211.1 0.114 DOwc,10R 20.2 0.148 SOwc,500 500,!IOY
trY,5R
43 Al 3ltf' 0.411 750,15wl:, 7.1 O.Ollll 71G,15Y, 10.0 0.049 10M,llOG, ~.75.i
10R 7R 10..C
!Ill Al Or. 5'18" 0.3111 1!1G,45wl:, 10.3 0.038 15Y.85R 8.o 0.049 500,45wl:, 11.0 0.035 15M,85st
.,...,..,_ 40R 5YtrR
39 Zn 3ltf' 0.99 100R 8.9 0.143 22.0 0.045 50wc,50R 8.9 0.143 20G,45Y, 25.11 0.038 5.8 0.171 11.4 0.105
35R
41 Al 318" 0.43 85blk. 8.9 0.048 100R 9.8 0.044 14.3 0.030 45G,40Y 8.9 0.048
5PPR 15PHR
42 Al 5118" 0.33 80blk. 8.9 0.037 100R 9.8 0.034 23.2 0.014 llOG, 8.9 0.037 8.5 0.039
20PHR 20PPR
43 Al 3ltf' 0.411 llOblk. 8.9 0.055 1~ 8.3 0.058 9.8 0.050 55G,20Y, 11.8 0.050
10PPR 25PPR
511 Al Dr. 5118" 0.39 75blk, 11.0 0.035 5wc,95R 11.0 0.035 30G,35Y, 7.9 0.049 8.9 0.057
.......... 1"""°10R 35R
TABLE 14 - Average corrosion rates to initial rusting (CIR) (ounces per squarefoot per yearj a for
ear.h aluminum-coated product exposed at each location for approximately 32 years.
Average CIR
Aluminum Coated
Unfabri- Barbed Chain- All Products
cated Field Wire Link Wire Standard
Location Wire Fence Qine) Fence Strand Averaged Deviationd
b
Brazos River, TX 0.057 0.055 0.038 0.058 0.051 0.034
b
Kure Beach, NC 80 ft 0.043 0.047 0.061 0.034 0.048 0.018
Kure Beach, NC 800 ft 0.027 0.029 0.048 0.053 0.035 0.040 0.019
b c c c
Manhattan, KS 0.027 0.027 0.004
Newark-Keamy, NJ 0.020 0.023 0.015 0.033 0.044 0.027 0.014
b
Point Reyes, CA 0.023 0.042 0.029 0.043 0.033 0.013
State College, PA 0.043 0.031 0.040 0.051 0.046 0.043 0.012
Warrington, England 0.061 0.051 0.051 0.059 0.048 0.056 0.010
TABLE 15 - Average corrosion rates to complete rust (CCR) (ounces per square foot per year) a for
each aluminum-coated product exposed at each location for appt0ximately 32 years.
Average CCR
Aluminum Coated
Unfabri- Barbed Chain- All Products
cated Field Wire Link Wire Standard
Location Wire Fence Qine) Fence Strand Averaged Oeviationd
b c
Brazos River, TX 0.026 0.017 0.027 0.023 0.006
b c
Kure Beach, NC 80 ft 0.026 0.025 0.021 0.024 0.005
c
Kure Beach, NC 800 ft 0.009 0.008 0.011 0.016 0.011 0.003
b c c c '?
Manhattan, KS
c c c c c
Newark-Keamy, NJ
b c
Point Reyes, CA 0.015 0.012 0.031 0.024 0.016
c c c c
State College, PA 0.011 0.011 0.000
c
Warrington, England 0.034 0.035 0.036 0.041 0.036 0.005
TABLE 16 - Average conosion rates to initial rusting (CIR) (ounces per square foot per year) a for
each zjnc-coated product exposed at each location for approximately 32 yeatS.
Average CIR
Zinc Coated
Unfabri- Barbed Chain- All Products
cated Field Wire Link Wire Standard
Location Wire Fence- Qine) Fence Strand Averaged Deviationd
b
Brazos River, TX 0.148 0.256 0.136 0.073 0.146 0.081
b
Kure Beach, NC 80 ft 0.226 0.175 0.376 0.142 0.278 0.130
Kure Beach, NC 800 ft 0.111 0.113 0.131 0.264 0.049 0.167 0.105
b c c
Manhattan, KS 0.018 0.021 0.019 0.002
Newark-Kearny, NJ 0.171 0.166 0.171 0.226 0.143 0.192 0.057
b c
Point Reyes, CA 0.065 0.132 0.116 0.099 0.056
c
State College, PA 0.061 0.058 0.062 0.088 0.068 0.021
Warrington, England 0.201 0.253 0.204 0.288 0.171 0.256 0.064
TABLE 17 - Average conosion rates to complete rust (CCR) (ounces per square foot per year) a for
each zinc-coated product exposed at each location for approximately 32 yeatS.
Average CCR
Zinc Coated
Unfabri- Barbed Chain- All Products
cated Field Wire Link Wire Standard
Location Wire Fence Qine) Fence Strand Averaged Deviationd
b c
Brazos River, TX 0.056 0.054 0.075 0.059 0.014
b c
Kure Beach, NC 80 ft 0.065 0.060 0.084 0.073 0.015
c
Kure Beach, NC 800 ft 0.045 0.048 0.056 0.069 0.055 0.015
b c c
Manhattan, KS 0.011 0.017 0.014 0.004
Newark-Kearny, NJ 0.134 0.109 0.125 0.095 0.045 0.105 0.032
b c c
Point Reyes, CA 0.034 0.062 0.042 0.025
c c
State College, PA 0.048 0.042 0.042 0.043 0.005
Warrington, England 0.171 0.168 0.160 0.222 0.105 0.187 0.065
TABLE 18-Style, coating metal, coating weight, and coating method of ACSR
specimens.
Specimen Number Coating Weight
Coating
Conventional Compacted Metal oz/ ft 2 glm2 Coating Method
46 52 Zn 0.87 265 electroplated
47 53 Al 1.92 586 process 3
48 54 Al 0.45 137 process 2
49 55 Al 0.34 104 process 1
50 56 Al 0.43 131 process 5
51 57 Al 0.30 92 process 4
TABLES 35
CW.per
Years Breaking Year
Years Years Since Strength Loae, Since
Location Exposed tD IR IR R,% bf cw. IR
• 1 bf = 4.45 N
36 ATMOSPHERIC CORROSION INVESTIGATION
TABLE 20 - Breaking strenr;ti ofwns removed dcnng the 30-year period 1961to1991.
Code No. 2 - 9 gage zinc-coated steel winJ O. 50 ozllf 2 •, original breaking strenr;ti 1487 lbf. b
% per
Years Breaking Year
Years Years Since Strength Loss, Since
Location Exposed to IR IR R,% lbf % IR
=
• 1 ozJftl 305.15 g/m 2
=
b 1 lbf 4.45 N
TABLES 37
TABLE 21 - Bteaking stren¢1 of wns removed dlling the 3~yesr period 1961 to 1991.
Code No. 3 - 9 gage zinc~ated steel wU9 0.99 ozAt 2 •, original brealcing stren¢t 1058 lbf. b
%per
Years Breaking Year
Years Years Since Strength Loss, Since
Location Exposed to IR IR R,% lbf % IR
TABLE 22 - 8tMldng allwlgfh al wilN twrttWed during the 30-)'NT peliod 1961 ID 1991.
Code No. 4 - 9 gage zinc-co.led..., .W. 2.tU o.rAt 2 •, originel bnlaldng shngfh 1030 /bf. •
"per
y..,.. &r.klng y.,
y..,. Years Since Shngth Losa, Since
ExllDHd IR lbf
LOCllllon IDIR R,"
" IR
TABLE 23 - BtMJdng shngfh a/MN twrttWed during the 3o-)'NT peliod 1961 ID 1991.
Code No. 5 - 9 gage UJminum-coated ateel wn 0. 52 o.rAt 2 •, origine/ breeking shngfh 1040 lbf. •
y..,. Breaking
"per
y.,
y..,. Years Since strength Losa, Since
Location Exllowt ID IR IR lbf IR
0 1011
" 2.8
800ftlot 17.1 0 0 1050 -1.0
302 0 0 1046 -0.6
TAal..E 24 - BIMldng aftnglll al wilN lflmOll9d during lhe 3Q-,_.. period 1981 b 1991.
Code No. 6 - 9 ~ llluminum-coeted *""
wn 0.54 oim'•. ot1g1t.i bNeldng -.ngttt 2885 "'-'
~per
Y•rs Ehlildng y..,
Location
Y.rs
Exposed
Y•rs
Clo IR
Since
IR R.~
.,,
Strength Loes,
~
Since
IR
• 1ozJlt2•305.15 g/m2
'1lbf•4.45 N
40 ATMOSPHERIC CORROSION INVESTIGATION
y..,. er.king
"'Y•r
per
v... v.... Since Strangth Loss, Since
Location EXDOMd tolR IR lbf IR
0 1388
"' 14.2
1IOO It lot 17.1 0 0 1465 9.4
18.2 0 0 1483 9.5
30.2 0 0 1447 10.5
v.... Br..idng
"'v-
per
v.... v.... Since Str9nglh Loea, Since
EXllOMd
Loclltlon tolR IR RI"' lbf
"' IR
"I*
v.... 8r..idng v..
v.... Ye.rs Since Slrwnglh Loea, Since
EXDOMd R,"
Location
Kane-:t1 18.0
to IR
10.0
IR
8.0 5
ltt
1403
" 5.7
IR
1.0
800 ft lot 17.1 10.0 7.1 1 1468 1.3 0.2
20.2 10.0 10.2 7 1505 -1.1 -0.1
21.2 10.0 11.2 7 1483 0.3 0.0
30.2 10.0 20.2 10 1491 -0.2 0.0
¥ops
y..,. er.king v..
v.... Y•111 Since Slrwnglll Loa. Since
Location Exposed tolR IR R, ¥. ltt
'1ltt=4.'5 N
42 ATMOSPHERIC CORROSION INVESTIGATION
TABLE 30 - Bl98ldng slr9ngttl al wires l9lflC1l/fld during !tie 30-~ period 1961 IO 1991
Code No. 13 - 9 gage 8lrJminum.coate steel Mia 0. 63 oz/ft'•. orl(Jinal breaking strangth 1423 /bf •
"per
y..,. 8leelmlg Year
Y•l'I v..... Since Slrengttl Lou, Since
IR
LOClltlon
Kunt Belct1
EXllCIMd
18.ci
tolR IR
0
!3."
0
llf
1373
" 3.5
800 ft lat 17.1 0 0 1409 1.0
30.2 0 0 1411 0.8
• 1oVn2.305.15 g1m2
• 1 llf • 4.45 N
TABLE 31 - Bf88king strength a/wifes remt:N«J during the 30-yflfJf period 1961IO1991.
Code No. 17 - 12 'I, gage a/Uminum-ooated steel Wir9 0. 29 OZ/ft'• ,
original b1981cing strength 47 lbf. •
"per
v... 8leelmlg YMI
v... Yeara Since Stnlngth Lou, Since
Location &Doled tolR IR lb( IR
y.,. y.,.
y.,.
Since
lr..idllg
Shnglh LDA.
._
v..
Location !lciiaud tolR IR RI~ lllf ~ IR
- -u
Newark-Keamy 15.I 0 0 507
11.1 0 0 510 -4.1
20.0 0 0 -1.1
22.0 0 0 411 ·1.1
21.1 25.0 3.1 10 417 ·1.4 -0.4
30.0 25.0 5.0 10 480 0.0 0.0
StnCollege
WllfringtDn
15.1
11.1
20.0
22.0
30.0
13.2
13.2
I.I
I.I
I.I
I.I
I.I
5.1
5.1
1.0
1.3
10.2
12.2
20.2
7.4
7.4
5
7
7
7
15
«>
«>
-411
515
511
514
456
414
0.4
-6.1
-3.1
-6.3
-4.1
7.1
1.2
0.1
-0.5
-0.4
-0.4
-0.2
1.0
0.2
TABLI!! 33 • 8t8eldng 8ll8ngtll af M98 remrN8d CUtng 11t8 30-year petlod 11J11 ID 1•1.
Code No. 20 - 12 'I 2 gage &Jumlnum-coated sl8el Wlf9 0.37 oim'•. odg/1181 bt9ekklg"'""""" '85 lbf. b
~per
y.,. ar..ldng v-
y.,. y.,. sir- Shnglh LDA. Since
Location !xPOMCI tolR IR RI~ lllf ~ IR
smt.College 15.I
11.1
20.0
I.I
I.I
I.I
I.I
10.2
11.1
10
10
10
-Ml
581
3.4
-7.3
-3.7
0.5
-0.7
-0.3
--
22.0 I.I 13.1 12 515 -4.1 -0.3
23.0 I.I 14.1 10 852 -15.4 -1.1
21.0 I.I 17.1 10 .a.o -0.4
30.0 I.I 21.1 25 5158 1.1 0.1
Yeers en.Icing
"per
y.,
y.,. v...
tolR
Since
IR
Strangth
lbl
....... Since
IR
L.oc:.tlon
Ka.nee.ch
EXPOl8d
18.0 0
R,"
0 757
" 1.4
800 ft lat 17.1 0 0 548 28.8
18.2 0 0 784 -2.1
20.2 0 0 784 -2.1
=
• 1 ozjftJ 305.15 g/m2
b1 ~·4.45N
TABLE 35 • BINldng strength dwltetl rwnotlfld du1ng the 30-Yflll" period 1961to1991.
Code No. 22 - 12'12 gege ~steel wn 3.36 ozAt 2 • ,. t:r1g1na1 bnleldng atren(lth 1012 lbf. b
v.... an.Icing
"per
v..
y..,. y.,. Since Strength l.Clla, Since
L.oc:.tlon ElCP»9d tolR IR lbl IR
FIG. 3. Overall View of the Kure Beach, NC 800-ft Test Site illustrates the
mounting of the chain link fabric test specimens.
FIG. 4. Specimen 32 - Hot-dip Galvanlzed Chain Link Fabric. FIG. 5. Specimen 32 - Hot-dip Galvanized Chain Link Fabric.
Original coating weight: 1.n ovtt2 (540 glm2). Exposure site: Brazos River, TX. Original coating weight; 1.n oZftt2 (540 gfm2). Exposure site: Kure Beach, NC
30-year condition of links (see Table 13): 95R, 5wc. (80-ft site). 30-year condition of links (see Table 13)~ 100R.
FIG. 6. Specimen 32- Hot-dip Galvanized Chain Link Fabric. FIG. 7. Specimen 32 - Hot-dip Galvanized Chain Link Fabric.
Original coating weight: 1.77 oz1tt2 (540 g/m2). Exposure site: Kure Beach, NC Original coating weight: 1.77 ovtt2 (540 g/m2). Exposure site: Manhattan, KS.
(800-ft site). 30-year condition of links (see Table 13): 95R, 5wc. 30-year condition of links (see Table 13): 40G, 60Y.
FIG. 8. Specimen 32- Hot·dip Galvanized Chain Link Fabric. FIG. 9. Specimen 32- Hot-dip Galvanized Chain Link Fabric.
Original coating weight: 1.n ozlft2 (540 g!m2). Exposure site: Newark· Original coating weight: 1.77 ozlft2 (540 g/m2). Exposure site: Point Reyes, CA.
Kearny, NJ. 30-year condition of links (see Table 13): 100R. 30-year condition of links (see Table 13): 60R, 40wc.
FIG. 13. Specimen 33 - Hot·dip Galvanized Chain Link Fabric. FIG. 14. Specimen 33- Hot-dip Galvanized Chain Link Fabric.
Original coating weight: 2.81 ozrtt2 (857 gfm2). Exposure site: Kure Beach, NC Original coating weight: 2.81 oz1tt2 (857 g/m2). Exposure site: Manhattan, KS.
(800·ft site). 30·year condition of links (see Table 13}: 40R, 60wc. 30·year condition of links (see Table 13): 40G, 60Y.
FIG. 15. Specimen 33 - Hot·dip Galvanized Chain Link Fabric. FIG. 16. Specimen 33- Hot·dip Galvanized Chain Link Fabric.
Original coating weight: 2.81 oztft2 (857 gtm2). Exposure site: Newark-Kearny, Original coating weight: 2.81 oz!tt2 (857 gfm2). Exposure site: Point Reyes, CA.
NJ. 30-year condition of links (see Table 13): 100R. 30-year condition of links (see Table 13): SPPR, 95wc.
FIG. 18, Specimen 34 - Zinc Electroplated Chain Link Fabric. FIG. 19. Specimen 34- Zinc Electroplated Chain Llnk Fabric.
Origlnal coating weight: 1.53 ozlft2 (467 gtm2). Exposure site: Brazos River, TX. Original coating weight: 1.53 oz/ft2 (467 gtm2). Exposure site: Kure Beach,
30-year condition of links (see Table 13}: SOR, 20wc. NC (800·ft site). 30-year condition of links (see Table 13): 60R, 35wc, 5G.
FIG. 23. Specimen 34 - Zinc Electroplated Chain Link Fabric. Original coating
weight: 1.53 oz1tt2 (467 g/m2). Exposure site: State College, PA.
30-year condition of links (see Tabfe 13): 100G.
;:::...
!::'
~
~
m
.....
()
~~
.....
~
~
t§
(/)
:j
~
FIG. 24. Specimen 35 - Zinc EJectroplated Chain Link Fabric. FIG. 25. Specimen 35 - Zinc Electroplated Chain Link Fabric. ::j
Original coating weight: 2.23 oz1tt2 (680 g!m2). Exposure site: Brazos River, TX. Original coating weight: 2.23 oz!ft2 (680 gtm2). Exposure site: Kure Beach, NC 0
30-year condition of links (see Table 13): 15R, 8Swc. (800-ft site). 30-year condition of links (see Table 13): 30R, '60wc, 10G. <::
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FIG. 30. Specimen 36 - Hot-Dip Atuminized Chain Link Fabric. FIG. 31. Specimen 36 - Hot-Dip Aluminized Chain Link Fabric. ~
Original coating weight: 0.57 oZ'ft2 (174 gtm2). Exposure site: Brazos River, TX. Original coating weight: 0.57 ozJtt2 (174 gtm2). Exposure site: Kure Beach, NC ~
30-year condition ol links (see Table 13): 10R, 15wc, 75G. (60-ft site). 30-year condition of links (see Table 13)~ 30R, 20Y, 50G, trM.
FIG. 32. Specimen 36 - Hot-Dip Aluminized Chain Link Fabric. FIG. 33. Specimen 36 - Hot-Dip Aluminized Chain Link Fabric.
Original coating weight; 0.57 oz!tt2 (174 g/m2). Exposure site: Kure Beach, NC Original coating weight: 0.57 oz!tt2 (174 g/m2). Exposure site: Manhattan, KS.
(800-ft site). 30-year condition of links (see Table 13): 2R, 10wc, 78G, 10M. 30-year condition of links (see Table 13): 50M, SOG.
FIG. 34. Specimen 36 - Hot· Dip Alumlnized Chain Link Fabric. FIG. 35. Spe<:lmen 36- Hot-Dip A1umlnlzed Chain Link Fabric. Note: This ls
Original coating weight: 0.57 ozlft2 (174 gtm2}. Exposure site: Newark.f<eamy, NJ. same specimen as illustrated In Fig. 34, with black corros ion product removed
30-year condition of links (see Table 13) : 10PPR, 90BLK. on o ne straight wire segment to illustrate that aluminum coating Is still Intact.
FIG. 36. Specimen 36 - Hot-Dip Alumlnized Chain Link Fabric. FIG. 37. Specimen 36 - Hot·Dip Alumlnlz&d Chain Link Fabric.
Original coating weight: 0.57 ozJft2 (174 g/m2). Exposure site: Point Reyes, CA. Original coating weight: 0.57 ozJft2 (174 g/m2). Exposure site: State College, PA.
30-year condition of llnks (see Table 13): SOM, SOG. 30-year condition of links (see Table 13): 100G.
FIG. 38. Specimen 37 - Hot-Dip Aluminized Chain Link Fabric. AG. 39. Specimen 37 - Hot-Dip Aluminlzed Chain Link Fabric.
Original coating weight: 0.44 ozlft2 (134 gtm2). Exposure site: Brazos River, TX. Original coating weight: 0.44 oz/ft2 (134 gtm2). Exposure site: Kure Beach, NC
30-year co ndition of links (see Table 13): 15R, 75wc, 100. (80·ft site). 30-year condition of links (see Table 13): SSA, 25Y, 20G.
FIG. 40. Specimen 37 - Hot-Dip Aluminized Chain Link Fabric. FIG. 41. Specimen 37- Hot-Dip Aluminized Chain Link Fabric.
Original coating weight: 0.44 oz!tt2 (134 gtm2). Exposure site: Kure Beach, NC Original coating weight: 0.44 oz1tt2 (134 g/m2). Exposure site: Manhattan, KS.
(800-ft site}. 30-year condition of links (see Table 13): 1A, 20wc, 74G, SM. 30-year condition of links (see Table 13): 40M, 60st.
FIG. 42. Specimen 37 - Hot-Olp Alumlnlzed Chain link Fabric. FIG. 43. Specimen 37 - Hot-Dip Aluminlzed Chain Link Fabric. Note: This Is
Original coating weight: 0.44 oz1tt2 {134 gfm2). Exposure site~ Newark-Kearny, same specimen as Illustrated In Fig. 42, with black corrosion product removed
NJ. 30-year condition of links (see Table 13): 10PPR, 90blk. on one straight wire segment to illustrate that aluminum coating ls stlll intact.
FIG. 44. Specimen 37 - Hot·Dip Aluminized Chain Link Fabric. FIG. 45. Specimen 37 - Hot-Dip Aluminlzed Chain Link Fabric.
Orlgfnal coating weight: 0.44 ozJft2 {134 gtm2). Exposure site: Point Reyes, CA. Original coating weight: 0.44 ozJtt2 (134 gtm2). Exposure site: State College, PA. a..
30-year condition of links {see Table 13) ~ 1PPR, 99wc. 30-year condition of links {see Table 13): 15PPR, 15Y, 70G. ~
FIG. 46. Specimen 38 - Hot-Dip Aluminized Chain Link Fabric. FIG. 47. Specimen 38 - Hot· Dip Aluminized Chain Link Fabric.
Original coating weight: 0.54 oz1n2 (165 gtm2). Exposure site: Brazos River, TX. Original coating weight: 0.54 ozltt2 (165 g/m2). Exposure site: Kure Beach, NC
30-year condition of links (see Table 13): SR, 20wc, 75G. (80-ft site). 30-year condition of links {see Table 13): 50R, 25Y, 25G.
FIG. 48. Specimen 38 - Hot-Oip Aluminized Chain Link Fabric. FIG. 49. Specimen 38 - Hot-Dip Aluminized Chain link Fabric.
Original coating weight: 0.54 oz!ft2 (165 gfm2). Exposure site: Kure Beach, NC Original coating weight: 0.54 ozlft2 (165 g/m2). Exposure site: Manhattan, KS.
{800 ft site}. 30-year condition of links (see Table 13}: trR, trY, 40wc, SOG, 10M. 30-year condition of links (see Table 13): SOM, SOst.
FIG. 50. Specimen 38 - Hol· Dlp Alumlnized Chain Link Fabric. AG. 51. Specimen 38 - Hol-Dip Aluminlzed Chain Link Fabric. Note: This is
Original coaling weight: 0.54 ovtt2 (165 gtm2). Exposure site: Newark-Keamy, NJ. same specimen as Illustrated in Fig. 50, with black corrosion product removed
30-year condition of links (see Table 13): tOPPR, 90 blk. on one straight wire segment to illustrate that aluminum coating is still intact.
FIG. 52. Specimen 38 - Hol·Oip Aluminized Chain Link Fabric. FIG. 53. Specimen 38 - Hot-Oip Aluminized Chain Link Fabr ic.
Original coating weight: 0.54 oztft2 (165 gfm2). Exposure site: Point Reyes, CA. Original coating weight: 0.54 ozJft2 (165 glm2). Exposure site: State College, PA.
30-year condition of links {see Table 13): 5PPR, 95wc. 30-year condition of links (see Table 13): 15PPR, SY, 80G.
ISBN 0-~031-2064-8