CON CISE INORGANIC CHEMISTRY FOURTH EDITION ——JD. oe ww. 99! Tet ay > CHAPMAN & HALL Melbourne « MadrasUK (Chapman & Hall, 2-6 Boundary Row, London SE1 8HN usa (Chapman & Hall, 29 West 35th Street, New York NY10001 JAPAN ‘Chapman & Hall Japan, Thomson Publishing Japan, Hicakawacho [Nemoto Building, 7, 1-711 Hicakawa-cho, Chiyoda-ku, Tokyo 102 AUSTRALIA Chapman & Hall Australia, Thomas Nelson Austria, 102 Dodds Sts South Melbourne, Victoria 3205, INDIA Chapman & Hall Indi, R, Seshadri 32 Second Main Rovd, CITE Maras 00 035 eS First published 1964 Fourth edition 991 © 1966, 1965. 1977, 1991 J.D, Lee ‘Typeset in 10/12 Times by Best-set Typesetter Lid, Printed in Singapore by Fong & Sons Printers Pe, Ltd ISBN 0 $12 402904 ‘Apart fom any fur dealing forthe purposes of research or private study ‘or etiticism or review. as permitted under the UK Copytight Designs Patens Act. 1988, this plication may not be reproduced, stored. of {tansmited in any form or by any means. without the prior permission a \ritng ofthe publishers. or inthe ease of reprographic reproduction only in accordance with the terms ofthe licences lasued bythe Copyright Licensing Agency in the UK. orn accordance with the term of icences issued by the appropriate Reproduction Rights Organization ouside the UK. Enquiries concerning reproduction outside the termsstated here should be sent othe publishers atthe UK address printed on this page. ‘The publisher makes no representation, express or implied. with regard to the accuracy ofthe information contained in this book and cannot accept any egal responsibility or ability for any errors or omisions that ‘may be made. British Library Cataloguing in Publication Data LLee.3.D. (obin David) 1931 Concise inorganie chemistry, athe, Inorganic chemistry Lie 546 ISBN 0-412-40290-$ Library of Congress Cataloging in-Pubication Data Lee.J.D. Gohn David). 1931— ‘Concise iorganicchemistry/4.D, Lee. —sthed. Pom Rev ed. of: A new concise inorganic chemistry. Seed. 1977 Includes bibliographical references and index TSBN0—412~d0290—3 (pbk) |. Chemistry. Physical and theoretical, 2, Chemical bonds {.Lee.J.D. Gohn David), 1931~ New concise inorganic chemisty Uti Ob453.2.L45. 1991 So—de20 o1sKI ceContents Preface to the fourth edition Stunits Nomenclature in the period table PART ONE THEORETICAL CONCEPTS AND HYDROGEN Chapter 1 Atomic structure and the periodic table Theo Atomic spectra of hydrogen and the Bohr theory Refinements to the Bohr theory ‘The dual nature of electrons — particles or waves The Heisenberg uncertainty principle. ‘The Schrodinger wave equation} Radial and angular functions Pauli exclusion principle Build-up of the elements, Hund's rule Sequence of energy levels ¢ elements in roups in theneriodietable | Farther reading Problems Chapter 2 Introduction to bonding ‘Attainment ofa stable configuration Types of bonds ‘Transitions betiveen the main types of bonding Ionic bonds Covalent bonds Oxidation numbers Coordinate bonds Double and triple bonds Metallic bonds and metallic structures: Melting points Conductivity Solubility Speed of reactions xx xxiv RXV ul 12 15 a 21 4 2 27