Professional Documents
Culture Documents
Composites Part B: Sciencedirect
Composites Part B: Sciencedirect
Composites Part B
journal homepage: www.elsevier.com/locate/compositesb
A R T I C LE I N FO A B S T R A C T
Keywords: A novel architecture of graphene oxide wrapped copper spheres (Cu/GO) is proposed for fabricating high wear-
Metal-matrix composites (MMCs) resistant Cu-based composites. Tribological results indicate that GO shell layers present an exceptional
Wear strengthening efficiency surpassing conventional nanoparticle, fiber and nanosheet reinforcements for Cu-based
Surface analysis materials reported to date. The friction torque of the composites shows a load-insensitive behavior stabilized at
Powder processing
0.26–0.41 Nm. Such good tribological performance is ascribed to integrated effects including strong metal/GO
interfacial coupling, uniform distributed GO, and the GO-assisted tribofilm formed on ridges and asperities of
wear tracks. The fabrication strategy is convenient, low cost, easily scalable, and can be expanded to the pre-
paration of other metal/GO materials.
∗
Corresponding author.
E-mail address: hustwenlong@mail.hust.edu.cn (W. Lu).
https://doi.org/10.1016/j.compositesb.2018.08.125
Received 14 July 2018; Received in revised form 23 August 2018; Accepted 27 August 2018
Available online 28 August 2018
1359-8368/ © 2018 Elsevier Ltd. All rights reserved.
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 1. (a) Schematic illustration of fabrication of GO wrapped Cu spherical particles; (b) SEM image of GA Cu spherical particles; (c) SEM and TEM images of Cu/GO
composites showing good Cu/GO interface bonding; (d) The digital photograph of the consolidated Cu/GO composite.
Table 1 7 ± 6 μm (Fig. 1b) supplied by Metal Products Trade Co. Ltd. China,
Typical composition of GA Cu-based powders in this work. were used as initial particles for the encapsulation. The chemical
Element Cu Al Ni Fe Mn Impurity composition of the powder is shown in Table 1. In a typical preparation
process, the Cu/GO powders were obtained from GO wrapping mod-
Content (wt.%) Balance 9.5 4.2 4.0 1.2 < 0.5 ified-GA powders by the electrostatic adsorption method. Fig. 1c clearly
displayed that GA powders were well encapsulated inside thin GO na-
nosheets. After the hybridization process, a cylindrical graphite mold
2. Materials and methods loaded with Cu/GO powders was put into an spark plasma sintering
apparatus (LABOX-1575, SINTER LAND, Japan) and then heated up to
2.1. Synthesis of Cu/GO samples 800 °C at a rate of 100 °C/min and a pressure of 40 MPa for 10 min
under an argon gas flow. After the apparatus was completely cooled,
Fig. 1a schematically depicts the synthesis strategy of Cu/GO sam- the product was taken out and the Cu/GO powders were consolidated
ples. Spherical GA powders with an average particle diameter of
Fig. 2. (a) XRD patterns and (b) Raman spectra of blank Cu matrix and Cu/GO powders; (c and d) FESEM images of the cross-section of the consolidated Cu/GO
composite showing good interfacial bonding between the Cu particles and GO after the SPS consolidation process.
132
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 3. (a) FESEM image of the surface microstructure of the consolidated Cu/GO composite; (b–g) C, Al, Mn, Fe, Ni and Cu maps of areas in (a).
into a tablet with a diameter of 26 mm and a height of 4 mm (Fig. 1d). diffraction (XRD) on the XRD-7000 S X-ray diffractometer with Cu Kα
To study the influence of the GO shell layers on anti-friction and anti- radiation. Raman spectra were recorded using the inVia Raman mi-
wear performance of Cu materials, the same consolidation process was croscope (RENISHAW). The morphology and microstructure of the
carried out for blank GA powders. After the SPS process, the as-pre- products were carried out on the JSM-7600 F field emission scanning
pared specimens were ground to remove the surface layer to eliminate electron microscope (FESEM) and the JEOL JEM 2100 transmission
carbon atmosphere effects induced by the graphite mold, followed by electron microscope (TEM).
mechanical polishing with emery papers down to 2000 grit.
133
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 4. (a) Dynamic friction torques (T) of the Cu/GO composite and the blank Cu matrix as a function of fretting cycles under varied loads of 43, 86 and 106 N. The
inset shows the static mean value of T; (b) Typical wear volumes of Cu and Cu/GO samples after fretting tests; (c) 3D morphologies with the depth profile of wear
tracks of the Cu/GO composite demonstrating the slight wear at different loads; (d) A summary of the friction coefficient versus the strengthening efficiency of
various reinforcements for Cu matrix composites, including GO shell layers in this work, and conventional nanoparticle, fiber and nanosheet reinforcements, as well
as their hybrid structured reinforcements for Cu matrix composites. The GO shell layers in this work present a superior strengthening efficiency which exceeds other
reinforcements in Cu matrix composites reported so far.
134
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 5. Typical FESEM images of wear tracks on Cu/GO samples after fretting under contact loads of (a) 43 and (b) 106 N; (c) The high magnification FESEM image
with corresponding line scanning of elements for the ridge area indicating the C-element accumulation in ridges after the fretting wear process; (d–k) The high
magnification FESEM image with element maps for an asperity of wear tracks demonstrating the accumulation of the C element.
morphology of the as-prepared GO wrapped Cu even after the high- spectroscopy (EDS) maps of elements in the composite are shown in
temperature sintering process (Fig. 2c). The magnified FESEM images Fig. 3b–g. It is clearly seen from EDS results that the GO is uniformly
of the Cu/GO composite show good interfaces between the Cu particles distributed in the composite without aggregation.
and GO layers after the SPS consolidation process (Fig. 2d). Such well
interfaces would effectively hinder crack propagation and improve the 3.2. Tribological behaviors
wear resistance during fretting. The surface microstructure of con-
solidated Cu/GO composite is shown in Fig. 3a. Energy-dispersive X-ray Fretting wear tests were performed on surfaces of the consolidated
135
W. Zhai et al. Composites Part B 157 (2019) 131–139
136
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 7. XPS spectra of typical elements on the wear tracks of the Cu/GO composite.
tracks mainly existed in the form of C-C and C]O which could be fretting process, these small GO nanosheets could be easily transferred
oxygen-containing groups in GO, further confirms the structural in- and accumulated into the ridges and asperities existing on wear tracks
tegrity of GO during the friction process [48,49]. (Fig. 5c and d). Consequently, the friction mainly occurs between the
Fig. 8 illustrates the schematic diagram of the anti-friction me- steel counterface and the GO nanosheet film, preventing the direct
chanism of GO shell layers before and after the fretting process. During contact between the Cu matrix and steel counterface. Since the van der
the fretting wear, slight plastic deformation was observed on the sur- waals force of GO nanosheets is relatively weak, which should play a
face of the Cu/GO composite (Fig. 5a and b), leading to the formation of significant role in reducing the friction between the contact surfaces.
wear-induced ridges and quasi-flat graphene-like nanosheets containing Thus, these GO nanosheets could act as anti-friction and anti-wear films
different carbon rings between friction interfaces. With the cyclic to reduce the wear volume and to promote the stable friction torque
137
W. Zhai et al. Composites Part B 157 (2019) 131–139
Fig. 8. Schematic diagram of the anti-friction mechanism of GO nanosheet films before and after the fretting process.
138
W. Zhai et al. Composites Part B 157 (2019) 131–139
139